A tale of two bogs - new 10Be production rates from UK and NZ calibrated by basal 14C ages 

2021 ◽  
Author(s):  
David Fink ◽  
Philip Hughes ◽  
Reka Fulop ◽  
Klaus Wilcken ◽  
Patrick Adams ◽  
...  
Keyword(s):  
Radiocarbon Dating ◽  
Published Data ◽  
British Isles ◽  
Production Rates ◽  
New Production ◽  
Site Specific ◽  
Global Average ◽  
The Past ◽  
Minimum Age ◽  
Exposure Ages

<p>Cosmogenic production rates (PRs) are the essential conversion factor between AMS cosmogenic concentrations and absolute exposure ages. The accuracy of cosmogenic glacial chronologies and reliability in their comparison to other paleoclimate systems  is largely contingent on the precision and accuracy of the adopted production rate. This is particularly critical in determining past glacial geochronologies at the scale of millennial temporal resolution. Most PR calibrations are carried out at deglaciation sites where radiocarbon provides the independent chronometric control usually based on 14C ages in basal sediments or varves from lake or bog cores which is assumed to represent the minimum age for glacial retreat. Under these conditions and hence provide PRs as maximum values. Given that today most AMS facilities can deliver 10-Be, 26-Al and 36-Cl data with total analytical errors less than 2% ( for 10 ka exposure), the precision of a PR remains largely dependent  on the error in the independent chronology and accuracy of AMS standards. The history over the past 20 years of the ever-decreasing value of  SLHL 10-Be cosmogenic spallation PRs   from initial estimates of about 7 atoms/g/a to the current  ‘accepted‘ (global average) values of ~4 atoms/g/a,   is an interesting story in itself and demonstrates the complexity in such determinations.  </p><p>Over the past few years new web-based calculators are now available to calculate uniformly new production rates from either new data or combinations of any set of published data (CRONUS-Earth, CRONUS-UW, CosmoCalc, ICE-D, CREp). This delivers a means by which new production rates can be seamlessly integrated and compared using identical constants, methods and statistics that were used to generate (currently accepted) global average or regional production rates.</p><p> For the British Isles, there are a number of 10-Be reference sites that give PRs (Lm scheme) between 3.89±3%  atoms/g/a  (Putnam, QG, v50, 2019) to 4.20±1% atoms/g/a (Small, JQS, v30, 2015) which convert to 3.95 and 4.28, respectively, using datasets in the ICE-D calculator). This difference in 10-Be spallation PRs has recently raised some debate and challenges for the timing of the local-LGM and demise of the British Ice Sheet. This work provides a new  British Isles site specific 10Be PR from the  Arenig Mountains in North Wales where radiocarbon dating of basal sediments from a bog core associated with a series of nearby cirque moraines provides independent age control.  Similarly in the South Island of New Zealand, the current accepted 10Be PR is 3.76±2% (Putnam, QG 2009; converts to 3.94±1% using ICE-D) and is the only available PR that is used for these southern hemispheric glacial sites. This work provides a new Australasian site specific 10Be PR from Arthurs Pass retreat moraines where radiocarbon dating of basal sediments from three cores extracted from a bog impounded by the moraine provides independent age control. </p>

Yet another in-situ cosmogenic 10-Be local production rate for the British Isles : Llyn Arenig Fach, North Wales

2020 ◽  
Author(s):  
David Fink ◽  
Philip Hughes ◽  
Reka Fulop ◽  
Klaus Wilcken ◽  
Patrick Adams ◽  
...  
Keyword(s):  
Production Rate ◽  
British Isles ◽  
Production Rates ◽  
Site Specific ◽  
Current Collection ◽  
North Wales ◽  
Minimum Age ◽  
Exposure Ages ◽  
Analytical Errors

