scholarly journals Continuous measurements of methane mixing ratios from ice cores

2012 ◽  
Vol 5 (5) ◽  
pp. 999-1013 ◽  
Author(s):  
C. Stowasser ◽  
C. Buizert ◽  
V. Gkinis ◽  
J. Chappellaz ◽  
S. Schüpbach ◽  
...  
Keyword(s):  
Measurement Technique ◽  
Transport Model ◽  
Ice Core ◽  
Flow Analysis ◽  
Ice Cores ◽  
Atmospheric Methane ◽  
Water Stream ◽  
Mixing Ratios ◽  
The North ◽  
Analysis System

Abstract. This work presents a new, field-deployable technique for continuous, high-resolution measurements of methane mixing ratios from ice cores. The technique is based on a continuous flow analysis system, where ice core samples cut along the long axis of an ice core are melted continuously. The past atmospheric air contained in the ice is separated from the melt water stream via a system for continuous gas extraction. The extracted gas is dehumidified and then analyzed by a Wavelength Scanned-Cavity Ring Down Spectrometer for methane mixing ratios. We assess the performance of the new measurement technique in terms of precision (±0.8 ppbv, 1σ), accuracy (±8 ppbv), temporal (ca. 100 s), and spatial resolution (ca. 5 cm). Using a firn air transport model, we compare the resolution of the measurement technique to the resolution of the atmospheric methane signal as preserved in ice cores in Greenland. We conclude that our measurement technique can resolve all climatically relevant variations as preserved in the ice down to an ice depth of at least 1980 m (66 000 yr before present) in the North Greenland Eemian Ice Drilling ice core. Furthermore, we describe the modifications, which are necessary to make a commercially available spectrometer suitable for continuous methane mixing ratio measurements from ice cores.

scholarly journals Continuous measurements of methane mixing ratios from ice cores

2012 ◽  
Vol 5 (1) ◽  
pp. 211-244 ◽  
Author(s):  
C. Stowasser ◽  
C. Buizert ◽  
V. Gkinis ◽  
J. Chappellaz ◽  
S. Schüpbach ◽  
...  
Keyword(s):  
Measurement Technique ◽  
Transport Model ◽  
Ice Core ◽  
Flow Analysis ◽  
Ice Cores ◽  
Atmospheric Methane ◽  
Water Stream ◽  
Mixing Ratios ◽  
The North ◽  
Analysis System

Abstract. This work presents a new, field-deployable technique for continuous, high-resolution measurements of methane mixing ratios from ice cores. The technique is based on a continuous flow analysis system, where ice core samples cut along the long axis of an ice core are melted continuously. The past atmospheric air contained in the ice is separated from the melt water stream via a system for continuous gas extraction. The extracted gas is dehumidified and then analyzed by a Wavelength Scanned-Cavity Ring Down Spectrometer for methane mixing ratios. We assess the performance of the new measurement technique in terms of precision (±0.8 ppbv, 1 σ), accuracy (±8 ppbv), temporal (ca. 100 s) and spatial resolution (ca. 6 cm). Using a firn air transport model, we compare the resolution of the measurement technique to the resolution of the atmospheric methane signal as preserved in ice cores in Greenland. We conclude that our measurement technique can resolve all climatically relevant variations as preserved in the ice down to an ice depth of at least 1980 m (66 000 yr before present) in the North Greenland Eemian Ice Drilling ice core. Furthermore, we describe the modifications which are necessary to make a commercially available spectrometer suitable for continuous methane mixing ratio measurements from ice cores.

scholarly journals What could have caused pre-industrial biomass burning emissions to exceed current rates?

2013 ◽  
Vol 9 (1) ◽  
pp. 289-306 ◽  
Author(s):  
G. R. van der Werf ◽  
W. Peters ◽  
T. T. van Leeuwen ◽  
L. Giglio
Keyword(s):  
Population Density ◽  
Biomass Burning ◽  
Transport Model ◽  
Ice Core ◽  
Ice Cores ◽  
Fire Emissions ◽  
Core Data ◽  
Mixing Ratios ◽  
The Past ◽  
Co Concentrations

