scholarly journals Landslides as geological hotspots of CO<sub>2</sub> emission: clues from the instrumented Séchilienne landslide, western European Alps

2021 ◽  
Vol 9 (3) ◽  
pp. 487-504
Author(s):  
Pierre Nevers ◽  
Julien Bouchez ◽  
Jérôme Gaillardet ◽  
Christophe Thomazo ◽  
Delphine Charpentier ◽  
...  
Keyword(s):  
Chemical Weathering ◽  
Global Climate ◽  
Pyrite Oxidation ◽  
Major Elements ◽  
European Alps ◽  
Flow Paths ◽  
Gypsum Dissolution ◽  
Physical Weathering ◽  
Mountain Ranges ◽  
Carbonate Formation

Abstract. This study makes use of a highly instrumented active landslide observatory (9 years of data) in the French Alps, the Séchilienne slope. Here, we use a combination of major element chemistry and isotopes ratios (87Sr / 86Sr, δ34S) measured in different water types of the stable and unstable part of the Séchilienne instability to assess the contribution of the different lithologies of the slope and the chemical weathering mechanisms. Chemical and isotopic ratios are used to characterize weathering processes and the origin of waters and their flow paths through the massif. A mixing model allows us to allocate the different major elements to different sources, to identify secondary carbonate formation as a major process affecting solutes in the subsurface waters of the instability, and to quantify the involvement of sulfuric and carbonic acids as a source of protons. We show that the instability creates favorable and sustained conditions for the production of sulfuric acid by pyrite oxidation, by opening new fractures and supplying fresh reactive surfaces. We clearly identify the contribution of the dissolution of each mineral phase to the chemistry of the waters, with a clear role of remote gypsum dissolution to the sulfate budget in the sampled waters. We are also able to refine the preexisting hydrogeological views on the local water circulation and water flow paths in the instability by showing the hydrological connectivity of the different zones. Overall, our results show that the Séchilienne landslide, despite its role in accelerating rock chemical and physical weathering, acts as a geological source of CO2 to the atmosphere. If generalizable to other large instabilities in mountain ranges, this study illustrates the complex coupling between physical and chemical erosion and their impact on the carbon cycle and global climate. The study also highlights the importance of distinguishing between sulfite oxidation and gypsum dissolution as a source of sulfate ions to rivers, particularly in mountain ranges.

scholarly journals Landslides as geological hotspots of CO<sub>2</sub> to the atmosphere: clues from the instrumented Séchilienne landslide, Western European Alps

2020 ◽  
Author(s):  
Pierre Nevers ◽  
Julien Bouchez ◽  
Jérôme Gaillardet ◽  
Christophe Thomazo ◽  
Laeticia Faure ◽  
...  
Keyword(s):  
Chemical Weathering ◽  
Pyrite Oxidation ◽  
Major Elements ◽  
European Alps ◽  
Geological Time ◽  
Geological Time Scale ◽  
Gypsum Dissolution ◽  
Physical Weathering ◽  
Mountain Ranges ◽  
Weathering Processes

Abstract. This study makes use of a highly instrumented active landslide observatory (9 years of data) in the French Alps, the Séchilienne slope. Using a combination of major element chemistry and isotopes ratios (87Sr / 86Sr, δ34S) measured in different water types of the stable and unstable part of the Séchilienne instability to assess the contribution of the different lithologies of the slope and the chemical weathering mechanisms. Chemical and isotopic ratios appear useful to characterize weathering processes and the origin of waters and their flowpaths through the massif. A mixing model allows us to allocate the different major elements to different sources and quantify the involvement sulfuric and carbonic acids as a source of protons. As a consequence of the model, we are able to show that the instability creates favorable and sustained conditions for the production of sulfuric acid by pyrite oxidation by supplying reactive surfaces. We clearly identify the contribution of gypsum dissolution to the sulfate budget in the landslide. We are also able to refine the pre-existing hydrogeological views on the local water circulation and water flow paths in the instability but showing the hydrological connectivity of the different zones. Overall, our results show that the Séchilienne landslide, despite its role in accelerating rock chemical and physical weathering, acts, at a geological time scale (i.e. at timescales longer that carbonate precipitation in the ocean) as a source of CO2 to the atmosphere. If generalizable to other instable zones in mountain ranges, this study illustrates the complex coupling between physical and chemical erosion and climate. The study also highlights the importance of deciphering between sulfite oxidation and gypsum dissolution as a source of sulfate ions to rivers, particularly in mountain ranges.

