Hydrothermal Synthesis of Copper (II) Oxide Microparticle

2020 ◽  
Vol 861 ◽  
pp. 337-343
Author(s):  
Pusit Pookmanee ◽  
Piyarat Somsri ◽  
Sukon Phanichphant ◽  
Chanchana Thanachayanont
Keyword(s):  
Hydrothermal Method ◽  
Single Phase ◽  
Functional Group ◽  
Ph Value ◽  
Fine Powder ◽  
Chemical Compositions ◽  
Mixed Solution ◽  
X Ray Diffraction ◽  
X Ray ◽  
Nitrate Trihydrate

CuO microparticle was syntheszied by hydrothermal method. The starting precursors were used as copper (II) nitrate trihydrate (Cu (NO3)2·3H2O), nitric acid (HNO3) and sodium hydroxide (NaOH). The final pH value of the mixed solution was used 2M NaOH to adjust the pH was 8 and treated at 100-200 oC for 4-6 h in a hydrothermal vessel. The black fine powder was obtained after dried at 100 oC for 5 h. The phase and structure of CuO microparticle were characterized by X-ray diffraction (XRD). A single phase monoclinic structure synthezied by hydrothermal method at 200 oC for 4 and 6 h was obtained without calcination steps. The morphology CuO microparticle was investigated by scanning electron microscopy (SEM). It was likely grain in shape and the particle size in range of 2.94-4.06 μm. The element composition of CuO microparticle was indicated by energy dispersive X-ray spectrometry (EDX). The chemical compositions showed the characteristic X-ray energy of copper (Kα = 0.98 keV) and oxygen (Kα = 0.53 keV), respectively. The functional group of CuO microparticle was indentified by Fourier transform spectrophotometry (FTIR). The wavenumber at 690, 514 and 437 cm-1 was corresponded to vibration of Cu-O stretching.

Copper (II) Oxide Powder Prepared by Low Temperature Hydrothermal Method

2020 ◽  
Vol 861 ◽  
pp. 270-276
Author(s):  
Pusit Pookmanee ◽  
Maneerat Mueangjai ◽  
Sukon Phanichphant ◽  
Chanchana Thanachayanont
Keyword(s):  
Particle Size ◽  
Low Temperature ◽  
Hydrothermal Method ◽  
Ph Value ◽  
Average Particle Size ◽  
Fine Powder ◽  
Chemical Compositions ◽  
Average Particle ◽  
Mixed Solution ◽  
X Ray

In this research, CuO powder was prepared by low temperature hydrothermal method. Copper (II) nitrate trihydrate (Cu (NO3)2.3H2O) and sodium hydroxide (NaOH) were used as the starting precursors. The final pH value of the mixed solution was adjusted to 9 by 4M NaOH and treated at 100 oC and 200 oC for 4 and 6 h. The black fine powder was obtained after dried at 80 oC for 4 h. The phase was characterized by X-ray diffraction (XRD). A single phase of monoclinic structure of CuO powder prepared by low temperature hydrothermal method at 200 oC for 4 and 6 h was obtained without calcination step. The morphology and particle size were investigated by scanning electron microscopy (SEM). The morphology was flower-like in shape and the average particle size in range of 0.3×0.7 μm. The element composition was indicated by energy dispersive X-ray spectrometry (EDX). The chemical compositions showed the characteristic X-ray energy of copper (Kα = 0.95 keV) and oxygen (Kα = 0.53 keV). The functional group was indentified by fourier transform spectrophotometry (FTIR). The wavenumber at 433-531 cm-1 was corresponded to vibration of Cu-O stretching.

Titanium Dioxide Doped with Nitrogen Nanopowder Prepared by Hydrothermal Method

2018 ◽  
Vol 283 ◽  
pp. 167-172
Author(s):  
Pusit Pookmanee ◽  
Khemmika Promwanna ◽  
Kanjanaporn Narong ◽  
Chanchana Thanachayanont ◽  
Chabaiporn Junin ◽  
...  
Keyword(s):  
Titanium Dioxide ◽  
Hydrothermal Method ◽  
Single Phase ◽  
Functional Group ◽  
Hydrothermal Reaction ◽  
Titanium Isopropoxide ◽  
Infrared Spectrophotometry ◽  
X Ray Diffraction ◽  
X Ray ◽  
Nitrogen Doped Titanium Dioxide

