Modelling and assimilation of lidar signals over Greater Paris during the MEGAPOLI summer campaign

Abstract. In this study, we investigate the ability of the chemistry transport model (CTM) Polair3D of the air quality modelling platform Polyphemus to simulate lidar backscattered profiles from model aerosol concentration outputs. This investigation is an important preprocessing stage of data assimilation (validation of the observation operator). To do so, simulated lidar signals are compared to hourly lidar observations performed during the MEGAPOLI (Megacities: Emissions, urban, regional and Global Atmospheric POLlution and climate effects, and Integrated tools for assessment and mitigation) summer experiment in July 2009, when a ground-based mobile lidar was deployed around Paris on-board a van. The comparison is performed for six different measurement days, 1, 4, 16, 21, 26 and 29 July 2009, corresponding to different levels of pollution and different atmospheric conditions. Overall, Polyphemus well reproduces the vertical distribution of lidar signals and their temporal variability, especially for 1, 16, 26 and 29 July 2009. Discrepancies on 4 and 21 July 2009 are due to high-altitude aerosol layers, which are not well modelled. In the second part of this study, two new algorithms for assimilating lidar observations based on the optimal interpolation method are presented. One algorithm analyses PM10 (particulate matter with diameter less than 10 μm) concentrations. Another analyses PM2.5 (particulate matter with diameter less than 2.5 μm) and PM2.5–10 (particulate matter with a diameter higher than 2.5 μm and lower than 10 μm) concentrations separately. The aerosol simulations without and with lidar data assimilation (DA) are evaluated using the Airparif (a regional operational network in charge of air quality survey around the Paris area) database to demonstrate the feasibility and usefulness of assimilating lidar profiles for aerosol forecasts. The evaluation shows that lidar DA is more efficient at correcting PM10 than PM2.5, probably because PM2.5 is better modelled than PM10. Furthermore, the algorithm which analyses both PM2.5and PM2.5–10 provides the best scores for PM10. The averaged root-mean-square error (RMSE) of PM10 is 11.63 μg m−3 with DA (PM2.5 and PM2.5–10), compared to 13.69 μg m−3 with DA (PM10) and 17.74 μg m−3 without DA on 1 July 2009. The averaged RMSE of PM10 is 4.73 μg m−3 with DA (PM2.5 and PM2.5–10), against 6.08 μg m−3 with DA (PM10) and 6.67 μg m−3 without DA on 26 July 2009.

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Modelling and assimilation of lidar signals over Greater Paris during the MEGAPOLI summer campaign

Atmospheric Chemistry and Physics Discussions ◽

10.5194/acpd-13-27115-2013 ◽

2013 ◽

Vol 13 (10) ◽

pp. 27115-27161

Author(s):

Y. Wang ◽

K. N. Sartelet ◽

M. Bocquet ◽

P. Chazette

Keyword(s):

Air Quality ◽

Transport Model ◽

Atmospheric Conditions ◽

Chemistry Transport Model ◽

Model Aerosol ◽

Paris Area ◽

The Vertical Distribution ◽

Lidar Observations ◽

Different Levels ◽

New Algorithms

Abstract. In this study, we investigate the ability of the chemistry transport model (CTM) Polair3D of the air quality modelling platform Polyphemus of simulating lidar backscattered profiles from model aerosol concentration outputs. To do so, simulated lidar signals are compared to hourly lidar observations performed during the MEGAPOLI (Megacities: Emissions, urban, regional and Global Atmospheric POLlution and climate effects, and Integrated tools for assessment and mitigation) summer experiment in July 2009, where a ground-based mobile lidar was deployed around Paris on-board a van. The comparison is performed for six different measurement days, 1, 4, 16, 21, 26 and 29 July 2009, corresponding to different levels of pollution and different atmospheric conditions. Polyphemus correctly reproduces the vertical distribution of aerosol optical properties and their temporal variability. In the second part of this study, two new algorithms for assimilating lidar observations are presented. The aerosol simulations without and with lidar data assimilation are evaluated using the Airparif (a regional operational network in charge of air quality survey around the Paris area) database to demonstrate the feasibility and the usefulness of assimilating lidar profiles for aerosol forecasts.

