scholarly journals Characterization of submicron aerosols influenced by biomass burning at a site in the Sichuan Basin, southwestern China

2016 ◽  
Author(s):  
Wei Hu ◽  
Min Hu ◽  
Weiwei Hu ◽  
Hongya Niu ◽  
Jing Zheng ◽  
...  
Keyword(s):  
High Resolution ◽  
Oxidation State ◽  
Biomass Burning ◽  
Sichuan Basin ◽  
Chemical Compositions ◽  
Aerosol Formation ◽  
Spectral Matrix ◽  
Inorganic Species ◽  
The Sichuan Basin ◽  
Primary Emissions

Abstract. Severe air pollution caused by large amount of pollutants and adverse synoptic processes appears often in Asia. However, limited studies on aerosols have been conducted under high emission intensity, and unique geographical and meteorological conditions. In this study, an Aerodyne high resolution time-of-flight aerosol mass spectrometry (HR-ToF-AMS) and other state-of-the-art instruments were utilized at a suburban site, Ziyang, in the Sichuan Basin during December 2012 to January 2013. The chemical compositions of atmospheric submicron aerosols (PM1) were determined, the sources of organic aerosols (OA) were apportioned, and the aerosol secondary formation and aging process were explored as well. Due to high humidity and static air, PM1 was maintained at a relatively stable level during the whole campaign, with the mean concentration of 59.7 ± 24.1 μg m−3. OA was the most abundant component (36 %) in PM1, characterized by a relatively high oxidation state. Positive matrix factorization analysis was applied to the high resolution organic mass spectral matrix, which deconvolved OA mass spectra into four factors: low volatility (LV-OOA) and semi-volatile oxygenated OA (SV-OOA), biomass burning (BBOA) and hydrocarbon-like OA (HOA). OOA (sum of LV-OOA and SV-OOA) dominated OA as high as 71 %. In total, secondary inorganic and organic formation contributed 76 % of PM. Secondary inorganic species correlated well with relative humidity (RH), indicating the humid air can favor the formation of secondary inorganic aerosols. With the increase of photochemical age, OA became more aged with higher oxidation state, and secondary organic aerosol formation contributed more significantly to OA. The slope of OOA against Ox (= O3 + NO2) steepened with the increase of RH, implying that besides the photochemical transformation, the aqueous-phase oxidation was also an important pathway of the OOA formation. Primary emissions, especially biomass burning, resulted in high concentration and proportion of black carbon (BC) in PM1. During the episode obviously influenced by primary emissions, the contributions of BBOA to OA (26 %) and PM1 (11 %) were much higher than those (10–17 %, 4–7 %) in the clean and other polluted episodes, highlighting the significant influence of biomass burning.

scholarly journals Characterization of submicron aerosols influenced by biomass burning at a site in the Sichuan Basin, southwestern China

2016 ◽  
Vol 16 (20) ◽  
pp. 13213-13230 ◽  
Author(s):  
Wei Hu ◽  
Min Hu ◽  
Wei-Wei Hu ◽  
Hongya Niu ◽  
Jing Zheng ◽  
...  
Keyword(s):  
High Resolution ◽  
Oxidation State ◽  
Biomass Burning ◽  
Sichuan Basin ◽  
Chemical Compositions ◽  
Aerosol Formation ◽  
Spectral Matrix ◽  
Synoptic Conditions ◽  
The Sichuan Basin ◽  
Primary Emissions

