scholarly journals ELUCIDATION OF ELECTROMAGNETIC WAVE EFFECT AND OUTGOING OF FUTURE TREND IN MICROWAVE CHEMISTRY AND BIOLOGY

2019 ◽  
Author(s):  
Satoshi Horikoshi
Keyword(s):  
Electromagnetic Wave ◽  
Chemical Reactions ◽  
Chemical Reaction ◽  
High Power ◽  
Electromagnetic Waves ◽  
Academic Science ◽  
Specific Substrate ◽  
Microwave Chemistry ◽  
Wave Effect ◽  
Microwave Effect

The German chemist Theodor Grotthuss was the first to formulate the first law of photochemistry in 1817; he postulated that a reaction could be driven by light when the energy of light is absorbed by molecules [1]. After that, photochemistry has greatly contributed to the development of photography. In addition, second laws of photochemistry (Stark-Einstein law) was enacted, and these two laws have elevated photochemistry as an academic (science) discipline over the last one hundred years. In addition, because of advances in light sources and various devices (engineering), such materials and processes as photocatalysts, organic solar cells, photopolymerization, quantum dots, and photochromism (among others) are currently being applied in various other fields.                The next significant surge in chemistry is microwave chemistry wherein microwaves, which represent electromagnetic waves other than light, were introduced as a driving force in the chemical reaction domain in the late 1980s. There are three characteristics in this chemistry when using microwaves. The first is the high heating efficiency caused by the energy of the microwaves that directly reach and are absorbed by the substance. The second is the selectivity with which a specific substrate is heated, while the third characteristic is the enhancement of chemical syntheses by the microwaves’ electromagnetic wave energy, often referred to as the microwave effect (or non-thermal effect). The phenomenon of the microwave effect (third characteristic) impacting chemical reactions has been summarized in much of the relevant literature, however, the reason why the microwave effect has not been clarified to anyone’s satisfaction is that the term microwave effect in microwave chemistry includes numerous factors. In order to fix microwaves in the chemical field, it is urgent to develop laws of “microwavechemistry”, and to do it is necessary to systematization against the phenomenas of electromagnetic waves for materials and reactions.         One of the reasons for the dramatic growth in photochemistry is the development of high power laser technology. In recent years, coherent semiconductor generator with the generating high power microwaves have become easy to get, so “microwavechemistry” can proceed to the next stage. We examined that the phenomena as microwave electromagnetic waves in chemical reactions by using a semiconductor generator and a power sensor. And, it clarified that the reaction rate and yield of a very small part of the chemical reaction change with the unique phenomenon to electromagnetic waves [2]. On the other hand, generally, as plants, enzymes, biological substances temperature rises, it inhibits growth and reaction. This phenomenon was used to overcome the electromagnetic wave effect. We have succeeded in improving these activities by irradiating weak microwaves which do not increase these temperatures [3]. If microwave heating is given to them, it will work negatively. In this invited presentation, it introduces the possibility of electromagnetic wave effect(s) in these and explain its industrial application.

Microwaves: Application in Electron Microscopy

1990 ◽  
Vol 48 (3) ◽  
pp. 140-141
Author(s):  
Anthony S-Y Leong ◽  
David W Gove
Keyword(s):  
Electron Microscopy ◽  
Light Microscopy ◽  
Chemical Reactions ◽  
Electromagnetic Waves ◽  
Tissue Fixation ◽  
Primary Method ◽  
Dipolar Molecules ◽  
Wide Range ◽  
Time Required ◽  
Cryostat Sections

Microwaves (MW) are electromagnetic waves which are commonly generated at a frequency of 2.45 GHz. When dipolar molecules such as water, the polar side chains of proteins and other molecules with an uneven distribution of electrical charge are exposed to such non-ionizing radiation, they oscillate through 180° at a rate of 2,450 million cycles/s. This rapid kinetic movement results in accelerated chemical reactions and produces instantaneous heat. MWs have recently been applied to a wide range of procedures for light microscopy. MWs generated by domestic ovens have been used as a primary method of tissue fixation, it has been applied to the various stages of tissue processing as well as to a wide variety of staining procedures. This use of MWs has not only resulted in drastic reductions in the time required for tissue fixation, processing and staining, but have also produced better cytologic images in cryostat sections, and more importantly, have resulted in better preservation of cellular antigens.