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Assimilation of OMI NO<sub>2</sub> retrievals into the limited-area chemistry-transport model DEHM (V2009.0) with a 3-D OI algorithm

Geoscientific Model Development ◽

10.5194/gmd-6-1-2013 ◽

2013 ◽

Vol 6 (1) ◽

pp. 1-16 ◽

Cited By ~ 17

Author(s):

J. D. Silver ◽

J. Brandt ◽

M. Hvidberg ◽

J. Frydendall ◽

J. H. Christensen

Keyword(s):

Air Quality ◽

Data Assimilation ◽

Transport Model ◽

Initial Conditions ◽

Three Dimensional ◽

Optimal Interpolation ◽

Limited Area ◽

Background Error ◽

Geophysical Field ◽

Chemistry Transport Model

Abstract. Data assimilation is the process of combining real-world observations with a modelled geophysical field. The increasing abundance of satellite retrievals of atmospheric trace gases makes chemical data assimilation an increasingly viable method for deriving more accurate analysed fields and initial conditions for air quality forecasts. We implemented a three-dimensional optimal interpolation (OI) scheme to assimilate retrievals of NO2 tropospheric columns from the Ozone Monitoring Instrument into the Danish Eulerian Hemispheric Model (DEHM, version V2009.0), a three-dimensional, regional-scale, offline chemistry-transport model. The background error covariance matrix, B, was estimated based on differences in the NO2 concentration field between paired simulations using different meteorological inputs. Background error correlations were modelled as non-separable, horizontally homogeneous and isotropic. Parameters were estimated for each month and for each hour to allow for seasonal and diurnal patterns in NO2 concentrations. Three experiments were run to compare the effects of observation thinning and the choice of observation errors. Model performance was assessed by comparing the analysed fields to an independent set of observations: ground-based measurements from European air-quality monitoring stations. The analysed NO2 and O3 concentrations were more accurate than those from a reference simulation without assimilation, with increased temporal correlation for both species. Thinning of satellite data and the use of constant observation errors yielded a better balance between the observed increments and the prescribed error covariances, with no appreciable degradation in the surface concentrations due to the observation thinning. Forecasts were also considered and these showed rather limited influence from the initial conditions once the effects of the diurnal cycle are accounted for. The simple OI scheme was effective and computationally feasible in this context, where only a single species was assimilated, adjusting the three-dimensional field for this compound. Limitations of the assimilation scheme are discussed.

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Urban Air Quality Modeling Using Low-Cost Sensor Network and Data Assimilation in the Aburrá Valley, Colombia

Atmosphere ◽

10.3390/atmos12010091 ◽

2021 ◽

Vol 12 (1) ◽

pp. 91

Author(s):

Santiago Lopez-Restrepo ◽

Andres Yarce ◽

Nicolás Pinel ◽

O.L. Quintero ◽

Arjo Segers ◽

...

Keyword(s):

Air Quality ◽

Data Assimilation ◽

Transport Model ◽

Cost Model ◽

Low Cost ◽

Model Performance ◽

Monitoring Network ◽

Correlation Factor ◽

Chemical Transport Model ◽

High Quality

The use of low air quality networks has been increasing in recent years to study urban pollution dynamics. Here we show the evaluation of the operational Aburrá Valley’s low-cost network against the official monitoring network. The results show that the PM2.5 low-cost measurements are very close to those observed by the official network. Additionally, the low-cost allows a higher spatial representation of the concentrations across the valley. We integrate low-cost observations with the chemical transport model Long Term Ozone Simulation-European Operational Smog (LOTOS-EUROS) using data assimilation. Two different configurations of the low-cost network were assimilated: using the whole low-cost network (255 sensors), and a high-quality selection using just the sensors with a correlation factor greater than 0.8 with respect to the official network (115 sensors). The official stations were also assimilated to compare the more dense low-cost network’s impact on the model performance. Both simulations assimilating the low-cost model outperform the model without assimilation and assimilating the official network. The capability to issue warnings for pollution events is also improved by assimilating the low-cost network with respect to the other simulations. Finally, the simulation using the high-quality configuration has lower error values than using the complete low-cost network, showing that it is essential to consider the quality and location and not just the total number of sensors. Our results suggest that with the current advance in low-cost sensors, it is possible to improve model performance with low-cost network data assimilation.