Abstract. Severe air pollution in Asia is often the consequence of a combination of large anthropogenic emissions and adverse synoptic conditions. However, limited studies on aerosols have been conducted under high emission intensity and under unique geographical and meteorological conditions. In this study, an Aerodyne high-resolution time-of-flight aerosol mass spectrometry (HR-ToF-AMS) and other state-of-the-art instruments were utilized at a suburban site, Ziyang, in the Sichuan Basin during December 2012 to January 2013. The chemical compositions of atmospheric submicron aerosols (PM1) were determined, the sources of organic aerosols (OA) were apportioned, and the aerosol secondary formation and aging process were explored as well. Due to high humidity and static air, PM1 maintained a relatively stable level during the whole campaign, with the mean concentration of 59.7 ± 24.1 µg m−3. OA was the most abundant component (36 %) in PM1, characterized by a relatively high oxidation state. Positive matrix factorization analysis was applied to the high-resolution organic mass spectral matrix, which deconvolved OA mass spectra into four factors: low-volatility (LV-OOA) and semivolatile oxygenated OA (SV-OOA), biomass burning (BBOA) and hydrocarbon-like OA (HOA). OOA (sum of LV-OOA and SV-OOA) dominated OA as high as 71 %. In total, secondary inorganic and organic formation contributed 76 % of PM1. Secondary inorganic species correlated well (Pearson r = 0.415–0.555, p < 0.01) with relative humidity (RH), suggesting the humid air can favor the formation of secondary inorganic aerosols. As the photochemical age of OA increased with higher oxidation state, secondary organic aerosol formation contributed more to OA. The slope of OOA against Ox( = O3+NO2) steepened with the increase of RH, implying that, besides the photochemical transformation, the aqueous-phase oxidation was also an important pathway of the OOA formation. Primary emissions, especially biomass burning, resulted in high concentration and proportion of black carbon (BC) in PM1. During the episode obviously influenced by primary emissions, the contributions of BBOA to OA (26 %) and PM1 (11 %) were much higher than those (10–17 %, 4–7 %) in the clean and other polluted episodes, highlighting the significant influence of biomass burning.

scholarly journals Mexico City aerosol analysis during MILAGRO using high resolution aerosol mass spectrometry at the urban supersite (T0) – Part 1: Fine particle composition and organic source apportionment

2009 ◽  
Vol 9 (2) ◽  
pp. 8377-8427 ◽  
Author(s):  
A. C. Aiken ◽  
D. Salcedo ◽  
M. J. Cubison ◽  
J. A. Huffman ◽  
P. F. DeCarlo ◽  
...  
Keyword(s):  
High Resolution ◽  
Mexico City ◽  
Biomass Burning ◽  
Emissions Inventory ◽  
Secondary Sources ◽  
Diurnal Cycles ◽  
Aerosol Mass ◽  
Aerosol Mass Spectrometry ◽  
Order Of Magnitude ◽  
Primary Emissions

Abstract. Submicron aerosol was analyzed during the MILAGRO field campaign in March 2006 at the T0 urban supersite in Mexico City with a High-Resolution Time-of-Flight Aerosol Mass Spectrometer (HR-ToF-AMS) and complementary instrumentation. Mass concentrations, diurnal cycles, and size distributions of inorganic and organic species are similar to results from the CENICA supersite in April 2003 with organic aerosol (OA) comprising about half of the fine PM mass. Positive Matrix Factorization (PMF) analysis of the high resolution OA spectra identified three major components: chemically-reduced urban primary emissions (hydrocarbon-like OA, HOA), oxygenated OA (OOA, mostly secondary OA or SOA), and biomass burning OA (BBOA) that correlates with levoglucosan and acetonitrile. BBOA includes several very large plumes from regional fires and likely also some refuse burning. A fourth OA component is a small local nitrogen-containing reduced OA component (LOA) which accounts for 9% of the OA mass but one third of the organic nitrogen, likely as amines. OOA accounts for almost half of the OA on average, consistent with previous observations. OA apportionment results from PMF-AMS are compared to the PM2.5 chemical mass balance of organic molecular markers (CMB-OMM, from GC/MS analysis of filters). Results from both methods are overall consistent. Both assign the major components of OA to primary urban, biomass burning/woodsmoke, and secondary sources at similar magnitudes. The 2006 Mexico City emissions inventory underestimates the urban primary PM2.5 emissions by a factor of ~4, and it is ~16 times lower than afternoon concentrations when secondary species are included. Additionally, the forest fire contribution is underestimated by at least an order-of-magnitude in the inventory.