Detection of delamination in composites by using electromagnetic penetrating radar

2014 ◽  
Vol 5 (2) ◽  
pp. 151-156
Author(s):  
Z. Mechbal ◽  
A. Khamlichi
Keyword(s):  
Electromagnetic Wave ◽  
Electromagnetic Waves ◽  
Electromagnetic Wave Propagation ◽  
Wave Reflection ◽  
Image Features ◽  
Partial Reflection ◽  
Straight Path ◽  
Reflected Signal ◽  
Short Time ◽  
Intervening Factors

Composites made from E-glass/epoxy or aramid/epoxy are frequently used in aircraft and aerospace industries. These materials are prone to suffer from the presence of delamination, which can reduce severely the performance of aircrafts and even threaten their safety. Since electric conductivity of these composites is rather small, they can propagate electromagnetic waves. Detection of delamination damage can then be monitored by using an electromagnetic penetrating radar scanner, which consists of emitting waves having the form of short time pulses that are centered on a given work frequency. While propagating, these waves undergo partial reflection when running into an obstacle or a material discontinuity. Habitually, the radar is moved at constant speed along a straight path and the reflected signal is processed as a radargram that gives the reflected energy as function of the two-way time and the antenna position.In this work, modeling of electromagnetic wave propagation in composites made from E-glass/epoxy was performed analytically. The electromagnetic wave reflection from a delamination defect was analyzed as function of key intervening factors which include the defect extent and depth, as well as the work frequency. Various simulations were performed and the obtained results have enabled to correlate the reflection pattern image features to the actual delamination defect characteristics which can provide quantification of delamination.

New Approach to the Theory of Circular Dichroism

1998 ◽  
Vol 63 (8) ◽  
pp. 1187-1201 ◽  
Author(s):  
Jaroslav Zamastil ◽  
Lubomír Skála ◽  
Petr Pančoška ◽  
Oldřich Bílek
Keyword(s):  
Electromagnetic Wave ◽  
Circular Dichroism ◽  
Electromagnetic Waves ◽  
Maxwell Equations ◽  
Optically Active ◽  
Semiclassical Approach ◽  
New Approach ◽  
Isotropic Media ◽  
New Formula ◽  
Circular Dichroïsm

Using the semiclassical approach for the description of the propagation of the electromagnetic waves in optically active isotropic media we derive a new formula for the circular dichroism parameter. The theory is based on the idea of the time damped electromagnetic wave interacting with the molecules of the sample. In this theory, the Lambert-Beer law need not be taken as an empirical law, however, it follows naturally from the requirement that the electromagnetic wave obeys the Maxwell equations.

scholarly journals Preparation and electromagnetic properties characterization of reduced graphene oxide/strontium hexaferrite nanocomposites

2020 ◽  
Vol 9 (1) ◽  
pp. 105-114 ◽  
Author(s):  
Shumin Du ◽  
Huaiyin Chen ◽  
Ruoyu Hong
Keyword(s):  
Electromagnetic Wave ◽  
Environmental Pollution ◽  
Electromagnetic Interference ◽  
Electromagnetic Waves ◽  
Rapid Development ◽  
Living Environment ◽  
World Health ◽  
Electromagnetic Properties ◽  
Strontium Hexaferrite ◽  
Wave Radiation

AbstractWith the rapid development of electronics and information technology, electronics and electrical equipment have been widely used in our daily lives. The living environment is full of electromagnetic waves of various frequencies and energy. Electromagnetic wave radiation has evolved into a new type of environmental pollution that has been listed by the WHO (World Health Organization) as the fourth largest source of environmental pollution after water, atmosphere, and noise. Studies have shown that when electromagnetic wave radiation is too much, it can cause neurological disorders. And electromagnetic interference will cause the abnormal operation of medical equipment, precision instruments and other equipment, and therefore cause incalculable consequences. Therefore, electromagnetic protection has become a hot issue of concern to the social and scientific circles.

Normal approximations for distributions arising in the stochastic approach to chemical reaction kinetics

1981 ◽  
Vol 18 (01) ◽  
pp. 263-267 ◽  
Author(s):  
F. D. J. Dunstan ◽  
J. F. Reynolds
Keyword(s):  
Reaction Kinetics ◽  
Chemical Reactions ◽  
Chemical Reaction ◽  
Stochastic Approach ◽  
Algebraic Functions ◽  
Chemical Reaction Kinetics ◽  
Normal Approximations ◽  
Formal Solutions

Earlier stochastic analyses of chemical reactions have provided formal solutions which are unsuitable for most purposes in that they are expressed in terms of complex algebraic functions. Normal approximations are derived here for solutions to a variety of reactions. Using these, it is possible to investigate the level at which the classical deterministic solutions become inadequate. This is important in fields such as radioimmunoassay.