Nitrogen-doped titanium dioxide (N-doped TiO2) nanopowder was successfully prepared by the hydrothermal method. Titanium isopropoxide and urea were used as the starting precursors. The hydrothermal reaction was controlled at 200 °C for 2, 4 and 6 h. The white powder was obtained and dried for 24h. The crystal structure was identified by X-ray diffraction (XRD). A single phase of anatase structure was obtained without calcination steps. The morphology was investigated by field emission scanning electron microscopy (FESEM). The particles were irregular in shape and highly agglomerated. The chemical composition was determined by energy dispersive X-ray spectrometry (EDXS). The characteristic X-ray energy of titanium (Kα = 4.51 keV and Kβ = 4.93 keV), oxygen (Kα = 0.52 keV) and nitrogen (Kα = 0.39 keV) were observed. The functional group was identified by Fourier transform infrared spectrophotometry (FTIR). The wavenumbers in the range 668 to 1389 cm-1 corresponded to vibrations of Ti–O–Ti bond. The wavenumber in the range of 1442 to 1500 cm-1 could be attributed to the nitrogen species in the TiO2 network.

Synthesis of Copper Oxide Nanopowder by Microwave Method

2018 ◽  
Vol 283 ◽  
pp. 154-159
Author(s):  
Pusit Pookmanee ◽  
Pimpaka Sangthep ◽  
Jiratchaya Tafun ◽  
Viruntachar Kruefu ◽  
Suchanya Kojinok ◽  
...  
Keyword(s):  
Fourier Transform ◽  
Copper Oxide ◽  
Single Phase ◽  
Functional Group ◽  
Copper Acetate ◽  
Chemical Compositions ◽  
Microwave Method ◽  
X Ray ◽  
Infrared Spectrometer ◽  
Scanning Electron

Copper oxide nanopowder was successfully synthesized by microwave method. Copper acetate and sodium hydroxide were used as the starting precursors. The microwave power was set to 800 Watt for 2-6 min and fine black nanopowder was obtained. The nanopowder was milled and dried at 80 °C for 12 h. The structure was identified by X-ray diffractometer (XRD). A monoclinic single phase of CuO nanopowder structure was obtained without calcination steps. The morphology was investigated by scanning electron microscope (FESEM). The particle was irregular in shape and agglomerated. The chemical composition was determined by energy dispersive X-ray spectrometer (EDXS). The chemical compositions showed the characteristic X-ray energy of copper (Kα=8.048 keV) and oxygen (Kα=0.525 keV), respectively. The functional group was investigated by fourier transform infrared spectrometer (FTIR). The functional groups of the vibration Cu-O bending showed the wavenumber at 491-615 cm-1.

Preparation of Heterojunction Semiconductor SnS2/SnO2 with Enhanced Photocatalytic Properties

2013 ◽  
Vol 316-317 ◽  
pp. 1059-1062 ◽  
Author(s):  
Ping Chen ◽  
Ming Sheng Qin ◽  
Fu Qiang Huang
Keyword(s):  
Photocatalytic Activity ◽  
Single Phase ◽  
Near Infrared ◽  
Photocatalytic Performance ◽  
Chemical Compositions ◽  
X Ray Diffraction ◽  
Simple Method ◽  
X Ray ◽  
Structure Morphology ◽  
Nir Absorption

The Formation of Heterojunction Structure between Two Semiconductors Was Considered as an Effective Method to Enhance the Photocatalytic Activity. here, we Reported a Simple Method to Prepare SnS2/SnO2Heterojunction Photocatalysts by Annealing SnS2in Air. the Structure, Morphology, Chemical Compositions and Optical Properties of the Obtained Materials Were Characterized by the X-ray Diffraction (XRD), Scanning Electron Microscope (SEM), Energy-dispersive X-ray Spectroscopy (EDX) and Ultraviolet-visible-near Infrared (UV-Vis-NIR) Absorption Spectra. the Photocatalytic Investigations Showed the Composites Have Higher Photocatalytic Activity than the Single-phase SnS2. the SnS2Powder which Annealed at 400 °C for 60 Min Showed the Highest Photocatalytic Performance.