Abstract. Recent studies based on trace gas mixing ratios in ice cores and charcoal data indicate that biomass burning emissions over the past millennium exceeded contemporary emissions by up to a factor of 4 for certain time periods. This is surprising because various sources of biomass burning are linked with population density, which has increased over the past centuries. We have analysed how emissions from several landscape biomass burning sources could have fluctuated to yield emissions that are in correspondence with recent results based on ice core mixing ratios of carbon monoxide (CO) and its isotopic signature measured at South Pole station (SPO). Based on estimates of contemporary landscape fire emissions and the TM5 chemical transport model driven by present-day atmospheric transport and OH concentrations, we found that CO mixing ratios at SPO are more sensitive to emissions from South America and Australia than from Africa, and are relatively insensitive to emissions from the Northern Hemisphere. We then explored how various landscape biomass burning sources may have varied over the past centuries and what the resulting emissions and corresponding CO mixing ratio at SPO would be, using population density variations to reconstruct sources driven by humans (e.g., fuelwood burning) and a new model to relate savanna emissions to changes in fire return times. We found that to match the observed ice core CO data, all savannas in the Southern Hemisphere had to burn annually, or bi-annually in combination with deforestation and slash and burn agriculture exceeding current levels, despite much lower population densities and lack of machinery to aid the deforestation process. While possible, these scenarios are unlikely and in conflict with current literature. However, we do show the large potential for increased emissions from savannas in a pre-industrial world. This is mainly because in the past, fuel beds were probably less fragmented compared to the current situation; satellite data indicates that the majority of savannas have not burned in the past 10 yr, even in Africa, which is considered "the burning continent". Although we have not considered increased charcoal burning or changes in OH concentrations as potential causes for the elevated CO concentrations found at SPO, it is unlikely they can explain the large increase found in the CO concentrations in ice core data. Confirmation of the CO ice core data would therefore call for radical new thinking about causes of variable global fire rates over recent centuries.

scholarly journals What could have caused pre-industrial biomass burning emissions to exceed current rates?

2012 ◽  
Vol 8 (4) ◽  
pp. 3159-3204 ◽  
Author(s):  
G. R. van der Werf ◽  
W. Peters ◽  
T. T. van Leeuwen ◽  
L. Giglio
Keyword(s):  
Population Density ◽  
Biomass Burning ◽  
Transport Model ◽  
Ice Core ◽  
Ice Cores ◽  
Current Data ◽  
Chemical Transport Model ◽  
Fire Emissions ◽  
Mixing Ratios ◽  
The Past

Abstract. Recent studies based on trace gas mixing ratios in ice cores and charcoal data indicate that biomass burning emissions over the past millennium exceeded contemporary emissions by up to a factor of 4 for certain time periods. This is surprising because various sources of biomass burning are linked with population density, which has increased over the past centuries. Here we have analyzed how emissions from several biomass burning sources could have fluctuated to yield emissions that are in correspondence with recent results based on ice core mixing ratios of carbon monoxide (CO) and its isotopic signature measured at South Pole station (SPO). Based on estimates of contemporary fire emissions and the TM5 chemical transport model, we found that CO mixing ratios at SPO are more sensitive to emissions from South America and Australia than from Africa, and are relatively insensitive to emissions from the Northern Hemisphere. We then explored how various biomass burning sources may have varied over the past centuries and what the resulting emissions and corresponding CO mixing ratio at SPO would be, using population density variations to reconstruct sources driven by humans (e.g. fuelwood burning) and a new model to relate savanna emissions to changes in fire return times. We found that to match the observed ice core CO data all savannas in the Southern Hemisphere had to burn annually, or bi-annually in combination with deforestation and slash and burn agriculture matching current levels despite much lower population densities and lack of machinery to aid the deforestation process. While possible, these scenarios are unlikely and in conflict with current literature. However, we do show the large potential for increased emissions from savannas in a pre-industrial world. This is mainly because in the past, fuel beds were probably less fragmented compared to the current situation; we show that the majority of savannas have not burned in the past 10 yr, even in Africa which is considered "the burning continent". Our new modelling results, together with existing literature, indicate that no definitive conclusions can be drawn about unprecedentedly high or low biomass burning rates from current data analyses.

scholarly journals A new continuous high-resolution detection system for sulphate in ice cores

