Effect of Nitrogen Content on Mechanical and Tribological Properties of HfCxNy Films Deposited by Reactive Magnetron Sputtering

2015 ◽  
Vol 817 ◽  
pp. 143-149
Author(s):  
Shuo Wang ◽  
Kan Zhang ◽  
Xin Guo ◽  
Su Xuan Du ◽  
Mao Wen ◽  
...  

Based on previous work on lubricant hard HfCxfilm, the HfCxNyfilmswere deposited by sputtering from theHf target in a mixture of discharging N2,Ar and CH4, and the N content in films was accurately controlled by changing the N2flow rate.Theintroduction of N into the films contributed to the presence of solid solution FCC-HfC(N) and FCC-HfNphase appeared at high N content in films. In addition, the a-C content in the filmsdecreasedwith increment ofN content in the films. In comparison with HfCxfilm, hardness of HfCxNyfilms were enhanced from 21 GPa to 25 GPa with N content rising to 6.8 at.% but then surplus N in the films impaired the hardness. The coefficient of friction and surface roughness for HfCxNyfilms increasedfrom 0.10 to 0.23 and 3.13 nm to 12.4 nm, respectively, with decreasing a-C content from 52.9 at.% to 46.3 at.%. However, the introduction of N into HfCxFilm improvedthe wear resistance of filmseffectively, and the specific friction rate for this HfCxNyfilm deposited at 8 sccm N2was only 6.17×10-7mm3/Nm about half of that of HfCxfilm (1.09×10-6mm3/Nm).

2020 ◽  
Vol 992 ◽  
pp. 745-750
Author(s):  
A.P. Vasilev ◽  
T.S. Struchkova ◽  
A.G. Alekseev

This paper presents the results from the investigation of effect the carbon fibers with tungsten disulfide on the mechanical and tribological properties of PTFE. Is carried out a comparison of mechanical and tribological properties of polymer composites PTFE-based with carbon fibers and PTFE with complex filler (carbon fibers with tungsten disulfide). It is shown that at a content of 8 wt.% CF+1 wt.% WS2 in PTFE, wear resistance increases significantly while maintaining the tensile strength, relative elongation at break and low coefficient of friction at the level of initial PTFE. The results of X-ray analysis and investigation of SEM supramolecular structure and friction surfaces of PTFE and polymer composites are presented. It is shown that the degree of crystallinity of polymer composites increases in comparison with the initial PTFE. The images of scanning electron microscope reveal that particles of tungsten disulfide concentrating on the friction surface is likely responsible to a reduction in the coefficient of friction and increase the wear resistance of PTFE-based polymer composites with complex fillers.


Author(s):  
M.N. Obaid ◽  
S.H. Radhi

Purpose: The number of people suffering from Degenerative Disc Disease (DDD) is increasing. The disease causes heavy pain and restrict a number of day-to-day life activities. In extreme cases, the degraded disc is removed under total disc replacement which is usually made up of Ultra-High Molecular Weight Polyethylene (UHMWPE). The material has astounding biocompatible characteristics mechanical properties and wear resistance. However, these characteristics are insufficient in arthroplasty application. Therefore, research investigations are ongoing to improve tribological properties through reinforcement that may result in a composite material of UHMWPE. Thus the current study is aimed at reinforcing UHMWPE with short fibres of polyesters to enhance the tribological properties and surface characteristic so as to improve wear resistance and nourish the fibroblast cells on synthetic disc. Design/methodology/approach: The researcher prepared UHMWPE composite material, reinforced with different weight fractions of short polyester fibres (2, 4, 6, 8 and 10% following hot press method. Further pin-on-disc device was used to study the tribological properties (coefficient of friction and volume of wear). The study tested surface roughness and surface characteristics by atomic force microscopy (AFM) device, hardness by shore D device, contact angle to study the effect of polyester short fibres on wettability of UHMWPE surface and tested the thermal properties and crystalline degree using Differential Scanning Calorimetry measurement (DSC) device. Findings: The results infer that the wear resistance got improved when using 2% w.t polyester though it got decreased initially. However, the value was still more than neat UHMWPE. There was a decrease observed in coefficient of friction, but after 4 w.t% polyester, the coefficient of friction got increased due to increasing percentage of fibres which make it harder and stiff compared to UHMWPE. There was a decline observed in surface roughness due to alignment of the fibres with smooth surface. The contact angle got increased in a moderate range while the roughness enhanced the growth of fibroblast cell. The hardness of composite material got increased, because the fibres turned stiffer and harder than the matrix. DSC results infer the improvements in thermal stability due to high thermal properties of polyester fibres compared to UHMWPE. The degree of crystallinity got increased which in turn enhanced wear resistance, especially at 6 w.t % polyester fibres. There was a mild increase observed in density since the density of polyester is higher than polymer. Research limitations/implications: The major challenge was the dispersion of fibres. Uniform distribution of fibres within the matrix (UHMWPE) was achieved through two steps of mixing processes such as mechanical mixture and twin extruder. In future studies, fatigue tests must be conducted to study the behaviour of prepared composite materials under fatigue cycle. Practical implications: A significant objective is how to connect among different properties to obtain good improvement in tribological and surface properties so as to enhance wear resistance and growth of fibrolase cells. Originality/value: In this study, polymeric short fibres were used as reinforcement with polymeric matrix to enhance the wettability of fibres with matrix. In this way, the bonding among them got increased which supports the tribological, surface, and crystalline behaviour.