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Meteorological controls on atmospheric particulate pollution during hazard reduction burns

10.5194/acp-2017-491 ◽

2017 ◽

Author(s):

Giovanni Di Virgilio ◽

Melissa Anne Hart ◽

Ningbo Jiang

Keyword(s):

Particulate Matter ◽

Air Quality ◽

Fine Particulate Matter ◽

Meteorological Conditions ◽

Atmospheric Conditions ◽

Hazard Reduction ◽

Particulate Pollution ◽

Fine Particulate ◽

Projected Changes ◽

Sydney Australia

Abstract. Internationally, severe wildfires are an escalating problem likely to worsen given projected changes to climate. Hazard reduction burns (HRB) are used to suppress wildfire occurrences, but they generate considerable emissions of atmospheric fine particulate matter, which depending upon prevailing atmospheric conditions, can degrade air quality. Our objectives are to improve understanding of the relationships between meteorological conditions and air quality during HRBs in Sydney, Australia. We identify the primary meteorological covariates linked to high PM2.5 pollution (particulates

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The value of satellite observations in the analysis and short-range prediction of Asian dust

Atmospheric Chemistry and Physics ◽

10.5194/acp-19-987-2019 ◽

2019 ◽

Vol 19 (2) ◽

pp. 987-998 ◽

Cited By ~ 4

Author(s):

Angela Benedetti ◽

Francesca Di Giuseppe ◽

Luke Jones ◽

Vincent-Henri Peuch ◽

Samuel Rémy ◽

...

Keyword(s):

Particulate Matter ◽

Air Quality ◽

Data Assimilation ◽

Optical Depth ◽

Short Range ◽

Asian Dust ◽

Satellite Observations ◽

Global Model ◽

Deep Blue ◽

Dust Events

Abstract. Asian dust is a seasonal meteorological phenomenon which affects east Asia, and has severe consequences on the air quality of China, North and South Korea and Japan. Despite the continental extent, the prediction of severe episodes and the anticipation of their consequences is challenging. Three 1-year experiments were run to assess the skill of the model of the European Centre for Medium-Range Weather Forecasts (ECMWF) in monitoring Asian dust and understand its relative contribution to the aerosol load over China. Data used were the Moderate Resolution Imaging Spectroradiometer (MODIS) Dark Target and the Deep Blue aerosol optical depth (AOD). In particular the experiments aimed at understanding the added value of data assimilation runs over a model run without any aerosol data. The year 2013 was chosen as representative of the availability of independent AOD data from two established ground-based networks (AERONET, Aerosol Robotic Network, and CARSNET, China Aerosol Remote Sensing Network), which could be used to evaluate experiments. Particulate matter (PM) data from the China Environmental Protection Agency were also used in the evaluation. Results show that the assimilation of satellite AOD data is beneficial to predict the extent and magnitude of desert dust events and to improve the short-range forecast of such events. The availability of observations from the MODIS Deep Blue algorithm over bright surfaces is an asset, allowing for a better localization of the sources and definition of the dust events. In general both experiments constrained by data assimilation perform better than the unconstrained experiment, generally showing smaller normalized mean bias and fractional gross error with respect to the independent verification datasets. The impact of the assimilated satellite observations is larger at analysis time, but lasts into the forecast up to 48 h. The performance of the global model in terms of particulate matter does not show the same degree of skill as the performance in terms of optical depth. Despite this, the global model is able to capture some regional pollution patterns. This indicates that the global model analyses may be used as boundary conditions for regional air quality models at higher resolution, enhancing their performance in situations in which part of the pollution may have originated from large-scale mechanisms. While assimilation is not a substitute for model development and characterization of the emission sources, results indicate that it can play a role in delivering improved monitoring of Asian dust optical depth.

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Assimilation of ground versus lidar observations for PM<sub>10</sub> forecasting

Atmospheric Chemistry and Physics ◽

10.5194/acp-13-269-2013 ◽

2013 ◽

Vol 13 (1) ◽

pp. 269-283 ◽

Cited By ~ 23

Author(s):

Y. Wang ◽

K. N. Sartelet ◽

M. Bocquet ◽

P. Chazette

Keyword(s):

