Assessment of total and available heavy metal contents in vineyards managed under different agriculture practices

2020 ◽  
Author(s):  
Adelcia Veiga ◽  
Carla Carla Ferreira ◽  
Anne-Karine Boulet ◽  
Ana Caetano ◽  
Óscar Gonzalez-Pelayo ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Management Practices ◽  
Quality Standards ◽  
No Tillage ◽  
Conventional Farming ◽  
Integrated Production ◽  
Bioavailable Fraction ◽  
Production Practices

<p>Land degradation is a major challenge, particularly in intensive agriculture areas such as typical vineyards. Soil contamination with heavy metals is a widespread phenomenon in vineyards, due to the intensive use of pesticides, fertilizers, manure and slurry. As a result, vineyard soils have accumulated heavy metals and other trace elements that may be phytotoxic, non-biodegradable and persistent, which represents a long term threat to the crop system and to the food chain. In Portugal, vineyard area represents the fourth largest area in Europe (178770 ha), being one of the most relevant crops. Different approaches, such as, environmental programs and innovative management practices have been adopted over the last years, in order to minimize soil contamination by heavy metals. However, the establishment of quality standards for heavy metals in agriculture soils are mainly based on their total content, which is insufficient to estimate their environmental potential risk. The toxicity of metals does not depend only on their total concentration, but rather on their availability. Nevertheless, knowledge on the “bioavailable fraction” of heavy metals on agriculture soils, and particularly in vineyards, is still limited. This study, developed under iSQAPER research project, aims to assess the total and available heavy metal content in vineyards managed under different management practices: (1) no tillage, (2) integrated production, and (3) conventional farming. The integrated production and the conventional farming in the study sites have been intensively managed for more than 5 years, and more than 30 years in the no tillage vineyard.  The study was performed in 2018, based on soil sampling before and after pesticide application (April and July, respectively). Soil samples were also analyzed for pH, soil organic matter content (SOM), total and available (DTPA-extractable) heavy metals content (Cu, Cd, Cr, Pb, Zn and Ni). Preliminary results show higher content of total Cu, Pb, Cr and Ni in the vineyard managed under no tillage than in the farms with conventional and integrated production practices. Cupper is the heavy metal with highest total concentrations, mainly due to the intensive application of Cu-based fungicides. In the vineyards with no tillage, the long term practices have led to total levels of Cu above the soil quality standards. Moreover, similar contents in total Zn were also observed in no- tillage and integrated production practices. The higher content of SOM observed in vineyards under integrated production may have favored the Zn accumulation in the topsoil layer of vineyards. Higher content of organic matter, were found in integrated production farming than in no-tillage and conventional practices, 2.6%, 1.3% and 1.2%, respectively. Understanding total and bioavailable fraction of heavy metals in vineyards is crucial to assess their potential toxicity on plants, animals and humans. The assessment of the best agricultural management practices is a key factor to mitigate land degradation in vineyards.   </p>

scholarly journals Effects of Management and Hillside Position on Soil Organic Carbon Stratification in Mediterranean Centenary Olive Grove

Agronomy ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 650
Author(s):  
Jesús Aguilera-Huertas ◽  
Beatriz Lozano-García ◽  
Manuel González-Rosado ◽  
Luis Parras-Alcántara
Keyword(s):  
Organic Carbon ◽  
Soil Organic Carbon ◽  
Soil Quality ◽  
Management Practices ◽  
Soil Management ◽  
Olive Grove ◽  
No Tillage ◽  
Short Term ◽  
Degradation Degree

