Hydro-Mechanical-Chemical modelling of Brucite – Periclase (de)hydration reactions

2020 ◽  
Author(s):  
Stefan Markus Schmalholz ◽  
Oliver Plümper ◽  
Evangelos Moulas ◽  
Yuri Podladchikov
Keyword(s):  
Stokes Equations ◽  
Ambient Pressure ◽  
Theoretical Models ◽  
Force Balance ◽  
Rock Deformation ◽  
Diffusion Creep ◽  
Ambient Conditions ◽  
Volume Deformation ◽  
Natural Rock ◽  
The Impact

<p>Metamorphic reactions involving hydration and dehydration frequently occur during orogenic cycles, for example, when ambient pressure and temperature conditions change due to subduction and subsequent exhumation, or when fluids infiltrate metastable mineral assemblages at constant ambient conditions. Such (de)hydration reactions can be associated with significant volume changes, which may cause significant differential stresses in the rock, potentially leading to fracturing. The impact of (de)hydration reactions on the rock’s stress state and on the magnitudes of associated differential stresses is still controversially debated. One reason for the debate is due to the different theoretical models used to quantify and simulate (de)hydration reactions coupled with rock deformation. In many models, the rock deformation is frequently simplified, by either completely ignoring rock deformation or by considering volume deformation only. Additionally, the fluid flow is often simplified, by for example considering constant porosity. Here, we present a method to derive a system of governing equations to describe coupled Hydro-Mechanical-Chemical processes, which is suitable to quantify rock deformation coupled to (de)hydration reactions. Reactions are mainly treated as density changes whereby the density changes are determined by tabulated densities from thermodynamic Gibbs free energy minimizations in pressure, temperature and composition space. The rock deformation is quantified by the continuum mechanics force balance equations, here the Stokes equations. Considered flow laws describe either linear viscous deformation or dislocation and diffusion creep. Equations for reactions and rock deformation are coupled by several equations for the conservation of mass, such as total mass or mass of solid components stored in the solid. The governing system of equations is solved with a pseudo-transient finite difference method. For simplicity, we apply the numerical model here to several Brucite – Periclase (de)hydration reactions and show results of models with different levels of coupling, for example, constant or variable porosity. We also quantify the differential stresses associated with the (de)hydration reactions. Furthermore, we compare the modelled stresses with microstructural observations and stress estimates from high-resolution EBSD measurements in natural rock.</p>

scholarly journals Experimental and Computational Investigation of binary drop collisions under elevated pressure

2017 ◽  
Author(s):  
Jan Breitenbach ◽  
Louis Maximilian Reitter ◽  
Muyuan Liu ◽  
Kuan-Ling Huang ◽  
Dieter Bothe ◽  
...  
Keyword(s):  
Relative Velocity ◽  
Computational Study ◽  
Ambient Pressure ◽  
Experimental System ◽  
Elevated Pressure ◽  
Computational Investigation ◽  
Ambient Conditions ◽  
Influencing Parameters ◽  
Gas Layer ◽  
The Impact

Spray systems often operate under extreme ambient conditions like high pressure, which can have a significant influence on important spray phenomena. One of these phenomena is binary drop collisions. Such collisions, depending on the relative velocity and the impact parameter (eccentricity of the collision), can lead to drop bouncing, coalescence or breakup. This experimental and computational study is focused on the description of the phenomenon of drop bouncing, which is caused by a thin gas layer preventing the drops coalescence. To identify the main influencing parameters of this phenomenon, experiments on binary drop collisions are performed in a pressure chamber. This experimental system allows us to investigate the effect of an ambient pressure (namely the density and viscosity of the surrounding gas) on the bouncing/coalescence threshold.DOI: http://dx.doi.org/10.4995/ILASS2017.2017.4758

Crown sealing and buckling instability during water entry of spheres

2016 ◽  
Vol 794 ◽  
pp. 506-529 ◽  
Author(s):  
J. O. Marston ◽  
T. T. Truscott ◽  
N. B. Speirs ◽  
M. M. Mansoor ◽  
S. T. Thoroddsen
Keyword(s):  
Contact Line ◽  
High Speed ◽  
Ambient Pressure ◽  
Classical Problem ◽  
Sphere Diameter ◽  
Ambient Conditions ◽  
Buckling Instability ◽  
Fine Spray ◽  
Liquid Pools ◽  
The Impact