<p>Cosmogenic production rates (PRs) are the essential conversion factor between AMS cosmogenic concentrations and absolute exposure ages. The accuracy of cosmogenic glacial chronologies and reliability in their comparison to other plaeoclimate systems  is largely contingent on the precision and accuracy of the adopted production rate. This is particularly critical in determining past glacial geochronologies at the scale of millennial temporal resolution. Most PR calibrations are carried out at deglaciation sites where radiocarbon provides the independent chronometric control usually based on calibrated 14C ages in basal sediments or varves  from lake or bog cores which is assumed to represent the minimum age for glacial retreat. Under these conditions PRs should be considered as maximum-limiting values. Given that today most AMS facilities can deliver 10-Be, 26-Al and 36-Cl data with analytical errors less than 2%, the accuracy of a PR for a given scaling method (ie transfer function of the site-specific production rate to a reference sea-level high latitude (SLHL) PR) remains largely dependent  on the error in the independent chronology and accuracy of AMS standards. The history over the past 20 years of the ever-changing value of  SLHL 10-Be cosmogenic spallation PRs  with a continual decreasing value from initial estimates of about 7 atoms/g/a to the current  ‘accepted ‘ value of ~4 atoms/g/a,   is an interesting story in itself and demonstrates the complexity in such determinations.  </p><p>Today there are both global (average) SLHL PRs and also regional-specific PR values (referenced to SLHL). For the British Isles, there are a number of 10-Be ‘British Isles’ choices that, for the Lm scaling scheme, range between 3.92±0.11  atoms/g/a  (Putnam et al., QG, v50, 2019) to 4.41±0.25 atoms/g/a (Small et al., JQS, v30, 2015). This range in 10-Be spallation PRs has recently raised some debate and challenges for the assumed extent and timing of the local-LGM and demise of the British Ice Sheet. This work provides a new  British Isles site specific 10-Be PR from the  Arenig Mountains in North Wales. We have measured 10-Be concentrations in 13 selected moraine boulders that are tentatively mapped as outer and inner Younger Dryas deglacial deposits hugging a cirque lake,  Llyn Arenig Fach,  just below the head wall  at  Arenig Fach.   Radiocarbon dating of basal sediments from a number of intermorainal core bogs has provided independent age control.  We will present our results and compare them to the current collection of other British Isles 10-Be production rates.  </p>

scholarly journals In situ cosmogenic ¹⁰Be in pyroxene with an application to surface exposure dating

2021 ◽  
Author(s):  
◽  
Julia Anne Collins
Keyword(s):  
New Zealand ◽  
Production Rate ◽  
Production Rates ◽  
New Production ◽  
Radiocarbon Age ◽  
Exposure Dating ◽  
Ice Surface ◽  
Cross Calibration ◽  
Exposure Ages

<p>Cosmogenic nuclides are an important tool in quantifying many Earth-surface processes. Beryllium-10 (¹⁰Be) is commonly extracted out of the mineral quartz; however many landscapes lack quartz bearing rocks. In order to establish a new chronometer based on ¹⁰Be in pyroxene for use in New Zealand and Antarctica, it is necessary to verify cleaning protocols and determine a local production rate. In this study, I have tested and modified an existing pyroxene decontamination procedure in order to further develop the use of ¹⁰Be in pyroxene as a chronometer. This method successfully removes the meteoric component of ¹⁰Be in pyroxene, allowing only the concentration of in situ produced ¹⁰Be to be measured. Additionally, production rates for ¹⁰Be in pyroxene have been determined empirically for New Zealand using cross-calibration with measured ³He concentrations and an independent radiocarbon age of the Murimotu debris avalanche in the central North Island, New Zealand of 10.6 ± 1.1 ka. Theoretical ¹⁰Be pyroxene production rates were also determined, based on the composition of the Murimotu pyroxene. The best estimate for the 10Be pyroxene production rate is 3.4 ± 0.8 atoms g⁻¹ yr⁻¹ at sea-level high latitude, which was determined via cross-calibration with the radiocarbon age for the deposit. This work shows that production rates for ¹⁰Be in pyroxene are both empirically and theoretically 8-27% lower than in quartz. The ³He/¹⁰Be ratio in the Murimotu pyroxene is 34.5 ± 9.9; this is indistinguishable from global ³He-pyroxene/¹⁰Be-quartz production ratios.  In a case study surface exposure ages were determined for bedrock samples and cobble erratics collected in a vertical transect on Mount Gran, Antarctica, by applying the aforementioned ¹⁰Be pyroxene decontamination procedure and radiocarbon derived production rates. A chronology for ice surface lowering was obtained for the adjacent Mackay Glacier, indicating the ice surface lowered approximately 60 m during a relatively rapid episode of thinning which occurred between ~13.5 ka and 11 ka.  This thesis presents a successful test of decontamination procedures, new production rates, and an example application, showing the promise of ¹⁰Be in pyroxene as a chronometer. The development of ¹⁰Be in pyroxene allows environments without quartz-bearing rocks to be dated using this widely used nuclide. The pairing of ¹⁰Be with ³He in pyroxene would allow complex exposure histories to be determined, expanding the application.</p>

scholarly journals Problems of landslide chronology in the Mátra mountains in Hungary

1997 ◽  
Vol 47 (1) ◽  
pp. 120-128
Author(s):  
Jósef Szabó ◽  
Eniko Félegyhazi
Keyword(s):  
Theoretical Basis ◽  
Radiocarbon Dating ◽  
Late Glacial ◽  
The Past ◽  
Pollen Diagrams ◽  
Minimum Age ◽  
Landslide Processes ◽  
Middle Mountains ◽  
Warm Spell ◽  
Marginal Zones

