Hydrogen Embrittlement and Hydrogen Trapping Behaviour in Advanced High Strength Steels

2021 ◽  
Vol 1016 ◽  
pp. 1344-1349
Author(s):  
Ali Smith
Keyword(s):  
Hydrogen Embrittlement ◽  
Retained Austenite ◽  
Hydrogen Diffusion ◽  
Hydrogen Permeation ◽  
High Strength Steels ◽  
High Strength ◽  
Hydrogen Trapping ◽  
Austenite Matrix ◽  
Advanced High Strength Steels ◽  
Step Loading

Modern advanced high strength steels (AHSS) for the automotive sector often contain retained austenite which promotes remarkable combinations of strength and ductility. These high strength steels may however be subject to a risk of hydrogen embrittlement. For the current contribution, hydrogen trapping and embrittlement behaviour were investigated in AHSS compositions having different levels of retained austenite. Hydrogen permeation tests revealed that hydrogen diffusion was slower for increased levels of retained austenite, being controlled most likely by reversible trapping at austenite-matrix interfaces. External hydrogen embrittlement tests via step loading also revealed that resistance to hydrogen was lower for increased levels of retained austenite. It was suggested that during step loading the hydrogen accumulated at austenite-matrix interfaces, leading to cracking when the applied stress was high enough.

A review of hydrogen embrittlement of martensitic advanced high-strength steels

2016 ◽  
Vol 34 (3) ◽  
pp. 153-186 ◽  
Author(s):  
Jeffrey Venezuela ◽  
Qinglong Liu ◽  
Mingxing Zhang ◽  
Qingjun Zhou ◽  
Andrej Atrens
Keyword(s):  
Hydrogen Embrittlement ◽  
High Strength Steels ◽  
High Strength ◽  
Applied Strain ◽  
Service Performance ◽  
Hydrogen Trapping ◽  
Comprehensive Understanding ◽  
Advanced High Strength Steels ◽  
Laboratory Results ◽  
Applied Strain Rate

AbstractThe martensitic advanced high-strength steels (MS-AHSS) are used to create fuel-efficient, crashworthy cars. Hydrogen embrittlement (HE) is an issue with high-strength steels; thus, the interaction of hydrogen with MS-AHSS needs to be studied. There are only a few published works on the HE of MS-AHSS. The current literature indicates that the HE susceptibility of MS-AHSS is affected by (i) the strength of the steel, (ii) the applied strain rate, (iii) the concentration of hydrogen, (iv) microstructure, (v) tempering, (vi) residual stress, (vii) fabrication route, (viii) inclusions, (ix) metallic coatings, and (x) specific precipitates. Some of the unresolved issues include (i) the correlation of laboratory results to service performance, (ii) establishing the conditions or factors that lead to a certain HE response, (iii) studying the effect of stress rate on HE, and (iv) a comprehensive understanding of hydrogen trapping in MS-AHSS.

scholarly journals Effects of Alloying Elements Addition on Delayed Fracture Properties of Ultra High-Strength TRIP-Aided Martensitic Steels

Metals ◽  
2019 ◽  
Vol 10 (1) ◽  
pp. 6 ◽  
Author(s):  
Tomohiko Hojo ◽  
Junya Kobayashi ◽  
Koh-ichi Sugimoto ◽  
Akihiko Nagasaka ◽  
Eiji Akiyama
Keyword(s):  
Hydrogen Embrittlement ◽  
Retained Austenite ◽  
Hydrogen Diffusion ◽  
High Strength ◽  
Alloying Elements ◽  
Bending Test ◽  
Hydrogen Trapping ◽  
Martensitic Steels ◽  
Diffusible Hydrogen ◽  
Martensite Matrix

