Severe Plastic Deformation of a Bainitic Rail Steel

2008 ◽  
Vol 584-586 ◽  
pp. 655-660 ◽  
Author(s):  
Anton Hohenwarter ◽  
Richard Stock ◽  
Reinhard Pippan

Severe Plastic Deformation (SPD) is known to be an effective method of producing nanocrystalline materials, for instance by HPT and ECAP. These techniques are also capable of reproducing microstructures which arise naturally when high pressure and friction is involved, for example in wheel-rail contact problems. The resulting deformation layers build the origin point for fatigue cracks. For that reason the knowledge of the mechanical properties of these deformation layers are of vital importance. In the framework of this study a baintic rail steel quality was deformed by High Pressure Torsion up to distinctive equivalent strains at a nominal pressure of 6 GPa up to a final equivalent strain of 16. Afterwards the evolution of the resulting microstructure was investigated by Scanning Electron Microscopy, by microhardness measurements and X-ray diffraction. The bainitic structure showed a strong alignment and fragmentation into the shear direction with increasing strain, which was accompanied by an increase in hardness as well. X-ray diffraction measurements showed that the amount of retained austenite decreases dramatically after small amounts of strain, which indicates that retained austenite cannot be stabilized by high pressures. Torque measurements during deformation showed after strong hardening at the beginning, a saturation behaviour for higher strains, whereas for instance pearlitic rail steel qualities show further hardening.

2010 ◽  
Vol 667-669 ◽  
pp. 17-24 ◽  
Author(s):  
Koichi Tsuchiya ◽  
Octav Ciuca

Process of nanostructure formation and amorphization by high pressure torsion (HPT) were studied for various intermetallic compounds. In ZrCu after HPT deformation, optical microscopy revealed that numerous shear bands formed running nearly parallel to the shear direction. Partial amorphization was confirmed by X-ray diffraction and TEM observations. Detailed TEM observations revealed localized amorphization within the nano-scale shear bands. For HPT deformation of zone-melted Zr50Cu40Al10 the preferential amorphization of ZrCu phase was observed. On the contrary, amorphization was not observed for Ni3Al even after HPT deformation of 100 turns; the sample remained to be disordered nanocrystalline of about 50 nm. The process and mechanism of the grain refinement and amorphization will be compared and discussed for these intermetallic compounds.


2016 ◽  
Vol 685 ◽  
pp. 525-529
Author(s):  
Zhanna G. Kovalevskaya ◽  
Margarita A. Khimich ◽  
Andrey V. Belyakov ◽  
Ivan A. Shulepov

The changes of the phase composition, structure and physicomechanical properties of Ti‑40 mas % Nb after severe plastic deformation are investigated in this paper. By the methods of microstructural, X-ray diffraction analysis and scanning electron microscopy it is determined that phase and structural transformations occur simultaneously in the alloy after severe plastic deformation. The martensitic structure formed after tempering disappears. The inverse α'' → β transformation occurs. The structure consisting of oriented refined grains is formed. The alloy is hardened due to the cold working. The Young modulus is equal to 79 GPa and it is less than that of initial alloy and close to the value obtained after tempering. It is possible that Young modulus is reduced by additional annealing.


Author(s):  
Innokenty Kantor ◽  
Alexander Kurnosov ◽  
Catherine McCammon ◽  
Leonid Dubrovinsky

AbstractA high-pressure quasi-single crystal X-ray diffraction study of a synthetic iron oxide Fe


2006 ◽  
Vol 114 ◽  
pp. 337-344 ◽  
Author(s):  
Bogusława Adamczyk-Cieślak ◽  
Jaroslaw Mizera ◽  
Krzysztof Jan Kurzydlowski

The texture of Al – 0.7 wt. % Li alloy processed by two different methods of severe plastic deformation (SPD) has been investigated by X-ray diffraction, and analyzed in terms of the orientation distribution function (ODF). It was found that severe plastic deformation by both Equal Channel Angular extrusion (ECAE) and Hydrostatic Extrusion (HE) resulted in an ultrafine grained structure in an Al – 0.7 wt. % Li alloy. The microstructure, grain shape and size, of materials produced by SPD strongly depend on the technological parameters and methods applied. The texture of the investigated alloy differed because of the different modes of deformation. In the initial state the alloy exhibited a very strong texture consisting of {111} fibre component. A similar fibrous texture characteristic was also found after HE whereas after the ECAE the initial texture was completely changed.


2019 ◽  
Vol 36 (4) ◽  
pp. 046103 ◽  
Author(s):  
Sheng Jiang ◽  
Jing Liu ◽  
Xiao-Dong Li ◽  
Yan-Chun Li ◽  
Shang-Ming He ◽  
...  

