scholarly journals Characterizing the hygroscopicty of growing particles in the Canadian Arctic summer

2021 ◽  
Author(s):  
Rachel Y.-W. Chang ◽  
Jonathan P. D. Abbatt ◽  
Matthew C. Boyer ◽  
Jai Prakash Chaubey ◽  
Douglas B. Collins
Keyword(s):  
Cloud Condensation Nuclei ◽  
Ultrafine Particle ◽  
Canadian Arctic ◽  
Cloud Droplet ◽  
Cloud Formation ◽  
Radiation Balance ◽  
Potential Contribution ◽  
Entire Study ◽  
The Impact ◽  
Arctic Summer

Abstract. The impact of aerosols on clouds is a well-studied, although still poorly constrained, part of the atmospheric system. New particle formation (NPF) is thought to contribute 40–80 % of the global cloud droplet number concentration, although it is extremely difficult to observe an air mass from NPF to cloud formation. NPF and growth occurs frequently in the Canadian Arctic summer atmosphere, although only a few studies have characterized the source and properties of these aerosols. This study presents cloud condensation nuclei (CCN) concentrations measured on board the CCGS Amundsen in the eastern Canadian Arctic Archipelago from 23 July to 23 August 2016 as part of the Network on Climate and Aerosols: Addressing Uncertainties in Remote Canadian Environments (NETCARE). The study was dominated by frequent ultrafine particle and/or growth events, and particles smaller than 100 nm dominated the size distribution for 92 % of the study period. Using κ-Kohler theory and aerosol size distributions, the mean hygroscopicity parameter (κ) calculated for the entire study was 0.12 (0.06–0.12, 25th–75th percentile), suggesting that the condensable vapours that led to particle growth were primarily non-hygroscopic, which we infer to be organic. Based on past measurement and modelling studies from NETCARE and the Canadian Arctic, it seems likely that the source of these non-hygroscopic, organic, vapours is the ocean. Examining specific growth events suggests that the mode diameter (Dmax) had to exceed 40 nm before CCN concentrations at 0.99 % SS started to increase, although a statistical analysis shows that CCN concentrations increased 13–274 cm−3 during all ultrafine particle and/or growth times (total particle concentrations > 500 cm−3, Dmax < 100 nm) compared to Background times (total concentrations < 500 cm−3) at SS of 0.26–0.99 %. This value increased to 25–425 cm−3 if the growth times were limited to times when Dmax was also larger than 40 nm. These results support past results from NETCARE by showing that the frequently observed ultrafine particle and growth events are dominated by a highly non-hygroscopic fraction, which we interpret to be organic vapours originating from the ocean, and that these growing particles can increase the background CCN concentrations at SS as low as 0.26 %, thus pointing to their potential contribution to cloud properties and thus climate through the radiation balance.

scholarly journals Frequent Ultrafine Particle Formation and Growth in the Canadian Arctic Marine Environment

2017 ◽  
Author(s):  
Douglas B. Collins ◽  
Julia Burkart ◽  
Rachel Y.-W. Chang ◽  
Martine Lizotte ◽  
Aude Boivin-Rioux ◽  
...  
Keyword(s):  
Marine Environment ◽  
Marine Boundary Layer ◽  
Cloud Condensation Nuclei ◽  
Ultrafine Particle ◽  
Canadian Arctic ◽  
Cloud Droplet ◽  
The Arctic ◽  
Arctic Regions ◽  
Lower Cloud ◽  
Marine Microbial Communities