We present new observations from an experimental investigation of the classical problem of the crown splash and sealing phenomena observed during the impact of spheres onto quiescent liquid pools. In the experiments, a 6 m tall vacuum chamber was used to provide the required ambient conditions from atmospheric pressure down to $1/16\text{th}$ of an atmosphere, whilst high-speed videography was exploited to focus primarily on the above-surface crown formation and ensuing dynamics, paying particular attention to the moments just prior to the surface seal. In doing so, we have observed a buckling-type azimuthal instability of the crown. This instability is characterised by vertical striations along the crown, between which thin films form that are more susceptible to the air flow and thus are drawn into the closing cavity, where they atomize to form a fine spray within the cavity. To elucidate to the primary mechanisms and forces at play, we varied the sphere diameter, liquid properties and ambient pressure. Furthermore, a comparison between the entry of room-temperature spheres, where the contact line pins around the equator, and Leidenfrost spheres (i.e. an immersed superheated sphere encompassed by a vapour layer), where there is no contact line, indicates that the buckling instability appears in all crown sealing events, but is intensified by the presence of a pinned contact line.

The Effects of Employment Protection legislationon Personnel Policies: A Review of Theoretical Modelsand Empirical results

2014 ◽  
pp. 126-140
Author(s):  
O. Mironenko
Keyword(s):  
Personnel Selection ◽  
Selection Criteria ◽  
Theoretical Models ◽  
Employment Protection ◽  
Empirical Results ◽  
Protection Legislation ◽  
Labour Contracts ◽  
Hiring And Firing ◽  
The Impact ◽  
Personnel Policies

Employers incur costs while fulfilling the requirements of employment protection legislation. The article contains a review of the core theoretical models and empirical results concerning the impact of these costs on firms’ practices in hiring, firing, training and remuneration. Overall, if wages are flexible or enforcement is weak, employment protection does not significantly influence employers’ behavior. Otherwise, stringent employment protection results in the reduction of hiring and firing rates, changes in personnel selection criteria, types of labour contracts and dismissal procedures, and, in some cases, it may lead to the growth of wages and firms’ investments to human capital.

scholarly journals Damage Evolution of Granodiorite after Heating and Cooling Treatments

Minerals ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 779
Author(s):  
Mohamed Gomah ◽  
Guichen Li ◽  
Salah Bader ◽  
Mohamed Elkarmoty ◽  
Mohamed Ismael
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Failure Mode ◽  
Physical And Mechanical Properties ◽  
P Wave ◽  
Physical Parameters ◽  
Slow Cooling ◽  
Heating And Cooling ◽  
Natural Rock ◽  
The Impact

The awareness of the impact of high temperatures on rock properties is essential to the design of deep geotechnical applications. The purpose of this research is to assess the influence of heating and cooling treatments on the physical and mechanical properties of Egyptian granodiorite as a degrading factor. The samples were heated to various temperatures (200, 400, 600, and 800 °C) and then cooled at different rates, either slowly cooled in the oven and air or quickly cooled in water. The porosity, water absorption, P-wave velocity, tensile strength, failure mode, and associated microstructural alterations due to thermal effect have been studied. The study revealed that the granodiorite has a slight drop in tensile strength, up to 400 °C, for slow cooling routes and that most of the physical attributes are comparable to natural rock. Despite this, granodiorite thermal deterioration is substantially higher for quick cooling than for slow cooling. Between 400:600 °C is ‘the transitional stage’, where the physical and mechanical characteristics degraded exponentially for all cooling pathways. Independent of the cooling method, the granodiorite showed a ductile failure mode associated with reduced peak tensile strengths. Additionally, the microstructure altered from predominantly intergranular cracking to more trans-granular cracking at 600 °C. The integrity of the granodiorite structure was compromised at 800 °C, the physical parameters deteriorated, and the rock tensile strength was negligible. In this research, the temperatures of 400, 600, and 800 °C were remarked to be typical of three divergent phases of granodiorite mechanical and physical properties evolution. Furthermore, 400 °C could be considered as the threshold limit for Egyptian granodiorite physical and mechanical properties for typical thermal underground applications.