Data Assimilation ◽

Western Europe ◽

Sensitivity Study ◽

Optimal Interpolation ◽

Temporal Influence ◽

Potential Impact ◽

Ground Based Lidar ◽

Observing System Simulation Experiment ◽

Lidar Observations ◽

Do So

Abstract. This article investigates the potential impact of future ground-based lidar networks on analysis and short-term forecasts of particulate matter with a diameter smaller than 10 μm (PM10). To do so, an Observing System Simulation Experiment (OSSE) is built for PM10 data assimilation (DA) using optimal interpolation (OI) over Europe for one month from 15 July to 15 August 2001. First, using a lidar network with 12 stations and representing the "true" atmosphere by a simulation called "nature run", we estimate the efficiency of assimilating the lidar network measurements in improving PM10 concentration for analysis and forecast. It is compared to the efficiency of assimilating concentration measurements from the AirBase ground network, which includes about 500 stations in western Europe. It is found that assimilating the lidar observations decreases by about 54% the root mean square error (RMSE) of PM10 concentrations after 12 h of assimilation and during the first forecast day, against 59% for the assimilation of AirBase measurements. However, the assimilation of lidar observations leads to similar scores as AirBase's during the second forecast day. The RMSE of the second forecast day is improved on average over the summer month by 57% by the lidar DA, against 56% by the AirBase DA. Moreover, the spatial and temporal influence of the assimilation of lidar observations is larger and longer. The results show a potentially powerful impact of the future lidar networks. Secondly, since a lidar is a costly instrument, a sensitivity study on the number and location of required lidars is performed to help define an optimal lidar network for PM10 forecasts. With 12 lidar stations, an efficient network in improving PM10 forecast over Europe is obtained by regularly spacing the lidars. Data assimilation with a lidar network of 26 or 76 stations is compared to DA with the previously-used lidar network. During the first forecast day, the assimilation of 76 lidar stations' measurements leads to a better score (the RMSE decreased by about 65%) than AirBase's (the RMSE decreased by about 59%).

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Assimilation of lidar signals: application to aerosol forecasting in the western Mediterranean basin

Atmospheric Chemistry and Physics ◽

10.5194/acp-14-12031-2014 ◽

2014 ◽

Vol 14 (22) ◽

pp. 12031-12053 ◽

Cited By ~ 32

Author(s):

Y. Wang ◽

K. N. Sartelet ◽

M. Bocquet ◽

P. Chazette ◽

M. Sicard ◽

...

Keyword(s):

Air Quality ◽

Mediterranean Basin ◽

Interpolation Method ◽

Period Length ◽

Research Network ◽

Optimal Interpolation ◽

Aerodynamic Diameter ◽

Western Mediterranean Basin ◽

Ground Based Lidar ◽

The Impact

Abstract. This paper presents a new application of assimilating lidar signals to aerosol forecasting. It aims at investigating the impact of a ground-based lidar network on the analysis and short-term forecasts of aerosols through a case study in the Mediterranean basin. To do so, we employ a data assimilation (DA) algorithm based on the optimal interpolation method developed in the Polair3D chemistry transport model (CTM) of the Polyphemus air quality modelling platform. We assimilate hourly averaged normalised range-corrected lidar signals (PR2) retrieved from a 72 h period of intensive and continuous measurements performed in July 2012 by ground-based lidar systems of the European Aerosol Research Lidar Network (EARLINET) integrated into the Aerosols, Clouds, and Trace gases Research InfraStructure (ACTRIS) network and an additional system in Corsica deployed in the framework of the pre-ChArMEx (Chemistry-Aerosol Mediterranean Experiment)/TRAQA (TRAnsport à longue distance et Qualité de l'Air) campaign. This lidar campaign was dedicated to demonstrating the potential operationality of a research network like EARLINET and the potential usefulness of assimilation of lidar signals to aerosol forecasts. Particles with an aerodynamic diameter lower than 2.5 μm (PM2.5) and those with an aerodynamic diameter higher than 2.5 μm but lower than 10 μm (PM10–2.5) are analysed separately using the lidar observations at each DA step. First, we study the spatial and temporal influences of the assimilation of lidar signals on aerosol forecasting. We conduct sensitivity studies on algorithmic parameters, e.g. the horizontal correlation length (Lh) used in the background error covariance matrix (50 km, 100 km or 200 km), the altitudes at which DA is performed (0.75–3.5 km, 1.0–3.5 km or 1.5–3.5 km a.g.l.) and the assimilation period length (12 h or 24 h). We find that DA with Lh = 100 km and assimilation from 1.0 to 3.5 km a.g.l. during a 12 h assimilation period length leads to the best scores for PM10 and PM2.5 during the forecast period with reference to available measurements from surface networks. Secondly, the aerosol simulation results without and with lidar DA using the optimal parameters (Lh = 100 km, an assimilation altitude range from 1.0 to 3.5 km a.g.l. and a 12 h DA period) are evaluated using the level 2.0 (cloud-screened and quality-assured) aerosol optical depth (AOD) data from AERONET, and mass concentration measurements (PM10 or PM2.5) from the French air quality (BDQA) network and the EMEP-Spain/Portugal network. The results show that the simulation with DA leads to better scores than the one without DA for PM2.5, PM10and AOD. Additionally, the comparison of model results to evaluation data indicates that the temporal impact of assimilating lidar signals is longer than 36 h after the assimilation period.