Characterization of Diatomite, Leonardite and Pumice

2016 ◽  
Vol 872 ◽  
pp. 211-215 ◽  
Author(s):  
Pusit Pookmanee ◽  
Atit Wannawek ◽  
Sakchai Satienperakul ◽  
Ratchadapon Putharod ◽  
Nattapol Laorodphan ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Scanning Electron Microscopy ◽  
Functional Group ◽  
Chemical Compositions ◽  
Carbonyl Groups ◽  
X Ray Diffraction ◽  
X Ray ◽  
Properties Of Materials ◽  
Scanning Electron

This research studies compositions of diatomite, leonardite and pumice for utilization appropriate to the properties of materials. Chemical compositions of these materials were characterized by X–ray fluorescence spectrometry (XRF) and energy dispersive X–ray spectrometry (EDXS). The silica was major component of these materials. The morphology was investigated by scanning electron microscopy (SEM). Diatomite was cylindrical in shape, leonardite was sheet or flake in shape and pumicewas prismatic in shape. The structure was studied by X–ray diffraction (XRD). It was found that the mineral composition of diatomite, leonardite and pumice showed cristobalite low, quartz and anorthite, respectively. The functional groups were identified by Fourier transform infraredspectrometry (FTIR). The functional group of siloxane was obtained and dominated vibration in these materials. And the vibration of carboxylic, alcoholic and carbonyl groups were obtained in leonardite.

Synthesis, Characterization and its Photocatalytic of Copper Oxide (CuO) Powder

2019 ◽  
Vol 962 ◽  
pp. 70-76 ◽  
Author(s):  
Pusit Pookmanee ◽  
Pimpaka Sangthep ◽  
Jiratchaya Tafun ◽  
Viruntachar Kruefu ◽  
Suchanya Kojinok ◽  
...  
Keyword(s):  
Methylene Blue ◽  
Copper Oxide ◽  
Single Phase ◽  
Functional Group ◽  
Copper Acetate ◽  
Chemical Compositions ◽  
Microwave Method ◽  
X Ray ◽  
Infrared Spectrometer ◽  
Scanning Electron

In this research, copper oxide (CuO) powder was successfully synthesized by microwave method. Copper acetate and sodium hydroxide were used as the starting precursors. The microwave power was annealed at 600-800 Watt for 6 min. The fine black powder was obtained, milled and dried at 80 °C for 12 h. The structure was identified by X-ray diffractometer (XRD). A monoclinic single phase was obtained without calcination steps. The morphology was investigated by field emission scanning electron microscope (FESEM). The particle was irregular in shape and agglomerated. The chemical composition was determined by energy dispersive X-ray spectrometer (EDXS). The chemical compositions showed the characteristic X-ray energy of copper (Cu, Lα = 0.929 keV) and oxygen (O, Kα = 0.525 keV). The functional group was investigated by fourier transform infrared spectrometer (FTIR). The functional groups of the vibration Cu-O bending showed the wavenumber at 514-615 cm-1. The degradation of methylene blue (MB) over CuO powder was studied by ultraviolet-visible spectrophotometer (UV-Vis). The highest percentage of MB degradation for CuO powder annealed at 800 Watt for 6 min was about 33.72.

Novel Synthesis of Plate-like LiFePO4 by Hydrothermal Method

2016 ◽  
Vol 19 (1) ◽  
pp. 033-036 ◽  
Author(s):  
Yi-Jie Gu ◽  
Chang-Jiao Li ◽  
Long Cheng ◽  
Peng-Gong Lv ◽  
Fu-Jie Fu ◽  
...  
Keyword(s):  
Hydrothermal Method ◽  
Single Phase ◽  
Lithium Iron Phosphate ◽  
Ph Value ◽  
Synthesis Method ◽  
Particle Morphology ◽  
Iron Phosphate ◽  
X Ray Diffraction ◽  
Ferrous Ions ◽  
Iron Compounds

Lithium iron phosphate (LiFePO4) was prepared by hydrothermal synthesis method using FeSO4·7H2O and LiH2PO4 as resource of Li and Fe. The ratio of Li: Fe was maintained 1:1. The results suggested that pH value played a crucial role in the synthesis of LiFePO4, especially for the generation of impurities. We found that adding citric acid to the precursor was an effective way for chelating ferrous ions, thereby preventing the undesirable iron compounds during hydrothermal treatment. The particle morphology and the crystal orientation of the prepared LiFePO4 particles were investigated by the XRD and SEM results. The X-ray diffraction pattern of the samples indicated that single-phase LiFePO4 were successfully synthesized by hydrothermal method with a stoichiometric 1:1 ratio of Li :Fe.

