Hydrogen Diffusion in Metals Assisted by Stress: 2D Numerical Modelling and Analysis of Directionality

2014 ◽  
Vol 225 ◽  
pp. 33-38 ◽  
Author(s):  
Jesús Toribio ◽  
Viktor Kharin ◽  
Diego Vergara ◽  
Miguel Lorenzo

Hydrogen diffusion within a metal or alloy is conditioned by the stress-strain state therein. For that reason it is feasible to consider that hydrogen diffuses in the material obeying a Fick type diffusion law including an additional term to account for the effect of the stress state represented by the hydrostatic stress. In this paper the hydrogen transport by diffusion in metals is modelled in notched specimens where loading generates a triaxiality stress state. To this end, two different approaches of stress-assisted hydrogen diffusion, one-dimensional (1D) and two-dimensional (2D), were compared in the vicinity of the notch tip in four notched specimens with diverse triaxiality level at two different loading rates. The obtained results show that the 2D approach predicts lower values of hydrogen concentration than the 1D approach, so that a loss of directionality of hydrogen diffusion, depending on both notch geometry parameters (radius and depth) and loading rate, appears when a 2D approach is considered.

1978 ◽  
Vol 100 (4) ◽  
pp. 348-355 ◽  
Author(s):  
Alice M. Agogino

A review of the literature on testing of notched specimens is provided with emphasis on short-term notched bar tension tests. The effects of notch geometry, stress state, and smooth-bar tensile properties on notched ductility, notch sensitivity, and mode of fracture are discussed. For design against failure due to notch weakening, a simple criterion based on a limiting value of notched ductility is proposed. Notched ductility for the metals considered in this study, can be approximated by the reduction in and from a smooth tension test divided by a tensile stress triaxiality factor that is proportional to the ratio of hydrostatic to octahedral shearing stresses associated with the notch.


2016 ◽  
Vol 684 ◽  
pp. 67-73 ◽  
Author(s):  
Franz Berge ◽  
Thorsten Henseler ◽  
Christina Krbetschek ◽  
Madlen Ullmann ◽  
Rudolf Kawalla

Magnesium and its alloys have high potential for lightweight applications in the automotive and aerospace industries. In order to design parts for new applications with optimized mechanical properties and higher, more economic production rates, the forming limit behaviour of thin sheets (t < 1.0 mm) has to be known for different temperatures and loading rates. In this study, forming limit curves of 0.8 mm thick AZ31 sheet were measured for deformation at 200 °C and 250 °C and at loading rates of 1 mm/s and 10 mm/s with the Nakajima test. The investigations showed that an increase in temperature from 200 °C to 250 °C tends toward higher forming limit values for all stress states. In contrast, an increase in the loading rate from 1 mm/s to 10 mm/s induces a reduction in formability. It can be seen that the temperature, loading rate, and stress state influence the force-distance curves, the distribution of the local major strains, and the sheet thickness reduction.


2014 ◽  
Vol 225 ◽  
pp. 13-18 ◽  
Author(s):  
Jesús Toribio ◽  
Viktor Kharin

The present paper offers a continuum modelling of trap-affected hydrogen diffusion in metals and alloys, accounting for different physical variables of both macroscopic nature (i.e., related to continuum mechanics, e.g., stress and strain) and microscopic characteristics (material microstructure, traps, etc.). To this end, the model of hydrogen diffusion assisted by the gradients of both hydrostatic stress and cumulative plastic strain,stress-and-strain assisted hydrogen diffusion, proposed and frequently used by the authors of the present paper (Toribio & Kharin) is analysed in addition to other well-known models such as those proposed by (i) McNabb & Foster, (ii) Oriani, (iii) Leblond & Dubois, (iv) Sofronis & McMeeking, (v) Krom and Bakker, showing their physical and mathematical differences and similarities to account for different physical variables.


2007 ◽  
Vol 55 (11) ◽  
pp. 121-126 ◽  
Author(s):  
M. von Sperling ◽  
J.G.B. de Andrada ◽  
W.R. de Melo Júnior

A system comprising a UASB reactor, shallow polishing ponds and shallow coarse filters, treating actual wastewater from the city of Belo Horizonte, Brazil, has been evaluated. The main focus of the research was to compare grain sizes and hydraulic loading rates in the coarse filters. Two filters operating in parallel were investigated, with the following grain sizes: Filter 1: 3 to 10 cm; Filter 2: 8 to 20 cm. Two hydraulic loading rates were tested: 0.5 and 1.0 m3/m3.d. The filter with the lower rock size had a better performance than the filter with the larger rock size in the removal of SS and, as a consequence, BOD and COD. A better performance was obtained with the hydraulic loading rate of 0.5 m3/m3.d, as compared to the rate of 1.0 m3/m3.d. The effluent quality during the period with the lower loading rate was very good for discharge into water bodies or for agricultural reuse (median effluent concentrations from Filter 1: BOD: 20 mg/L; COD: 106 mg/L; SS: 28 mg/L; E. coli: 528 MPN/100 mL).


