Effect of Eggshell Powder Using for an Extender on the Mechanical and Thermal Behaviors of Polylactic Acid Composites

2021 ◽  
Vol 904 ◽  
pp. 207-212
Author(s):  
Atiwat Wiriya-Amornchai ◽  
Prathumrat Nu-Yang ◽  
Phawarisa Raksawong ◽  
Phonlakrit Salakkham ◽  
Supakrid Katib ◽  
...  
Keyword(s):  
Polylactic Acid ◽  
Melt Blending ◽  
Thermal Behaviors ◽  
X Ray ◽  
Degradation Temperature ◽  
Blending Method ◽  
Injection Molded ◽  
Internal Mixer ◽  
The Impact ◽  
Accelerate Degradation

In this paper, the composites between polylactic acid (PLA) and eggshell powder (ESP) from the chicken shell were prepared by melt blending method in the internal mixer and then injection molded to produce the bio-composite specimen. The effect of the ESP concentration in the composites was investigated on the mechanical and thermal behaviors. The results indicated that the tensile strength and elongation decreased with increased ESP loading. Furthermore, the impact strength was not altered for PLA filled system with 10-30% of ESP. At the 10%wt of ESP in the PLA-composites was not significantly different of the onset (Tonset) and maximum degradation temperature (Td) from neat PLA but at higher ESP loading, Tonset and Td tend to decrease, therefore ESP could be able to accelerate degradation in the composites. The cold crystallization (Tcc) showed decreasing when the ESP was incorporate about 10-30 %wt. Otherwise, the incorporation of ESP affected on the declination of crystallinity in the PLA composites. The morphology, size and elements were examined using a scanning electron microscope (SEM) coupled with an energy dispersive X-ray system (EDX). It was indicated that agglomeration of ESP in the PLA matrix.

Effect Addition of Octadecylamine Modified Clay (ODA-MMT) to Polylactide/Polycaprolactone (PLA/PCL) Blend

2011 ◽  
Vol 364 ◽  
pp. 317-321 ◽  
Author(s):  
Siti Zulaiha Hairaldin ◽  
Wan Md Zin Wan Yunus ◽  
Nor Azowa Ibrahim
Keyword(s):  
Polymer Nanocomposite ◽  
Average Diameter ◽  
Sem Analysis ◽  
Clay Nanocomposites ◽  
Melt Blending ◽  
X Ray Diffraction ◽  
X Ray ◽  
Blending Method ◽  
Sem Micrograph ◽  
Internal Mixer

In this study, Octadecylamine Modified montmorillonites (ODAMMT) were used to prepare polylactide/polycaprolactone (PLA/PCL) clay nanocomposites. PLA and PCL were blend using an internal mixer by melt blending method. The other sample was blend with natrium monmorillonite (NaMMT) and Octadecylamine modified monmorillonite to produce PLA/PCL-NaMMT and PLA/PCL-ODAMMT. To characterize the polymer nanocomposite, X-ray diffraction (XRD), FTIR and SEM analysis were conducted. Comparison of morphology were made up between neat PLA/PCL, PLA/PCL with presence of of montmorillonite and octadecylamine modified monmorillonite respectively based on SEM micrograph. The number-average diameter was calculated for PLA/PCL, PLA/PCL-NaMMT, and PLA/PCL-ODAMMT.

scholarly journals Enantiomeric Polylactide Blends in the Presence of Montmorillonite Clay

2018 ◽  
Vol 34 (6) ◽  
pp. 2716-2720
Author(s):  
Onanong Cheerarot ◽  
Yodthong Baimark
Keyword(s):  
Wide Angle ◽  
Melt Blending ◽  
X Ray Diffraction ◽  
Scanning Calorimetry ◽  
X Ray ◽  
Transmission Electron ◽  
Blending Method ◽  
Stereocomplex Formation ◽  
Internal Mixer ◽  
Nanocomposite Structures

The stereocomplex polylactides (scPLAs) of the asymmetric poly(L-lactide)(PLLA)/poly(D-lactide) (PDLA) ratios from 80:20 to 60:40 were prepared via the simple melt blending method using an internal mixer at 200°C. An organo-modified clay, Cloisite® 30B, was used for nanocomposite preparation. The formation of the stereocomplex and nanocomposite structures were confirmed by differential scanning calorimetry (DSC), wide-angle X-ray diffraction (WAXD) and transmission electron microscopy (TEM). An increase in the PDLA content could enhance the stereocomplex formation. The presence of Cloisite®30B decreased the melting temperature and crystallinity of the blends. This was due to the thinner crystalline size generated and/or more disordered crystals.