scholarly journals Major Elements in the Upstream of Three Gorges Reservoir: An Investigation of Chemical Weathering and Water Quality during Flood Events

Water ◽  
2021 ◽  
Vol 13 (4) ◽  
pp. 454
Author(s):  
Di Wang ◽  
Guilin Han ◽  
Mingming Hu ◽  
Yuchun Wang ◽  
Jinke Liu ◽  
...  
Keyword(s):  
Water Quality ◽  
Three Gorges Reservoir ◽  
Chemical Weathering ◽  
Global Climate ◽  
Water Quality Assessment ◽  
Major Elements ◽  
Balance Model ◽  
Three Gorges ◽  
Atmospheric Input ◽  
Piper Diagram

Rivers transport terrestrial matter into the ocean, constituting a fundamental channel between inland and oceanic ecosystem and affect global climate change. To reveal chemical weathering processes and environmental health risks during flood periods, water samples were collected in the upper reaches of Three Gorges Reservoir (TGR) in 2020. HCO3− and Ca2+ were the most abundant anions and cations of the river water, respectively. The range of HCO3− concentration was between 1.81 and 3.02 mmol/L, while the mean content of Ca2+ was 1.03 mmol/L. The results of the Piper diagram and element ratios revealed that the river solutes were mainly contributed by carbonate weathering and gypsum-rich evaporite dissolution. A mass balance model indicated that the contribution order of sources to cations in the main channel (Yibin-Luzhou) was evaporites > carbonates > atmospheric input > silicates. The order in the Chongqing—Three Gorges Dam was carbonates > atmospheric input > evaporites > silicates. These results showed a lithologic control on hydrochemical characteristics. Most sampling sites were suitable for agricultural irrigation according to the water quality assessment. However, indexes sodium adsorption ratio (SAR) and soluble sodium percentage (Na%) were higher than 1.0 in Yibin-Luzhou and 30% in Yibin–Chongqing, respectively, suggesting a potential sodium hazard. In addition, except Tuojiang River and Shennong River, the risk of sodium hazard in tributaries was relatively low. High Na+ concentration in irrigation water can damage soil structure and function and ultimately affect agricultural production. Water quality in the upstream of a Piper diagram should attract enough attention.

scholarly journals Co-variation of silicate, carbonate and sulfide weathering drives CO2 release with erosion

2021 ◽  
Vol 14 (4) ◽  
pp. 211-216
Author(s):  
Aaron Bufe ◽  
Niels Hovius ◽  
Robert Emberson ◽  
Jeremy K. C. Rugenstein ◽  
Albert Galy ◽  
...  
Keyword(s):  
Erosion Rate ◽  
Global Climate ◽  
Stream Water ◽  
Sulfide Oxidation ◽  
Silicate Weathering ◽  
Emission Rates ◽  
Mountain Ranges ◽  
Weathering Rates ◽  
Southern Taiwan ◽  
Co2 Release

AbstractGlobal climate is thought to be modulated by the supply of minerals to Earth’s surface. Whereas silicate weathering removes carbon dioxide (CO2) from the atmosphere, weathering of accessory carbonate and sulfide minerals is a geologically relevant source of CO2. Although these weathering pathways commonly operate side by side, we lack quantitative constraints on their co-variation across erosion rate gradients. Here we use stream-water chemistry across an erosion rate gradient of three orders of magnitude in shales and sandstones of southern Taiwan, and find that sulfide and carbonate weathering rates rise with increasing erosion, while silicate weathering rates remain steady. As a result, on timescales shorter than marine sulfide compensation (approximately 106–107 years), weathering in rapidly eroding terrain leads to net CO2 emission rates that are at least twice as fast as CO2 sequestration rates in slow-eroding terrain. We propose that these weathering reactions are linked and that sulfuric acid generated from sulfide oxidation boosts carbonate solubility, whereas silicate weathering kinetics remain unaffected, possibly due to efficient buffering of the pH. We expect that these patterns are broadly applicable to many Cenozoic mountain ranges that expose marine metasediments.

scholarly journals Current glacier recession causes significant rockfall increase: The immediate paraglacial response of deglaciating cirque walls

2020 ◽  
Author(s):  
Ingo Hartmeyer ◽  
Robert Delleske ◽  
Markus Keuschnig ◽  
Michael Krautblatter ◽  
Andreas Lang ◽  
...  
Keyword(s):  
Minor Effect ◽  
European Alps ◽  
Atmospheric Conditions ◽  
Glacier Surface ◽  
Terrestrial Lidar ◽  
Physical Weathering ◽  
Ice Surface ◽  
Recent Climate ◽  
Ample Supply ◽  
A Minor

