Geochemical and Sr-Nd isotopic characteristics of the lamprophyre in the Tethyan Himalaya, South Tibet

2020 ◽  
Author(s):  
Zhi-Chao Liu ◽  
Jian-Gang Wang ◽  
Xiao-Chi Liu
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Lithospheric Mantle ◽  
Indian Plate ◽  
Late Triassic ◽  
Geochemical Data ◽  
Low Grade ◽  
Northern Margin ◽  
Two Samples ◽  
Tethyan Himalaya

<p>A lamprophyre dyke has been found in Ramba area within the Tethyan Himalaya. It intruded into the Late Triassic low-grade metasedimentary rocks (Langjiexue Group) and show typical porphyritic textures, with phlogopite as the dominant phenocrysts. In this study, we performed phlogopite 40Ar/39Ar dating and whole-rock major and trace element as well as Sr and Nd isotope geochemical analyses on the lamprophyre. The <sup>40</sup>Ar/<sup>39</sup>Ar plateau ages (13.1 ± 0.2 Ma and 13.5 ± 0.2 Ma) of the phlogopites from two samples are both in excellent agreement with the inverse isochron ages of 13.1 ±0.3 Ma and 13.6 ± 0.3 Ma, recording the times at which the lamprophyre dyke has cooled below ~300 °C. The lamprophyre has low contents of SiO<sub>2</sub> (51.43–55.15 wt%) and Al<sub>2</sub>O<sub>3</sub> (11.10–11.85 wt%), high Fe<sub>2</sub>O<sub>3T</sub> (8.57–9.27 wt%) and MgO (9.14–9.49 wt %) contents with Mg<sup>#</sup> of 66–69, higher content of K<sub>2</sub>O (3.26–5.57 wt%) relative to Na<sub>2</sub>O (0.50–1.39 wt%) with K<sub>2</sub>O/Na<sub>2</sub>O of 2.3–11.1. Furthermore, the lamprophyre has high abundances of large ion lithophile elements (e.g., Rb, Ba, Sr), shows depletions in high field strength elements (e.g., Nb, Ta, Ti), and displays enrichment in light rare-earth elements over heavy rare earth elements with (La/Yb)<sub>N</sub> of 42.3~47.0. Besides, the lamprophyre is characterized by high initial <sup>87</sup>Sr/<sup>86</sup>Sr ratios of 0.7196~0.7204 and negative ε<sub>Nd</sub>(t) values of -10.7~-10.8. Geochemical data suggest that the Ramba lamprophyre was likely generated by partial melting of a metasomatized, phlogopite-bearing harzburgite lithospheric mantle source, followed by crystal fractionation and varying degree of crustal assimilation. The studied lamprophyre provides a window into the composition of the subcontinental lithospheric mantle (SCLM) in the northern margin of the Indian plate. We suggest that the northern Indian plate might be involved in the Andean-type orogeny from the subduction of the Proto-Tethys Ocean during Cambrian to Early Ordovician.</p>

Significance of the metasomatized lithospheric mantle in the formation of early basalts and Cu – platinum group element sulfide mineralization in the Coldwell Complex, Midcontinent Rift, Canada

2019 ◽  
Vol 56 (7) ◽  
pp. 693-714 ◽  
Author(s):  
David J. Good ◽  
Peter C. Lightfoot
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Trace Element ◽  
Lithospheric Mantle ◽  
Group Element ◽  
Light Rare Earth ◽  
Midcontinent Rift ◽  
Northern Margin ◽  
Lithospheric Mantle Source ◽  
Light Rare Earth Elements

A diverse suite of tholeiitic to alkaline basalt and gabbroic intrusions located in the Coldwell Complex on the northern margin of the Midcontinent Rift exhibit unusual trace element signatures that show enriched large ion lithophile elements and light rare earth elements with negative Nb and Zr anomalies. These features are not typical of magmas derived by partial melting within or above a rising mantle plume, as might be expected in an early Midcontinent Rift magmatic event. In this paper, we provide a detailed geochemical study of a 500 m thick sequence of metabasalt that represents the earliest stage of magmatism in the Coldwell Complex. We show that contamination or crystallization processes or subsequent metasomatism cannot explain the trace element variations. Instead, we propose partial melting in a metasomatized Subcontinental Lithospheric Mantle source to explain the decoupled behavior of large ion lithophile elements from light rare earth elements and heavy rare earth elements and rare earth elements from high field strength elements and the enriched Nd isotope signature of metabasalt. Similar features occur in unit 5b of the Mamainse Point Volcanic Group located at the northern margin of the Rift. An objective of this paper is to relate Two Duck Lake gabbro, host rock for low-sulfur, high precious metal sulfide mineralization at the Marathon deposit, to the metabasalt sequence. The excellent match of trace element abundances in Two Duck Lake gabbro to metabasalt unit 3 confirms an early Coldwell Complex age for metabasalt and a Subcontinental Lithospheric Mantle source for Cu – platinum group element mineralized gabbros.

