Properties of Organic/Inorganic Hybrid Material Synthesized from Acrylic Resin and Silane-Terminated CS

2007 ◽  
Vol 544-545 ◽  
pp. 809-812 ◽  
Author(s):  
Young Taec Kang ◽  
Jin Kook Lee ◽  
Dong Pil Kang
Keyword(s):  
Thin Film ◽  
Contact Angle ◽  
Hybrid Materials ◽  
Sol Gel ◽  
Acrylic Resin ◽  
Thermal Polymerization ◽  
Electric Resistivity ◽  
Hybrid Thin Film ◽  
Inorganic Hybrid ◽  
Aluminum Sheets

Organic/inorganic hybrid materials synthesized from acrylic resin and silane-terminated colloidal silica(CS). The silane-terminated CS was prepared in variation with the kind of silane to CS. The CS treated with methyltrimethoxysilane(MTMS) and then treated with vinyl trimethoxysilane(VTMS), 3-glycidoxypropyltrimethoxysilane(ATMS) or 3-methacyloxypropyl trimethoxysialne(ETMS) by sol-gel method, respectively. The variation of silane-terminated CS and acrylic resin were hybridized by thermal-polymerization. Thin films of organic/inorganic hybrid materials were prepared using spin coater on the glass and aluminum sheets. Their contact angle, surface electric resistivity and thermal resistance improved with the amount of silaneterminated CS. The contact angle and surface electric resistivity of hybrid thin film with VTMS were enhanced. The surface of hybrid thin film with VTMS was homogeneous through FE-SEM.

Characteristics of Thin Film of Nano-Hybrid Synthesized from Acrylic Resin and Colloidal Silca-Silane Sol

2006 ◽  
Vol 510-511 ◽  
pp. 218-221
Author(s):  
Dong Pil Kang ◽  
Hoy Yul Park ◽  
Young Taec Kang ◽  
Moon Kyong Na ◽  
Hee Woong Lee
Keyword(s):  
Thin Films ◽  
Contact Angle ◽  
Sol Gel ◽  
Thermal Dissociation ◽  
Acrylic Resin ◽  
Insulation Property ◽  
Inorganic Hybrid ◽  
Aluminum Sheets ◽  
Dissociation Temperature ◽  
Surface Contact Angle

Organic-inorganic hybrid blends were prepared in variation with the ratio of sol solution to urethaneacrylic resin. Such sol solutions were synthesized from colloidal silica (CS)/ methyltrimethoxysilane(MTMS)/vinyltrimethoxysilane(VTMS) by sol-gel reaction through two step reactions. Thin films of organic-inorganic hybrid blends were prepared using spin coater on the glass and aluminum sheets. In order to understand surface properties of thin films, contact angle and roughness were measured. Surface contact angle and roughness of thin films increased as the amount of sol solution increased. Thermal dissociation temperature of thin films was observed using TGA. Thin films were stable until 270 oC. Thermal dissociation temperature of thin films improved with increasing sol solution. In order to observe insulation property of thin films, electrical resistance measurements were performed. Surface and volume resistance of thin films increased as the amount of sol solution increased.

Study on acrylic resin/titania organic–inorganic hybrid materials prepared by the sol–gel process

Polymer ◽  
2004 ◽  
Vol 45 (9) ◽  
pp. 2967-2976 ◽  
Author(s):  
Mingna Xiong ◽  
Bo You ◽  
Shuxue Zhou ◽  
Limin Wu
Keyword(s):  
Hybrid Materials ◽  
Sol Gel ◽  
Acrylic Resin ◽  
Inorganic Hybrid ◽  
Sol Gel Process

UV Curable Organic-Inorganic Hybrid Materials

2000 ◽  
Vol 628 ◽  
Author(s):  
Guang-Way Jang ◽  
Ren-Jye Wu ◽  
Yuung-Ching Sheen ◽  
Ya-Hui Lin ◽  
Chi-Jung Chang
Keyword(s):  
Hybrid Materials ◽  
Colloidal Silica ◽  
Sol Gel ◽  
Solution Ph ◽  
Uv Curable ◽  
Inorganic Hybrid ◽  
Degradation Temperature ◽  
Sol Gel Process ◽  
The Stability ◽  
Thermal Degradation Temperature