scholarly journals Simultaneous Measurements of Chemical Compositions of Fine Particles during Winter Haze Period in Urban Sites in China and Korea

Atmosphere ◽  
2020 ◽  
Vol 11 (3) ◽  
pp. 292 ◽  
Author(s):  
Minhan Park ◽  
Yujue Wang ◽  
Jihyo Chong ◽  
Haebum Lee ◽  
Jiho Jang ◽  
...  
Keyword(s):  
Biomass Burning ◽  
Fine Particles ◽  
Chemical Compositions ◽  
Aerosol Formation ◽  
Wind Speeds ◽  
Simultaneous Measurements ◽  
Dust Sources ◽  
Secondary Formation ◽  
Combustion Sources ◽  
Burning Coal

We performed simultaneous measurements of chemical compositions of fine particles in Beijing, China and Gwangju, Korea to better understand their sources during winter haze period. We identified PM2.5 events in Beijing, possibly caused by a combination of multiple primary combustion sources (biomass burning, coal burning, and vehicle emissions) and secondary aerosol formation under stagnant conditions and/or dust sources under high wind speeds. During the PM2.5 events in Gwangju, the contribution of biomass burning and secondary formation of nitrate and organics to the fine particles content significantly increased under stagnant conditions. We commonly observed the increases of nitrogen-containing organic compounds and biomass burning inorganic (K+) and organic (levoglucosan) markers, suggesting the importance of biomass burning sources during the winter haze events (except dust event cases) at both sites. Pb isotope ratios indicated that the fraction of Pb originated from possibly industry and coal combustion sources increased during the PM2.5 events in Gwangju, relative to nonevent days.

scholarly journals Spatial and temporal variation of anthropogenic black carbon emissions in China for the period 1980–2009

2011 ◽  
Vol 11 (12) ◽  
pp. 32877-32920 ◽  
Author(s):  
Y. Qin ◽  
S. D. Xie
Keyword(s):  
Black Carbon ◽  
Spatial Resolution ◽  
Biomass Burning ◽  
Carbon Emissions ◽  
Sichuan Basin ◽  
Statistical Data ◽  
High Spatial Resolution ◽  
Spatial And Temporal Variation ◽  
Time Varying ◽  
The Sichuan Basin

Abstract. Multi-year inventories of anthropogenic black carbon emissions, including both fuel consumption and biomass burning, at a high spatial resolution of 0.25° × 0.25° have been constructed in China using GIS methodology for the period 1980–2009, based on official statistical data and time-varying emission factors. Results show that black carbon emissions increased from 0.87 Tg in 1980 to 1.88 Tg in 2009 with a peak in about 1995, and had been continually increasing in the first decade of the 21 century. Residential contribution to the total BC emissions declined from 82.03% in 1980 to 42.33% in 2009 at a continuous diminishing trend, but had always been the dominant contributor in China. While contributions from industry and transportation sectors had increased notably. BC emissions were mainly concentrated in the central eastern districts, the three northeastern provinces and the Sichuan Basin, covering 22.30% of China's territory, but were responsible for 43.02%, 50.47%, 50.69% and 54.30% of the national black carbon emissions in 1985, 1995, 2005 and 2009, respectively. Besides, China made up 70–85% of BC emissions in East Asia, half of the emissions in Asia, and accounted for averagely 18.97% of the global BC emissions during the estimation period.

scholarly journals The Warming Tibetan Plateau improves winter air quality in the Sichuan Basin, China

2020 ◽  
Author(s):  
Shuyu Zhao ◽  
Tian Feng ◽  
Xuexi Tie ◽  
Zebin Wang
Keyword(s):  
Climate Change ◽  
Air Pollution ◽  
Air Quality ◽  
Tibetan Plateau ◽  
Sichuan Basin ◽  
The Tibetan Plateau ◽  
Aerosol Formation ◽  
Warming Rate ◽  
The Sichuan Basin ◽  
The Impact