scholarly journals Geological, Geochronological, and Geochemical Insights into the Formation of the Giant Pulang Porphyry Cu (–Mo–Au) Deposit in Northwestern Yunnan Province, SW China

Minerals ◽  
2019 ◽  
Vol 9 (3) ◽  
pp. 191 ◽  
Author(s):  
Qun Yang ◽  
Yun-Sheng Ren ◽  
Sheng-Bo Chen ◽  
Guo-Liang Zhang ◽  
Qing-Hong Zeng ◽  
...  
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Yunnan Province ◽  
Oceanic Lithosphere ◽  
Late Triassic ◽  
Porphyry Cu ◽  
Icp Ms ◽  
Heavy Rare Earth Elements ◽  
Granodiorite Porphyry ◽  
Northwestern Yunnan

The giant Pulang porphyry Cu (–Mo–Au) deposit in Northwestern Yunnan Province, China, is located in the southern part of the Triassic Yidun Arc. The Cu orebodies are mainly hosted in quartz monzonite porphyry (QMP) intruding quartz diorite porphyry (QDP) and cut by granodiorite porphyry (GP). New LA-ICP-MS zircon U–Pb ages indicate that QDP (227 ± 2 Ma), QMP (218 ± 1 Ma, 219 ± 1 Ma), and GP (209 ± 1 Ma) are significantly different in age; however, the molybdenite Re–Os isochron age (218 ± 2 Ma) indicates a close temporal and genetic relationship between Cu mineralization and QMP. Pulang porphyry intrusions are enriched in light rare-earth elements (LREEs) and large ion lithophile elements (LILEs), and depleted in heavy rare-earth elements (HREEs) and high field-strength elements (HFSEs), with moderately negative Eu anomalies. They are high in SiO2, Al2O3, Sr, Na2O/K2O, Mg#, and Sr/Y, but low in Y, and Yb, suggesting a geochemical affinity to high-silica (HSA) adakitic rocks. These features are used to infer that the Pulang HSA porphyry intrusions were derived from the partial melting of a basaltic oceanic-slab. These magmas reacted with peridotite during their ascent through the mantle wedge. This is interpreted to indicate that the Pulang Cu deposit and associated magmatism can be linked to the synchronous westward subduction of the Ganzi–Litang oceanic lithosphere, which has been established as Late Triassic.

Evolution of deep mantle sourced carbonated melt in the mantle lithosphere

2020 ◽  
Author(s):  
Guoliang Zhang
Keyword(s):  
Rare Earth ◽  
Field Strength ◽  
Rare Earth Elements ◽  
Lithospheric Mantle ◽  
High Field ◽  
Volcanic Rocks ◽  
Mantle Lithosphere ◽  
High Field Strength ◽  
Alkali Basalts ◽  
Deep Mantle

<p>Deep sourced magmas play a key role in distribution of carbon in the Earth’s system. Oceanic hotspots rooted in deep mantle usually produce CO<sub>2</sub>-rich magmas. However, the association of CO<sub>2</sub> with the origin of these magmas remains unclear. Here we report geochemical analyses of a suite of volcanic rocks from the Caroline Seamount Chain formed by the deep-rooted Caroline hotspot in the western Pacific. The most primitive magmas have depletion of SiO<sub>2</sub> and high field strength elements and enrichment of rare earth elements that are in concert with mantle-derived primary carbonated melts. The carbonated melts show compositional variations that indicate reactive evolution within the overlying mantle lithosphere and obtained depleted components from the lithospheric mantle. The carbonated melts were de-carbonated and modified to oceanic alkali basalts by precipitation of perovskite, apatite and ilmenite that significantly decreased the concentrations of rare earth elements and high field strength elements. These magmas experienced a stage of non-reactive fractional crystallization after the reactive evolution was completed. Thus, the carbonated melts would experience two stages, reactive and un-reactive, of evolution during their transport through in thick oceanic lithospheric mantle. We suggest that the mantle lithosphere plays a key role in de-carbonation and conversion of deep-sourced carbonated melts to alkali basalts. This work was financially supported by the National Natural Science Foundation of China (91858206, 41876040).</p>

scholarly journals Rare Earth Elements Assessment in the Granitoids of Part of Southwestern Nigeria