Effect of magnesium oxysulfate (MOS) morphology on the crystallization, mechanical, and rheological properties of polypropylene/MOS composites

2018 ◽  
Vol 32 (5) ◽  
pp. 710-726 ◽  
Author(s):  
Li Dang ◽  
Xueying Nai ◽  
Xin Liu ◽  
Zhihui Lv ◽  
Wu Li
Keyword(s):  
Rheological Properties ◽  
Polarized Light ◽  
Mechanical Tests ◽  
Melt Blending ◽  
X Ray Diffraction ◽  
Small Amplitude Oscillatory Shear ◽  
Blending Method ◽  
Magnesium Oxysulfate ◽  
Significant Yield ◽  
The Impact

Polypropylene (PP) composites containing magnesium oxysulfate particle (MOSp), magnesium oxysulfate whisker (MOSw), or magnesium oxysulfate sector (MOSs) were prepared via melt blending method. Scanning electron microscopy results showed that three magnesium oxysulfate (MOS) fillers all dispersed homogeneously in PP matrix and displayed vague and fuzzy interfaces. Wide-angle X-ray diffraction (WXRD) patterns showed that MOSp induced the most amount of β-PP, which was supported by polarized light microscopy (PLM) photographs. Moreover, PLM photographs also showed that the presence of MOSp, MOSw, or MOSw decreased the PP spherulites, especially for MOSp. As such, mechanical tests showed that incorporation of MOSp into PP matrix greatly improved the impact strength and least lowered the nominal strain at break. The yield strength and Young’s modulus of composites were greatly enhanced with MOSw. Two possible reasons for this phenomenon are rigidity of MOSw and microstructure of composites. Rheological properties were measured via small amplitude oscillatory shear. The results showed that PP melts containing MOSw exhibited significant yield stress and “shear-thinning” behaviors, which indicated the formation of MOSw network and the transition from “liquid-like” PP matrix to “solid-like” composites. The rheological results greatly proved the enhancement in tensile properties of MOSw-incorporated composites.

Preparation and Property Study of PMMA/ASA Alloy

2011 ◽  
Vol 130-134 ◽  
pp. 2383-2387
Author(s):  
Guo Dong Tang ◽  
Si Chen ◽  
Yan Qin Shi ◽  
Xu Wang
Keyword(s):  
Flow Rate ◽  
Melt Blending ◽  
Dsc Analysis ◽  
Melt Flow ◽  
Scanning Calorimetry ◽  
Melt Flow Rate ◽  
Interface Phase ◽  
Blending Method ◽  
Method Effects ◽  
The Impact

Polymethyl methacrylate (PMMA)/ acrylonitrile-styrene-acrylate terpolymer (ASA) alloy was prepared via melt blending method. Effects of ASA melt flow rate and PMMA/ASA ratio on mechanical property of the alloy were studied. It showed that when the high melt flow rate ASA was used, alloy’s tensile strength and flexural strength were little different from using low melt flow rate ASA, while the impact strength was significantly higher than the latter. Differential scanning calorimetry (DSC) analysis showed that a glass transition (Tg) platform emerged in low melt flow rate ASA at 48.5°C, which represented the Tg of the interface phase formed between SAN grafted acrylate rubber particles and SAN matrix. Scanning electron microscope (SEM) experiment further showed that when low melt flow rate ASA was used, alloy’s cross section was smooth which showed the characteristics of brittle fracture.

Compatibilized PP/EPDM-Kenaf Fibre Composite Using Melt Blending Method

2011 ◽  
Vol 264-265 ◽  
pp. 743-747 ◽  
Author(s):  
Hazleen Anuar ◽  
N.A. Hassan ◽  
F. Mohd Fauzey
Keyword(s):  
Fibre Composite ◽  
Thermoplastic Elastomer ◽  
Hibiscus Cannabinus ◽  
Melt Blending ◽  
Scanning Electron Micrograph ◽  
Kenaf Fiber ◽  
Fiber Loading ◽  
Kenaf Fibre ◽  
Blending Method ◽  
Internal Mixer

