Structural Formation of the Cement Pastes Based on the Concrete Modified Dispersed Mineral Components

2020 ◽  
Vol 1011 ◽  
pp. 14-22
Author(s):  
A. Khalyushev ◽  
Sergey Stelmakh ◽  
Evgeniy Shcherban ◽  
A. Chernilnik

With the increase in the number of finely dispersed mineral additives in concrete, their water demand increases and the effect of micro-filling weakens. To solve this problem, various methods of dry surface modification are proposed. As a result of the finely dispersed mineral powders’ surface modification, an improvement in their rheological characteristics, a decrease in wettability, a change in granulometry and other properties are achieved. This article discusses the surface modification effect’s laws in a high-voltage electric field on the autogenous properties of mineral dispersed concrete components, structure formation processes, mechanical properties, and cement stone hydration products. According to the results of the study, it was found that the surface modification of bulk materials - concrete components - in a high-voltage electric field changes autohesion properties in comparison with control samples. The data indicate lower values ​​of bulk density and angle of repose. This is due to a change in the balance of forces that arise during the mutual contact of particles after surface modification. With a certain balance of these forces, autohesion will contribute to the dense packing of particles and thereby affect the structure formation processes. The results of changes in the plastic strength of cement pastes confirm that there is an intensification of the structure formation process. Moreover, a more intense increase in plastic strength is observed during bipolar charging of particles in comparison with unipolar charging. This is due to an increase in the number of heterogeneous charges in the system and, as a consequence, an increase in the strength of adhesive contacts, as evidenced by the data of X-ray phase analysis.

2020 ◽  
Vol 1011 ◽  
pp. 23-30
Author(s):  
A. Khalyushev ◽  
A. Mayilyan ◽  
Sergey Stelmakh ◽  
Evgeniy Shcherban

The aim of the research was to study the activation technology of the materials for concrete by their surface modification in a high-voltage electric field. It is noted that the mineral additives modified in a high-voltage electric field are characterized by a higher activity of the calcium hydroxide absorption. It was established that, despite the presence of a large number of crystalline compounds in metakaolin, its pozzolanic activity in the absorption of calcium hydroxide from a saturated solution is quite high. The same value of the hydration activity coefficient is also determined for the ground slag. The authors found that a characteristic feature of the dispersed mineral additives, surface-modified in a high-voltage electric field in comparison with control samples, are the lower values ​​of bulk density and repose angle. This is due to a change in the forces balance that occurs during the mutual contact of particles. The influence of the mineral additives’ surface modification in a high-voltage electric field on interparticle interactions in the “solid – liquid” system is evaluated. It is established that in the absence of a repulsion barrier, the particles form the aggregates that increase their sedimentation rate. During unipolar or bipolar charging of particles in an electric field, the sedimentation rate slows down or accelerates accordingly. These effects are used to modify the cement surface.


2022 ◽  
Vol 906 ◽  
pp. 59-67
Author(s):  
Alexandr Sergeevich Inozemtcev ◽  
Evgenij Korolev ◽  
Duong Thanh Qui

With the development of 3D technologies in construction, the development of formulations that are indifferent to the influence of the environment is in demand. Conditions of intense water loss from cement systems arise during the layer-by-layer printing process. This leads to a decrease in density, high shrinkage, and a decrease in the strength and durability of the composite. The use of superabsorbent polymer (SAP) solutions, in contrast to granules, will provide hardening Portland cement with a water supply for internal care of hydration processes. The aim of the work is to study the effect of SAP solution on the processes of structure formation of cement stone, hardening in unfavorable conditions. In this paper, the features of the structure formation of cement systems in the presence of SAP are established. It is shown that the use of polymer in an amount of no more than 1.5% by the weight of Portland cement provides the formation of a more perfect crystalline structure of the cement stone, which allows for an increase in the degree of cement hydration. When the amount of SAP is ≥ 1.5% by the weight of Portland cement, a decrease in the intensity of the maxima corresponding to hydration products is observed.


