Application of Octadecylamine-Based Adsorbent on Carbon Dioxide Capture

2020 ◽  
Vol 1010 ◽  
pp. 367-372
Author(s):  
Maratun Najiha Abu Tahari ◽  
Azizul Hakim Lahuri ◽  
Zaitun Ghazali ◽  
Salma Samidin ◽  
Siti Sarahah Sulhadi ◽  
...  
Keyword(s):  
Carbon Dioxide Capture ◽  
Xrd Analysis ◽  
Fatty Amine ◽  
Wet Impregnation ◽  
Impregnation Process ◽  
Pore Blockage ◽  
Solid Adsorbents ◽  
Desorption Isotherms ◽  
Amine Compounds ◽  
Adsorption Desorption

Porous surface of silica gel (SG) have been modified with alkyl fatty amine compounds (octadecylamine, ODA) via wet impregnation process. The ODA-based adsorbents were physically characterized by XRD. The presence of crystalline peaks on ODA/SG diffractograms were ascertained the well-dispersion of ODA on the SG surface. XRD analysis displayed the increasing intensity of crystalline ODA with higher percent amine loaded and shifting of the several crystalline peaks of ODA verified the interaction of SG600-ODA. Capacity of CO2 capture by prepared solid adsorbents were evaluated using CO2 adsorption-desorption isotherms. This study shows that increasing percentage of ODA were improved the amount of CO2 uptake by following this trend: 35ODA/SG > 25ODA/SG > 15ODA/SG > SG > 5ODA/SG. However, promotion of 5 wt.% ODA unabled to enhance the capacity of CO2 captured due to pore blockage and reduction in SG pore surface, thus hindered the physisorption between CO2 and SG.

scholarly journals XRD and CO2 Adsorption Studies of Modified Silica Gel with Octadecylamine

2017 ◽  
Vol 888 ◽  
pp. 529-533
Author(s):  
Maratun Najiha Abu Tahari ◽  
Azizul Hakim ◽  
Tengku Sharifah Marliza ◽  
Nurul Hanisah Mohd ◽  
Mohd Ambar Yarmo
Keyword(s):  
Heat Treatment ◽  
Silica Gel ◽  
Xrd Analysis ◽  
Straight Chain ◽  
Modified Silica Gel ◽  
Wet Impregnation ◽  
Impregnation Process ◽  
Process Characterization ◽  
Amine Compounds ◽  
Adsorption Desorption

Porous surface of silica gel (SG) have been modified with long and straight chain fatty amine compounds (octadecylamine, ODA) via wet impregnation process. SG was undergo heat treatment with various temperature which are 100, 200, 400 and 600 °C before continuing with impregnation process. Characterization by XRD of the treated samples were showed no significant different in their diffractograms. The best temperature for heat treatment was 600 °C and it was referred to the ability of the SG600 type adsorbents in adsorbing CO2 resulted from adsorption desorption isotherm of CO2. The 5 and 35 wt. % of ODA supported on the SG (ODA/SG600) was further characterized using XRD analysis which displayed the increasing intensity of crystalline ODA with higher percent amine loaded and shifting of the several crystalline peak of ODA verified the interaction of SG600-ODA. These further strengthen the prevailing dispersion of ODA on the surface of SG600.

Photocatalytic Activity of TiO2 Nanotube Modified by Cobalt

2011 ◽  
Vol 110-116 ◽  
pp. 559-564
Author(s):  
Xin Sheng Yang ◽  
Hern Kim
Keyword(s):  
Xrd Analysis ◽  
Treatment Temperature ◽  
Degradation Efficiency ◽  
Impregnation Method ◽  
High Concentration ◽  
Wet Impregnation ◽  
Impregnation Process ◽  
Uv Illumination ◽  
Wet Impregnation Method ◽  
Enhanced Degradation

Cobalt modified TiO2nanotube was prepared by wet impregnation method from anodized nanotube. The microstructure and phase characteristic were studied by SEM, EDX and XRD analysis. The photocatalytic degradation of methylene blue under UV illumination was studied. Enhanced degradation efficiency could be obtained after sodium borohydride reducing. For the samples using low concentration of CoCl2in wet impregnation process, the degradation efficiency increased with the increase of CoCl2concentration and for high concentration, the degradation efficiency decreased. With increasing the post-treatment temperature, the degradation efficiency decreased.

scholarly journals Synthesis and Characterization of Nanoporous Monetite Which Can Be Applicable for Drug Carrier

2012 ◽  
Vol 2012 ◽  
pp. 1-5 ◽  
Author(s):  
Esmael Salimi ◽  
Jafar Javadpour
Keyword(s):  
Surface Area ◽  
Cetyltrimethylammonium Bromide ◽  
Drug Carrier ◽  
Synthesis And Characterization ◽  
X Ray ◽  
Plate Shape ◽  
Desorption Isotherms ◽  
Adsorption Desorption

Wormhole-like mesostructured monetite was successfully synthesized using cetyltrimethylammonium bromide (C19H42BrN, CTAB), as a porosity agent. X-ray techniques and FTIR reveal that the crystalline grains consist of highly crystalline pure monetite phase. Monetite rods with diameter around 20–40 nm and length in the range of 50–200 nm were confirmed by FESEM and TEM. Based on N2adsorption-desorption isotherms investigation, surface area increased up to 31.5 m2/g due to the removal of surfactant after calcinations at 400°C. The results indicate that CTAB can not only affect monetite crystallization but also change particles morphology from plate shape to rod-like.

