Mechanochemical Synthesis of Nanosized Hydroxyapatite Powder and its Conversion to Dense Bodies

2011 ◽  
Vol 694 ◽  
pp. 118-122 ◽  
Author(s):  
Sharifah Adzila ◽  
Iis Sopyan ◽  
Mohd Hamdi Bin Abd Shukor ◽  
Ramesh Singh
Keyword(s):  
High Speed ◽  
Rotation Speed ◽  
High Strength ◽  
X Ray Diffraction ◽  
Nanosize Powder ◽  
Ammonium Hydrogen ◽  
Tcp Phase ◽  
Nanosized Hydroxyapatite ◽  
The Stability

In this work, nanosized hydroxyapatite (HA) powder was synthesized via mechanochemical method by a dry mixture of calcium hydroxide Ca(OH)2 and di-ammonium hydrogen phosphate (NH4)2HPO4 powders. The effect of mechanochemical process on powder properties was investigated. Three rotation speeds of 170 rpm, 270 rpm and 370 rpm were chose with 15 hours milling time respectively. Characterization of nanopowders was accomplished by Fourier transform infra red (FTIR), X-ray diffraction (XRD) and nanosizer analysis. The green compacted powders with 200 MPa isostatically pressed were prepared and sintered in atmosphere condition at various temperatures ranging from 1150oC - 1350oC. The results showed that the rotation speed affected the obtained powders where the crystallite size was found increased with rotation speed (9 – 21 nm). In contrast, the particle size distribution decreased with rotation speed (322-192 nm). The sintering process has influenced the stability of powder by yielding TCP phase at a lower sintering temperature, 1150oC. However, powder synthesized at 370 rpm has showed a significant hardness, 5.3 GPa after compacted and sintered at 1250oC with the relative density of 95%. This phenomenon is believed to be related with the nanosize powder synthesized at high speed which has contributes the high strength of the sintered bodies.

Synthesis and Characterization of Porous ZrO2-Y2O3-TiO2 Ceramics Prepared by Coprecipitation

2012 ◽  
Vol 727-728 ◽  
pp. 1387-1392 ◽  
Author(s):  
Luan M. Medeiros ◽  
Fernando S. Silva ◽  
Juliana Marchi ◽  
Walter Kenji Yoshito ◽  
Dolores Ribeiro Ricci Lazar ◽  
...  
Keyword(s):  
Ceramic Composite ◽  
High Strength ◽  
Ceramic Composites ◽  
Rice Starch ◽  
X Ray Diffraction ◽  
Zirconia Ceramics ◽  
Pore Former ◽  
X Ray ◽  
Cold Pressed

Zirconium dioxide (zirconia) ceramics are known by its high strength and toughness and titanium dioxide (titania) ceramics has outstanding surface properties. The ceramic composite formed between the two oxides are expected to have advantages of both ceramics, especially when its surface area is increased by pores. In this work, ceramic composites of ZrO2-Y2O3-TiO2were synthesized by coprecipitation and rice starch was added as pore former in 10, 20 and 30 wt%. Powders were cold pressed as cylindrical pellets and sintered at 1500 °C for 01 hour and ceramics were characterized by techniques as Archimedes method for density measurements, X-ray diffraction and scanning electron microscopy. Results showed that pores are inhomogeneously distributed through ceramic bodies.

scholarly journals Síntese, caracterização e estabilidade de nanopartículas de magnetita

2021 ◽  
Vol 3 (4) ◽  
pp. 2738-2749
Author(s):  
Monise Cristina Ribeiro Casanova Coltro ◽  
Warde Antonieta da Fonseca-Zang ◽  
Joachim Werner Zang ◽  
Danilo César Silva e Sousa
Keyword(s):  
New Technology ◽  
X Ray Diffraction ◽  
Synthesis Of Nanoparticles ◽  
Research Areas ◽  
Magnetite Fe3o4 ◽  
Mineral Substance ◽  
Abundant Element ◽  
The Stability ◽  
Average Size