2018 ◽  
Vol 276 ◽  
pp. 192-197 ◽  
Author(s):  
Lenka Bodnarova ◽  
Sergii Guzii ◽  
Rudolf Hela ◽  
Pavel Krivenko ◽  
Grigorii Vozniuk

The influence of СаСО3on nano-structured, flowability and plastic strength of alkali activated alumonosilicate binders based on metakaolin for the range of oxide ratios in a structural formula of the Na2O∙Al2O3∙(2.5-4.5)SiO2∙(12-17)H2O + (5-15%)CaCO3system was studied. The results of the study showed that the ratios of SiO2/Al2O3– 3.8, H2O/Al2O3– 13.75, and content of СаСО3of 5% by mass were the most optimal ones from the point of view of meeting requirements for these binders to be used as base in protective coatings.The results of the study showed that process flowability of the binder with optimal ratios of oxides and 5 % by mass of additive 2 hours after preparation was by 5.4% lower, being by 5 times lower than that of the binder without the additive (СаСО3). The binder containing 5% СаСО3by mass during 2 hours after preparation exhibited the same plastic strength (37 Pa), whereas this value of the binder without CaCO3has increased, in average by 5.5 times, affecting negatively shelf life of this binder to be used as base in protective coatings.A conclusion was made that the addition of СаСО3intensified the nano-structured formation processes in the direction of formation of Na-Ca zeolite-like phases; shortening time required the cement stone to gain water resistance in normal conditions.


The article presents the study of processes of structure formation of cement stone and products of hardening of organic-mineral compositions with fibrous filler (shavings) by the electronic scanning microscopy method. It is established that the additive-free cement stone at the age of 28 days has a dense and homogeneous structure, consists of calcium hydro-silicates, Portlandite and calcite - newgrowths characteristic for cement systems. Cellulose fibers, which make up the bulk of the substance of shavings, are sufficiently active, which determines the high adhesion of the hydration products of the cement binder to their surface. It is shown that the introduction of shavings into the organo-mineral composition leads to inhibition of cement hydration processes. Organo-mineral compositions with different shavings content (two compositions) were analyzed. The first composition is characterized by a fairly dense structure, the cement stone consists of globular nanoscale nuclei of hydrosilicates, Portlandite and calcite. The second composition has a loose porous structure, cement stone consists of non-hydrated cement grains, newgrowths are represented by calcite and vaterite. The structure of the contact zone "osprey fiber-cement stone" in the organo-mineral composition of the first composition indicates a good adhesion of the filler surface with the phases of hydrated cement. The use of shavings as a fibrous filler (the first composition) increases the tensile and bending strength, as well as the wear resistance of organo-mineral compositions. The data obtained by scanning electron microscopy are confirmed by the results of studying the processes of structure formation of cement stone by quantitative x-ray phase analysis.


Jurnal Teknik ◽  
2018 ◽  
Vol 7 (1) ◽  
Author(s):  
Mauludi Manfaluthy

WHO (World Health Organization) concludes that not much effect is caused by electric field up to 20 kV / m in humans. WHO standard also mentions that humans will not be affected by the magnetic field under  100 micro tesla and that the electric field will affect the human body with a maximum standard of 5,000 volts per meter. In this study did not discuss about the effect of high voltage radiation SUTT (High Voltage Air Channel) with human health. The research will focus on energy utilization of SUTT radiation. The combination of electric field and magnetic field on SUTT (70-150KV) can generate electromagnetic (EM) and radiation waves, which are expected to be converted to turn on street lights around the location of high voltage areas or into other forms. The design of this prototype works like an antenna in general that captures electromagnetic signals and converts them into AC waves. With a capacitor that can store the potential energy of AC and Schottky diode waves created specifically for low frequency waves, make the current into one direction (DC). From the research results obtained the current generated from the radiation is very small even though the voltage is big enough.Keywords : Radiance Energy, Joule Thief, and  LED Module.


1983 ◽  
Vol 26 (1) ◽  
pp. 49-50
Author(s):  
I. P. Klimashevskii ◽  
B. L. Kondrat'ev ◽  
V. A. Poletaev ◽  
V. M. Yurkevich

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