This work successfully prepared an UV curable organic-inorganic hybrid material consisting of organic modified colloidal silica. Applications of UV curable organic-inorganic hybrid materials include abrasion resistant coatings, photo-patternable thin films and waveguides. Colloidal silica containing reactive functional groups were also prepared by reacting organic silane and tetraethyl orthosilicate (TEOS) using sol-gel process. In addition, the efficiency of grafting organic moiety onto silica nanoparticles was investigated by applying TGA and FTIR techniques. Experimental results indicated a strong interdependence between surface modification efficiency and solution pH. Acrylate-SiO2 hybrid formation could result in a shifting of thermal degradation temperature of organic component from about 200°C to near 400°C. In addition, the stability of organic modified colloidal silica in UV curable formula and the physical properties of resulting coatings were discussed. Furthermore, the morphology of organic modified colloidal silica was investigated by performing TEM and SEM studies‥

Organic-inorganic hybrid thin film light-emitting devices: interfacial engineering and device physics

2021 ◽  
Author(s):  
Chunxiu Zang ◽  
Mengxin Xu ◽  
Letian Zhang ◽  
Shihao Liu ◽  
Wenfa Xie
Keyword(s):  
Thin Film ◽  
Quantum Dots ◽  
Sandwich Structure ◽  
Device Physics ◽  
Hybrid Thin Film ◽  
Inorganic Hybrid ◽  
Light Emitting ◽  
Light Emitting Devices ◽  
Interfacial Engineering ◽  
Organic Light

Thin film light-emitting devices (LEDs) with sandwich structure, such as organic light emitting devices (OLEDs), quantum dots LEDs (QLEDs) and perovskite LEDs (PeLEDs), have attracted wide attentions because of their...

Effect of ZnO on a Superhydrophilic Self-Cleaning Properties of TiO2/SiO2 Thin Film on Glass Slide Substrate

2015 ◽  
Vol 1131 ◽  
pp. 237-241 ◽  
Author(s):  
Akkarat Wongkaew ◽  
Chanida Soontornkallapaki ◽  
Naritsara Amhae ◽  
Wichet Lamai
Keyword(s):  
Thin Film ◽  
Contact Angle ◽  
Visible Light ◽  
Band Gap ◽  
Sol Gel ◽  
Dip Coating ◽  
Band Gap Energy ◽  
Gap Energy ◽  
Coating Method ◽  
Dip Coating Method

This work aims to study the effect of ZnO containing in TiO2/SiO2 film on the superhydrophilic property after exposed to different types of light. The metal solutions were prepared by sol-gel technique and the film was deposited on glass slides by dip coating method. The parameter studied was the amount of ZnO in the TiO2/SiO2 film. The contents of ZnO were 5-20% weight (increased by 5%). The amount of TiO2 was constant at 30% weight. The obtained films were analyzed for their roughness. The results indicated that film roughness changed according to the ZnO contents. With 5%ZnO in the thin film, the roughness was 0.726 nm while 20%ZnO obtained the roughness of 2.128 nm. UV-Vis spectrophotometer was used for measuring of transmittance of films. At wavelength of 550 nm, the transmittances of each film were greater than 90%. Band gap energy of each film was calculated from the transmittance data. It was found that the average band gap energy of the films was 2.47 eV. Then, the films contained various amount of ZnO were grouped into 2 sets. The first set was exposed to visible light while the other set was exposed to UV. The duration of exposure was 5 hr. Both sets of films after exposed to any light were kept in a black box controlled relative humidity of 85%. Each film was measured contact angle every day. It was found that the 30%TiO2/5%Zn/SiO2 film exposed to visible light showed the best superhydrophilic property. The contact angle was about 0-5° within 3 days. This may due to the reduction of band gap energy in the presence of ZnO in TiO2/SiO2 films to 2.41 eV and the roughness of the film.

Sign in / Sign up

Export Citation Format

Share Document