Abstract. The source strength and capability of aerosol particles in the Arctic to act as cloud condensation nuclei have important implications for understanding the indirect aerosol-cloud effect within the polar climate system. It has been shown in several Arctic regions that ultrafine particle (UFP) formation and growth is a key contributor to aerosol number concentrations during the summer. This study uses aerosol number size distribution measurements from ship-board measurement expeditions aboard the research icebreaker CCGS Amundsen in the summers of 2014 and 2016 throughout the Canadian Arctic to gain a deeper understanding of the drivers of UFP formation and growth within this marine boundary layer. UFP number concentrations (diameter > 4 nm) in the range of 101–104 cm−3 were observed across the two seasons, with concentrations greater than 103 cm−3 occurring more frequently in 2016. Higher concentrations in 2016 were associated with UFP formation and growth, with events occurring on 41 % of days, while events were only observed on 6 % of days in 2014. Assessment of relevant parameters for aerosol nucleation showed that the median condensation sink in this region was approximately 1.2 h−1 in 2016 and 2.2 h−1 in 2014, which lie at the lower end of ranges observed at even the most remote stations reported in the literature. Apparent growth rates of all observed events in both expeditions averaged 4.3 ± 4.1 nm h−1, in general agreement with other recent studies at similar latitudes. Higher solar radiation, lower cloud fractions, and lower sea ice concentrations combined with differences in the developmental stage and activity of marine microbial communities within the Canadian Arctic were documented and help explain differences between the aerosol measurements made during the 2014 and 2016 expeditions. These findings help to motivate further studies of biosphere-atmosphere interactions within the Arctic marine environment to explain the production of UFP and their growth to sizes relevant for cloud droplet activation.

scholarly journals Frequent ultrafine particle formation and growth in Canadian Arctic marine and coastal environments

2017 ◽  
Vol 17 (21) ◽  
pp. 13119-13138 ◽  
Author(s):  
Douglas B. Collins ◽  
Julia Burkart ◽  
Rachel Y.-W. Chang ◽  
Martine Lizotte ◽  
Aude Boivin-Rioux ◽  
...  
Keyword(s):  
Marine Boundary Layer ◽  
Cloud Condensation Nuclei ◽  
Ultrafine Particle ◽  
Canadian Arctic ◽  
Cloud Droplet ◽  
The Arctic ◽  
Polar Climate ◽  
Arctic Regions ◽  
Lower Cloud ◽  
Marine Microbial Communities

Abstract. The source strength and capability of aerosol particles in the Arctic to act as cloud condensation nuclei have important implications for understanding the indirect aerosol–cloud effect within the polar climate system. It has been shown in several Arctic regions that ultrafine particle (UFP) formation and growth is a key contributor to aerosol number concentrations during the summer. This study uses aerosol number size distribution measurements from shipboard expeditions aboard the research icebreaker CCGS Amundsen in the summers of 2014 and 2016 throughout the Canadian Arctic to gain a deeper understanding of the drivers of UFP formation and growth within this marine boundary layer. UFP number concentrations (diameter > 4 nm) in the range of 101–104 cm−3 were observed during the two seasons, with concentrations greater than 103 cm−3 occurring more frequently in 2016. Higher concentrations in 2016 were associated with UFP formation and growth, with events occurring on 41 % of days, while events were only observed on 6 % of days in 2014. Assessment of relevant parameters for aerosol nucleation showed that the median condensation sink in this region was approximately 1.2 h−1 in 2016 and 2.2 h−1 in 2014, which lie at the lower end of ranges observed at even the most remote stations reported in the literature. Apparent growth rates of all observed events in both expeditions averaged 4.3 ± 4.1 nm h−1, in general agreement with other recent studies at similar latitudes. Higher solar radiation, lower cloud fractions, and lower sea ice concentrations combined with differences in the developmental stage and activity of marine microbial communities within the Canadian Arctic were documented and help explain differences between the aerosol measurements made during the 2014 and 2016 expeditions. These findings help to motivate further studies of biosphere–atmosphere interactions within the Arctic marine environment to explain the production of UFP and their growth to sizes relevant for cloud droplet activation.

scholarly journals Regional new particle formation as modulators of cloud condensation nuclei and cloud droplet number in the eastern Mediterranean

2019 ◽  
Vol 19 (9) ◽  
pp. 6185-6203 ◽  
Author(s):  
Panayiotis Kalkavouras ◽  
Aikaterini Bougiatioti ◽  
Nikos Kalivitis ◽  
Iasonas Stavroulas ◽  
Maria Tombrou ◽  
...  
Keyword(s):  
Eastern Mediterranean ◽  
Cloud Condensation Nuclei ◽  
Cloud Droplet ◽  
Particle Formation ◽  
Cloud Formation ◽  
New Particle Formation ◽  
Condensation Nuclei ◽  
Low Cloud ◽  
Condensational Growth ◽  
The Impact