The short- and medium—long-term effects of management and hillside position on soil organic carbon (SOC) changes were studied in a centenary Mediterranean rainfed olive grove. One way to measure these changes is to analyze the soil quality, as it assesses soil degradation degree and attempts to identify management practices for sustainable soil use. In this context, the SOC stratification index (SR-COS) is one of the best indicators of soil quality to assess the degradation degree from SOC content without analyzing other soil properties. The SR-SOC was calculated in soil profiles (horizon-by-horizon) to identify the best soil management practices for sustainable use. The following time periods and soil management combinations were tested: (i) in the medium‒long-term (17 years) from conventional tillage (CT) to no-tillage (NT), (ii) in the short-term (2 years) from CT to no-tillage with cover crops (NT-CC), and (iii) the effect in the short-term (from CT to NT-CC) of different topographic positions along a hillside. The results indicate that the SR-SOC increased with depth for all management practices. The SR-SOC ranged from 1.21 to 1.73 in CT0, from 1.48 to 3.01 in CT1, from 1.15 to 2.48 in CT2, from 1.22 to 2.39 in NT-CC and from 0.98 to 4.16 in NT; therefore, the soil quality from the SR-SOC index was not directly linked to the increase or loss of SOC along the soil profile. This demonstrates the time-variability of SR-SOC and that NT improves soil quality in the long-term.

scholarly journals Atmospheric Heavy Metal Input to Forest Soils in Rural Areas of Denmark

2007 ◽  
Vol 7 ◽  
pp. 192-197 ◽  
Author(s):  
M. F. Hovmand ◽  
Kaare Kemp
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Rural Areas ◽  
Forest Floor ◽  
Ambient Atmosphere ◽  
Chronological Order ◽  
Forest Sites ◽  
Yearly Average ◽  
Atmospheric Inputs

Atmospheric bulk deposition of heavy metals (HM) was measured from 1972/73 to the present time at five to ten forest sites in rural areas of Denmark. From 1979, HM in aerosols were measured at one to four forest sites. On the basis of these long-term continuous measurements, the atmospheric inputs to the forest floor have been calculated. Yearly HM emission estimates to the European atmosphere seems to correlate well with yearly average values of HM deposition, as well as with HM concentrations in the ambient atmosphere. HM emissions have been estimated since the 1950s. Using the correlation between emission and deposition, HM deposition values maybe extrapolated in reverse chronological order. The accumulated atmospheric HM deposition has been estimated in this way over a period of 50 years.

scholarly journals TINGKAT BIOKONSENTRASI LOGAM BERAT DAN GAMBARAN HISTOPATOLOGI IKAN MUJAIR (Oreochromis Mossambicus) YANG HIDUP DI PERAIRAN TUKAD BADUNG KOTA DENPASAR

2015 ◽  
Vol 9 (1) ◽  
pp. 25
Author(s):  
Made Rahayu Kusumadewi ◽  
I Wayan Budiarsa Suyasa ◽  
I Ketut Berata
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Hexavalent Chromium ◽  
Metal Contamination ◽  
Heavy Metal Contamination ◽  
Quality Standards ◽  
Oreochromis Mossambicus ◽  
Metal Exposure ◽  
Histopathological Changes ◽  
Food Ingredient

Tukad Badung River is one of the potential contamination of heavy metal sare very highin the city of Denpasar. Tilapia (Oreochromis mossambicus) isa commonspecies of fish found in the river and became the object of fishing by the public. The fish is usually consume das a food ingredient forever yangler. Fish can be used as bio-indicators of chemical contamination in the aquatic environment. Determination of heavy metal bioconcentration and analysis of liver histopathology gills organs and muscles is performed to determine the content of heavy metals Pb, Cd, and Cr+6, and the influence of heavy metal exposure to changes in organ histopathology Tilapia that live in Tukad Badung. In this observational study examined the levels of heavy metal contamination include Pb, Cd and Cr+6 in Tilapia meat with AAS method (Atomic Absorption Spectrofotometric), and observe the histopathological changes in organ preparations gills, liver, and muscle were stained with HE staining (hematoxylin eosin). Low Pb content of the fish that live in Tukad Badung 0.8385 mg/kg and high of 20.2600 mg/kg. The content of heavy metals Pb is above the quality standards specified in ISO 7378 : 2009 in the amount of 0.3 mg / kg. The content of Cr+6 low of 1.1402 mg / kg and the highest Cr+6 is 6.2214 mg / kg. The content of Cr+6 is above the quality standards established in the FAO Fish Circular 764 is equal to 1.0 mg / kg. In fish with Pb bioconcentration of 0.8385 mg / kg and Cr+6 of 1.1402 mg / kg was found that histopathological changes gill hyperplasia and fusion, the liver was found degeneration, necrosis, and fibrosis, and in muscle atrophy found. Histopathologicalchangessuch asedema and necrosis ofthe liveris foundin fishwith Pb bioconcentration of 4.5225mg/kg and Cr+6 amounted to2.5163mg/kg. Bio concentration of heavy metal contamination of lead (Pb) and hexavalent chromium (Cr+6) on Tilapia ( Oreochromis mossambicus ) who lives in Tukad Badung river waters exceed the applicable standard. Histopathological changes occur in organs gills, liver, and muscle as a result of exposure to heavy metals lead and hexavalent chromium. Advised the people not to eat Tilapia that live in Tukad Badung