2019 ◽  
Vol 26 (4) ◽  
pp. 1245-1252 ◽  
Author(s):  
Daniel Sneed ◽  
John S. C. Kearney ◽  
Dean Smith ◽  
Jesse S. Smith ◽  
Changyong Park ◽  
...  

The transparent conducting oxide, SnO2, is a promising optoelectronic material with predicted tailorable properties via pressure-mediated band gap opening. While such electronic properties are typically modeled assuming perfect crystallinity, disordering of the O sublattice under pressure is qualitatively known. Here a quantitative approach is thus employed, combining extended X-ray absorption fine-structure (EXAFS) spectroscopy with X-ray diffraction, to probe the extent of Sn—O bond anharmonicities in the high-pressure cubic (Pa\bar{3}) SnO2 – formed as a single phase and annealed by CO2 laser heating to 2648 ± 41 K at 44.5 GPa. This combinational study reveals and quantifies a large degree of disordering in the O sublattice, while the Sn lattice remains ordered. Moreover, this study describes implementation of direct laser heating of non-metallic samples by CO2 laser alongside EXAFS, and the high quality of data which may be achieved at high pressures in a diamond anvil cell when appropriate thermal annealing is applied.


2019 ◽  
Vol 52 (6) ◽  
pp. 1378-1384
Author(s):  
Sergey Gromilov ◽  
Anatoly Chepurov ◽  
Valeri Sonin ◽  
Egor Zhimulev ◽  
Aleksandr Sukhikh ◽  
...  

The Fe–C system, which is widely used to grow commercial high-pressure–high-temperature diamond monocrystals, is rather complicated due to the formation of carbides. The carbide Fe3C is a normal run product, but the pressure at which Fe7C3 carbide becomes stable is a subject of discussion. This paper demonstrates the synthesis of Fe7C3 carbide and its detailed study using single-crystal and powder X-ray diffraction, as well as electron probe micro-analysis and scanning electron microscopy. The experiments were performed using a multiple-anvil high-pressure apparatus of `split-sphere' (BARS) type at a pressure of 5.5 GPa and a temperature of 1623 K. Our results show that in the Fe–C system, in addition to diamond, a phase that corresponds to the Fe7C3 carbide was synthesized. This means that both carbides (Fe7C3 and Fe3C) are stable at 5.5 GPa. Two crystal phases are described, Fe14C6 and Fe28C12−x . Fe14C6 is based on the well known rhombic structure of Fe7C3, while Fe28C12−x has a different packing order of Fe6C polyhedrons. The results obtained in this study should be taken into account when synthesizing and growing diamond at high pressures and temperatures in metal–carbon systems with a high iron content, as well as when conducting experimental studies on the synthesis of diamond directly from carbide.


Minerals ◽  
2020 ◽  
Vol 10 (2) ◽  
pp. 99 ◽  
Author(s):  
Ruilian Tang ◽  
Jiuhua Chen ◽  
Qiaoshi Zeng ◽  
Yan Li ◽  
Xue Liang ◽  
...  

Goethite is a major iron-bearing sedimentary mineral on Earth. In this study, we conducted in situ high-pressure x-ray diffraction, Raman, and electrical impedance spectroscopy measurements of goethite using a diamond anvil cell (DAC) at room temperature and high pressures up to 32 GPa. We observed feature changes in both the Raman spectra and electrical resistance at about 5 and 11 GPa. However, the x-ray diffraction patterns show no structural phase transition in the entire pressure range of the study. The derived pressure-volume (P-V) data show a smooth compression curve with no clear evidence of any second-order phase transition. Fitting the volumetric data to the second-order Birch–Murnaghan equation of state yields V0 = 138.9 ± 0.5 Å3 and K0 = 126 ± 5 GPa.


2014 ◽  
Vol 28 (25) ◽  
pp. 1450168 ◽  
Author(s):  
Nirup Bandaru ◽  
Ravhi S. Kumar ◽  
Jason Baker ◽  
Oliver Tschauner ◽  
Thomas Hartmann ◽  
...  

Structural behavior of bulk WS 2 under high pressure was investigated using synchrotron X-ray diffraction and diamond anvil cell up to 52 GPa along with high temperature X-ray diffraction and high pressure Raman spectroscopy analysis. The high pressure results obtained from X-ray diffraction and Raman analysis did not show any pressure induced structural phase transformations up to 52 GPa. The high temperature results show that the WS 2 crystal structure is stable upon heating up to 600°C. Furthermore, the powder X-ray diffraction obtained on shock subjected WS 2 to high pressures up to 10 GPa also did not reveal any structural changes. Our results suggest that even though WS 2 is less compressible than the isostructural MoS 2, its crystal structure is stable under static and dynamic compressions up to the experimental limit.


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