Characterization of mesoporous region by the scanning of the hysteresis loop in adsorption–desorption isotherms

Adsorption ◽  
2021 ◽  
Author(s):  
C. F. Toncón-Leal ◽  
J. Villarroel-Rocha ◽  
M. T. P. Silva ◽  
T. P. Braga ◽  
K. Sapag
Keyword(s):  
Hysteresis Loop ◽  
Desorption Isotherms ◽  
Adsorption Desorption

Preparation and Characterization of Fe2O3/ SBA-15 for Fischer-Tropsch Process

2020 ◽  
Vol 850 ◽  
pp. 144-150
Author(s):  
Agija Stanke ◽  
Valdis Kampars ◽  
Oana A. Lazar ◽  
Marius Enachescu
Keyword(s):  
Average Pore Size ◽  
Direct Synthesis ◽  
Synthesis Method ◽  
Xrd Analysis ◽  
Hexagonal Structure ◽  
Catalyst Characterization ◽  
Average Pore ◽  
Pluronic P123 ◽  
Silica Source ◽  
Adsorption Desorption

In this study Fe2O3/SBA-15 catalyst was synthesized via direct synthesis method under acidic conditions using triblock copolymer Pluronic P123 as template, tetraethyl orthosilicate as a silica source and Fe (NO3)3∙9H2O as iron source. Template was removed using extraction and calcination. The obtained catalyst was characterized using XRD analysis, WDXRF spectroscopy, N2 adsorption-desorption analysis and STEM–EDX measurements. Results of catalyst characterization showed that the synthesized Fe2O3/SBA-15 is mesoporous silica with 2D p6mm hexagonal mesostructure loaded with 15.6 wt.% Fe2O3. Average pore size was 6.95 nm, homogeneous immobilized Fe2O3 nanoparticles do not disrupt the porous hexagonal structure of the support.

Preparation of Cr Metal Supported on Sulfated Zirconia Catalyst

2019 ◽  
Vol 948 ◽  
pp. 221-227
Author(s):  
Latifah Hauli ◽  
Karna Wijaya ◽  
Ria Armunanto
Keyword(s):  
Sulfated Zirconia ◽  
Reduction Process ◽  
Catalyst Preparation ◽  
Impregnation Method ◽  
Wet Impregnation ◽  
Zirconia Catalyst ◽  
Isotherm Adsorption ◽  
Sulfated Zirconia Catalyst ◽  
Adsorption Desorption ◽  
Wet Impregnation Method

Catalyst of Chromium (Cr) metal supported on sulfated zirconia (SZ) was prepared by wet impregnation method. This study aim to determine the optimal concentration of Cr metal that impregnated on SZ catalyst. Preparation of catalyst was conducted at different concentrations of Cr metal (0.5%, 1%, 1.5% (w/w)), impregnated on SZ catalyst, then followed by the calcinationand reduction process. Catalysts were charaterized by FTIR, XRD, XRF, SAA, TEM, and acidity test. The results showed the Cr/SZ 1% had the highest acidity value of 8.22 mmol/g which confirmed from FTIR spectra. All the crystal phase of these catalysts were in monoclinic. The specific surface area increased with the increasing of Cr metal concentration on SZ catalyst and the isotherm adsorption-desorption of N2 gas observed all the catalysts as mesoporous material. The impregnation process formed particles agglomeration.

scholarly journals Effect of Both the Phase Composition and Modification Methods on Structural-Adsorption Parameters of Dispersed Silicas

2018 ◽  
Vol 3 (1) ◽  
pp. 1 ◽  
Author(s):  
Tatyana Rakitskaya ◽  
Tatyana Kiose ◽  
Kristina Golubchik ◽  
Viacheslav Baumer ◽  
Vitaliya Volkova
Keyword(s):  
Water Vapor ◽  
Water Vapor Adsorption ◽  
X Ray Diffraction ◽  
Adsorption Parameters ◽  
X Ray ◽  
Vapor Adsorption ◽  
Crystallite Sizes ◽  
Desorption Isotherms ◽  
Adsorption Desorption ◽  
Modified Forms

Tripoli from two Ukrainian deposits was studied in its natural and modified forms. The investigation of natural and modified tripoli involves the identification of their phase compositions through X-ray diffraction and the analysis of their water vapor adsorption-desorption isotherms. The obtained results are evidence of changes in the structural-adsorption parameters of tripoli as a result of modification. Their treatment in boiling water or acid causes apparent alterations of contents of the main phases and sizes of their crystallites, whereas their calcination causes not only the dehydroxylation of surfaces and the agglomeration of phases, but even phase transformation in the case of carbonate tripoli. After analyzing water vapor adsorption-desorption isotherms of natural and modified tripolis, some correlations between their adsorption parameters, phase compositions, main phase contents and crystallite sizes have been found.

Sign in / Sign up

Export Citation Format

Share Document