2017 ◽  
Vol 29 (5) ◽  
pp. 883-895 ◽  
Author(s):  
Md Abu S Shohag ◽  
Zhengqian Jiang ◽  
Emily C Hammel ◽  
Lucas Braga Carani ◽  
David O Olawale ◽  
...  

Real-time load monitoring of critical civil and mechanical structures especially dynamic structures such as wind turbine blades is imperative for longer service life. This article proposed a novel sensor system based on the proprietary in situ triboluminescent optical fiber (ITOF) sensor for dynamic load monitoring. The new ITOF sensor patch consists of an ITOF sensor network with micro-exciters integrated within a polymer matrix. The sensor patch was subjected to repeated flexural loading and produced triboluminescent emissions due to the friction between micro-exciters and ITOF sensors corresponding to each loading cycle. The friction-induced triboluminescent intensity directly depends on the loading rate, the coefficient of friction, and the applied load on patch. In general, the triboluminescent intensity increases exponentially with an increase in load. Additionally, the sensor patches comprising the coarser micro-exciters exhibited better results. Similarly, better results were achieved at higher loading rates although a threshold loading rate is required to excite the triboluminescent crystals for this sample configuration. The proposed new sensor has the ability to monitor dynamic continuous applied loads.


2003 ◽  
Vol 18 (4) ◽  
pp. 755-757 ◽  
Author(s):  
W. H. Jiang ◽  
M. Atzmon

Plastic deformation of amorphous Al90Fe5Gd5 was investigated using nanoindentation and atomic force microscopy. While serrated flow was detected only at high loading rates, shear bands were observed for all loading rates, ranging from 1 to 100 nm/s. However, the details of shear-band formation depend on the loading rate.


2018 ◽  
Vol 64 (246) ◽  
pp. 543-554 ◽  
Author(s):  
ACHILLE CAPELLI ◽  
INGRID REIWEGER ◽  
JÜRG SCHWEIZER

ABSTRACTSnow slab avalanches are caused by cracks forming and propagating in a weak snow layer below a cohesive slab. The gradual damage process leading to the formation of the initial failure within the weak layer (WL) is still not entirely understood. To this end, we designed a novel test apparatus that allows performing loading experiments with large snow samples (0.25 m2) including a WL at different loading rates and simultaneously monitoring the acoustic emissions (AE) response. By analyzing the AE generated by micro-cracking, we studied the evolution of the damage process preceding snow failure. At fast loading rates, the exponent of the AE energy distribution (b-value) gradually changed, and both the energy rate and the inverse waiting time increased exponentially with increasing load. These changes in AE signature indicate a transition from small to large events and an acceleration of the damage processes leading to brittle failure. For the experiments at slow loading rate, these changes in the AE signature were not or only partially present, even if the sample failed, indicating a different evolution of the damage process. The observed characteristics in AE response provide new insights on how to model snow failure as a critical phenomenon.


1983 ◽  
Vol 15 (8-9) ◽  
pp. 359-368 ◽  
Author(s):  
L van den Berg ◽  
K J Kennedy

Cheese whey and a dilute waste from a cheese factory with a Chemical Oxygen Demand of 66,000 and 4,000 mg (COD)/L respectively, were treated at high loading rates in 0.7 to 1.2 L downflow anaerobic stationary fixed film reactors and an upflow sludge bed reactor. In downflow stationary fixed film reactors treating cheese whey, COD removal efficiencies of 97% were achieved at a loading rate of 5 kg COD/m3/day and 92% at a maximum loading rate of 22 kg COD/m3/day. With dairy plant waste, loading rates of up to 15 kg COD/m3/day were possible with COD removal efficiencies averaging 75%, decreasing slightly with increasing loading rates. In an upflow sludge bed reactor the COD removal efficiency of dairy plant waste, decreased from 87% at 5 kg COD/m3/day to 73% at 15 kg COD/m3/day. A stationary fixed film reactor treating a skim milk powder waste (4,000 ppm) could only be operated at up to 10 kg COD/m3/day with a treatment efficiency of 72%. Methane was produced from all wastes at rates corresponding to 0.32 m3 CH4 (0°C, 1 atm) per kg COD removed. Results show that stationary fixed film reactors are capable of treating dairy wastes at high loading rates and high COD removal efficiencies.


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