Nanopartículas de ferro são muito utilizadas em diversas áreas de pesquisa. O elemento químico ferro (Fe), sendo o quarto elemento mais abundante na crosta terrestre, e a substância mineral magnetita, com propriedade magnética, apresentam aplicações nas áreas industrial, ambiental, biomédica e de novas tecnologias. Este trabalho apresenta processo de síntese de nanopartículas partindo-se de sais precursores, bem como a caracterização dos produtos e as rotas para estabilizá-los. Os sais químicos precursores utilizados foram o cloreto férrico (FeCl3) e o sulfato ferroso (FeSO4) na proporção de 2:1, sob agitação por ultrassom e pH ácido. Para formação do precipitado de nanopartículas usou-se solução aquosa de hidróxido de sódio (NaOH) de pH 12. A difratometria de raio-X, mostra a presença de magnetita (Fe3O4) indicada pelos picos característicos de difração em graus 2Ө = 18° (largo), 31° (fino), 36° (bem definido), 43,4°, 45°, 53,6°, 57,7°, 63,3°. A microscopia eletrônica de transmissão mostra a morfologia dos produtos da síntese. Fatores que influenciam a estabilidade das partículas são agitação, o ajuste de pH, condições de secagem. O tamanho médio das nanopartículas de magnetitas é de aproximadamente 15 nm.   Iron nanoparticles are widely used in several research areas. The chemical element iron (Fe), being the fourth most abundant element in the earth's crust, and the mineral substance magnetite, with magnetic properties, have applications in industrial, environmental, biomedical, and new technology areas. This work presents the process of synthesis of nanoparticles starting from precursor salts, as well as the characterization of the products and the routes to stabilize them. The precursor chemical salts were ferric chloride (FeCl3) and ferrous sulfate (FeSO4) in a 2:1 ratio, under ultrasound agitation and acidic pH. For the nanoparticles growth was applied aqueous solution of sodium hydroxide (NaOH) at pH 12. X-ray diffraction shows the presence of magnetite (Fe3O4) indicated by characteristic diffraction peaks in degrees 2Ө = 18° (wide), 31° (fine), 36° (well defined), 43.4°, 45°, 53.6°, 57.7°, 63.3°. Scanning electron microscopy shows the morphology of the synthesis products. Factors that influence the stability of the particles are agitation, the pH adjustment, and the conditions of drying. The average size of the magnetite nanoparticles is approximately 15 nm.

Microstructure, thermal, and mechanical characterization of rapidly solidified high strength Fe84.3Cr4.3Mo4.6V2.2C4.6

2010 ◽  
Vol 25 (6) ◽  
pp. 1164-1171 ◽  
Author(s):  
A. Schlieter ◽  
U. Kühn ◽  
J. Eckert ◽  
H-J. Seifert
Keyword(s):  
Mechanical Properties ◽  
High Speed ◽  
High Speed Steel ◽  
High Strength ◽  
Cast State ◽  
High Fracture ◽  
Complex Carbides ◽  
Rapidly Solidified ◽  
Heating Up

Systematic microstructural and mechanical investigations of the Fe84.3Cr4.3Mo4.6V2.2C4.6 alloy cast under special manufacturing conditions in the as-cast state and after specific heat treatment are presented to point out that the special manufacturing of the alloy led to high compression strength (up to 4680 MPa) combined with large fracture strain (about 20%) already in the as-cast state. One select chemical composition of the alloy, which was mentioned previously [Kühn et al., Appl. Phys. Lett.90, 261901 (2007)] enhanced mechanical properties already in the as-cast state. Furthermore, that composition is comparable to commercial high-speed steel. By the special manufacturing used, a high purity of elements and a high cooling rate, which led to a microstructure similar to a composite-like material, composed of dendritic area (martensite, bainite, and ferrite) and interdendritic area (e.g., complex carbides). The presented article demonstrates an alloy that exhibits already in the as-cast state high fracture strength and large ductility. Furthermore, these outstanding mechanical properties remain unchanged after heating up to 873 K.