To develop ultra high-strength cold stamping steels for automobile frame parts, the effects of alloying elements on hydrogen embrittlement properties of ultra high-strength low alloy transformation induced plasticity (TRIP)-aided steels with a martensite matrix (TM steels) were investigated using the four-point bending test and conventional strain rate tensile test (CSRT). Hydrogen embrittlement properties of the TM steels were improved by the alloying addition. Particularly, 1.0 mass% chromium added TM steel indicated excellent hydrogen embrittlement resistance. This effect was attributed to (1) the decrease in the diffusible hydrogen concentration at the uniform and fine prior austenite grain and packet, block, and lath boundaries; (2) the suppression of hydrogen trapping at martensite matrix/cementite interfaces owing to the suppression of precipitation of cementite at the coarse martensite lath matrix; and (3) the suppression of the hydrogen diffusion to the crack initiation sites owing to the high stability of retained austenite because of the existence of retained austenite in a large amount of the martensite–austenite constituent (M–A) phase in the TM steels containing 1.0 mass% chromium.

scholarly journals Heat Treatment Design for a QP Steel: Effect of Partitioning Temperature

Metals ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 1136
Author(s):  
Marcel Carpio ◽  
Jessica Calvo ◽  
Omar García ◽  
Juan Pablo Pedraza ◽  
José María Cabrera
Keyword(s):  
Retained Austenite ◽  
High Strength Steels ◽  
High Strength ◽  
Tensile Tests ◽  
Quenching Temperature ◽  
Advanced High Strength Steels ◽  
New Family ◽  
Automotive Parts ◽  
Fresh Martensite ◽  
Industry Needs

Designing a new family of advanced high-strength steels (AHSSs) to develop automotive parts that cover early industry needs is the aim of many investigations. One of the candidates in the 3rd family of AHSS are the quenching and partitioning (QP) steels. These steels display an excellent relationship between strength and formability, making them able to fulfill the requirements of safety, while reducing automobile weight to enhance the performance during service. The main attribute of QP steels is the TRIP effect that retained austenite possesses, which allows a significant energy absorption during deformation. The present study is focused on evaluating some process parameters, especially the partitioning temperature, in the microstructures and mechanical properties attained during a QP process. An experimental steel (0.2C-3.5Mn-1.5Si (wt%)) was selected and heated according to the theoretical optimum quenching temperature. For this purpose, heat treatments in a quenching dilatometry and further microstructural and mechanical characterization were carried out by SEM, XRD, EBSD, and hardness and tensile tests, respectively. The samples showed a significant increment in the retained austenite at an increasing partitioning temperature, but with strong penalization on the final ductility due to the large amount of fresh martensite obtained as well.

scholarly journals Effect of Quenching and Partitioning Temperatures in the Q-P Process on the Properties of AHSS with Various Amounts of Manganese and Silicon

2012 ◽  
Vol 706-709 ◽  
pp. 2734-2739 ◽  
Author(s):  
Hana Jirková ◽  
Ludmila Kučerová ◽  
Bohuslav Mašek
Keyword(s):  
Tensile Strength ◽  
Retained Austenite ◽  
Isothermal Holding ◽  
Bainitic Ferrite ◽  
High Strength Steels ◽  
High Strength ◽  
Experimental Program ◽  
Quenching Temperature ◽  
Quenching And Partitioning ◽  
Advanced High Strength Steels

The use of the combined influence of retained austenite and bainitic ferrite to improve strength and ductility has been known for many years from the treatment of multiphase steels. Recently, the very fine films of retained austenite along the martensitic laths have also become the centre of attention. This treatment is called the Q-P process (quenching and partitioning). In this experimental program the quenching temperature and the isothermal holding temperature for diffusion carbon distribution for three advanced high strength steels with carbon content of 0.43 % was examined. The alloying strategies have a different content of manganese and silicon, which leads to various martensite start and finish temperatures. The model treatment was carried out using a thermomechanical simulator. Tested regimes resulted in a tensile strength of over 2000MPa with a ductility of above 14 %. The increase of the partitioning temperature influenced the intensity of martensite tempering and caused the decrease of tensile strength by 400MPa down to 1600MPa and at the same time more than 10 % growth of ductility occurred, increasing it to more than 20%.

