Comparative Study of the Current Transport Mechanisms in Ni2Si Ohmic Contacts on n- and p-Type Implanted 4H-SiC

2014 ◽  
Vol 778-780 ◽  
pp. 665-668 ◽  
Author(s):  
Marilena Vivona ◽  
Giuseppe Greco ◽  
Salvatore di Franco ◽  
Filippo Giannazzo ◽  
Fabrizio Roccaforte ◽  
...  
Keyword(s):  
Temperature Dependence ◽  
Ohmic Contacts ◽  
Electrical Characterization ◽  
Nickel Silicide ◽  
Specific Contact Resistance ◽  
Current Transport ◽  
Specific Contact ◽  
Thermionic Field Emission ◽  
P Type

The knowledge of the temperature behavior of Ohmic contacts is an important issue to understand the device operation. This work reports an electrical characterization as a function of the temperature carried out on nickel silicide (Ni2Si) Ohmic contacts, used both for n-type and p-type implanted 4H-SiC layers. The temperature dependence of the specific contact resistance suggested that a thermionic field emission mechanism dominates the current transport for contacts on p-type material, whereas a current transport by tunneling is likely occurring in the contacts on n-type implanted SiC. Furthermore, from the temperature dependence of the electrical characteristics, the activation energies for Al and P dopants were determined, resulting of 145 meV and 35 meV, respectively. The thermal stability of the electrical parameters has been demonstrated upon a long-term (up to ~100 hours) cycling in the temperature range 200-400°C.

Current Transport Mechanisms in Au-Free Metallizations for CMOS Compatible GaN HEMT Technology

2020 ◽  
Vol 1004 ◽  
pp. 725-730
Author(s):  
Fabrizio Roccaforte ◽  
Monia Spera ◽  
Salvatore Di Franco ◽  
Raffaella Lo Nigro ◽  
Patrick Fiorenza ◽  
...  
Keyword(s):  
Barrier Height ◽  
Ohmic Contacts ◽  
Specific Contact Resistance ◽  
Current Transport ◽  
Large Area ◽  
Si Substrates ◽  
Ohmic Behavior ◽  
Specific Contact ◽  
Thermionic Field Emission

Gallium nitride (GaN) and its AlGaN/GaN heterostructures grown on large area Si substrates are promising systems to fabricate power devices inside the existing Si CMOS lines. For this purpose, however, Au-free metallizations are required to avoid cross contaminations. In this paper, the mechanisms of current transport in Au-free metallization on AlGaN/GaN heterostructures are studied, with a focus on non-recessed Ti/Al/Ti Ohmic contacts. In particular, an Ohmic behavior of Ti/Al/Ti stacks was observed after an annealing at moderate temperature (600°C). The values of the specific contact resistance ρc decreased from 1.6×104 Ω.cm2 to 7×105 Ω.cm2 with increasing the annealing time from 60 to 180s. The temperature dependence of ρc indicated that the current flow is ruled by a thermionic field emission (TFE) mechanism, with barrier height values of 0.58 eV and 0.52 eV, respectively. Finally, preliminary results on the forward and reverse bias characterization of Au-free tungsten carbide (WC) Schottky contacts are presented. This contact exhibited a barrier height value of 0.82 eV.

High Quality Non-Alloyed Pt Ohmic Contacts to P-Type GaN Using Two-Step Surface Treatment

1999 ◽  
Vol 595 ◽  
Author(s):  
Ja-Soon Jang ◽  
Seong-Ju Park ◽  
Tae-Yeon Seong
Keyword(s):  
Surface Treatment ◽  
Ohmic Contacts ◽  
Specific Contact Resistance ◽  
Transport Mechanisms ◽  
High Quality ◽  
Ammonium Sulfide ◽  
Current Voltage ◽  
Specific Contact ◽  
Thermionic Field Emission ◽  
P Type

AbstractTwo-step surface-treatment is introduced to obtain low resistance Pt contacts to ptype GaN. The first step is performed after the mesa etching process using buffered oxide etch (BOE) and ammonium sulfide [(NH4)2Sx]. This is followed by the second step using BOE. The Pt contact, which was treated sequentially using ultrasonically boiled BOE (10 min) and boiled (NH4)2Sx (10 min), produces a specific contact resistance of 3.0 (±3.8)×10-5 Ωcm2. However, the contact, that was simply BOE-treated, yields 3.1 (±1.1)×10-2 Ωcm2. This indicates that the two-step surface treatment is promising technique for obtaining high quality ohmic contacts to p-GaN. Investigation of the electronic transport mechanisms using current-voltage-temperature (I-V-T) data indicates that thermionic field emission is dominant in the surface-treated Pt contacts.