scholarly journals The rainfall effect onto solidification and stabilization of heavy metal-polluted sediments

2020 ◽  
Vol 7 (7) ◽  
pp. 192234
Author(s):  
Yan Sun ◽  
Daofang Zhang ◽  
Feipeng Li ◽  
Hong Tao ◽  
Moting Li ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Diffusion Coefficient ◽  
Simulated Acid Rain ◽  
Curing Process ◽  
Deterioration Rate ◽  
Before And After ◽  
Calculated Diffusion Coefficient ◽  
Leaching Procedure

Rainfall makes impacts on the process of solidification/stabilization (S/S) and the long-term safety of solidified matrix. In this study, the effect of rainfall on solidification/stabilization process was investigated by the rainfall test. The unconfined compressive strength (UCS) and toxicity characteristic leaching procedure (TCLP) were adopted to characterize the properties of S/S sediments before and after the rainfall test. The samples cured for 28 days were selected for semi-dynamic leaching tests with a simulated acidic leachant prepared at pH of 2.0, 4.0 and 7.0. The effectiveness of S/S treatment was evaluated by diffusion coefficient ( D e ) and leachability index (LX). The results indicated that UCS decreased at maximum deterioration rate of 34.23% after 7 days of curing, along with the minimum rate of 7.98% after 28 days by rainfall, with greater than 14 days referred. The rainfall had little effect on the leaching characteristics of heavy metals during the curing process. However, the simulated acid rain made significant impacts on the leaching behaviours of the heavy metals in the S/S materials. All the values of cumulative fraction of leached heavy metals were less than 2.0%, exhibition of good stabilization of cement. Furthermore, the calculated diffusion coefficient ( D e ) for Cu was 1.28 × 10 1 cm 2 s –1 , indicating its low mobility of heavy metal ions in S/S sediments. Furthermore, the calculated diffusion coefficients ( D i ) for Cd, Cu and Pb were 7.44 × 10 −11 , 8.18 × 10 −12 and 7.85 × 10 −12 cm 2 s –1 , respectively, indicating their relatively low mobility of heavy metal in S/S sediments.

scholarly journals Effect of Pig and Cattle Slurry Application on Heavy Metal Composition of Maize Grown on Different Soils

2018 ◽  
Vol 10 (8) ◽  
pp. 2684 ◽  
Author(s):  
Giorgio Provolo ◽  
Giulia Manuli ◽  
Alberto Finzi ◽  
Giorgio Lucchini ◽  
Elisabetta Riva ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Organic Fertilizer ◽  
Pig Manure ◽  
Soil Enrichment ◽  
Maize Cultivation ◽  
Time Required ◽  
Cu And Zn ◽  
Different Soils