Abstract. A detailed survey and mapping o f the landslide processes and surface forms in the volcanic middle mountains of Hungary formed in the Middle and Late Miocene was carried out in the past decade. As a result of investigations it can be stated that their occurrence is mainly confined to the areas as follows: a) marginal zones of volcanic mountains, b) steep inner slopes of the former calderas of eruption, c) valley slopes cut into stratovolcanic Structures. In their characteristic regions of occurrence landslide forms are important, in some places even determinant components of morphology. The overwhelming majority of the landforms are no more active and can be considered fossilised. Consequently, landslide processes used to play a significant role in forming slope morphology in previous stages o f geomorphic evolution. Research performed heretofore has provided only rather ambiguous answer to the question concerning the time of emergence of landslides on a theoretical basis. Due to the absence of young sediments traditional stratigraphic methods could not yield satisfactory results. The authors therefore attempted to determine the time of the upfilling of lakes or bogs located in undrained depressions clammed by slides and the minimum age of the landslides through the analyses of borehole samples. In the Mátra sediments upfilling of 7 such depressions were carried out. In several cases pollen diagrams were obtained and in two boreholes radiocarbon dating of samples were performed. The paper summarises the results of the borehole analyses and evaluates pollen records supported by C14 dating in detail. Analyses performed using various methods indicate a beginning of the bog formation in the Early Holocene, consequently landslides occurred presumably in the wake of the Preboreal or prior to that in a warm spell following the Late Glacial. Although these results cannot be extrapolated to all the landslides identified in the two mountains (their number is ca. 20) without more ado nevertheless they are orientating.

scholarly journals In situ cosmogenic ¹⁰Be in pyroxene with an application to surface exposure dating

2021 ◽  
Author(s):  
◽  
Julia Anne Collins
Keyword(s):  
New Zealand ◽  
Production Rate ◽  
Production Rates ◽  
New Production ◽  
Radiocarbon Age ◽  
Exposure Dating ◽  
Ice Surface ◽  
Cross Calibration ◽  
Exposure Ages

<p>Cosmogenic nuclides are an important tool in quantifying many Earth-surface processes. Beryllium-10 (¹⁰Be) is commonly extracted out of the mineral quartz; however many landscapes lack quartz bearing rocks. In order to establish a new chronometer based on ¹⁰Be in pyroxene for use in New Zealand and Antarctica, it is necessary to verify cleaning protocols and determine a local production rate. In this study, I have tested and modified an existing pyroxene decontamination procedure in order to further develop the use of ¹⁰Be in pyroxene as a chronometer. This method successfully removes the meteoric component of ¹⁰Be in pyroxene, allowing only the concentration of in situ produced ¹⁰Be to be measured. Additionally, production rates for ¹⁰Be in pyroxene have been determined empirically for New Zealand using cross-calibration with measured ³He concentrations and an independent radiocarbon age of the Murimotu debris avalanche in the central North Island, New Zealand of 10.6 ± 1.1 ka. Theoretical ¹⁰Be pyroxene production rates were also determined, based on the composition of the Murimotu pyroxene. The best estimate for the 10Be pyroxene production rate is 3.4 ± 0.8 atoms g⁻¹ yr⁻¹ at sea-level high latitude, which was determined via cross-calibration with the radiocarbon age for the deposit. This work shows that production rates for ¹⁰Be in pyroxene are both empirically and theoretically 8-27% lower than in quartz. The ³He/¹⁰Be ratio in the Murimotu pyroxene is 34.5 ± 9.9; this is indistinguishable from global ³He-pyroxene/¹⁰Be-quartz production ratios.  In a case study surface exposure ages were determined for bedrock samples and cobble erratics collected in a vertical transect on Mount Gran, Antarctica, by applying the aforementioned ¹⁰Be pyroxene decontamination procedure and radiocarbon derived production rates. A chronology for ice surface lowering was obtained for the adjacent Mackay Glacier, indicating the ice surface lowered approximately 60 m during a relatively rapid episode of thinning which occurred between ~13.5 ka and 11 ka.  This thesis presents a successful test of decontamination procedures, new production rates, and an example application, showing the promise of ¹⁰Be in pyroxene as a chronometer. The development of ¹⁰Be in pyroxene allows environments without quartz-bearing rocks to be dated using this widely used nuclide. The pairing of ¹⁰Be with ³He in pyroxene would allow complex exposure histories to be determined, expanding the application.</p>

scholarly journals Impact of Coronavirus Outbreaks on Science and Society: Insights from Temporal Bibliometry of SARS and COVID-19