Abstract. A significant fraction of atmospheric particles that serve as cloud condensation nuclei (CCN) are thought to originate from the condensational growth of new particle formation (NPF) from the gas phase. Here, 7 years of continuous aerosol and meteorological measurements (June 2008 to May 2015) at a remote background site of the eastern Mediterranean were recorded and analyzed to assess the impact of NPF (of 162 episodes identified) on CCN and cloud droplet number concentration (CDNC) formation in the region. A new metric is introduced to quantitatively determine the initiation and duration of the influence of NPF on the CCN spectrum. NPF days were found to increase CCN concentrations (from 0.10 % to 1.00 % supersaturation) between 29 % and 77 %. Enhanced CCN concentrations from NPF are mostly observed, as expected, under low preexisting particle concentrations and occur in the afternoon, relatively later in the winter and autumn than in the summer. Potential impacts of NPF on cloud formation were quantified by introducing the observed aerosol size distributions and chemical composition into an established cloud droplet parameterization. We find that the supersaturations that develop are very low (ranging between 0.03 % and 0.27 %) for typical boundary layer dynamics (σw ∼0.3 m s−1) and NPF is found to enhance CDNC by a modest 13 %. This considerable contrast between CCN and CDNC response is in part from the different supersaturation levels considered, but also because supersaturation drops from increasing CCN because of water vapor competition effects during the process of droplet formation. The low cloud supersaturation further delays the appearance of NPF impacts on CDNC to clouds formed in the late evening and nighttime – which has important implications for the extent and types of indirect effects induced by NPF events. An analysis based on CCN concentrations using prescribed supersaturation can provide very different, even misleading, conclusions and should therefore be avoided. The proposed approach here offers a simple, yet highly effective way for a more realistic impact assessment of NPF events on cloud formation.

Role of dimethyl sulfide on the formation and growth of aerosols, and its impact on liquid clouds in the Arctic summer

2020 ◽  
Author(s):  
Roya Ghahreman ◽  
Wanmin Gong ◽  
Ann-Lise Norman ◽  
Stephen R. Beagley ◽  
Ayodeji Akingunola ◽  
...  
Keyword(s):  
Dimethyl Sulfide ◽  
Model Simulation ◽  
Cloud Condensation Nuclei ◽  
Cloud Droplet ◽  
Liquid Water Content ◽  
High Arctic ◽  
Cloud Microphysics ◽  
The Arctic ◽  
The Impact ◽  
Arctic Summer

&lt;p&gt;Atmospheric dimethyl sulfide, DMS, is the main biogenic source of sulfate particles in the Arctic atmosphere. Sulfate particles have a net cooling effect, which can partially offset Arctic warming from absorbing aerosols, such as black carbon. As efficient cloud condensation nuclei (CCN), sulfate particles are also able to influence the cloud&amp;#8217;s microphysical properties.&amp;#160;&lt;/p&gt;&lt;p&gt;DMS production and emission to the atmosphere increase during the Arctic summer, due to a greater ice-free sea surface area and higher biological activity. In the model simulation of a field campaign conducted over the Canadian high Arctic during the summer of 2014 (NETCARE; Abbatt et al. 2019), the inclusion of DMS in the model, GEM-MACH, resulted in a significant increase, up to 100%, in the modelled atmospheric SO&lt;sub&gt;2&lt;/sub&gt;&amp;#160;in some regions of the Canadian Arctic. Analysis of the modelled size-segregated aerosol sulfate indicated that DMS has the most significant impact on particles in the size range of 50 &amp;#8211; 200 nm in this case. Simulations have shown that localized regions of high seawater DMS can have a significant impact on atmospheric concentrations.&lt;/p&gt;&lt;p&gt;Further investigation of DMS impact on the Arctic summer cloud microphysics was carried out by using a fully coupled version of GEM-MACH. Overall, the model simulations show that the inclusion of DMS in model leads to an increase in cloud droplet number concentrations (CDNC) and a decrease in droplet mean mass diameters (MMD), and has no significant effects on liquid water content (LWC). The impact of DMS on Canadian weather forecasts will be evaluated using operational forecast tools.&lt;/p&gt;

scholarly journals Broadening of Cloud Droplet Spectra through Eddy Hopping: Turbulent Entraining Parcel Simulations