Phase Transformation Behavior and Mechanical Properties of Ti-Mo-Sn Alloys

2013 ◽  
Vol 747-748 ◽  
pp. 855-859
Author(s):  
Xiao Xue Chen ◽  
Shun Guo ◽  
Xin Qing Zhao
Keyword(s):  
Mechanical Properties ◽  
Cold Rolling ◽  
Cold Deformation ◽  
High Strength ◽  
Mechanical Tests ◽  
X Ray Diffraction ◽  
Superior Mechanical Properties ◽  
Low Modulus ◽  
Mo Content

A series of Ti-Mo-Sn alloys with different Mo contents from 7% to 15% (wt. %) were prepared, and the effects of Mo content and thermo-mechanical treatment on their microstructural evolution and mechanical behavior were investigated. The experimental results indicated that the β to α martensite transformation can be effectively suppressed with increasing Mo content. After cold rolling treatment, superior mechanical properties and low modulus were achieved in Ti-8Mo-4Sn alloy, with tensile strength of 1108MPa, yield strength of 1003MPa and low Youngs modulus of 53GPa. The influence of severe cold deformation on the macrostructure and mechanical properties was discussed based on the characterization of X-Ray diffraction and mechanical tests. It was demonstrated that the cold rolling induced fine α martensite and high density dislocations lead to the high strength of the Ti-Mo-Sn alloys. The fine α martensite as well as the β matrix with low stability guarantee low Youngs modulus.

Synthesis and characterization of the pentazolate anion cyclo-N5ˉ in (N5)6(H3O)3(NH4)4Cl

Science ◽  
2017 ◽  
Vol 355 (6323) ◽  
pp. 374-376 ◽  
Author(s):  
Chong Zhang ◽  
Chengguo Sun ◽  
Bingcheng Hu ◽  
Chuanming Yu ◽  
Ming Lu
Keyword(s):  
Thermal Analysis ◽  
Single Crystal ◽  
Diffraction Analysis ◽  
Decomposition Temperature ◽  
Synthesis And Characterization ◽  
X Ray Diffraction ◽  
X Ray ◽  
Onset Decomposition Temperature ◽  
The Stability

Pentazole (HN5), an unstable molecular ring comprising five nitrogen atoms, has been of great interest to researchers for the better part of a century. We report the synthesis and characterization of the pentazolate anion stabilized in a (N5)6(H3O)3(NH4)4Cl salt. The anion was generated by direct cleavage of the C–N bond in a multisubstituted arylpentazole using m-chloroperbenzoic acid and ferrous bisglycinate. The structure was confirmed by single-crystal x-ray diffraction analysis, which highlighted stabilization of the cyclo-N5ˉ ring by chloride, ammonium, and hydronium. Thermal analysis indicated the stability of the salt below 117°C on the basis of thermogravimetry-measured onset decomposition temperature.

The Study and Characterization of a Novel Structure of 1,3,5-Benzenetricarboxylic Acid

2013 ◽  
Vol 830 ◽  
pp. 202-206
Author(s):  
Hai Yan Tan ◽  
Cheng Liu ◽  
Jin Ping Wu
Keyword(s):  
Relevant Information ◽  
X Ray Diffraction ◽  
Monoclinic System ◽  
X Ray ◽  
Novel Structure ◽  
Ft Ir ◽  
Benzenetricarboxylic Acid ◽  
The Stability ◽  
Lamella Structure

A novel ten-interpenetrating structure of 1,3,5-benzenetricarboxylic acid was grown under solvothemal condition after heated it 16 hours. It was characterized by FT-IR, HNMR, X-ray diffraction, HRTEM. HRTEM obtain the relevant information of structural morphologies. The result of HRTEM showsed this material owned special lamella structure. X-ray diffraction showed the crystal of the new structure is of monoclinic system, space groupP1 with a=26.5039(17), b=16.4121(17),c=26.550(2)Å,α=90.00, β=91.533(2), γ=90.00, V=11544.4(17)Å3, Z=8, Dc=1.451g/cm3,μ=0.126mm-1,F(000)=5184, R=0.0891 and w (R)=0.1819 for 11318 observed reflection with I>2(I),hydrogen bond contributed to the stability of the structure. The fluorescence spectra indicated that the title compound had two stronger emission peak at 346nm and 400nm. Keywords:1, 3, 5-benzenetricarboxylic acid; novel structure; ten-interpenetrating

scholarly journals Microstructure Characterization of Welds in X5CrNiCuNb16-4 Steel in Overaged Condition