Abstract. In the European Alps almost half the glacier volume disappeared over the past 150 years. The loss is reflected in glacier retreat and ice surface lowering even at high altitude. In steep glacial cirques surface lowering exposes rock to atmospheric conditions for the very first time in many millennia. Instability of rockwalls has long been identified as one of the direct consequences of deglaciation, but so far cirque-wide quantification of rockfall at high-resolution is missing. Based on terrestrial LiDAR a rockfall inventory for the permafrost-affected rockwalls of two rapidly deglaciating cirques in the Central Alps of Austria (Kitzsteinhorn) is established. Over six-years (2011–2017) 78 rockwall scans were acquired to generate data of high spatial and temporal resolution. 632 rockfalls were registered ranging from 0.003 to 879.4 m³, mainly originating from pre-existing structural rock weaknesses. 60 % of the rockfall volume detached from less than ten vertical meters above the glacier surface, indicating enhanced rockfall activity over tens of years following deglaciation. Debuttressing seems to play a minor effect only. Rather, preconditioning is assumed to start inside the Randkluft (gap between cirque wall and glacier) where sustained freezing and ample supply of liquid water likely cause enhanced physical weathering and high plucking stresses. Following deglaciation, pronounced thermomechanical strain is induced and an active layer penetrates into the formerly perennially frozen bedrock. These factors likely cause the observed paraglacial rockfall increase close to the glacier surface. This paper presents the most extensive dataset of high-alpine rockfall to date and the first systematic documentation of a cirque-wide erosion response of glaciated rockwalls to recent climate warming.

scholarly journals Mineral protection regulates the long-term global preservation of natural organic carbon

2021 ◽  
Author(s):  
Jordon Hemingway ◽  
Daniel Rothman ◽  
Katherine Grant ◽  
Sarah Rosengard ◽  
Timothy Eglinton ◽  
...  
Keyword(s):  
Organic Carbon ◽  
Redox State ◽  
Global Climate ◽  
Atmospheric Oxygen ◽  
Atmospheric Composition ◽  
Earth Surface ◽  
Mountain Ranges ◽  
Surface Redox ◽  
Carbon Erosion

&lt;p&gt;The vast majority of organic carbon (OC) produced by life is respired back to carbon dioxide (CO&lt;sub&gt;2&lt;/sub&gt;), but roughly 0.1% escapes and is preserved over geologic timescales. By sequestering reduced carbon from Earth&amp;#8217;s surface, this &amp;#8220;slow OC leak&amp;#8221; contributes to CO&lt;sub&gt;2&lt;/sub&gt; removal and promotes the accumulation of atmospheric oxygen and oxidized minerals. Countering this, OC contained within sedimentary rocks is oxidized during exhumation and erosion of mountain ranges. By respiring previously sequestered reduced carbon, erosion consumes atmospheric oxygen and produces CO&lt;sub&gt;2&lt;/sub&gt;. The balance between these two processes&amp;#8212;preservation and respiration&amp;#8212;regulates atmospheric composition, Earth-surface redox state, and global climate. Despite this importance, the governing mechanisms remain poorly constrained. To provide new insight, we developed a method that investigates OC composition using bond-strength distributions coupled with radiocarbon ages. Here I highlight a suite of recent results using this approach, and I show that biospheric OC interacts with particles and becomes physiochemically protected during aging, thus promoting preservation. I will discuss how this mechanistic framework can help elucidate why OC preservation&amp;#8212;and thus atmospheric composition, Earth-surface redox state, and climate&amp;#8212;has varied throughout Earth history.&lt;/p&gt;

scholarly journals The Effect of Weathering on Salt Release from Coal Mine Spoils

Minerals ◽  
2019 ◽  
Vol 9 (12) ◽  
pp. 760
Author(s):  
Melinda Hilton ◽  
Mandana Shaygan ◽  
Neil McIntyre ◽  
Thomas Baumgartl ◽  
Mansour Edraki
Keyword(s):  
Particle Size ◽  
Coal Mine ◽  
Chemical Weathering ◽  
Physical Weathering ◽  
Particle Size Fractions ◽  
Mine Spoils ◽  
Weathering Processes ◽  
Three Samples ◽  
Two Samples ◽  
Physical And Chemical