Influence of the Processing Variables on the Microstructure Evolution of a Bainitic Carbide-Free Steel

2016 ◽  
Vol 879 ◽  
pp. 867-872 ◽  
Author(s):  
M.C. Taboada ◽  
I. Gutiérrez ◽  
D. Jorge-Badiola ◽  
S.M.C. van Bohemen ◽  
F. Hisker ◽  
...  
Keyword(s):  
Retained Austenite ◽  
High Strength Steels ◽  
High Strength ◽  
High Volume ◽  
X Ray Diffraction ◽  
Tempered Martensite ◽  
Trip Steels ◽  
Volume Fractions ◽  
Advanced High Strength Steels ◽  
Processing Variables

New trends focused on achieving higher performance steels has led to a so-called 3rd Generation Advanced High Strength Steels (AHSS), in which the typical polygonal ferrite found in TRIP steels as a matrix phase is replaced by harder phases as Carbide-Free Bainite (CFB) and/or (tempered) martensite. Besides, large volume fractions of retained austenite (R.A.) with adequate stability are aimed for to improve the formability of the steels. Si containing steels are regarded as the most suitable to retard cementite formation and consequently reach high volume fractions of RA. In this work, CFB annealing schedules were applied to dilatometer samples of Fe-0.22C-2.0Mn-1.3Si. The overaging temperature TB was varied between 390 oC and 480 oC, and other processing variables investigated were the austenitizing temperature Taus, and the overaging holding time tB. The annealed samples analyzed with LOM, FEG-SEM, EBSD and X-ray diffraction techniques show that markedly different complex microstructures made up of bainite, ferrite, MA phase and retained austenite (R.A) are accomplished depending on the specific thermal cycle. These results are described in detail and discussed in relation to the dilatometry measurements.

scholarly journals Substructure Development and Damage Initiation in a Carbide-Free Bainitic Steel upon Tensile Test

Metals ◽  
2019 ◽  
Vol 9 (12) ◽  
pp. 1261
Author(s):  
Mari Carmen Taboada ◽  
Amaia Iza-Mendia ◽  
Isabel Gutiérrez ◽  
Denis Jorge-Badiola
Keyword(s):  
Retained Austenite ◽  
High Strength Steels ◽  
High Strength ◽  
Tensile Tests ◽  
Formation Mechanisms ◽  
Tempered Martensite ◽  
Damage Initiation ◽  
Advanced High Strength Steels ◽  
Significant Strength ◽  
The Stability

Carbide-free bainitic (CFB) steels belong to the family of advanced high strength steels (AHSS) that are struggling to become part of the third-generation steels to be marketed for the automotive industry. The combined effects of the bainitic matrix and the retained austenite confers a significant strength with a remarkable ductility to these steels. However, CFB steels usually show much more complex microstructures that also contain MA (Martensite–Austenite) phase and auto-tempered martensite (ATM). These phases may compromise the ductility of CFB steels. The present work analyzes the substructure evolution during tensile tests in the necking zone, and deepens into the void and crack formation mechanisms and their relationship with the local microstructure. The combination of FEG-SEM imaging, EBSD, and X-ray diffraction has been necessary to characterize the substructure development and damage initiation. The bainite matrix has shown great ductility through the generation of high angle grain boundaries and/or large orientation gradients around voids, which are usually found close to the bainite and MA/auto-tempered martensite interfaces or fragmenting the MA phase. Special attention has been paid to the stability of the retained austenite (RA) during the test, which may eventually be transformed into martensite (Transformation Induced Plasticity, or TRIP effect).

scholarly journals Enhancing the Mechanical Properties of a Hot Rolled High-Strength Steel Produced by Ultra-Fast Cooling and Q&P Process

Metals ◽  
2019 ◽  
Vol 9 (9) ◽  
pp. 958 ◽  
Author(s):  
Teng Wu ◽  
Run Wu ◽  
Bin Liu ◽  
Wen Liang ◽  
Deqing Ke
Keyword(s):  
Retained Austenite ◽  
High Strength Steels ◽  
High Strength ◽  
Controlled Rolling ◽  
Grain Structure ◽  
Ultra Fast Cooling ◽  
Advanced High Strength Steels ◽  
Fast Cooling ◽  
Austenite Grains ◽  
Hot Rolled