2007 ◽  
Vol 45 ◽  
pp. 178-182 ◽  
Author(s):  
Matthias Bigler ◽  
Anders Svensson ◽  
Jørgen Peder Steffensen ◽  
Patrik Kaufmann
Keyword(s):  
Detection System ◽  
Ice Core ◽  
Flow Analysis ◽  
Ice Cores ◽  
Volcanic Eruptions ◽  
Barium Sulphate ◽  
High Temporal Resolution ◽  
Continuous Flow Analysis ◽  
Explosive Volcanic Eruptions ◽  
Analysis System

AbstractSulphate (SO42–) is a major ion found in polar ice cores and is related to different aerosol sources and processes. Explosive volcanic eruptions, even far away, can cause distinct sulphate peaks in ice core records. Thus, a robust sulphate detection system which is suitable for fieldwork and which enables the measurement of sulphate at high temporal resolution is of great interest. In this study, we present the adaptation of a new continuous flow analysis system for sulphate that is based on a spectrophotometric method using dimethylsulfonazo III and an inline reactor column containing barium sulphate particles. The method shows a detection limit of ∽70 ng g–1 and a linear range up to at least 3000 ng g–1. It is simple, robust and less prone to interferences compared to the previously used method.

scholarly journals Towards reconstructing the Arctic atmospheric methane history over the 20th century: measurement and modeling results for the NGRIP firn

2021 ◽  
Author(s):  
Taku Umezawa ◽  
Satoshi Sugawara ◽  
Kenji Kawamura ◽  
Ikumi Oyabu ◽  
Stephen J. Andrews ◽  
...  
Keyword(s):  
Mole Fraction ◽  
Transport Model ◽  
Ice Core ◽  
Ice Cores ◽  
Intermediate Stage ◽  
Air Transport ◽  
The Arctic ◽  
Data Sets ◽  
Atmospheric Methane ◽  
North Greenland

Abstract. Systematic measurements of atmospheric methane (CH4) mole fractions at the northern high latitudes only began in the early 1980s, and whilst CH4 measurements from Greenland ice cores covered the period before ~1900, no reliable observational record is available for the intermediate period. In this study, we reconstruct the atmospheric CH4 for that period, when the mole fraction started to increase rapidly. We use a set of trace gas data measured from firn (an intermediate stage between snow and glacial ice formation) air samples collected at the NGRIP (North Greenland Ice Core Project) site in 2001, in combination with a firn air transport model whose performance is validated by using a set of published firn air data at the NEEM (North Greenland Eemian ice Drilling) site. We examine a variety of possible firn diffusivity profiles using a suite of measured trace gases, and reconstruct the CH4 mole fraction by an iterative dating method. We find that, given the currently available firn air data sets from Greenland, reliable reconstruction of the Arctic CH4 mole fraction is possible only back to the mid 1970s. For the earlier period, it is difficult to identify the atmospheric CH4 history that consistently reproduce the depth profiles of CH4 in firn at both NGRIP and NEEM sites. Therefore, the currently proposed Arctic CH4 history should still be considered preliminary and uncertain, and should not be treated as the known history for constraining firn-air transport models.

scholarly journals A Synoptic Scale Perspective on Greenland Ice Core δ18O Variability and Related Teleconnection Patterns

Atmosphere ◽  
2021 ◽  
Vol 12 (3) ◽  
pp. 294
Author(s):  
Norel Rimbu ◽  
Monica Ionita ◽  
Gerrit Lohmann
Keyword(s):  
Ice Core ◽  
Ice Cores ◽  
Synoptic Scale ◽  
Local Climate ◽  
Rossby Wave Breaking ◽  
Weather Patterns ◽  
Teleconnection Patterns ◽  
Climate Anomalies ◽  
The North ◽  
Oxygen Isotope Ratios

The variability of stable oxygen isotope ratios (δ18O) from Greenland ice cores is commonly linked to changes in local climate and associated teleconnection patterns. In this respect, in this study we investigate ice core δ18O variability from a synoptic scale perspective to assess the potential of such records as proxies for extreme climate variability and associated weather patterns. We show that positive (negative) δ18O anomalies in three southern and central Greenland ice cores are associated with relatively high (low) Rossby Wave Breaking (RWB) activity in the North Atlantic region. Both cyclonic and anticyclonic RWB patterns associated with high δ18O show filaments of strong moisture transport from the Atlantic Ocean towards Greenland. During such events, warm and wet conditions are recorded over southern, western and central part of Greenland. In the same time the cyclonic and anticyclonic RWB patterns show enhanced southward advection of cold polar air masses on their eastern side, leading to extreme cold conditions over Europe. The association between high δ18O winters in Greenland ice cores and extremely cold winters over Europe is partly explained by the modulation of the RWB frequency by the tropical Atlantic sea surface temperature forcing, as shown in recent modeling studies. We argue that δ18O from Greenland ice cores can be used as a proxy for RWB activity in the Atlantic European region and associated extreme weather and climate anomalies.

