Assessment of Bulk Mechanical Properties of HDPE Hybrid Composite Filled with 1D/2D Nanofiller System

2018 ◽  
Vol 917 ◽  
pp. 12-16 ◽  
Author(s):  
Nitesh Dhar Badgayan ◽  
Santosh Kumar Sahu ◽  
Sutanu Samanta ◽  
Pattela Srinivasa Rama Sreekanth

Current work reports on evaluation of bulk mechanical properties of High Density Polyethylene (HDPE) reinforced with functionalized 1D (Multi Walled Carbon Nanotubes- (MWCNTs) and 2D (hexagonal-Boron Nitride Nanoplatelets-(h-BNNPs) fillers. Mechanical mixing and injection moulding technique was used to prepare the composites. Evaluation of bulk mechanical properties like hardness, yield stress, fracture stress, impact toughness and Young`s modulus was carried out. The optimum properties were exhibited by HDPE/0.25 MWCNT/0.1 BNNP. Hardness, yield stress, fracture stress, impact toughness and Young`s modulus was observed to increase by 93.84, 80.83, 59.23, 115 and 42.05% on comparison with pure HDPE. TEM images confirm the tubular and hexagonal morphology of MWCNT and h-BNNP. It is concluded from test results that addition of MWCNT and h-BNNP into HDPE has improvised mechanical properties.

2009 ◽  
Vol 08 (01n02) ◽  
pp. 23-27 ◽  
Author(s):  
KWABENA A. NARH ◽  
AHMED-TIJANI AGWEDICHAM ◽  
LAILA J. JALLO ◽  
KYONG Y. RHEE ◽  
JI H. LEE

Composites of polyethylene oxide and carbon nanotubes were produced by first deagglomerating highly agglomerated multi-walled carbon nanotubes in water, using a high-intensity ultrasonic probe, and then mixing with a solution of the polymer using a high-speed mixer. The deagglomeration of the nanotubes was carried out at different amplitudes of the vibrating ultrasonic probe. Differential scanning calorimetry results show an increase in melting temperature with increase in amplitude of sonication. Also, tensile test results show improved mechanical properties, with increased degree of deagglomeration of the nanotubes. SEM images show that the extent of nanotubes dispersion in the polymer matrix correlates with the extent of deagglomeration.


2011 ◽  
Vol 13 (2) ◽  
pp. 62-69 ◽  
Author(s):  
Maria Wladyka-Przybylak ◽  
Dorota Wesolek ◽  
Weronika Gieparda ◽  
Anna Boczkowska ◽  
Ewelina Ciecierska

The effect of the surface modification of carbon nanotubes on their dispersion in the epoxy matrix Functionalization of multi-walled carbon nanotubes (MWCNTs) has an effect on the dispersion of MWCNT in the epoxy matrix. Samples based on two kinds of epoxy resin and different weight percentage of MWCNTs (functionalized and non-functionalized) were prepared. Epoxy/carbon nanotubes composites were prepared by different mixing methods (ultrasounds and a combination of ultrasounds and mechanical mixing). CNTs modified with different functional groups were investigated. Surfactants were used to lower the surface tension of the liquid, which enabled easier spreading and reducing the interfacial tension. Solvents were also used to reduce the liquid viscosity. Some of them facilitate homogeneous dispersion of nanotubes in the resin. The properties of epoxy/nanotubes composites strongly depend on a uniform distribution of carbon nanotubes in the epoxy matrix. The type of epoxy resin, solvent, surfactant and mixing method for homogeneous dispersion of CNTs in the epoxy matrix was evaluated. The effect of CNTs functionalization type on their dispersion in the epoxy resins was evaluated on the basis of viscosity and microstructure studies.


2021 ◽  
Vol 3 (6) ◽  
Author(s):  
Seyed Ali Mirsalehi ◽  
Amir Ali Youzbashi ◽  
Amjad Sazgar

AbstractIn this study, epoxy hybrid nanocomposites reinforced by carbon fibers (CFs) were fabricated by a filament winding. To improve out-of-plane (transverse) mechanical properties, 0.5 and 1.0 Wt.% multi-walled carbon nanotubes (MWCNTs) were embedded into epoxy/CF composites. The MWCNTs were well dispersed into the epoxy resin without using any additives. The transverse mechanical properties of epoxy/MWCNT/CF hybrid nanocomposites were evaluated by the tensile test in the vertical direction to the CFs (90º tensile) and flexural tests. The fracture surfaces of composites were studied by scanning electron microscopy (SEM). The SEM observations showed that the bridging of the MWCNTs is one of the mechanisms of transverse mechanical properties enhancement in the epoxy/MWCNT/CF composites. The results of the 90º tensile test proved that the tensile strength and elongation at break of nanocomposite with 1.0 Wt.% MWCNTs improved up to 53% and 50% in comparison with epoxy/CF laminate composite, respectively. Furthermore, the flexural strength, secant modulus, and elongation of epoxy/1.0 Wt.% MWCNT/CF hybrid nanocomposite increased 15%, 7%, and 9% compared to epoxy/CF laminate composite, respectively.


2017 ◽  
Vol 54 (1) ◽  
pp. 41-44 ◽  
Author(s):  
Maria Adina Vulcan ◽  
Celina Damian ◽  
Paul Octavian Stanescu ◽  
Eugeniu Vasile ◽  
Razvan Petre ◽  
...  

This paper deals with the synthesis of polyurea and its use as polymer matrix for nanocomposites reinforced with multi-walled carbon nanotubes (MWCNT). Two types of materials were obtained during this research, the first cathegory uses the polyurea as matrix and the second one uses a mixture between epoxy resin and polyurea. The nanocomposites were characterized by Thermogravimetric Analysis (TGA), Dynamic Mechanical Analysis (DMA), Scanning Electron Microscopy (SEM) and Tensile Tests .The elastomeric features of nanocomposites were highlighted by the results which showed low value of Tg. Also higher thermal stability with ~40oC compared with commercial products (M20) were observed, but lower mechanical properties compared to neat polyurea.


2017 ◽  
Vol 51 (12) ◽  
pp. 1693-1701 ◽  
Author(s):  
EA Zakharychev ◽  
EN Razov ◽  
Yu D Semchikov ◽  
NS Zakharycheva ◽  
MA Kabina

This paper investigates the structure, length, and percentage of functional groups of multi-walled carbon nanotubes (CNT) depending on the time taken for functionalization in HNO3 and H2SO4 mixture. The carbon nanotube content and influence of functionalization time on mechanical properties of polymer composite materials based on epoxy matrix are studied. The extreme dependencies of mechanical properties of carbon nanotube functionalization time of polymer composites were established. The rise in tensile strength of obtained composites reaches 102% and elastic modulus reaches 227% as compared to that of unfilled polymer. The composites exhibited best mechanical properties by including carbon nanotube with 0.5 h functionalization time.


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