2018 ◽  
Vol 75 (10) ◽  
pp. 3365-3379 ◽  
Author(s):  
Gustavo C. Abade ◽  
Wojciech W. Grabowski ◽  
Hanna Pawlowska
Keyword(s):  
Droplet Size ◽  
Turbulent Mixing ◽  
Cloud Condensation Nuclei ◽  
Cloud Droplet ◽  
Cloud Microphysics ◽  
Droplet Growth ◽  
Size Spectrum ◽  
Entrainment Rate ◽  
The Mean ◽  
The Impact

This paper discusses the effects of cloud turbulence, turbulent entrainment, and entrained cloud condensation nuclei (CCN) activation on the evolution of the cloud droplet size spectrum. We simulate an ensemble of idealized turbulent cloud parcels that are subject to entrainment events modeled as a random process. Entrainment events, subsequent turbulent mixing inside the parcel, supersaturation fluctuations, and the resulting stochastic droplet activation and growth by condensation are simulated using a Monte Carlo scheme. Quantities characterizing the turbulence intensity, entrainment rate, CCN concentration, and the mean fraction of environmental air entrained in an event are all specified as independent external parameters. Cloud microphysics is described by applying Lagrangian particles, the so-called superdroplets. These are either unactivated CCN or cloud droplets that grow from activated CCN. The model accounts for the addition of environmental CCN into the cloud by entraining eddies at the cloud edge. Turbulent mixing of the entrained dry air with cloudy air is described using the classical linear relaxation to the mean model. We show that turbulence plays an important role in aiding entrained CCN to activate, and thus broadening the droplet size distribution. These findings are consistent with previous large-eddy simulations (LESs) that consider the impact of variable droplet growth histories on the droplet size spectra in small cumuli. The scheme developed in this work is ready to be used as a stochastic subgrid-scale scheme in LESs of natural clouds.

Shipboard Measurements of Aerosol Properties in the Coupled Ocean-Atmosphere System of the Northwest Tropical Atlantic

2020 ◽  
Author(s):  
Tim Bates ◽  
Patricia Quinn
Keyword(s):  
Solar Radiation ◽  
Marine Boundary Layer ◽  
Cloud Condensation Nuclei ◽  
Cloud Droplet ◽  
Lower Atmosphere ◽  
Radiation Balance ◽  
Tropical Atlantic ◽  
Shallow Convection ◽  
Condensation Nuclei ◽  
Aerosol Properties

&lt;p&gt;The fair-weather cumulus clouds, that cover much of the low-latitude oceans, affect the radiation balance of the planet by reflecting incoming solar radiation and absorbing outgoing longwave radiation.&amp;#160; These clouds also drive atmospheric circulation by mixing the lower atmosphere in a process called shallow convection.&amp;#160; This mixing, in turn, affects sea surface temperature and salinity by moderating the air-sea exchange of energy and moisture.&amp;#160; Marine boundary layer (MBL) atmospheric aerosols play a role in the processes described above by scattering and absorbing solar radiation and by serving as cloud condensation nuclei (CCN) thereby influencing cloud droplet concentrations and size; the extent, lifetime, and albedo of clouds; and the frequency and intensity of precipitation. Quantifying the role of aerosols over the Northwest Tropical Atlantic is critical to advance understanding of shallow convection and air-sea interactions.&lt;/p&gt;&lt;p&gt;MBL aerosol properties were measured aboard the RV Ronald H. Brown during the EUREC4A and ATOMIC field studies in January/February 2020.&amp;#160; Aerosols encountered during the study include background sulfate/sea spray particles and African dust/biomass burning particles.&amp;#160; Aerosol physical, chemical, optical and cloud condensation nuclei properties will be presented and their interaction with local and regional circulation.&lt;/p&gt;

scholarly journals Comparison of Aircraft Measurements during GoAmazon2014/5 and ACRIDICON-CHUVA

2019 ◽  
Author(s):  
Fan Mei ◽  
Jian Wang ◽  
Jennifer M. Comstock ◽  
Ralf Weigel ◽  
Martina Krämer ◽  
...  
Keyword(s):  
Size Distribution ◽  
Cloud Condensation Nuclei ◽  
Aerosol Particles ◽  
Cloud Droplet ◽  
Droplet Size Distribution ◽  
Department Of Energy ◽  
Atmospheric Environment ◽  
Radiation Balance ◽  
Uncertainty Sources ◽  
The Individual