2020 ◽  
Vol 1 (5) ◽  
Author(s):  
Victoria B. Omotunde ◽  
Akinade S. Olatunji ◽  
Maryam O. Abdus-Salam
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Inductively Coupled Plasma ◽  
Granite Gneiss ◽  
Biotite Granite ◽  
Geochemical Data ◽  
Southwestern Nigeria ◽  
Lithological Mapping ◽  
Inductively Coupled ◽  
Gneiss Granite

The Rare Earth Elements (REE) composition of granitoids in and around Ila-Orangun area Southwestern Nigeria was assessed in order to ascertain their potential for possible exploitation. Detailed lithological mapping of the area was undertaken followed by whole rock geochemical analysis of representative samples of the granitoids using Inductively Coupled Plasma Mass Spectrometry (ICP-MS) technique. Petrographic study of the samples was carried out as well as the interpretation of the geochemical data using diverse geochemical discrimination plots. The rock units mapped were biotite granite gneiss, granite gneiss and hornblende biotite granite. Biotite hornblende gneiss, quartzite, talc-chlorite-tremolite-schist, mica schist and pegmatites were the surrounding country rocks. The REE concentrations (in ppm) revealed higher concentrations of the light REEs compared to the heavy REEs. The fractionation ratio, (La/Yb)N ranged from 4.35-15.04 (granite gneiss) and 13.78-18.48 (hornblende biotite granite) indicating enrichment in LREEs over the HREEs. The spider plot for the REEs also showed that the granitoids are LREE-enriched and HREE-depleted suggesting fractional crystallisation and a distinct negative Eu anomaly indicating plagioclase fractionation. Enrichment plot also revealed that the REEs in the granitoids are significantly enriched. Comparison with other areas showed that the granitoids of the study area especially the hornblende biotite granite has higher concentrations of REEs and may be a possible pointer of REE mineralisation.

scholarly journals The distribution of the trace element contents in lignite and ash from Drama lignite deposit, using multivariate statistical analysis

2001 ◽  
Vol 34 (3) ◽  
pp. 1255
Author(s):  
S. PANILAS ◽  
G. HATZIYANNIS
Keyword(s):  
Trace Elements ◽  
Rare Earth ◽  
Statistical Analysis ◽  
Rare Earth Elements ◽  
Multivariate Statistical Analysis ◽  
Major And Trace Elements ◽  
Major Elements ◽  
Geochemical Data ◽  
Multivariate Statistical ◽  
Inorganic Matter

Multivariate statistical analysis was used on existing geochemical data of the Drama lignite deposit, eastern Macedonia, Greece. Factor analysis with varimax rotation technique was applied to study the distribution of major, trace and rare earth elements in the lignite and 850°C lignitic ash, to find a small set of factors that could explain most of the geochemical variability. The study showed that major elements AI, Na, Κ, contained in the lignite samples, presented high correlation with most of the trace and rare earth elements. In 850°C lignitic ashes major and trace elements present different redistribution. Only Al remained correlated with the trace elements Co, Cr, Rb, Ta, Th, Ti, Sc and rare earths related with inorganic matter in the lignite beds. Trace elements Fe, Mo, U, V, W, and Lu were associated with organic matter of lignite and had also been affected by the depositional environment.

scholarly journals Metallogenic Epoch and Tectonic Setting of Saima Niobium Deposit in Fengcheng, Liaoning Province, NE China

Minerals ◽  
2019 ◽  
Vol 9 (2) ◽  
pp. 80 ◽  
Author(s):  
Nan Ju ◽  
Yun-Sheng Ren ◽  
Sen Zhang ◽  
Zhong-Wei Bi ◽  
Lei Shi ◽  
...  
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Nepheline Syenite ◽  
Large Scale ◽  
Tectonic Setting ◽  
Liaoning Province ◽  
Late Triassic ◽  
Ne China ◽  
The North ◽  
Heavy Rare Earth Elements

