scholarly journals Thermal and haline effects on the calculation of air-sea CO<sub>2</sub> fluxes revisited

2012 ◽  
Vol 9 (11) ◽  
pp. 16381-16417 ◽  
Author(s):  
D. K. Woolf ◽  
P. E. Land ◽  
J. D. Shutler ◽  
L. M. Goddijn-Murphy

Abstract. The presence of vertical temperature and salinity gradients in the upper ocean and the occurrence of variations in temperature and salinity on time scales from hours to many years complicate the calculation of the flux of carbon dioxide (CO2) across the sea surface. Temperature and salinity affect the interfacial concentration of aqueous CO2 primarily through their effect on solubility with lesser effects related to saturated vapour pressure and the relationship between fugacity and partial pressure. The effects of temperature and salinity profiles and changes in the aqueous concentration act primarily through the partitioning of the carbonate system. Contrary to some recent analysis, it is shown that the effect on CO2 fluxes of a cool skin on the sea surface is large and ubiquitous. An opposing effect on calculated fluxes is related to the occurrence of warm layers near the surface; this effect can be locally large but will usually coincide with periods of low exchange. A salty skin and salinity anomalies in the upper ocean also affect CO2 flux calculations, though the haline effects are generally weaker than the thermal effects.

2014 ◽  
Vol 11 (4) ◽  
pp. 1895-1948 ◽  
Author(s):  
L. M. Goddijn-Murphy ◽  
D. K. Woolf ◽  
P. E. Land ◽  
J. D. Shutler ◽  
C. Donlon

Abstract. Climatologies, or long-term averages, of essential climate variables are useful for evaluating models and providing a baseline for studying anomalies. The Surface Ocean Carbon Dioxide (CO2) Atlas (SOCAT) has made millions of global underway sea surface measurements of CO2 publicly available, all in a uniform format and presented as fugacity, fCO2. fCO2 is highly sensitive to temperature and the measurements are only valid for the instantaneous sea surface temperature (SST) that is measured concurrent with the in-water CO2 measurement. To create a climatology of fCO2 data suitable for calculating air–sea CO2 fluxes it is therefore desirable to calculate fCO2 valid for climate quality SST. This paper presents a method for creating such a climatology. We recomputed SOCAT's fCO2 values for their respective measurement month and year using climate quality SST data from satellite Earth observation and then extrapolated the resulting fCO2 values to reference year 2010. The data were then spatially interpolated onto a 1° × 1° grid of the global oceans to produce 12 monthly fCO2 distributions for 2010. The partial pressure of CO2 (pCO2) is also provided for those who prefer to use pCO2. The CO2 concentration difference between ocean and atmosphere is the thermodynamic driving force of the air–sea CO2 flux, and hence the presented fCO2 distributions can be used in air–sea gas flux calculations together with climatologies of other climate variables.


Water ◽  
2018 ◽  
Vol 10 (10) ◽  
pp. 1326 ◽  
Author(s):  
Dan Song ◽  
Linghui Guo ◽  
Zhigang Duan ◽  
Lulu Xiang

Studying the interaction between the upper ocean and the typhoons is crucial to improve our understanding of heat and momentum exchange between the ocean and the atmosphere. In recent years, the upper ocean responses to typhoons have received considerable attention. The sea surface cooling (SSC) process has been repeatedly discussed. In the present work, case studies were examined on five strong and super typhoons that occurred in 2016—LionRock, Meranti, Malakas, Megi, and Chaba—to search for more evidence of SSC and new features of typhoons’ impact on sea surface features. Monitoring data from the Central Meteorological Observatory, China, sea surface temperature (SST) data from satellite microwave and infrared remote sensing, and sea level anomaly (SLA) data from satellite altimeters were used to analyze the impact of typhoons on SST, the relationship between SSC and pre-existing eddies, the distribution of cold and warm eddies before and after typhoons, as well as the relationship between eddies and the intensity of typhoons. Results showed that: (1) SSC generally occurred during a typhoon passage and the degree of SSC was determined by the strength and the translation speed of the typhoon, as well as the pre-existing sea surface conditions. Relatively lower sea level (or cold core eddy) favors causing intense SSC; (2) After a typhoon passed, the SLA obviously decreased along with the SSC. The pre-existing positive SLAs or warm eddies decreased or disappeared during the typhoon’s passage, whereas negative SLAs or cold eddies were enhanced. It is suggested that the presence of warm eddies on the path has intensified the typhoons; (3) A criterion based on the ratio of local inertial period to application time of the typhoon wind-forcing was raised to dynamically distinguish slow- and fast-moving typhoons. And subcritical (slow-moving) situations were found in the LionRock case at its turning points where a cold core eddy was generated by long-time forcing. Moreover, the LionRock developed into a super typhoon due to reduced negative feedback when it was stalling over a comparably warmer sea surface. Therefore, the distinctive LionRock case is worthy of further discussion.