Methylene Blue Degradation over Photocatalyst Bismuth Vanadate Powder Synthesized by the Hydrothermal Method

2010 ◽  
Vol 93-94 ◽  
pp. 177-180 ◽  
Author(s):  
Pusit Pookmanee ◽  
Kanlaya Pingmuang ◽  
Wiyong Kangwansupamonkon ◽  
Sukon Phanichphant
Keyword(s):  
Methylene Blue ◽  
Hydrothermal Method ◽  
Ammonium Hydroxide ◽  
Bismuth Vanadate ◽  
Mixed Solution ◽  
X Ray Diffraction ◽  
Methylene Blue Degradation ◽  
X Ray ◽  
Ammonium Vanadate ◽  
Calcination Step

Bismuth vanadate powder was synthesized by the hydrothermal method with bismuth nitrate and ammonium vanadate as the starting precursors with the mole ratio of bismuth and vanadium of 1:1. The mixed solution was adjusted with ammonium hydroxide until the pH of final solution was 7 and hydrothermally treated at 100 °C for 2-6h. The phase was studied by X-ray diffraction (XRD). Monoclinic structure was obtained after hydrothermal treated at 100 °C for 6h without calcination step. The morphology was investigated by scanning electron microscopy (SEM). The particle was needle-like in shape and highly agglomerate. The degradation of methylene blue over photocatalyst bismuth vanadate powder was examined by ultraviolet spectroscopy (UV). Bismuth vanadate powder synthesized by the hydrothermal method at 100 °C for 6h showed the highest photocatalytic activity.

Synthesis of Single-Phase Nanocrystalline YIG by Co-Precipitation: The Influence of pH Value of Precursor Solution and Calcinating

2011 ◽  
Vol 311-313 ◽  
pp. 1294-1299 ◽  
Author(s):  
Liang Zheng ◽  
Hui Zheng ◽  
Jiang Xia Deng ◽  
Zhi Hua Ying ◽  
Jun Wu ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Grain Size ◽  
Single Phase ◽  
Ph Value ◽  
Precursor Solution ◽  
X Ray Diffraction ◽  
X Ray ◽  
Co Precipitation ◽  
Influence Of Ph ◽  
Scanning Electron

Single-phase nanocrystalline YIG powders have been successfully synthesized through chemical co-precipitation methods. The influence of pH value of the precursor solution and calcinating conditions (temperatures ranging from 700 to 900°C and times ranging from 0.5 to 12 hours) on the purity and grain size of the single-phase nanocrystalline YIG powders were investigated by X-ray diffraction (XRD) and scanning electron microscopy (SEM) technique. The results show that a pure single-phase YIG powder was obtained as the pH value of precursor solution above 10 and the YIG grain grows bigger as calcinating temperature and time increased. Finally, the optimal condition to form single-phase nanocrystalline YIG with the smallest grain size is calcinating at 750°C for 7 hours.

Titanium Dioxide Powder Prepared by a Low Temperature Hydrothermal Method

2010 ◽  
Vol 93-94 ◽  
pp. 627-630 ◽  
Author(s):  
Pusit Pookmanee ◽  
Tarika Kuntatun ◽  
Wiyong Kangwansupamonkon ◽  
Sukon Phanichphant
Keyword(s):  
Titanium Dioxide ◽  
Low Temperature ◽  
Hydrothermal Method ◽  
Chemical Compositions ◽  
Mixed Solution ◽  
Rutile Structure ◽  
X Ray ◽  
Titanium Dioxide Powder ◽  
Calcination Step ◽  
Dioxide Powder

Titanium dioxide powder was prepared by a low temperature hydrothermal method. Titanium isopropoxide, ammonium hydroxide and nitric acid were used as the starting precursors. The mixed solution with final pH of 1 was treated in the autoclave hydrothermal at 80-100 °C for 2-4h. The phase of titanium dioxide powder was studied by X-ray diffraction (XRD). Anatase and rutile structure were obtained at 80 °C for 2-4h without calcination step. Anatase structure was obtained at 100 °C for 2-4h without calcination step. The morphology of titanium dioxide powder was investigated by scanning electron microscopy (SEM). The particle was irregular in shape and agglomerated with the range particle size of 0.5-0.8 µm. The chemical composition of titanium dioxide powder was examined by energy dispersive spectroscopy (EDS).The element chemical compositions show the characteristic X-ray energy level as follows: titanium Kα = 4.51 keV and Kβ = 4.93 keV and oxygen Kα = 0.52 keV, respectively.

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