Abstract. The indirect effect of atmospheric aerosol particles on the Earth’s radiation balance remains one of the most uncertain components affecting climate change throughout the industrial period. This issue is partially a result of the incomplete understanding of aerosol-cloud interactions. One objective of the GoAmazon2014/5 and ACRIDICON-CHUVA projects was to improve the understanding of the influence of the emissions of the tropical megacity of Manaus (Brazil) on the surrounding atmospheric environment of the rainforest and to investigate its role in the life cycle of convective clouds. During one of the intensive observation periods (IOPs) in the dry season from September 1 to October 10, 2014, comprehensive instrument suites collected data from several ground sites. In a coordinated way, the advanced suites of sophisticated instruments were deployed in situ both from the U.S. Department of Energy Gulfstream-1 (G1) aircraft and the German High Altitude and Long-Range Research Aircraft (HALO) during three coordinated flights on September 9, 21, and October 1. Here we report on the comparison of measurements collected by the two aircraft during these three flights. Such comparisons are difficult to obtain, but they are essential for assessing the data quality from the individual platforms and quantifying their uncertainty sources. Similar instruments mounted on the G1 and HALO collected vertical profile measurements of aerosol particles number concentration and size distribution, cloud condensation nuclei concentration, ozone, and carbon monoxide concentration, cloud droplet size distribution, and downward solar irradiance. We find that the above measurements from the two aircraft agreed within the range given by the measurement uncertainties. Aerosol chemical composition measured by instruments on HALO agreed with the corresponding G1 data collected at high altitudes only. Furthermore, possible causes of discrepancies between the data sets collected by the G1 and HALO instrumentation are addressed in this paper. Based on these results, criteria for meaningful aircraft measurement comparisons are discussed.

scholarly journals Impact of mineral dust on cloud formation in a Saharan outflow region

2011 ◽  
Vol 11 (12) ◽  
pp. 32363-32390 ◽  
Author(s):  
L. Smoydzin ◽  
A. Teller ◽  
H. Tost ◽  
M. Fnais ◽  
J. Lelieveld
Keyword(s):  
Radiative Forcing ◽  
Mineral Dust ◽  
Eastern Mediterranean ◽  
Cloud Condensation Nuclei ◽  
Coupled Model ◽  
Cloud Formation ◽  
Dust Particles ◽  
Ice Nuclei ◽  
Outflow Region ◽  
The Impact

Abstract. We present a numerical modelling study investigating the impact of mineral dust on cloud formation over the Eastern Mediterranean for two case studies: (i) 25 September 2008 and (ii) 28/29 January 2003. On both days dust plumes crossed the Mediterranean and interacted with clouds forming along frontal systems. For our investigation we used the fully online coupled model WRF-chem. The results show that increased aerosol concentrations due to the presence of mineral dust can enhance the formation of ice crystals. This leads to slight shifts of the spatial and temporal precipitation patterns compared to scenarios where dust was not considered to act as ice nuclei. However, the total amount of precipitation did not change significantly. The only exception occurred when dust entered into an area of orographic ascent, causing glaciation of the clouds, leading to a local enhancement of rainfall. The impact of dust particles acting as giant cloud condensation nuclei on precipitation formation was found to be small. Based on our simulations the contribution of dust to the CCN population is potentially significant only for warm phase clouds. Nevertheless, the dust-induced differences in the microphysical structure of the clouds can contribute to a significant radiative forcing.

scholarly journals Comparison of aircraft measurements during GoAmazon2014/5 and ACRIDICON-CHUVA

2020 ◽  
Vol 13 (2) ◽  
pp. 661-684 ◽  
Author(s):  
Fan Mei ◽  
Jian Wang ◽  
Jennifer M. Comstock ◽  
Ralf Weigel ◽  
Martina Krämer ◽  
...  
Keyword(s):  
Cloud Condensation Nuclei ◽  
Cloud Droplet ◽  
Convective Cloud ◽  
Department Of Energy ◽  
Atmospheric Environment ◽  
Radiation Balance ◽  
Mixing Ratios ◽  
Aerosol Cloud ◽  
Uncertainty Sources ◽  
The Individual