Entropy ◽  
2021 ◽  
Vol 23 (5) ◽  
pp. 626
Author(s):  
Ramya Gupta ◽  
Abhishek Prasad ◽  
Suresh Babu ◽  
Gitanjali Yadav
Keyword(s):  
Published Data ◽  
Science And Society ◽  
Time Dimension ◽  
Scientific Publications ◽  
The Past ◽  
Economic Trends ◽  
Global Events ◽  
One Year ◽  
Personal Devices ◽  
Share Information

A global event such as the COVID-19 crisis presents new, often unexpected responses that are fascinating to investigate from both scientific and social standpoints. Despite several documented similarities, the coronavirus pandemic is clearly distinct from the 1918 flu pandemic in terms of our exponentially increased, almost instantaneous ability to access/share information, offering an unprecedented opportunity to visualise rippling effects of global events across space and time. Personal devices provide “big data” on people’s movement, the environment and economic trends, while access to the unprecedented flurry in scientific publications and media posts provides a measure of the response of the educated world to the crisis. Most bibliometric (co-authorship, co-citation, or bibliographic coupling) analyses ignore the time dimension, but COVID-19 has made it possible to perform a detailed temporal investigation into the pandemic. Here, we report a comprehensive network analysis based on more than 20,000 published documents on viral epidemics, authored by over 75,000 individuals from 140 nations in the past one year of the crisis. Unlike the 1918 flu pandemic, access to published data over the past two decades enabled a comparison of publishing trends between the ongoing COVID-19 pandemic and those of the 2003 SARS epidemic to study changes in thematic foci and societal pressures dictating research over the course of a crisis.

SUITABILITY OF ACID-SOLUBLE AND ACID-INSOLUBLE LEATHER FRACTIONS IN RADIOCARBON DATING

Radiocarbon ◽  
2020 ◽  
pp. 1-8
Author(s):  
Alyssa M Tate ◽  
Brittany Hundman ◽  
Jonathan Heile
Keyword(s):  
Radiocarbon Dating ◽  
Insoluble Fraction ◽  
Economic Life ◽  
Chemical Pretreatment ◽  
Acid Base ◽  
The Past ◽  
Acid Soluble Collagen ◽  
Method Of Production ◽  
Insight Into

ABSTRACT Leather has been produced by a variety of methods throughout human history, providing researchers unique insight into multiple facets of social and economic life in the past. Archaeologically recovered leather is often fragile and poorly preserved, leading to the use of various conservation and restoration efforts that may include the application of fats, oils, or waxes. Such additives introduce exogenous carbon to the leather, contaminating the specimen. These contaminants, in addition to those accumulated during interment, must be removed through chemical pretreatment prior to radiocarbon (14C) dating to ensure accurate dating. DirectAMS utilizes organic solvents, acid-base-acid (ABA) and gelatinization for all leather samples. Collagen yield from leather samples is variable due to the method of production and the quality of preservation. However, evaluating the acid-soluble collagen fraction, when available, provides the most accurate 14C dates for leather samples. In instances where gelatinization does not yield sufficient material, the resulting acid-insoluble fraction may be dated. Here we examine the effectiveness of the combined organic solvent and ABA pretreatment with gelatinization for leather samples, as well as the suitability of the acid-insoluble fraction for 14C dating.

scholarly journals Recomposing the City: A Survey of Recent Sound Art in Belfast

2013 ◽  
Vol 23 ◽  
pp. 47-54 ◽  
Author(s):  
Gascia Ouzounian
Keyword(s):  
Public Spaces ◽  
Sound Art ◽  
Site Specific ◽  
Sonic Art ◽  
The Past ◽  
Post Conflict ◽  
The City ◽  
Radical Transformation

This article introduces examples of recent sound art in Belfast, a city that has undergone radical transformation over the past decade and is home to a burgeoning community of sound artists. The text investigates the ways in which sonic art can redraw boundaries in a city historically marked by myriad political, socioeconomic, religious and sectarian divisions. The article focuses on sound works that reimagine a “post-conflict” Belfast. These include site-specific sound installations in urban and public spaces, soundwalks, sculptures, locative and online works, and experimental sonic performances that draw upon traditional Irish song and music.

scholarly journals Radiocarbon Dating of Calcined Bones: Where Does the Carbon Come from?

