scholarly journals Specific features of sorption kinetics of heavy metal ions with polysaccharide materials from aqueous media

2017 ◽  
Vol 5 ◽  
2018 ◽  
Vol 77 (10) ◽  
pp. 2355-2368 ◽  
Author(s):  
Khalida Naseem ◽  
Zahoor H. Farooqi ◽  
Muhammad Z. Ur Rehman ◽  
Muhammad A. Ur Rehman ◽  
Robina Begum ◽  
...  

Abstract This review is based on the adsorption characteristics of sorghum (Sorghum bicolor) for removal of heavy metals from aqueous media. Different parameters like pH, temperature of the medium, sorghum concentration, sorghum particle size, contact time, stirring speed and heavy metal concentration control the adsorption efficiency of sorghum biomass for heavy metal ions. Sorghum biomass showed maximum efficiency for removal of heavy metal ions in the pH range of 5 to 6. It is an agricultural waste and is regarded as the cheapest biosorbent, having high adsorption capacity for heavy metals as compared to other reported adsorbents, for the treatment of heavy metal polluted wastewater. Adsorption of heavy metal ions onto sorghum biomass follows pseudo second order kinetics. Best fitted adsorption isotherm models for removal of heavy metal ions on sorghum biomass are Langmuir and Freundlich adsorption isotherm models. Thermodynamic aspects of heavy metal ions adsorption onto sorghum biomass have also been elaborated in this review article. How adsorption efficiency of sorghum biomass can be improved by different physical and chemical treatments in future has also been elaborated. This review article will be highly useful for researchers working in the field of water treatment via biosorption processing. The quantitative demonstrated efficiency of sorghum biomass for various heavy metal ions has also been highlighted in different sections of this review article.


Sensors ◽  
2019 ◽  
Vol 19 (3) ◽  
pp. 599 ◽  
Author(s):  
Nerea De Acha ◽  
César Elosúa ◽  
Jesús Corres ◽  
Francisco Arregui

Due to the risks that water contamination implies for human health and environmental protection, monitoring the quality of water is a major concern of the present era. Therefore, in recent years several efforts have been dedicated to the development of fast, sensitive, and selective sensors for the detection of heavy metal ions. In particular, fluorescent sensors have gained in popularity due to their interesting features, such as high specificity, sensitivity, and reversibility. Thus, this review is devoted to the recent advances in fluorescent sensors for the monitoring of these contaminants, and special focus is placed on those devices based on fluorescent aptasensors, quantum dots, and organic dyes.


Materials ◽  
2020 ◽  
Vol 13 (19) ◽  
pp. 4373
Author(s):  
Danil Kurshanov ◽  
Pavel Khavlyuk ◽  
Mihail Baranov ◽  
Aliaksei Dubavik ◽  
Andrei Rybin ◽  
...  

Heavy metal ions are not subject to biodegradation and could cause the environmental pollution of natural resources and water. Many of the heavy metals are highly toxic and dangerous to human health, even at a minimum amount. This work considered an optical method for detecting heavy metal ions using colloidal luminescent semiconductor quantum dots (QDs). Over the past decade, QDs have been used in the development of sensitive fluorescence sensors for ions of heavy metal. In this work, we combined the fluorescent properties of AgInS2/ZnS ternary QDs and the magnetism of superparamagnetic Fe3O4 nanoparticles embedded in a matrix of porous calcium carbonate microspheres for the detection of toxic ions of heavy metal: Co2+, Ni2+, and Pb2+. We demonstrate a relationship between the level of quenching of the photoluminescence of sensors under exposure to the heavy metal ions and the concentration of these ions, allowing their detection in aqueous solutions at concentrations of Co2+, Ni2+, and Pb2+ as low as ≈0.01 ppm, ≈0.1 ppm, and ≈0.01 ppm, respectively. It also has importance for application of the ability to concentrate and extract the sensor with analytes from the solution using a magnetic field.


Minerals ◽  
2019 ◽  
Vol 9 (5) ◽  
pp. 291 ◽  
Author(s):  
Dongxiao Ouyang ◽  
Yuting Zhuo ◽  
Liang Hu ◽  
Qiang Zeng ◽  
Yuehua Hu ◽  
...  

Tailings generated from mineral processing have attracted worldwide concerns due to creating serious environmental pollution. In this work, porous adsorbents were prepared as a porous block by using silicate tailings, which can adsorb heavy metal ions from the solution and are easy to separate. The synthesized silicate porous material (SPM) was characterized by X-ray diffraction (XRD), Brunner–Emmet–Teller (BET), and scanning electron microscope (SEM). The material presented a surface area of 3.40 m2⸱g−1, a porosity of 54%, and the compressive strength of 0.6 MPa. The maximum adsorption capacities of Pb2+, Cd2+, and Cu2+ by SPM were 44.83 mg·g−1, 35.36 mg·g−1, and 32.26 mg·g−1, respectively. The experimental data were fitted well by the Freundlich and Langmuir adsorption models. The kinetics of the adsorption process were fitted well by the pseudo-first order kinetic equation. These results show that the porous materials prepared with silicate tailings could act as an effective and low-cost adsorbent for the removal of heavy metal ions from wastewater. This study may provide a new thought on the high-value utilization of tailing for alleviating environmental pressure.


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