Abstract. The indirect effect of atmospheric aerosol particles on the Earth's radiation balance remains one of the most uncertain components affecting climate change throughout the industrial period. The large uncertainty is partly due to the incomplete understanding of aerosol–cloud interactions. One objective of the GoAmazon2014/5 and the ACRIDICON (Aerosol, Cloud, Precipitation, and Radiation Interactions and Dynamics of Convective Cloud Systems)-CHUVA (Cloud Processes of the Main Precipitation Systems in Brazil) projects was to understand the influence of emissions from the tropical megacity of Manaus (Brazil) on the surrounding atmospheric environment of the rainforest and to investigate its role in the life cycle of convective clouds. During one of the intensive observation periods (IOPs) in the dry season from 1 September to 10 October 2014, comprehensive measurements of trace gases and aerosol properties were carried out at several ground sites. In a coordinated way, the advanced suites of sophisticated in situ instruments were deployed aboard both the US Department of Energy Gulfstream-1 (G1) aircraft and the German High Altitude and Long-Range Research Aircraft (HALO) during three coordinated flights on 9 and 21 September and 1 October. Here, we report on the comparison of measurements collected by the two aircraft during these three flights. Such comparisons are challenging but essential for assessing the data quality from the individual platforms and quantifying their uncertainty sources. Similar instruments mounted on the G1 and HALO collected vertical profile measurements of aerosol particle number concentrations and size distribution, cloud condensation nuclei concentrations, ozone and carbon monoxide mixing ratios, cloud droplet size distributions, and downward solar irradiance. We find that the above measurements from the two aircraft agreed within the measurement uncertainties. The relative fraction of the aerosol chemical composition measured by instruments on HALO agreed with the corresponding G1 data, although the total mass loadings only have a good agreement at high altitudes. Furthermore, possible causes of the discrepancies between measurements on the G1 and HALO are examined in this paper. Based on these results, criteria for meaningful aircraft measurement comparisons are discussed.

scholarly journals New particle formation in the southern Aegean Sea during the Etesians: importance for CCN production and cloud droplet number

2017 ◽  
Vol 17 (1) ◽  
pp. 175-192 ◽  
Author(s):  
Panayiotis Kalkavouras ◽  
Elissavet Bossioli ◽  
Spiros Bezantakos ◽  
Aikaterini Bougiatioti ◽  
Nikos Kalivitis ◽  
...  
Keyword(s):  
Water Vapor ◽  
Eastern Mediterranean ◽  
Cloud Condensation Nuclei ◽  
Cloud Droplet ◽  
Aegean Sea ◽  
Particle Formation ◽  
Cloud Formation ◽  
Particle Nucleation ◽  
Surface Winds ◽  
New Particle Formation

Abstract. This study examines how new particle formation (NPF) in the eastern Mediterranean in summer affects CCN (cloud condensation nuclei) concentrations and cloud droplet formation. For this, the concentration and size distribution of submicron aerosol particles, along with the concentration of trace gases and meteorological variables, were studied over the central (Santorini) and southern Aegean Sea (Finokalia, Crete) from 15 to 28 July 2013, a period that includes Etesian events and moderate northern surface winds. Particle nucleation bursts were recorded during the Etesian flow at both stations, with those observed at Santorini reaching up to 1.5  ×  104 particles cm−3; the fraction of nucleation-mode particles over Crete was relatively diminished, but a higher number of Aitken-mode particles were observed as a result of aging. Aerosol and photochemical pollutants covaried throughout the measurement period; lower concentrations were observed during the period of Etesian flow (e.g., 43–70 ppbv for ozone and 1.5–5.7 µg m−3 for sulfate) but were substantially enhanced during the period of moderate surface winds (i.e., increase of up to 32 for ozone and 140 % for sulfate). We find that NPF can double CCN number (at 0.1 % supersaturation), but the resulting strong competition for water vapor in cloudy updrafts decreases maximum supersaturation by 14 % and augments the potential droplet number only by 12 %. Therefore, although NPF events may strongly elevate CCN numbers, the relative impacts on cloud droplet number (compared to pre-event levels) is eventually limited by water vapor availability and depends on the prevailing cloud formation dynamics and the aerosol levels associated with the background of the region.

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