Transmissive 2-bit anisotropic coding metasurface

2022 ◽  
Author(s):  
Pengtao Lai ◽  
Zenglin Li ◽  
Wei Wang ◽  
Jia Qu ◽  
Liang Wei Wu ◽  
...  
Keyword(s):  
Angular Momentum ◽  
Electromagnetic Wave ◽  
Circular Polarization ◽  
Orbital Angular Momentum ◽  
Electromagnetic Waves ◽  
Beam Splitter ◽  
Far Field ◽  
Polarization Conversion ◽  
Field Patterns ◽  
Phase Profile

Abstract Coding metasurfaces have attracted tremendous interests due to unique capabilities of manipulating electromagnetic wave. However, archiving transmissive coding metasurface is still challenging. Here we propose a transmissive anisotropic coding metasurface that enables the independent control of two orthogonal polarizations. The polarization beam splitter and the OAM generator have been studied as typical applications of anisotropic 2-bit coding metasurface. The simulated far field patterns illustrate that the x and y polarized electromagnetic waves are deflected into two different directions, respectively. The anisotropic coding metasurface has been experimentally verified to realize an orbital angular momentum (OAM) beam with l = 2 of right-handed polarized wave, resulting from both contributions from linear-to-circular polarization conversion and the phase profile modulation. This work is beneficial to enrich the polarization manipulation field and develop transmissive coding metasurfaces.

scholarly journals Mapping the Space of Chemical Reactions using Attention-Based Neural Networks

2020 ◽  
Author(s):  
Philippe Schwaller ◽  
Daniel Probst ◽  
Alain C. Vaucher ◽  
Vishnu H Nair ◽  
David Kreutter ◽  
...  
Keyword(s):  
Neural Networks ◽  
Reaction Center ◽  
Chemical Reactions ◽  
Chemical Reaction ◽  
Classification Accuracy ◽  
Similarity Searching ◽  
Reaction Space ◽  
Fine Grained ◽  
Visual Clustering ◽  
Better Than

<div><div><div><p>Organic reactions are usually assigned to classes grouping reactions with similar reagents and mechanisms. Reaction classes facilitate communication of complex concepts and efficient navigation through chemical reaction space. However, the classification process is a tedious task, requiring the identification of the corresponding reaction class template via annotation of the number of molecules in the reactions, the reaction center and the distinction between reactants and reagents. In this work, we show that transformer-based models can infer reaction classes from non-annotated, simple text-based representations of chemical reactions. Our best model reaches a classification accuracy of 98.2%. We also show that the learned representations can be used as reaction fingerprints which capture fine-grained differences between reaction classes better than traditional reaction fingerprints. The unprecedented insights into chemical reaction space enabled by our learned fingerprints is illustrated by an interactive reaction atlas providing visual clustering and similarity searching. </p><p><br></p><p>Code: https://github.com/rxn4chemistry/rxnfp</p><p>Tutorials: https://rxn4chemistry.github.io/rxnfp/</p><p>Interactive reaction atlas: https://rxn4chemistry.github.io/rxnfp//tmaps/tmap_ft_10k.html</p></div></div></div>

scholarly journals Microwave Assisted Synthesis of Organic Compounds and Nanomaterials

2021 ◽  
Author(s):  
Anjali Jha
Keyword(s):  
Green Chemistry ◽  
Organic Synthesis ◽  
Electric Fields ◽  
Chemical Reactions ◽  
Dipole Moments ◽  
Electric Heating ◽  
Microwave Assisted Synthesis ◽  
Microwave Chemistry ◽  
Microwave Assisted ◽  
Promising Area

In the Conventional laboratory or industry heating technique involve Bunsen burner, heating mental/hot plates and electric heating ovens. To produce a variety of useful compounds for betterment of mankind, the Microwave Chemistry was introduced in year 1955 and finds a place in one of the Green chemistry method. In Microwave chemistry is the science of applying microwave radiation to chemical reactions. Microwaves act as high frequency electric fields and will generally heat any material containing mobile electric charges, such as polar molecules in a solvent or conducting ions in a solid. Polar solvents are heated as their component molecules are forced to rotate with the field and lose energy in collisions i.e. the dipole moments of molecules are important in order to proceed with the chemical reactions in this method. It can be termed as microwave-assisted organic synthesis (MAOS), Microwave-Enhanced Chemistry (MEC) or Microwave-organic Reaction Enhancement synthesis (MORE). Microwave-Assisted Syntheses is a promising area of modern Green Chemistry could be adopted to save the earth.

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