2019 ◽  
Vol 19 (1) ◽  
pp. 57-69
Author(s):  
A. Ziewiec ◽  
A. Zielińska-Lipiec ◽  
J. Kowalska ◽  
K. Ziewiec
Keyword(s):  
Electron Microscopy ◽  
Aging Time ◽  
Energy Dispersive Spectrometry ◽  
Solution Treatment ◽  
X Ray Diffraction ◽  
Density Distributions ◽  
Transmission Electron ◽  
Steel Welds ◽  
The Stability

AbstractThe paper presents the results of the investigation of microstructure of the welded X5CrNiCuNb16-4 (17-4PH) steel after solution treatment and aging at 620°C for different periods. The microstructure and the phase composition of the steel was investigated using light microscopy (LM), scanning electron microscopy (SEM), energy dispersive spectrometry (EDS), transmission electron microscopy (TEM) and the X-ray diffraction (XRD). Hardness was measured for samples aged at different times. Density distributions of Cu precipitates were established. The investigation has shown that the microstructure of the X5CrNiCuNb16-4 steel welds after aging at 620 ° C consists of tempered martensite, fine Cu precipitates and austenite. It was observed that the size of the Cu precipitates increases with increasing the aging time, what affects the decrease of hardness. Simultaneously, the quantity of reversed austenite increases with increase of aging time. It was revealed that enrichment of the austenite in Ni, Cu and C affects the increase of Ms, but this factor does not determine the stability of austenite.

scholarly journals Stability, spatial extension and extinction of an electric arc in aeronautical conditions of pressure under 540 V DC

2019 ◽  
Vol 87 (3) ◽  
pp. 30901
Author(s):  
Romaric Landfried ◽  
Mohamed Boukhlifa ◽  
Thierry Leblanc ◽  
Philippe Teste ◽  
Jonathan Andrea
Keyword(s):  
High Speed ◽  
Electric Arc ◽  
High Speed Camera ◽  
Arc Length ◽  
Electrode Gap ◽  
Arc Current ◽  
The Mean ◽  
The Stability ◽  
Energy Dissipated

This work deals with the characterization of DC electric arcs in aeronautical conditions of pressure (from 104 Pa to 105 Pa). Observations have been made with the help of a high speed camera and various characteristics of electric arc under 540 V DC have been studied: the stability arc length, the extinction gap, the arc duration and the mean energy dissipated in the arc. The arc current intensity range is 10–100 A. The obtained results show that the arc stability length, extinction electrode gap, arc duration and energy dissipation in the arc have a direct correlation with the pressure and the current in the circuit.

Processing and Characterization of Porous Ti2AlC Using Space Holder Technique

2016 ◽  
Vol 704 ◽  
pp. 197-203 ◽  
Author(s):  
Jesus Gonzalez-Julian ◽  
Martin Bram
Keyword(s):  
Low Cost ◽  
High Strength ◽  
Max Phase ◽  
Space Holder ◽  
Porous Ti ◽  
Low Thermal Expansion ◽  
Final Microstructure ◽  
Ammonium Hydrogen ◽  
Oxidation And Corrosion

Ti2AlC is one of the most promising MAX phase materials due to its combination of properties at high temperatures (> 800 °C) such as high strength, good oxidation and corrosion resistances, low thermal expansion, readily machinable, high thermal conductivity and nonsusceptibility to thermal shock. Porous structures based on Ti2AlC are excellent candidates for diverse applications such as heat exchangers and filters, although more systematic studies are required to implement this material. In this work, porous Ti2AlC material was obtained using a low cost and eco-friendly process, the space holder technique. Commercial Ti2AlC powder was mixed with different contents (30, 50 and 70 vol.%) of ammonium hydrogen bicarbonate (NH4HCO3) as space holder. Afterwards, the obtained powder was uniaxially pressed, followed by elimination of space holder by a heat treatment at low temperature. Finally, porous Ti2AlC structures were consolidated at 1350 °C under argon atmosphere. Processing, final microstructure and pore characterization of the consolidated materials are described in detail.

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