Nano-Electro-Structural Evolution of Ni-Si Ohmic Contacts to 3C-SiC

2009 ◽  
Vol 615-617 ◽  
pp. 569-572
Author(s):  
Jens Eriksson ◽  
Fabrizio Roccaforte ◽  
Filippo Giannazzo ◽  
Raffaella Lo Nigro ◽  
Giuseppe Moschetti ◽  
...  
Keyword(s):  
Ohmic Contacts ◽  
Annealing Temperature ◽  
Structural Evolution ◽  
Electrical Characterization ◽  
Nickel Silicide ◽  
Specific Contact Resistance ◽  
Specific Contact ◽  
Nanoscale Measurements

This paper reports on the macro- and nanoscale electro-structural evolution, as a function of annealing temperature, of nickel-silicide Ohmic contacts to 3C-SiC, grown on 6H-SiC substrates by a Vapor-Liquid-Solid (VLS) technique. The structural and electrical characterization of the contacts, carried out by combining different techniques, showed a correlation between the annealing temperature and the electrical characteristics in both the macro- and the nanoscale measurements. Increasing the annealing temperature between 600 and 950 °C caused a gradual increase of the uniformity of the nanoscale current-distribution, with an accompanying reduction of the specific contact resistance from 5 x 10-5 to 8.4 x 10-6 Ωcm2. After high temperature annealing (950 °C) the structural composition of the contacts stabilized, as only the Ni2Si phase was detected. A comparison with previous literature findings suggests a superior crystalline quality of the single domain VLS 3C-SiC layers.

Pt:Ti Diffusion Barrier, Interconnect, and Simultaneous Ohmic Contacts to n- and p-Type 4H-SiC

2018 ◽  
Vol 924 ◽  
pp. 381-384 ◽  
Author(s):  
Robert S. Okojie ◽  
Dorothy Lukco
Keyword(s):  
Diffusion Barrier ◽  
Ohmic Contacts ◽  
Focused Ion Beam ◽  
Ion Beam ◽  
Specific Contact Resistance ◽  
Long Term Stability ◽  
Specific Contact ◽  
P Type ◽  
Fabrication Costs

We report the initial results of using co-sputtered Pt:Ti 80:20 at. % composition ratio metallization as a diffusion barrier against gold (Au) and oxygen (O), as an interconnect layer, as well as forming simultaneous ohmic contacts to n-and p-type 4H-SiC. Having a single conductor with such combined multi-functional attributes would appreciably reduce the fabrication costs, processing time and complexity that are inherent in the production of SiC based devices. Auger Electron Spectroscopy, Focused Ion Beam-assisted Field Emission Scanning Electron Microscopy and Energy Dispersive Spectroscopy analyses revealed no Au and O migration to the SiC contact surface and minimal diffusion through the Pt:Ti barrier layer after 15 minutes of exposure at 800 oC in atmosphere, thus offering potential long term stability of the ohmic contacts. Specific contact resistance values of 7 x 10-5 and 7.4 x 10-4 Ω-cm2 were obtained on the n (Nd=7 x 1018 cm-3) and p (Na=2 x 1020 cm-3) -type 4H-SiC, respectively. The resistivity of 75 μΩ-cm was obtained for the Pt:Ti layer that was sandwiched between two SiO2 layers and annealed in pure O ambient up to 900 °C, which offers promise as a high temperature interconnect metallization.

scholarly journals High Quality Non-Alloyed Pt Ohmic Contacts to P-Type GaN Using Two-Step Surface Treatment

2000 ◽  
Vol 5 (S1) ◽  
pp. 521-527
Author(s):  
Ja-Soon Jang ◽  
Seong-Ju Park ◽  
Tae-Yeon Seong
Keyword(s):  
Surface Treatment ◽  
Ohmic Contacts ◽  
Specific Contact Resistance ◽  
Transport Mechanisms ◽  
High Quality ◽  
Ammonium Sulfide ◽  
Current Voltage ◽  
Specific Contact ◽  
Thermionic Field Emission ◽  
P Type

