Water Vapour and Methane Coupling in the Stratosphere observed with SCIAMACHY Solar Occultation Measurements
Abstract. An improved stratospheric water vapour data set has been derived from SCIAMACHY/ENVISAT solar occultation measurements. It is based on the same algorithm which has already been successfully applied to methane and carbon dioxide retrievals, thus resulting in a consistent data set for theses three constituents covering the altitudes 17–45 km, the latitude range between about 50 and 70° N, and the time interval August 2002 to April 2012. The new water vapour data agree with collocated results from ACE-FTS and MLS/Aura within about 5 %. A significant positive water vapour trend for the time 2003–2011 is observed at lower stratospheric altitudes of about 0.015 ppmv/year around 17 km. Between 30 and 37 km the trends become significantly negative (about −0.01 ppmv/year). The combined analysis of the SCIAMACHY methane and water vapour time series reveals that stratospheric methane and water vapour are strongly correlated and show a clear temporal variation related to the Quasi-Biannual-Oscillation (QBO). Above about 20 km most of the water vapour seems to be produced by methane, but short-term fluctuations and a temporal variation on a scale of 5–6 years are observed. At lower altitudes the balance between water vapour and methane is affected by stratospheric transport of water vapour and methane from the tropics to higher latitudes via the shallow branch of the Brewer-Dobson circulation and by the increasing methane input into the stratosphere due to the rise of tropospheric methane after 2007.