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Chemical transport model simulations of organic aerosol in southern California: model evaluation and gasoline and diesel source contributions

Atmospheric Chemistry and Physics ◽

10.5194/acp-17-4305-2017 ◽

2017 ◽

Vol 17 (6) ◽

pp. 4305-4318 ◽

Cited By ~ 21

Author(s):

Shantanu H. Jathar ◽

Matthew Woody ◽

Havala O. T. Pye ◽

Kirk R. Baker ◽

Allen L. Robinson

Keyword(s):

Particulate Matter ◽

Air Quality ◽

Southern California ◽

Transport Model ◽

Chemical Transport ◽

Organic Aerosol ◽

Production Model ◽

Anthropogenic Sources ◽

Chemical Transport Model ◽

Mobile Sources

Abstract. Gasoline- and diesel-fueled engines are ubiquitous sources of air pollution in urban environments. They emit both primary particulate matter and precursor gases that react to form secondary particulate matter in the atmosphere. In this work, we updated the organic aerosol module and organic emissions inventory of a three-dimensional chemical transport model, the Community Multiscale Air Quality Model (CMAQ), using recent, experimentally derived inputs and parameterizations for mobile sources. The updated model included a revised volatile organic compound (VOC) speciation for mobile sources and secondary organic aerosol (SOA) formation from unspeciated intermediate volatility organic compounds (IVOCs). The updated model was used to simulate air quality in southern California during May and June 2010, when the California Research at the Nexus of Air Quality and Climate Change (CalNex) study was conducted. Compared to the Traditional version of CMAQ, which is commonly used for regulatory applications, the updated model did not significantly alter the predicted organic aerosol (OA) mass concentrations but did substantially improve predictions of OA sources and composition (e.g., POA–SOA split), as well as ambient IVOC concentrations. The updated model, despite substantial differences in emissions and chemistry, performed similar to a recently released research version of CMAQ (Woody et al., 2016) that did not include the updated VOC and IVOC emissions and SOA data. Mobile sources were predicted to contribute 30–40 % of the OA in southern California (half of which was SOA), making mobile sources the single largest source contributor to OA in southern California. The remainder of the OA was attributed to non-mobile anthropogenic sources (e.g., cooking, biomass burning) with biogenic sources contributing to less than 5 % to the total OA. Gasoline sources were predicted to contribute about 13 times more OA than diesel sources; this difference was driven by differences in SOA production. Model predictions highlighted the need to better constrain multi-generational oxidation reactions in chemical transport models.

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Assimilation of lidar signals: application to aerosol forecasting in the Mediterranean Basin

Atmospheric Chemistry and Physics Discussions ◽

10.5194/acpd-14-13059-2014 ◽

2014 ◽

Vol 14 (9) ◽

pp. 13059-13107 ◽

Cited By ~ 1

Author(s):

Y. Wang ◽

K. N. Sartelet ◽

M. Bocquet ◽

P. Chazette ◽

M. Sicard ◽

...

Keyword(s):