Two-step surface-treatment is introduced to obtain low resistance Pt contacts to p-type GaN. The first step is performed after the mesa etching process using buffered oxide etch (BOE) and ammonium sulfide [(NH4)2Sx]. This is followed by the second step using BOE. The Pt contact, which was treated sequentially using ultrasonically boiled BOE (10 min) and boiled (NH4)2Sx (10 min), produces a specific contact resistance of 3.0 (±3.8)×10−5 Ωcm2. However, the contact, that was simply BOE-treated, yields 3.1 (±1.1)×10−2 Ωcm2. This indicates that the two-step surface treatment is promising technique for obtaining high quality ohmic contacts to p-GaN. Investigation of the electronic transport mechanisms using current-voltage-temperature (I-V-T) data indicates that thermionic field emission is dominant in the surface-treated Pt contacts.

scholarly journals Ohmic Contacts on p-Type Al-Implanted 4H-SiC Layers after Different Post-Implantation Annealings

Materials ◽  
2019 ◽  
Vol 12 (21) ◽  
pp. 3468 ◽  
Author(s):  
Monia Spera ◽  
Giuseppe Greco ◽  
Domenico Corso ◽  
Salvatore Di Franco ◽  
Andrea Severino ◽  
...  
Keyword(s):  
Ohmic Contacts ◽  
Device Fabrication ◽  
Electrical Activation ◽  
Specific Contact Resistance ◽  
Emission Model ◽  
Ohmic Behavior ◽  
Specific Contact ◽  
Thermionic Field Emission ◽  
P Type ◽  
Post Implantation

This paper reports on the electrical activation and Ohmic contact properties on p-type Al-implanted silicon carbide (4H-SiC). In particular, the contacts were formed on 4H-SiC-implanted layers, subjected to three different post-implantation annealing processes, at 1675 °C, 1175 °C, and 1825 °C. Under these post-implantation annealing conditions, the electrical activation of the Al dopant species increased from 39% to 56%. The Ti/Al/Ni contacts showed an Ohmic behavior after annealing at 950 °C. The specific contact resistance ρc could be lowered by a factor of 2.6 with the increase of the post-implantation annealing temperature. The result can be useful for application in device fabrication. Moreover, the dependence of ρc on the active acceptor concentration followed the thermionic field emission model, with a barrier height of 0.63 eV.

Study of Ti/Al/Ni Ohmic Contacts to p-Type Implanted 4H-SiC

2018 ◽  
Vol 924 ◽  
pp. 377-380 ◽  
Author(s):  
Marilena Vivona ◽  
Giuseppe Greco ◽  
Corrado Bongiorno ◽  
Salvatore di Franco ◽  
Raffaella Lo Nigro ◽  
...  
Keyword(s):  
Ohmic Contacts ◽  
Annealing Temperature ◽  
Specific Contact Resistance ◽  
Electrical Characteristics ◽  
Key Factors ◽  
Ohmic Behavior ◽  
Specific Contact ◽  
Thermionic Field Emission ◽  
P Type ◽  
Resistance Value

This work reports on the electrical and microstructural properties of Ti/Al/Ni contacts to p-type implanted 4H-SiC obtained by rapid thermal annealing of a metal stack of Ti (70 nm)/Al (200 nm)/Ni (50 nm). The contact characteristics were monitored at increasing value of the annealing temperature. The Ohmic behavior of the contact, with a specific contact resistance value of 2.3×10-4Ω·cm2, is obtained for an annealing at 950 °C. The structural analyses of the contact, carried out by XRD and TEM, reveal the occurrence of reactions, with the detection of the Al3Ni2and AlTi phases in the upper part of the contact and of an epitaxially oriented TiC layer at the interface. These reactions are considered the key factors in the formation of an Ohmic contact in our annealed Ti/Al/Ni system. The temperature-dependence study of the electrical characteristics reveals a predominant thermionic field emission (TFE) mechanism for the current conduction through the contact, with a barrier height of 0.56 eV.