2021 ◽  
Vol 16 (1) ◽  
pp. 43-48
Author(s):  
Michal Krbaťa ◽  
◽  
Jana Escherová ◽  

The paper deals with the change in mechanical properties and wear of 1.2842 universal tool steel after plasma nitriding, which is widely used to produce cutting tools with good durability and low operating costs. Plasma nitriding was performed at a temperature of 500 °C for 10-hour period in a standard N2 /H2 atmosphere with 1:3 gases ratio. Microstructure, phase structure, thickness of a nitriding layer and surface roughness of samples were measured with optical microscopes and a profilometer. Verification of a chemical composition was carried out on the BAS TASMAN Q4 device. Wear resistance was measured on a universal TRIBOLAB UTM 3 tribometer, through a, “pin on disc“ method. The results of experiments have shown that plasma nitriding process, significantly improves the mechanical and tribological properties of selected materials.


2015 ◽  
Vol 642 ◽  
pp. 184-189
Author(s):  
Yan Liang Su ◽  
Yueh Feng Lin

W(100-x)%Cx% coatings with different tungsten and carbon contents were deposited by unbalanced magnetron sputtering. The microstructures and mechanical properties of the W(100-x)%C x% coatings was characterized by scanning electron microscope (SEM), X-ray diffraction (XRD), nanoindentation and adhesion testing techniques. The tribological performance of the coatings was investigated using a pin-on-disc trobometer under dry conditions. Experimental results indicated that coating microstructure, mechanical properties and wear resistance varied according to the tungsten and carbon contents of the coatings. The W72%C28% coating had the highest hardness/elastic modulus (H/E) ratio. In the ball-on-disc wear tests, it was found that the W72%C28% coating exhibited the best wear resistance.


MRS Advances ◽  
2020 ◽  
Vol 5 (54-55) ◽  
pp. 2753-2762
Author(s):  
Mathew Brownell ◽  
Arun K. Nair

AbstractPolytetrafluoroethylene (PTFE) film is observed to increase surface roughness during annealing. Longer annealing times leads to greater surface roughness. The coefficient of friction of PTFE film is affected by the shape of microscale sized particles on the film surface. In this study, we investigate the coefficient of friction of PTFE films using a coarse-grained molecular dynamics model based on experimental observations. We observe how the variation in PTFE chain length and film density affect the topography of PTFE films. We also investigate how these properties of PTFE, and the indenter radius affect the coefficient of friction observed during surface scratch. We find that short PTFE chain lengths create a dense film with greater particle spacing, but longer chains form a mesh structure which reduces the density and creates overlapping portions of particles in the film. We develop a convolutional neural network to classify PTFE film surface and predict the coefficient of friction of a modeled film based solely on the equilibrated film topography. The accuracy of the network was seen to increase when the density and images of internal fiber orientation were added as input features. These results indicate that the coefficient of friction of PTFE films in part is governed by the internal structure of the film.


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