Abstract. Impacts of global climate change on the occurrence and development of air pollution have attracted more attentions. This study investigates impacts of the warming Tibetan Plateau on air quality in the Sichuan Basin. Meteorological observations and ERA-interim reanalysis data reveal that the Tibetan Plateau has been rapidly warming during the last 40 years (1979–2017), particularly in winter when the warming rate is approximately twice as much as the annual warming rate. Since 2013, the winter temperature over the plateau has even risen by 2 °C. Here, we use the WRF-CHEM model to assess the impact of the 2 °C warming on air quality in the Sichuan Basin. The model results show that the 2 °C warming causes an increase in the Planetary Boundary Layer (PBL) height and a decrease in the relative humidity (RH) in the basin. The elevated PBL height strengthens vertical diffusion of PM2.5, while the decreased RH significantly reduces secondary aerosol formation. Overall, PM2.5 concentration is reduced by 17.5 % (~ 25.1 μg m−3), of which the reduction in primary and secondary aerosols is 5.4 μg m−3 and 19.7 μg m−3, respectively. These results reveal that the recent warming plateau has improved air quality in the basin, to some certain extent, mitigating the air pollution therein. Nevertheless, climate system is particularly complicated, and more studies are needed to demonstrate the impact of climate change on air quality in the downstream regions as the plateau is likely to continue warming.

scholarly journals Factor analysis of combined organic and inorganic aerosol mass spectra from high resolution aerosol mass spectrometer measurements

2012 ◽  
Vol 12 (18) ◽  
pp. 8537-8551 ◽  
Author(s):  
Y. L. Sun ◽  
Q. Zhang ◽  
J. J. Schwab ◽  
T. Yang ◽  
N. L. Ng ◽  
...  
Keyword(s):  
High Resolution ◽  
Ammonium Nitrate ◽  
Mass Spectrometer ◽  
Mass Spectra ◽  
Organic Aerosol ◽  
Organic Nitrates ◽  
Spectral Matrix ◽  
Aerosol Mass Spectrometer ◽  
Aerosol Mass ◽  
Inorganic Species

Abstract. Positive matrix factorization (PMF) was applied to the merged high resolution mass spectra of organic and inorganic aerosols from aerosol mass spectrometer (AMS) measurements to investigate the sources and evolution processes of submicron aerosols in New York City in summer 2009. This new approach is able to study the distribution of organic and inorganic species in different types of aerosols, the acidity of organic aerosol (OA) factors, and the fragment ion patterns related to photochemical processing. In this study, PMF analysis of the unified AMS spectral matrix resolved 8 factors. The hydrocarbon-like OA (HOA) and cooking OA (COA) factors contain negligible amounts of inorganic species. The two factors that are primarily ammonium sulfate (SO4-OA) and ammonium nitrate (NO3-OA), respectively, are overall neutralized. Among all OA factors the organic fraction of SO4-OA shows the highest degree of oxidation (O/C = 0.69). Two semi-volatile oxygenated OA (OOA) factors, i.e., a less oxidized (LO-OOA) and a more oxidized (MO-OOA), were also identified. MO-OOA represents local photochemical products with a diurnal profile exhibiting a pronounced noon peak, consistent with those of formaldehyde (HCHO) and Ox(= O3 + NO2). The NO+/NO2+ ion ratio in MO-OOA is much higher than that in NO3-OA and in pure ammonium nitrate, indicating the formation of organic nitrates. The nitrogen-enriched OA (NOA) factor contains ~25% of acidic inorganic salts, suggesting the formation of secondary OA via acid-base reactions of amines. The size distributions of OA factors derived from the size-resolved mass spectra show distinct diurnal evolving behaviors but overall a progressing evolution from smaller to larger particle mode as the oxidation degree of OA increases. Our results demonstrate that PMF analysis of the unified aerosol mass spectral matrix which contains both inorganic and organic aerosol signals may enable the deconvolution of more OA factors and gain more insights into the sources, processes, and chemical characteristics of OA in the atmosphere.