scholarly journals Transport Properties of Natural and Artificial Smart Fabrics Impregnated by Graphite Nanomaterial Stacks

Nanomaterials ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 1018
Author(s):  
Carola Esposito Corcione ◽  
Francesca Ferrari ◽  
Raffaella Striani ◽  
Antonio Greco
Keyword(s):  
Electrical Conductivity ◽  
Transport Properties ◽  
Low Cost ◽  
Empirical Relationship ◽  
Theoretical Models ◽  
Expandable Graphite ◽  
Easy Method ◽  
Textile Materials ◽  
Fabric Materials ◽  
The Impact

In this work, we studied the transport properties (thermal and electrical conductivity) of smart fabric materials treated with graphite nanomaterial stacks–acetone suspensions. An innovative and easy method to produce graphite nanomaterial stacks–acetone-based formulations, starting from a low-cost expandable graphite, is proposed. An original, economical, fast, and easy method to increase the thermal and electrical conductivity of textile materials was also employed for the first time. The proposed method allows the impregnation of smart fabric materials, avoiding pre-coating of the fibers, thus reducing costs and processing time, while obtaining a great increase in the transport properties. Two kinds of textiles, cotton and Lycra®, were selected as they represent the most used natural and artificial fabrics, respectively. The impact of the dimensions of the produced graphite nanomaterial stacks–acetone-based suspensions on both the uniformity of the treatment and the transport properties of the selected textile materials was accurately evaluated using several experimental techniques. An empirical relationship between the two transport properties was also successfully identified. Finally, several theoretical models were applied to predict the transport properties of the developed smart fabric materials, evidencing a good agreement with the experimental data.

scholarly journals A Study of the Impact of Graphite on the Kinetics of SPS in Nano- and Submicron WC-10%Co Powder Compositions

Ceramics ◽  
2021 ◽  
Vol 4 (2) ◽  
pp. 331-363
Author(s):  
Eugeniy Lantcev ◽  
Aleksey Nokhrin ◽  
Nataliya Malekhonova ◽  
Maksim Boldin ◽  
Vladimir Chuvil'deev ◽  
...  
Keyword(s):  
Activation Energy ◽  
Solid Phase ◽  
Continuous Heating ◽  
Diffusion Creep ◽  
Hard Alloys ◽  
Fine Grained ◽  
Plasma Sintering ◽  
Spark Plasma ◽  
The Impact ◽  
Kinetics Of

This study investigates the impact of carbon on the kinetics of the spark plasma sintering (SPS) of nano- and submicron powders WC-10wt.%Co. Carbon, in the form of graphite, was introduced into powders by mixing. The activation energy of solid-phase sintering was determined for the conditions of isothermal and continuous heating. It has been demonstrated that increasing the carbon content leads to a decrease in the fraction of η-phase particles and a shift of the shrinkage curve towards lower heating temperatures. It has been established that increasing the graphite content in nano- and submicron powders has no significant effect on the SPS activation energy for “mid-range” heating temperatures, QS(I). The value of QS(I) is close to the activation energy of grain-boundary diffusion in cobalt. It has been demonstrated that increasing the content of graphite leads to a significant decrease in the SPS activation energy, QS(II), for “higher-range” heating temperatures due to lower concentration of tungsten atoms in cobalt-based γ-phase. It has been established that the sintering kinetics of fine-grained WC-Co hard alloys is limited by the intensity of diffusion creep of cobalt (Coble creep).