Cattle and pig manure contain useful mineral nutrients (N, P, and K) and are therefore used as organic fertilizer. However, excessive applications of manure can cause environmental problems and threaten animal and human health because these materials also hold significant amounts of heavy metals, particularly Cu and Zn. To assess the potential risk due to the increased concentrations of heavy metals (Cu, Mn, Zn, and Cr) in a harvested crop, two maize hybrids were grown in pots on four different soils with three different fertilisers (urea, pig manure, and cattle manure). Both soil and manure characteristics influenced the heavy metal concentrations in the plant shoots. Organic fertilisation strongly interacted with the soils and, in general, reduced the shoot content of Cu, Mn, and Zn. A preliminary assessment of the heavy metal balance of the agricultural systems based on the intensive livestock production and maize cultivation showed that the potential soil enrichment of the long-term application of livestock manure arises mainly from the application of pig slurries that have a high content of Cu and Zn. The time required to apply an amount of metal that is equal to the initial soil content is 60–300 years for Zn and 240–450 years for Cu, depending on the soil type and the initial heavy metal content.

scholarly journals Evaluation of the effects of bio stabilised waste on soil in terms of heavy metal accumulation and leaching

2018 ◽  
Vol 13 (3) ◽  
pp. 1 ◽  
Author(s):  
Francesco Lombardi ◽  
Giulia Costa ◽  
Maria Chiara Di Lonardo ◽  
Alessio Lieto
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Metal Accumulation ◽  
Organic Matter Content ◽  
Total Content ◽  
Heavy Metal Accumulation ◽  
Matter Content ◽  
Aerobic Biodegradation ◽  
Solid Matrix

This work evaluated and compared potential impacts related to the accumulation and/or release of heavy metals resulting from the application of different types of stabilized waste to soil. Namely, the following three types of flows were considered: waste produced by aerobic bio-stabilization of municipal solid waste at a Mechanical Biological Treatment (MBT) plant, and compost produced either from aerobic composting or from a combination of anaerobic and aerobic biodegradation processes. After a preliminary characterization of the materials (organic matter content, volatile solid, and heavy metals content), heavy metal accumulation in soil caused by possible long-term application of these organic materials was evaluated by implementing a discretized mass balance based on the total content of the heavy metals in each type of solid matrix investigated. In addition, results of percolation leaching tests performed on each type of material were presented and discussed. Results highlight that although the total content of heavy metals of the three types of materials differed considerably, with the MBT waste presenting the highest concentrations, the results of the leaching percolation tests were quite similar.

Heavy Metal Pollution Characteristics in the Sediment of Elephant Lake in Nanchang City, Jiangxi

2013 ◽  
Vol 448-453 ◽  
pp. 380-384
Author(s):  
Yue Liang ◽  
Wen Hua Li ◽  
Xiao Zhen Liu ◽  
Jian Xiong
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Microwave Digestion ◽  
Quality Standards ◽  
Icp Oes ◽  
Sediment Samples ◽  
Bcr Method ◽  
Cd Contamination ◽  
Metal Contents ◽  
Pre Treatment

In order to understand the pollution features of heavy metals in sediments of Elephant Lake in Nanchang city, sediment samples were collected and detected .Using microwave digestion and BCR Method for sediment pre-treatment, the concentrations of heavy elements were measured by ICP-OES emission spectrometer. Sediment heavy metal contents were in descending order of Zn> Pb> Cu> Cr> As> Cd. According to the national soil environmental quality standards of P.R.China, there was Cd contamination in lakebed mud. And five kinds of metals existed mainly in oxidizable (F3) and residual (F4) , indicating less risk of migration of heavy metals .

scholarly journals Heavy Metal Residues in Soil and Accumulation in Maize at Long-Term Wastewater Irrigation Area in Tongliao, China

2015 ◽  
Vol 2015 ◽  
pp. 1-9 ◽  
Author(s):  
Yintao Lu ◽  
Hong Yao ◽  
Dan Shan ◽  
Yichen Jiang ◽  
Shichao Zhang ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Growth Cycle ◽  
Wastewater Irrigation ◽  
Pollution Level ◽  
Irrigated Area ◽  
Metal Contents ◽  
Maize Roots ◽  
Translocation Factors