Thermoplastic Elastomer (TPE) composite reinforced with Hibiscus cannabinus, L fiber (kenaf fiber, KF) was prepared via melt blending method using internal mixer at temperature 180°C, screw rotational speed at 40rpm for 10 min. TPE matrix is a blend of polypropylene (PP) and ethylene-propylene-diene monomer (EPDM) at a ratio of 70:30. The optimum fiber loading were investigated from 0% to 20% by volume. The effect of coupling agent maleic anhydride polypropylene (MAPP) on the TPE composite has been investigated. The result shown that, with increasing the kenaf fiber content gradually increased the tensile strength and flexural strength for both treated and untreated PP/EPDM-KF composite. However, at 20% of kenaf fiber loading, it showed decreasing in impact strength due to brittleness of the samples. From the scanning electron micrograph (SEM) it has shown that the composite, with compatibilizer promotes better interaction between TPE and kenaf fiber.

scholarly journals A review on graft compatibilizer for thermoplastic elastomer blend

2021 ◽  
Vol 2080 (1) ◽  
pp. 012003
Author(s):  
K.K. Nitiyah ◽  
Luqman Musa ◽  
M.S.M. Rasidi ◽  
Shayfull Zamree Abd Rahim ◽  
Rozyanty Rahman ◽  
...  
Keyword(s):  
Lactic Acid ◽  
Natural Rubber ◽  
Thermoplastic Elastomer ◽  
Synthetic Polymers ◽  
The Other ◽  
Poly Lactic Acid ◽  
Melt Blending ◽  
Internal Mixer ◽  
The Impact ◽  
Elastomer Blend

Abstract A biodegradable thermoplastic elastomer (TPE) blend is developed by blending poly (lactic acid) (PLA) and natural rubber (NR) or epoxidized natural rubber (ENR) and it is a sustainable substitution in recent years for synthetic polymers. PLA is high in mechanical strength and compostable, but it is highly stiff and brittle. The incorporation of NR or ENR to PLA increases the impact strength and toughness of PLA. However, the disparity in polarity between PLA and elastomer phase like NR and ENR results in TPE blend being incompatible. Hence, compatibilization is essential to improve its polarity and develop interactions. Compatibilizer that composed of two different polymer is known is graft compatibilizer with the aid of grafting agent. The graft compatibilizers are divided into two categories. The first type is made up of one polymer and grafting agent and, the other one is composed of two polymer groups and grafting agent. These two types of graft compatibilizer can be prepared via two different method such as direct melt blending and solution. Apart from this, the TPE blend is produced via the melt blending technique with mixing machines such as internal mixer and extruder. This article has reviewed the preparation of the graft compatibilizer and blending technique of TPE. Based on the findings, the graft compatibilizers has a significant role in improving miscibility and compatibility across blend composed of different phase.

Thermal Analysis of Polylactic Acid/Liquid Natural Rubber Reinforced with Multi-Walled Carbon Nanotubes

2016 ◽  
Vol 1133 ◽  
pp. 481-485 ◽  
Author(s):  
Adilah Mat Ali ◽  
Sahrim H. Ahmad
Keyword(s):  
Carbon Nanotubes ◽  
Thermal Properties ◽  
Natural Rubber ◽  
Polylactic Acid ◽  
Melt Blending ◽  
Blending Method ◽  
Liquid Natural Rubber ◽  
Multi Walled Carbon Nanotubes ◽  
Walled Carbon Nanotubes ◽  
Thermal Stability Of

This article studies the thermal properties of multi-walled carbon nanotubes (MWCNT) reinforced polylactic acid (PLA)/liquid natural rubber (LNR) blends which prepared via melt blending method. Various percentages (0.5, 1.5, 2.5, 3.5 and 4 wt%) of MWCNT were added into PLA/LNR blend. TGA shows that the addition of MWCNT into PLA/LNR blends helps to improve thermal stability of the PLA/LNR/MWCNT nanocomposites. DSC shows that the glass transition temperature increased when 0.5%, 1.5%, 2.5% and 3.5% of MWCNT was added to the PLA/LNR blend. The cold crystallization and melting temperature were reduced when MWCNT was added in the PLA/LNR blend systems. The SEM micrographs confirm the effect of good dispersion of 3.5wt% of MWCNT in PLA/LNR blend helps to promote well combined MWCNT-matrix networks and generate the synergistic effect of the system which is improved the thermal properties significantly.

scholarly journals Polyethylene glycol grafted with carboxylated graphene oxide as a novel interface modifier for polylactic acid/graphene nanocomposites