Radiocarbon ◽  
2009 ◽  
Vol 51 (2) ◽  
pp. 601-611 ◽  
Author(s):  
A Zazzo ◽  
J-F Saliège ◽  
A Person ◽  
H Boucher
Keyword(s):  
Radiocarbon Dating ◽  
Tooth Enamel ◽  
Skeletal Remains ◽  
Archaeological Sites ◽  
Carbonate Content ◽  
The Past ◽  
Mineral Fraction ◽  
Different Temperatures ◽  
C Value ◽  
Paleodietary Reconstruction

Over the past decade, radiocarbon dating of the carbonate contained in the mineral fraction of calcined bones has emerged as a viable alternative to dating skeletal remains in situations where collagen is no longer present. However, anomalously low δ13C values have been reported for calcined bones, suggesting that the mineral fraction of bone is altered. Therefore, exchange with other sources of carbon during heating cannot be excluded. Here, we report new results from analyses on cremated bones found in archaeological sites in Africa and the Near East, as well as the results of several experiments aiming at improving our understanding of the fate of mineral and organic carbon of bone during heating. Heating of modern bone was carried out at different temperatures, for different durations, and under natural and controlled conditions, and the evolution of several parameters (weight, color, %C, %N, δ13C value, carbonate content, crystallinity indexes measured by XRD and FTIR) was monitored. Results from archaeological sites confirm that calcined bones are unreliable for paleoenvironmental and paleodietary reconstruction using stable isotopes. Experimental results suggest that the carbon remaining in bone after cremation likely comes from the original inorganic pool, highly fractionated due to rapid recrystallization. Therefore, its reliability for 14C dating should be seen as close to that of tooth enamel, due to crystallographic properties of calcined bones.

A review on tribological performance of ionic liquids as additives to bio lubricants

2020 ◽  
pp. 135065012097380
Author(s):  
Tehreem Naveed ◽  
Rehan Zahid ◽  
Riaz Ahmad Mufti ◽  
Muhammad Waqas ◽  
Muhammad Talha Hanif
Keyword(s):  
Ionic Liquids ◽  
Friction And Wear ◽  
Combustion Engine ◽  
Tribological Performance ◽  
Environmental Concerns ◽  
Published Data ◽  
Oil Reserves ◽  
Mineral Oils ◽  
The Past ◽  
Interacting Surfaces

All the moving components in an internal combustion engine require a lubricant that allows smooth sliding and/or rolling of interacting surfaces. Lubricant not only minimizes the friction and wear but also dissipates the heat generated due to friction and removes debris from the area of contact. Environmental concerns, decreasing mineral oil reserves and difficult disposal of nonbiodegradable conventional lubricants have urged the researchers to shift towards environmental-friendly lubricants. Number of tribological studies carried out in the past have proved that ionic liquid-based bio-lubricants are sustainable and biodegradable alternative to mineral oils. This paper presents a brief review of properties of ionic liquids and their ability to reduce friction and wear between the interacting surfaces. Tribological performance and compatibility of ionic liquids with various base-oils have been compared under boundary lubrication. The results reveal that phosphonium-based ionic liquids namely tetra-decyl tri-hexyl phosphonium bis(2,4,4-trimethylpentyl) phosphinate (P66614)i(C8)2PO2 and tri-hexyl tetra-decyl phosphonium bis(2-ethylhexyl) phosphate (P-DEHP) are more suitable for tribological applications. Since, ionic liquids can be tailored according to the application and millions of combinations are possible therefore, there is a need to summarize the published data in a more systematic and logical way.

Application of Polyhedral Mesh for Vortex Formation Study for Simple Single Pump Sump

CFD letters ◽  
2021 ◽  
Vol 13 (9) ◽  
pp. 13-27
Author(s):  
Mohamad Lutfi Samsudin ◽  
Hasril Hasini
Keyword(s):  
Experimental Data ◽  
Complex Geometry ◽  
Vortex Formation ◽  
Tetrahedral Mesh ◽  
Published Data ◽  
Hexahedral Mesh ◽  
The Past ◽  
Polyhedral Mesh ◽  
Pump Sump ◽  
Comparison Of The Results

Meshing of domain in CFD is an important step to ensure accuracy of the solution. In the past, hexahedral or tetrahedral mesh systems were commonly used, and both have their merits and demerits. For large and complex geometry, polyhedral is another option but its accuracy is claimed to be lacking. In this paper, the use of polyhedral mesh system by past researchers are reviewed. Evaluation on the application of polyhedral mesh system for the study of the vortex formation with a simple single pump sump model is made. Validation was made through the comparison of the results from hexahedral, tetrahedral and polyhedral mesh sizes and the experimental data from published data. The polyhedral mesh system was found to perform satisfactorily and was able to match the results from the hexahedral mesh system as well as the experimental data.

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