2022 ◽  
Vol 14 (2) ◽  
pp. 312
Author(s):  
Iwona Wrobel-Niedzwiecka ◽  
Małgorzata Kitowska ◽  
Przemyslaw Makuch ◽  
Piotr Markuszewski

A feed-forward neural network (FFNN) was used to estimate the monthly climatology of partial pressure of CO2 (pCO2W) at a spatial resolution of 1° latitude by 1° longitude in the continental shelf of the European Arctic Sector (EAS) of the Arctic Ocean (the Greenland, Norwegian, and Barents seas). The predictors of the network were sea surface temperature (SST), sea surface salinity (SSS), the upper ocean mixed-layer depth (MLD), and chlorophyll-a concentration (Chl-a), and as a target, we used 2 853 pCO2W data points from the Surface Ocean CO2 Atlas. We built an FFNN based on three major datasets that differed in the Chl-a concentration data used to choose the best model to reproduce the spatial distribution and temporal variability of pCO2W. Using all physical–biological components improved estimates of the pCO2W and decreased the biases, even though Chl-a values in many grid cells were interpolated values. General features of pCO2W distribution were reproduced with very good accuracy, but the network underestimated pCO2W in the winter and overestimated pCO2W values in the summer. The results show that the model that contains interpolating Chl-a concentration, SST, SSS, and MLD as a target to predict the spatiotemporal distribution of pCO2W in the sea surface gives the best results and best-fitting network to the observational data. The calculation of monthly drivers of the estimated pCO2W change within continental shelf areas of the EAS confirms the major impact of not only the biological effects to the pCO2W distribution and Air-Sea CO2 flux in the EAS, but also the strong impact of the upper ocean mixing. A strong seasonal correlation between predictor and pCO2W seen earlier in the North Atlantic is clearly a yearly correlation in the EAS. The five-year monthly mean CO2 flux distribution shows that all continental shelf areas of the Arctic Ocean were net CO2 sinks. Strong monthly CO2 influx to the Arctic Ocean through the Greenland and Barents Seas (>12 gC m−2 day−1) occurred in the fall and winter, when the pCO2W level at the sea surface was high (>360 µatm) and the strongest wind speed (>12 ms−1) was present.


Author(s):  
Noviandi Noviandi ◽  
Ahmad Ilham

Rainfall which is occurred in an area explain the Onset Rainy Season (ORS). ORS is a characteristic of the rainy season which is important to know, but the characteristics of the rain itself is very difficult to predict. We use the method of Fuzzy Inference System (FIS) to predict ORS. Unfortunately, FIS is weak to determine parameters so that influences the working FIS method. In this study, we use PSO to optimize parameter of the FIS method to increase perform of the FIS method for onset prediction of the rainy season with the predictor Sea Surface Temperature Nino 3.4 and Index Ocean Dipole. We used coefficient correlation to determine the relationship between two variables as predictors and RMSE as evaluate to all methods. The experiment result has shown that the work of FIS-PSO after optimizing produced the good work with the coefficient correlation = 0.57 and RMSE = 2.96 that is the smallest value that is better performance if compared with other methods. It can be concluded that the method proposed can increase the onset prediction of the rainy season.


2017 ◽  
Vol 30 (22) ◽  
pp. 9195-9211 ◽  
Author(s):  
John T. Fasullo ◽  
Peter R. Gent

Abstract An accurate diagnosis of ocean heat content (OHC) is essential for interpreting climate variability and change, as evidenced for example by the broad range of hypotheses that exists for explaining the recent hiatus in global mean surface warming. Potential insights are explored here by examining relationships between OHC and sea surface height (SSH) in observations and two recently available large ensembles of climate model simulations from the mid-twentieth century to 2100. It is found that in decadal-length observations and a model control simulation with constant forcing, strong ties between OHC and SSH exist, with little temporal or spatial complexity. Agreement is particularly strong on monthly to interannual time scales. In contrast, in forced transient warming simulations, important dependencies in the relationship exist as a function of region and time scale. Near Antarctica, low-frequency SSH variability is driven mainly by changes in the circumpolar current associated with intensified surface winds, leading to correlations between OHC and SSH that are weak and sometimes negative. In subtropical regions, and near other coastal boundaries, negative correlations are also evident on long time scales and are associated with the accumulated effects of changes in the water cycle and ocean dynamics that underlie complexity in the OHC relationship to SSH. Low-frequency variability in observations is found to exhibit similar negative correlations. Combined with altimeter data, these results provide evidence that SSH increases in the Indian and western Pacific Oceans during the hiatus are suggestive of substantial OHC increases. Methods for developing the applicability of altimetry as a constraint on OHC more generally are also discussed.


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