scholarly journals Impact of precipitation intermittency on NAO-temperature signals in proxy records

2013 ◽  
Vol 9 (2) ◽  
pp. 871-886 ◽  
Author(s):  
M. Casado ◽  
P. Ortega ◽  
V. Masson-Delmotte ◽  
C. Risi ◽  
D. Swingedouw ◽  
...  
Keyword(s):  
General Circulation ◽  
Ice Core ◽  
Circulation Model ◽  
Ice Cores ◽  
Stable Isotope Ratio ◽  
Global Network ◽  
Temporal Correlations ◽  
The North ◽  
The North Atlantic Oscillation ◽  
The Impact

Abstract. In mid and high latitudes, the stable isotope ratio in precipitation is driven by changes in temperature, which control atmospheric distillation. This relationship forms the basis for many continental paleoclimatic reconstructions using direct (e.g. ice cores) or indirect (e.g. tree ring cellulose, speleothem calcite) archives of past precipitation. However, the archiving process is inherently biased by intermittency of precipitation. Here, we use two sets of atmospheric reanalyses (NCEP (National Centers for Environmental Prediction) and ERA-interim) to quantify this precipitation intermittency bias, by comparing seasonal (winter and summer) temperatures estimated with and without precipitation weighting. We show that this bias reaches up to 10 °C and has large interannual variability. We then assess the impact of precipitation intermittency on the strength and stability of temporal correlations between seasonal temperatures and the North Atlantic Oscillation (NAO). Precipitation weighting reduces the correlation between winter NAO and temperature in some areas (e.g. Québec, South-East USA, East Greenland, East Siberia, Mediterranean sector) but does not alter the main patterns of correlation. The correlations between NAO, δ18O in precipitation, temperature and precipitation weighted temperature are investigated using outputs of an atmospheric general circulation model enabled with stable isotopes and nudged using reanalyses (LMDZiso (Laboratoire de Météorologie Dynamique Zoom)). In winter, LMDZiso shows similar correlation values between the NAO and both the precipitation weighted temperature and δ18O in precipitation, thus suggesting limited impacts of moisture origin. Correlations of comparable magnitude are obtained for the available observational evidence (GNIP (Global Network of Isotopes in Precipitation) and Greenland ice core data). Our findings support the use of archives of past δ18O for NAO reconstructions.

scholarly journals A 60 000 year Greenland stratigraphic ice core chronology

2008 ◽  
Vol 4 (1) ◽  
pp. 47-57 ◽  
Author(s):  
A. Svensson ◽  
K. K. Andersen ◽  
M. Bigler ◽  
H. B. Clausen ◽  
D. Dahl-Jensen ◽  
...  
Keyword(s):  
North Atlantic ◽  
Time Scale ◽  
Ice Core ◽  
Ice Cores ◽  
The North ◽  
Annual Layer ◽  
Zone Ii ◽  
Absolute Age ◽  
Age Estimates ◽  
New Time

Abstract. The Greenland Ice Core Chronology 2005 (GICC05) is a time scale based on annual layer counting of high-resolution records from Greenland ice cores. Whereas the Holocene part of the time scale is based on various records from the DYE-3, the GRIP, and the NorthGRIP ice cores, the glacial part is solely based on NorthGRIP records. Here we present an 18 ka extension of the time scale such that GICC05 continuously covers the past 60 ka. The new section of the time scale places the onset of Greenland Interstadial 12 (GI-12) at 46.9±1.0 ka b2k (before year AD 2000), the North Atlantic Ash Zone II layer in GI-15 at 55.4±1.2 ka b2k, and the onset of GI-17 at 59.4±1.3 ka b2k. The error estimates are derived from the accumulated number of uncertain annual layers. In the 40–60 ka interval, the new time scale has a discrepancy with the Meese-Sowers GISP2 time scale of up to 2.4 ka. Assuming that the Greenland climatic events are synchronous with those seen in the Chinese Hulu Cave speleothem record, GICC05 compares well to the time scale of that record with absolute age differences of less than 800 years throughout the 60 ka period. The new time scale is generally in close agreement with other independently dated records and reference horizons, such as the Laschamp geomagnetic excursion, the French Villars Cave and the Austrian Kleegruben Cave speleothem records, suggesting high accuracy of both event durations and absolute age estimates.