Soil and plant samples were collected from Tongliao, China, during the maize growth cycle between May and October 2010. Heavy metals, such as Cr, Pb, Ni, and Zn, were analyzed. The concentrations of Cr, Pb, Ni, and Zn in the wastewater-irrigated area were higher than those in the topsoil from the groundwater-irrigated area. The concentrations of metals in the maize increased as follows: Pb < Ni < Zn < Cr. In addition, Cr, Pb, and Ni mainly accumulated in the maize roots, and Zn mainly accumulated in the maize fruit. The results of translocation factors (TF) and bioconcentration factors (BCF) of maize for heavy metals revealed that maize is an excluder plant and a potential accumulator plant and can serve as an ideal slope remediation plant. In addition, the increasing heavy metal contents in soils that have been polluted by wastewater irrigation must result in the accumulation of Cr, Pb, Ni, and Zn in maize. Thus, the pollution level can be decreased by harvesting and disposing of and recovering the plant material.

scholarly journals Biosolids and heavy metals in soils

2003 ◽  
Vol 60 (4) ◽  
pp. 793-806 ◽  
Author(s):  
Maria Lucia Azevedo Silveira ◽  
Luís Reynaldo Ferracciú Alleoni ◽  
Luiz Roberto Guimarães Guilherme
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Heavy Metal Concentration ◽  
Treatment Method ◽  
Soil Fertilization ◽  
Free Ions ◽  
Metal Contents ◽  
Agricultural Areas ◽  
Inorganic Ligands

The application of sewage sludge or biosolids on soils has been widespread in agricultural areas. However, depending on their characteristics, they may cause increase in heavy metal concentration of treated soils. In general, domestic biosolids have lower heavy metal contents than industrial ones. Origin and treatment method of biosolids may markedly influence their characteristics. The legislation that controls the levels of heavy metal contents in biosolids and the maximum concentrations in soils is still controversial. In the long-term, heavy metal behavior after the and of biosolid application is still unknown. In soils, heavy metals may be adsorbed via specific or non-specific adsorption reactions. Iron oxides and organic matter are the most important soil constituents retaining heavy metals. The pH, CEC and the presence of competing ions also affect heavy metal adsorption and speciation in soils. In solution, heavy metals can be present either as free-ions or complexed with organic and inorganic ligands. Generally, free-ions are more relevant in environmental pollution studies since they are readily bioavailable. Some computer models can estimate heavy metal activity in solution and their ionic speciation. Thermodynamic data (thermodynamic stability constant), total metal and ligand concentrations are used by the GEOCHEM-PC program. This program allows studying heavy metal behavior in solution and the effect of changes in the conditions, such as pH and ionic strength and the application of organic and inorganic ligands caused by soil fertilization.

scholarly journals DETEKSI FORMALIN DAN LOGAM BERAT PADA IKAN SEGAR DI PASAR TRADISIONAL KOTA KUPANG

Jurnal Kimia ◽  
2020 ◽  
pp. 147
Author(s):  
A. T. Lema ◽  
J. M. Jacob
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Metal Content ◽  
Quantitative Detection ◽  
Fish Products ◽  
Fresh Fish ◽  
Fish Market ◽  
Qualitative Detection ◽  
Short And Long Term

Nowadays, the use of formalin as a preservative in fish is often found in society. Besides, the consumption of fresh fish products containing heavy metals will potentially cause various diseases both short and long-term. The aims of this study were to assess the knowledge of society about formalin, detect the presence of formalin, and analyze the heavy metal content of Pb, Cd, and Hg in Yellow striped fish, Tuna and Mackerel fish. The qualitative detection was done using Schiff reagents, while the quantitative detection was done by using the Spectrophotometry based on the reaction of formaldehyde and Nash reagents. The results showed that 50 percent of society did not know about the use of formaldehyde and its characteristics in fish. The Qualitative testing on 9 samples found that 2 samples contained positive formalin, while 7 samples were negative. The quantitative test showed that the highest formalin content was found in Tuna and Mackerel fish with concentration of 3.36 ppm, and 1.26 ppm, respectively. Also, mercury was found as the highest concentration in fish roughly 1 to 1.60 ppm for those samples from three different markets.                                                                                                                                                 Keywords: formalin, heavy metal, fresh fish, market, Kupang city

Sign in / Sign up

Export Citation Format

Share Document