Characterization and light absorption of Brown Carbon in Sichuan Basin, Southwestern China: Impacts of biomass burning and secondary formation

2020 ◽  
Author(s):  
Yang Chen
Keyword(s):  
Light Absorption ◽  
Radiative Forcing ◽  
Sichuan Basin ◽  
Absorption Efficiency ◽  
Radiation Budget ◽  
Southwestern China ◽  
Aerosol Formation ◽  
Brown Carbon ◽  
The Sichuan Basin ◽  
The Impact

&lt;p&gt;Brc Carbon is a class of light-absorbing organic species, playing important roles on solar radiation budget and therefore influences climate forcing over regional and even global scales. We analyzed and evaluated the light absorption and radiative forcing of BrC in Chongqing, Wanzhou (Three Gorges Reservoir region), and Chengdu in the Sichuan Basin of Southwest China. The light-absorbing properties were evaluated, including mass absorption efficiency, absorption &amp;#197;ngstr&amp;#246;m exponent, and contributions to radiative forcing. The sources of BrC are also identified, including the contribution of secondary aerosol formation and primary emissions. This study contributes to the understandings of sources and the impact of brown carbon in the Sichuan Basin, southwestern China.&lt;/p&gt;

Observation of elevated fungal tracers due to biomass burning in the Sichuan Basin at Chengdu City, China

2012 ◽  
Vol 431 ◽  
pp. 68-77 ◽  
Author(s):  
Yihong Yang ◽  
Chuen-yu Chan ◽  
Jun Tao ◽  
Mang Lin ◽  
Guenter Engling ◽  
...  
Keyword(s):  
Biomass Burning ◽  
Sichuan Basin ◽  
The Sichuan Basin

scholarly journals Mexico City aerosol analysis during MILAGRO using high resolution aerosol mass spectrometry at the urban supersite (T0) – Part 1: Fine particle composition and organic source apportionment

2009 ◽  
Vol 9 (17) ◽  
pp. 6633-6653 ◽  
Author(s):  
A. C. Aiken ◽  
D. Salcedo ◽  
M. J. Cubison ◽  
J. A. Huffman ◽  
P. F. DeCarlo ◽  
...  
Keyword(s):  
High Resolution ◽  
Mexico City ◽  
Biomass Burning ◽  
Emissions Inventory ◽  
Secondary Sources ◽  
Diurnal Cycles ◽  
Aerosol Mass ◽  
Aerosol Mass Spectrometry ◽  
Order Of Magnitude ◽  
Primary Emissions

Abstract. Submicron aerosol was analyzed during the MILAGRO field campaign in March 2006 at the T0 urban supersite in Mexico City with a High-Resolution Time-of-Flight Aerosol Mass Spectrometer (HR-ToF-AMS) and complementary instrumentation. Mass concentrations, diurnal cycles, and size distributions of inorganic and organic species are similar to results from the CENICA supersite in April 2003 with organic aerosol (OA) comprising about half of the fine PM mass. Positive Matrix Factorization (PMF) analysis of the high resolution OA spectra identified three major components: chemically-reduced urban primary emissions (hydrocarbon-like OA, HOA), oxygenated OA (OOA, mostly secondary OA or SOA), and biomass burning OA (BBOA) that correlates with levoglucosan and acetonitrile. BBOA includes several very large plumes from regional fires and likely also some refuse burning. A fourth OA component is a small local nitrogen-containing reduced OA component (LOA) which accounts for 9% of the OA mass but one third of the organic nitrogen, likely as amines. OOA accounts for almost half of the OA on average, consistent with previous observations. OA apportionment results from PMF-AMS are compared to the PM2.5 chemical mass balance of organic molecular markers (CMB-OMM, from GC/MS analysis of filters). Results from both methods are overall consistent. Both assign the major components of OA to primary urban, biomass burning/woodsmoke, and secondary sources at similar magnitudes. The 2006 Mexico City emissions inventory underestimates the urban primary PM2.5 emissions by a factor of ~4, and it is ~16 times lower than afternoon concentrations when secondary species are included. Additionally, the forest fire contribution is at least an order-of-magnitude larger than in the inventory.

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