Transport Model ◽

Interpolation Method ◽

Period Length ◽

Research Network ◽

Optimal Interpolation ◽

Aerodynamic Diameter ◽

Background Error ◽

The Mediterranean ◽

Ground Based Lidar ◽

The Impact

Abstract. This paper presents a new application of assimilating lidar signals to aerosol forecasting. It aims at investigating the impact of a ground-based lidar network on analysis and short-term forecasts of aerosols through a case study in the Mediterranean. To do so, we employ a data assimilation (DA) algorithm based on the optimal interpolation method developed in the chemistry transport model (CTM) {Polair3D of the air quality modelling platform POLYPHEMUS. We assimilate hourly-averaged normalised range corrected lidar signals (PR2) retrieved from a 72 h period of intensive and continuous measurements performed in July 2012 by ground-based lidar systems of the European Aerosol Research Lidar Network (EARLINET) integrated into the Aerosols, Clouds, and Trace gases Research InfraStructure Network (ACTRIS) and an additional system in Corsica deployed in the framework of the pre-ChArMEx (Chemistry-Aerosol Mediterranean Experiment)/TRAQA (TRAnsport à longue distance et Qualité de l'Air) campaign. This lidar campaign was dedicated to demonstrating the potential operationality of a research network like EARLINET and the potential usefulness of assimilation of lidar signals to aerosol forecasts. Particles with an aerodynamic diameter lower than 2.5 μm (PM2.5) and those with an aerodynamic diameter higher than 2.5 μm but lower than 10 μm (PM2.5–10) are analysed separately using the lidar observations at each DA step. First, we study the spatial and temporal influences of the assimilation of lidar signals on aerosol forecasting. We conduct sensitivity studies on algorithmic parameters, e.g. the horizontal correlation length (Lh) used in the background error covariance matrix (50 km, 100 km or 200 km), the altitudes at which DA is performed (0.75–3.5 km, 1.0–3.5 km or 1.5–3.5 km a.g.l.) and the assimilation period length (12 h or 24 h). We find that DA with Lh = 100 km and assimilation from 1.0 to 3.5 km a.g.l. during a 12 h assimilation period length leads to the best scores for PM10 and PM2.5 during the forecast period with reference to available measurements from surface networks. Secondly, the aerosol simulation results without and with lidar DA using the optimal parameters (Lh

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Evaluation of potential sources of a priori ozone profiles for TEMPO tropospheric ozone retrievals

Atmospheric Measurement Techniques ◽

10.5194/amt-11-3457-2018 ◽

2018 ◽

Vol 11 (6) ◽

pp. 3457-3477 ◽

Cited By ~ 3

Author(s):

Matthew S. Johnson ◽

Xiong Liu ◽

Peter Zoogman ◽

John Sullivan ◽

Michael J. Newchurch ◽

...

Keyword(s):

Air Quality ◽

Tropospheric Ozone ◽

Transport Model ◽

A Priori ◽

Retrieval Algorithm ◽

Chemical Transport Model ◽

Diurnal Variability ◽

Potential Sources ◽

Tropospheric O3 ◽

Lidar Observations

Abstract. Potential sources of a priori ozone (O3) profiles for use in Tropospheric Emissions: Monitoring of Pollution (TEMPO) satellite tropospheric O3 retrievals are evaluated with observations from multiple Tropospheric Ozone Lidar Network (TOLNet) systems in North America. An O3 profile climatology (tropopause-based O3 climatology (TB-Clim), currently proposed for use in the TEMPO O3 retrieval algorithm) derived from ozonesonde observations and O3 profiles from three separate models (operational Goddard Earth Observing System (GEOS-5) Forward Processing (FP) product, reanalysis product from Modern-era Retrospective Analysis for Research and Applications version 2 (MERRA2), and the GEOS-Chem chemical transport model (CTM)) were: (1) evaluated with TOLNet measurements on various temporal scales (seasonally, daily, and hourly) and (2) implemented as a priori information in theoretical TEMPO tropospheric O3 retrievals in order to determine how each a priori impacts the accuracy of retrieved tropospheric (0–10 km) and lowermost tropospheric (LMT, 0–2 km) O3 columns. We found that all sources of a priori O3 profiles evaluated in this study generally reproduced the vertical structure of summer-averaged observations. However, larger differences between the a priori profiles and lidar observations were calculated when evaluating inter-daily and diurnal variability of tropospheric O3. The TB-Clim O3 profile climatology was unable to replicate observed inter-daily and diurnal variability of O3 while model products, in particular GEOS-Chem simulations, displayed more skill in reproducing these features. Due to the ability of models, primarily the CTM used in this study, on average to capture the inter-daily and diurnal variability of tropospheric and LMT O3 columns, using a priori profiles from CTM simulations resulted in TEMPO retrievals with the best statistical comparison with lidar observations. Furthermore, important from an air quality perspective, when high LMT O3 values were observed, using CTM a priori profiles resulted in TEMPO LMT O3 retrievals with the least bias. The application of near-real-time (non-climatological) hourly and daily model predictions as the a priori profile in TEMPO O3 retrievals will be best suited when applying this data to study air quality or event-based processes as the standard retrieval algorithm will still need to use a climatology product. Follow-on studies to this work are currently being conducted to investigate the application of different CTM-predicted O3 climatology products in the standard TEMPO retrieval algorithm. Finally, similar methods to those used in this study can be easily applied by TEMPO data users to recalculate tropospheric O3 profiles provided from the standard retrieval using a different source of a priori.

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