The quenching and partitioning (Q&P) process of advanced high strength steels results in a significant enhancement in their strength and ductility. The development of controlled rolling and cooling technology provides an efficient tool for microstructural design in steels. This approach allows to control phase transformations in order to generate the desired microstructure in steel and, thus, to achieve the required properties. To refine grain structure in a Fe-Si-Mn-Nb steel and to generate the microstructure consisting of martensitic matrix with embedded retained austenite grains, hot rolling and pressing combined with ultrafast cooling and Q&P process is employed. The slender martensite in hot rolled Q&P steel improves the strength of test steel and the flake retained austenite improves the plasticity and work hardening ability through the Transformation Induced Plasticity (TRIP) effect.

Techniques for investigation of hydrogen embrittlement of advanced high strength steels

2018 ◽  
Vol 36 (5) ◽  
pp. 413-434 ◽  
Author(s):  
Darya Rudomilova ◽  
Tomáš Prošek ◽  
Gerald Luckeneder
Keyword(s):  
Hydrogen Embrittlement ◽  
Secondary Ion Mass Spectrometry ◽  
High Strength Steels ◽  
Thermal Desorption Spectroscopy ◽  
High Strength ◽  
Atmospheric Conditions ◽  
Kelvin Probe ◽  
Advanced High Strength Steels ◽  
Scanning Kelvin Probe ◽  
Atmospheric Exposure

AbstractProduction volumes of advanced high strength steels (AHSS) are growing rapidly due to material and energy savings they provide in a number of application areas. In order to use their potential fully, it is necessary to minimize any danger of unexpected failures caused by hydrogen embrittlement. It is possible only if deeper understanding of underlying mechanisms is obtained through further research. Besides description of main grades of AHSS and mechanisms of HE, this paper reviews available tools for determination of hydrogen content and susceptibility to HE focusing on atmospheric conditions. Techniques such as slow strain rate testing, constant load testing, electrochemical permeation technique, scanning Kelvin probe and scanning Kelvin probe force microscopy have already been used to study the effect of hydrogen entered under atmospheric exposure conditions. Nanoindentation, hydrogen microprint technique, thermal desorption spectroscopy, Ag decoration or secondary ion mass spectrometry can be also conducted after atmospheric exposure.

scholarly journals Hydrogen trapping in some advanced high strength steels

2016 ◽  
Vol 111 ◽  
pp. 770-785 ◽  
Author(s):  
Qinglong Liu ◽  
Jeffrey Venezuela ◽  
Mingxing Zhang ◽  
Qingjun Zhou ◽  
Andrej Atrens
Keyword(s):  
High Strength Steels ◽  
High Strength ◽  
Hydrogen Trapping ◽  
Advanced High Strength Steels

scholarly journals Hydrogen Embrittlement and Diffusion in High Strength Low Alloyed Steels with Different Microstructures

2018 ◽  
Author(s):  
Marina Cabrini ◽  
Sergio Lorenzi ◽  
Diego Pesenti Bucella ◽  
Tommaso Pastore
Keyword(s):  
Hydrogen Embrittlement ◽  
Strain Rate ◽  
Hydrogen Diffusion ◽  
High Strength Steels ◽  
High Strength ◽  
Tempered Martensite ◽  
Hsla Steels ◽  
And Diffusion ◽  
Embrittlement Resistance ◽  
Hydrogen Embrittlement Resistance

<span lang="EN-US">The paper deals with the effect of microstructure on the hydrogen diffusion in traditional ferritic-pearlitic HSLA steels and new high strength steels, with tempered martensite microstructures or banded ferritic-bainitic-martensitic microstructures. Diffusivity was correlated to the hydrogen embrittlement resistance of steels, evaluated by means of slow strain rate tests.</span>

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