Dynamic interaction of multiple buoyant jets

2012 ◽  
Vol 708 ◽  
pp. 539-575 ◽  
Author(s):  
Adrian C. H. Lai ◽  
Joseph H. W. Lee
Keyword(s):  
Stokes Equations ◽  
Dynamic Pressure ◽  
Unit Length ◽  
Iterative Solution ◽  
Scalar Fields ◽  
Passive Scalar ◽  
Dynamic Interaction ◽  
Ambient Conditions ◽  
Buoyant Jet ◽  
Buoyant Jets

AbstractAn array of closely spaced round buoyant jets interact dynamically due to the pressure field induced by jet entrainment. Mutual jet attraction can result in a significant change in jet trajectories. Jet merging also leads to overlapping of the passive scalar fields associated with the individual jets, resulting in mixing characteristics that are drastically different from those of an independent free jet. A general semi-analytical model for the dynamic interaction of multiple buoyant jets in stagnant ambient conditions is proposed. The external irrotational flow field induced by the buoyant jets is computed by a distribution of point sinks with strength equal to the entrainment per unit length along the unknown jet trajectories and accounting for boundary effects. The buoyant jet trajectories are then determined by an iterative solution of an integral buoyant jet model by tracking the changes in the external entrainment flow and dynamic pressure fields. The velocity and concentration fields of the jet group are obtained by momentum or kinetic energy superposition for merged jets and plumes, respectively. The modelling approach is supported by numerical solution of the Reynolds-averaged Navier–Stokes equations. The model shows that jet merging and mixing can be significantly affected by jet interactions. Model predictions of the multiple jet trajectories, merging height, as well as the centreline velocity and concentration of the buoyant jet group are in good agreement with experimental data for: (i) a clustered momentum jet group; (ii) a turbulent plume pair; and (iii) a rosette buoyant jet group. Dynamic interactions between a jet group are shown to decrease with the addition of an ambient cross-flow.

Experimental Evaluation of Compressor Blade Fouling

2016 ◽  
Author(s):  
Rainer Kurz ◽  
Grant Musgrove ◽  
Klaus Brun
Keyword(s):  
Boundary Layer ◽  
Gas Turbines ◽  
Blade Surface ◽  
Air Filtration ◽  
Ambient Conditions ◽  
Compressor Blades ◽  
Performance Deterioration ◽  
Quantitative Results ◽  
The Impact ◽  
Dust Retention

Fouling of compressor blades is an important mechanism leading to performance deterioration in gas turbines over time. Experimental and simulation data are available for the impact of specified amounts of fouling on performance, as well as the amount of foulants entering the engine for defined air filtration systems and ambient conditions. This study provides experimental data on the amount of foulants in the air that actually stick to a blade surface for different conditions of the blade surface. Quantitative results both indicate the amount of dust as well as the distribution of dust on the airfoil, for a dry airfoil, as well as airfoils that were wet from ingested water, as well as different types of oil. The retention patterns are correlated with the boundary layer shear stress. The tests show the higher dust retention from wet surfaces compared to dry surfaces. They also provide information about the behavior of the particles after they impact on the blade surface, showing that for a certain amount of wet film thickness, the shear forces actually wash the dust downstream, and off the airfoil. Further, the effect of particle agglomeration of particles to form larger clusters was observed, which would explain the disproportional impact of very small particles on boundary layer losses.

scholarly journals Simulation of X-Band Rainfall Observations from S-Band Radar Data

2006 ◽  
Vol 23 (9) ◽  
pp. 1195-1205 ◽  
Author(s):  
V. Chandrasekar ◽  
S. Lim ◽  
E. Gorgucci
Keyword(s):  
Doppler Radar ◽  
Theoretical Models ◽  
Radar Data ◽  
Shape Distribution ◽  
Microphysical Properties ◽  
Rain Medium ◽  
Microphysical Parameters ◽  
X Band ◽  
State Water ◽  
The Impact

Abstract To design X-band radar systems as well as evaluate algorithm development, it is useful to have simultaneous X-band observation with and without the impact of path attenuation. One way to develop that dataset is through theoretical models. This paper presents a methodology to generate realistic range profiles of radar variables at attenuating frequencies, such as X band, for rain medium. Fundamental microphysical properties of precipitation, namely, size and shape distribution information, are used to generate realistic profiles of X band starting with S-band observation. Conditioning the simulation from S band maintains the natural distribution of rainfall microphysical parameters. Data from the Colorado State University’s University of Chicago–Illinois State Water Survey (CHILL) radar and the National Center for Atmospheric Research S-band dual-polarization Doppler radar (S-POL) are used to simulate X-band radar variables. Three procedures to simulate the radar variables and sample applications are presented.

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