Titanium Tungsten (TiW) for Ohmic contacts to n-and p-type 4H-SiC

2000 ◽  
Vol 640 ◽  
Author(s):  
S.-K. Lee ◽  
C.-M. Zetterling ◽  
M. Östling
Keyword(s):  
High Temperature ◽  
Contact Resistance ◽  
Ohmic Contacts ◽  
Specific Contact Resistance ◽  
Term Stability ◽  
Long Term Stability ◽  
Ohmic Behavior ◽  
Specific Contact ◽  
P Type

ABSTRACTIn the present work, we investigated sputtered titanium tungsten (TiW) contacts for Ohmic contacts to both n- and p-type 4H-SiC with long-term stability under high temperature (500°C).. Epitaxial layers with a doping concentration of 1.3×1019 and 6×1018 cm−3 were used. After high temperature annealing (>950°C) sputtered TiW contacts showed Ohmic behavior with good uniform distribution of the specific contact resistance. We obtained an average specific contact resistance (pc) of 4×10−5 Ωcm2 and 1.2 ∼ 1.7×10−4 Ωcm2 for p- and n-type, respectively from linear TLM measurement. We also found some variation of the specific contact resistance and the sheet resistance from our TLM measurement for p-type contacts. We will discuss this behavior with the measurement of SIMS. Long-term stability with a top-cap layer is also discussed

In-Based Ohmic Contacts to the Base Layer of GaAs-AlGaAs Heterojunction Bipolar Transistors

1990 ◽  
Vol 181 ◽  
Author(s):  
F. Ren ◽  
S. J. Pearton ◽  
W. S. Hobson ◽  
T. R. Fullowan ◽  
A. B. Emerson ◽  
...  
Keyword(s):  
Contact Resistance ◽  
Heterojunction Bipolar Transistors ◽  
Ohmic Contacts ◽  
Bipolar Transistors ◽  
Base Layer ◽  
Specific Contact Resistance ◽  
Current Transport ◽  
Specific Contact ◽  
P Type

ABSTRACTThe use of AuBe-In/Ag/Au p-ohmic contacts for the base layer of GaAs-AIGaAs heterojunction bipolar transistors (HBTs) is described. Annealing at 420°C for 20 sec produces a contact resistivity of 0.095 Ω mm and a specific contact resistance of l.5 × 10-7 Ω cm2, and the surface morphology of the contact is excellent. The role of the silver is as a diffusion barrier to prevent Au spiking into the base layer which could degrade the HBT performance. The presence of the In layer is highly desirable in order to reduce the contact resistance, probably by forming an InGaAs phase at the metal-GaAs interface. Beryllium acts as the p-type dopant, and the top Au layer is used to lower the contact sheet resistance. Current transport through the structure is dominated by tunneling through the barrier due to field emission in the highly doped base layer at p-type doping levels above ∼1019 cm−3

scholarly journals Thermally Stable Ohmic Contact to p-Type 4H-SiC Based on Ti3SiC2 Phase

2016 ◽  
Vol 858 ◽  
pp. 553-556 ◽  
Author(s):  
Tony Abi-Tannous ◽  
Maher Soueidan ◽  
Gabriel Ferro ◽  
Mihai Lazar ◽  
Christophe Raynaud ◽  
...  
Keyword(s):  
Thin Films ◽  
Electrical Properties ◽  
Magnetron Sputtering ◽  
Ohmic Contact ◽  
Room Temperature ◽  
Ohmic Contacts ◽  
Specific Contact Resistance ◽  
Specific Contact ◽  
Thermionic Field Emission ◽  
P Type

In this study, the electrical properties of Ti3SiC2 based ohmic contacts formed on p-type 4H-SiC(0001) 4°-off substrates were studied. The Ti3SiC2 thin films were grown by thermal annealing (from 900°C to 1200°C) of Ti50Al50 layer deposited by magnetron sputtering. XRD analyzes were performed on the samples to further investigate the compounds formed after annealing. Using TLM structures, the Specific Contact Resistance (SCR) at room temperature of all contacts was measured. The temperature dependence (up to 600°C) of the SCR was studied to understand the current mechanisms at the interface and to determine the barrier height value by fitting the experimental results using the thermionic field emission theory. Aging tests showed that Ti3SiC2 based contacts were stable up to 200h at 600°C under Ar.

Sign in / Sign up

Export Citation Format

Share Document