PANDA, the French analytical platform dedicated to ice core

2021 ◽  
Author(s):  
Sophie Darfeuil ◽  
Patrick Ginot ◽  
Joel Savarino ◽  
Nicolas Caillon ◽  
Xavier Faïn ◽  
...  
Keyword(s):  
Trace Metals ◽  
Major Ions ◽  
Ice Core ◽  
Flow Analysis ◽  
Common Interest ◽  
Continuous Flow Analysis ◽  
Laser Spectrometry ◽  
O Isotopes ◽  
And Performance ◽  
Analysis System

<p>Since 2018, under the impetus of the IGE (Grenoble) and the LSCE (Saclay) and the common interest of the "Carottes de Glace France" consortium, an analytical platform dedicated to glacier archives was created to meet the growing analytical needs requested by projects involving French partners (Ice Memory, EAIIST, BE-OI ...) and international collaborations with a ten-year vision. Within this framework 5 modules have been developed between the IGE and the LSCE. 3 modules are installed at the IGE, including a CHEMISTRY module which includes a large number of instruments coupled to the CFA (Continuous Flow Analysis) system, allowing high-resolution multi tracer analysis on a single ice stick (water isotopes, dust, conductivity, colorimetry, black carbon, trace metals and gas) as well as several auto-samplers for discrete analyses (major ions, organic species, trace metals, sugars ...). The GAS module is shared between continuous analyses on the CFA system (laser spectrometry CH<sub>4</sub>/CO) and discrete analyses (Gas chromatography CH<sub>4</sub>/CO<sub>2</sub>). The ISOTOPY module allows the analysis of nitrogen (N), sulfur (S) and oxygen (O) isotopes. At the LSCE, the WATER ISOTOPY module allows continuous (Picarro coupled to a CFA line equipped with conductivity cells and auto-sampler) or discrete (Picarro or mass spectrometer) analyses for δD, δ<sup>18</sup>O and δ<sup>17</sup>O in water. The AIR ISOTOPY module completes the platform for analyses by mass spectrometry of δ<sup>15</sup>N of N<sub>2</sub>, the triple isotopic composition of O<sub>2</sub> and noble gases isotopes (36/38/40 Ar; 82/84/86 Kr; 129-132 Xe). An overview of the capacity and performance of the platform will be presented.</p>

scholarly journals Precipitation record since AD 1600 from ice cores on the central Tibetan Plateau

2008 ◽  
Vol 4 (3) ◽  
pp. 175-180 ◽  
Author(s):  
T. Yao ◽  
K. Duan ◽  
B. Xu ◽  
N. Wang ◽  
X. Guo ◽  
...  
Keyword(s):  
Tibetan Plateau ◽  
Ice Core ◽  
Ice Cores ◽  
The North ◽  
Northern Tibetan Plateau ◽  
Central Tibetan Plateau ◽  
Precipitation Record ◽  
Ice Field ◽  
The 19Th Century

Abstract. Lack of reliable long-term precipitation record from the northern Tibetan Plateau has constrained our understanding of precipitation variations in this region. We drilled an ice core on the Puruogangri Ice Field in the central Tibetan Plateau in 2000 to reveal the precipitation variations. The well dated part of the core extends back to AD 1600, allowing us to construct a 400-year annual accumulation record. This record shows that the central Tibetan plateau experienced a drier period with an average annual precipitation of ~300 mm in the 19th century, compared to ~450 mm in the wetter periods during 1700–1780 and the 20th century. This pattern agrees with precipitation reconstructions from the Dunde and Guliya ice cores on the northern Plateau but differs from that found in the Dasuopu ice cores from the southern Plateau The north-south contrasts in precipitation reconstruction reveals difference in moisture origin between the south Tibetan Plateau dominated by the Asian monsoon and the north Tibetan Plateau dominated by the continental recycling and the westerlies.

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