2020 ◽  
Vol 7 (7) ◽  
pp. 192154
Author(s):  
Mingjun Niu ◽  
Hao Wang ◽  
Jing Li ◽  
Hongyan Chen ◽  
Lin Li ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Graphene Oxide ◽  
Polyethylene Glycol ◽  
Polylactic Acid ◽  
Melt Blending ◽  
Elongation At Break ◽  
Graphene Nanocomposites ◽  
Practical Strategy ◽  
Blending Method ◽  
Synthesis Procedure

Strength and toughness are both of great importance for the application of polylactic acid (PLA). Unfortunately, these two properties are often contradictory. In this work, an effective and practical strategy is proposed by using carboxylated graphene oxide (GC) grafted with polyethylene glycol (PEG), i.e. GC-g-PEG. The synthesis procedure of GC-g-PEG is firstly optimized. Then, a series of PLA nanocomposites were prepared by the melt blending method via masterbatch. In comparison to that achieved over pure PLA, these nanocomposites are of higher crystallinity, thermal stability and mechanical strength. This is mainly attributed to well-tailored interface and good dispersion. Especially, while retaining the tensile strength of the original PLA, the elongation at break increases by seven times by adding 0.3 wt% GC-g-PEG.

scholarly journals Effects of Pulp Fiber and Epoxidized Tung Oil Content on the Properties of Biocomposites Based on Polylactic Acid

2020 ◽  
Vol 4 (2) ◽  
pp. 56 ◽  
Author(s):  
Van Khoi Nguyen ◽  
Thanh Tung Nguyen ◽  
Thu Ha Pham Thi ◽  
Thu Trang Pham
Keyword(s):  
Mechanical Properties ◽  
Polylactic Acid ◽  
Fiber Composites ◽  
Pulp Fiber ◽  
Fiber Reinforced ◽  
Pulp Fibers ◽  
Plant Fibers ◽  
Tung Oil ◽  
Degradation Temperature ◽  
Internal Mixer

Recently, various environmental-friendly materials have been investigated and developed, especially composites of polylactic acid (PLA) and plant fibers. This paper investigates the effects of pulp fiber (PF) and epoxidized Tung oil (ETO) content on the properties of biocomposites, based on polylactic acid. The bleached pulp fiber reinforced PLA (PLA/PF) composites with 10–50 wt% fiber contents and 0–15% epoxidized Tung oil contents (with a certain number of fiber) were prepared in an internal mixer (Plastograph® EC) at 150 °C. The mechanical properties of PLA/PF composites were improved significantly. The pulp fiber reinforced PLA composites, with the fiber content of 30 wt%, were found to have the highest mechanical properties. The tensile and flexural properties of PLA/Tung oil-soaked-pulp fiber composites were higher than those of PLA/Tung oil unsoaked pulp fiber composites. In addition, the degradation temperature of PLA-based composites decreased after adding more pulp fiber. The pulp fibers were well-dispersed in the PLA matrix with the content up to 30 wt%. The interaction between pulp fiber and PLA matrix improved by the addition of epoxidized Tung oil. Epoxidized Tung oil also improved tensile and flexural strength of composite materials when it was added with a number of below 10% of fiber.

Plasticizer effect on melt blending of polylactide stereocomplex

e-Polymers ◽  
2017 ◽  
Vol 17 (5) ◽  
pp. 409-416 ◽  
Author(s):  
Yottha Srithep ◽  
Dutchanee Pholharn
Keyword(s):  
Thermal Stability ◽  
Differential Scanning Calorimetry ◽  
Crystallization Rate ◽  
Wide Angle ◽  
Melt Blending ◽  
X Ray Diffraction ◽  
Scanning Calorimetry ◽  
X Ray ◽  
Neat Plla ◽  
Internal Mixer

AbstractPoly(l-lactide) (PLLA)/poly(d-lactide) (50/50) with plasticizer contents ranging from 2% to 16% w/w were prepared by melt blending using an internal mixer. Wide-angle X-ray diffraction, Fourier transform infrared spectroscopy and differential scanning calorimetry results confirmed that complete stereocomplex polylactide crystallites without any homocrystallites were produced. Compared to neat PLLA, the melting temperature of the stereocomplex polylactide and its plasticized samples was approximately 55°C higher. Higher plasticizer contents decreased glass transition temperature of the stereocomplex, which implied higher flexibility and enhanced the crystallization rate. However, the plasticizer in the stereocomplex reduced the thermal stability.

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