The Saima deposit is a newly discovered niobium deposit which is located in the eastern of Liaoning Province, NE China. Its mineralization age and geochemical characteristics are firstly reported in this study. The Nb orebodies are hosted by the grey–brown to grass-green aegirine nepheline syenite. Detailed petrographical studies show that the syenite consists of orthoclase (~50%), nepheline (~30%), biotite (~15%) and minor arfvedsonite (~3%) and aegirine (~2%), with weak hydrothermal alteration dominated by silicification. In situ LA-ICP-MS zircon U-Pb dating indicates that the aegirine nepheline syenite was emplaced in the Late Triassic (229.5 ± 2.2 Ma), which is spatially, temporally and genetically related to Nb mineralization. These aegirine nepheline syenites have SiO2 contents in the range of 55.86–63.80 wt. %, low TiO2 contents of 0.36–0.64 wt. %, P2O5 contents of 0.04–0.11 wt. % and Al2O3 contents of more than 15 wt. %. They are characterized by relatively high (K2O + Na2O) values of 9.72–15.51 wt. %, K2O/Na2O ratios of 2.42–3.64 wt. % and Rittmann indexes (σ = [ω(K2O + Na2O)]2/[ω(SiO2 − 43)]) of 6.84–17.10, belonging to the high-K peralkaline, metaluminous type. These syenites are enriched in large ion lithophile elements (LILEs, e.g., Cs, Rb and Ba) and light rare earth elements (LREEs) and relatively depleted in high field strength elements (HFSEs, e.g., Nb, Zr and Ti) and heavy rare earth elements (HREEs), with transitional elements showing an obvious W-shaped distribution pattern. Based on these geochronological and geochemical features, we propose that the ore-forming intrusion associated with the Nb mineralization was formed under post-collision continental-rift setting, which is consistent with the tectonic regime of post-collision between the North China Craton and Paleo-Asian oceanic plate during the age in Ma for Indosinian (257–205 Ma). Intensive magmatic and metallogenic events resulted from partial melting of lithospheric mantle occurred during the post-collisional rifting, resulting in the development of large-scale Cu–Mo mineralization and rare earth deposits in the eastern part of Liaoning Province.

Metasomatic Processes in the Lithospheric Mantle Beneath the No. 30 Kimberlite (Wafangdian Region, North China Craton)

2019 ◽  
Vol 57 (4) ◽  
pp. 499-517 ◽  
Author(s):  
Ren Z. Zhu ◽  
Pei Ni ◽  
Jun Y. Ding ◽  
Guo G. Wang ◽  
Ming S. Fan ◽  
...  
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Trace Element ◽  
North China Craton ◽  
Lithospheric Mantle ◽  
North China ◽  
Compositional Data ◽  
Early Stage ◽  
Mantle Metasomatism ◽  
Element Data

AbstractThis paper presents the first major and trace element compositions of mantle-derived garnet xenocrysts from the diamondiferous No. 30 kimberlite pipe in the Wafangdian region, and these are used to constrain the nature and evolution of mantle metasomatism beneath the North China Craton (NCC). The major element data were acquired using an electron probe micro-analyzer and the trace element data were obtained using laser ablation inductively coupled plasma-mass spectrometry. Based on Ni-in-garnet thermometry, equilibrium temperatures of 1107–1365 °C were estimated for peridotitic garnets xenocrysts from the No. 30 kimberlite, with an average temperature of 1258 °C, and pressures calculated to be between 5.0 and 7.4 GPa. In a CaO versus Cr2O3 diagram, 52% of the garnets fall in the lherzolite field and 28% in the harzburgite field; a few of the garnets are eclogitic. Based on rare earth element patterns, the lherzolitic garnets are further divided into three groups. The compositional variations in garnet xenocrysts reflect two stages of metasomatism: early carbonatite melt/fluid metasomatism and late kimberlite metasomatism. The carbonatite melt/fluids are effective at introducing Sr and the light rare earth elements, but ineffective at transporting much Zr, Ti, Y, or heavy rare earth elements. The kimberlite metasomatic agent is highly effective at element transport, introducing, e.g., Ti, Zr, Y, and the rare earth elements. Combined with compositional data for garnet inclusions in diamonds and megacrysts from the Mengyin and Wafangdian kimberlites, we suggest that these signatures reflect a two-stage evolution of the sub-continental lithospheric mantle (SCLM) beneath the NCC: (1) early-stage carbonatite melt/fluid metasomatism resulting in metasomatic modification of the SCLM and likely associated with diamond crystallization; (2) late-stage kimberlite metasomatism related to the eruption of the 465 Ma kimberlite.

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