Coal mine spoils have the potential to create environmental impacts, such as salt load to surrounding environments, particularly when exposed to weathering processes. This study was conducted to understand the effect of physical and chemical weathering on the magnitude, rate, and dynamics of salt release from different coal mine spoils. Five spoil samples from three mines in Queensland were sieved to three different particle size fractions (<2 mm, 2–6 mm, and >6 mm). Two samples were dispersive spoils, and three samples were nondispersive spoils. The spoils were subjected to seven wet–dry cycles, where the samples were periodically leached with deionised water. The rate, magnitude, and dynamics of solutes released from spoils were spoil specific. One set of spoils did not show any evidence of weathering, but initially had higher accumulation of salts. In contrast, broad oxidative weathering occurred in another set of spoils; this led to acid generation and resulted in physical weathering, promoting adsorption–desorption and dissolution and, thus, a greater release of salts. This study indicated that the rate and magnitude of salt release decreased with increasing particle size. Nevertheless, when the spoil is dispersive, the degree of weathering manages salt release irrespective of initial particle size. This study revealed that the long-term salt release from spoils is not only governed by geochemistry, weathering degree, and particle size but also controlled by the water/rock ratio and hydrological conditions of spoils.

scholarly journals Controls on the Dynamics of Rare Earth Elements During Subtropical Hillslope Processes and Formation of Regolith-Hosted Deposits

2020 ◽  
Vol 115 (5) ◽  
pp. 1097-1118 ◽  
Author(s):  
Martin Yan Hei Li ◽  
Mei-Fu Zhou ◽  
Anthony E. Williams-Jones
Keyword(s):  
Rare Earth ◽  
Soil Ph ◽  
South China ◽  
Chemical Weathering ◽  
Major Elements ◽  
Weathering Crust ◽  
Erosion Rates ◽  
Gradual Development ◽  
Efficient Exploration ◽  
Hillslope Processes

Abstract Subtropical weathering of granitic catchments in South China has led to the formation of numerous giant regolith-hosted rare earth element (REE) deposits that currently account for more than 15% of global REE production and more than 95% of global heavy REE (HREE) production. Understanding the controls on mobilization and redistribution of the REEs during subtropical weathering in these granitic catchments is crucial for efficient exploration for this type of deposit in the world. As exemplified by the Bankeng light REE (LREE) deposit in South China, the key factors controlling the mobilization and redistribution of the REEs, especially the easily exchangeable REEs, are soil pH and primary REE mineralogy. The nature of the primary REE minerals, apatite, monazite-(Ce), and subordinate bastnäsite-(Ce), parisite-(Ce), and xenotime-(Y) places an important control on the behavior of the REEs during incipient weathering. Dissolution of these minerals is slow during incipient weathering, and, therefore, enrichment in REEs in this stage results largely from the removal of major elements during the decomposition of albite, K-feldspar, and biotite. Dissolution of the primary REE minerals higher in the profile liberates the REEs, which are then transported to locations where the soil pH abruptly increases due to water-regolith interaction, such as the pedolith-saprolite interface, and adsorption on kaolinite-group minerals efficiently fixes the REEs in regolith. Geomorphologically, the Bankeng deposit, like most of the other regolith-hosted REE deposits in South China, is located on concave-convex hillslopes, where erosion is prevalent at the ridgetop and decreases in intensity downslope. Results of this study show that strong erosion, coupled with intense chemical weathering at the ridgetop, is responsible for the enrichment in REEs by releasing the REEs, especially the LREEs, from their primary sources and supplying kaolinite and halloysite needed for the REE adsorption by decomposing albite, K-feldspar, and biotite. Decomposition of these major rock-forming minerals also leads to an enrichment of the REEs through the removal of components. The HREEs are lost preferentially to the groundwater and transported downslope, resulting in the enrichment of these elements in the lower part of the weathering crust at the footslope. Significant lateral Ce transport is also probable. A series of oxic fronts were developed at the footslope, with the most persistent one along the saprolite-saprock interface, due to seasonal fluctuations of the groundwater table. Cerium was immobilized there, predominantly through adsorption on Fe-Mn oxyhydroxides, causing enormous accumulation. Therefore, hillslope processes and groundwater flow could redistribute the REEs across the entire catchment, preferentially enriching the LREEs at the ridgetop and the HREEs at the footslope. Also, intense erosion facilitates chemical weathering and the accumulation of REEs, but the development of a thick weathering crust is favored by weak erosion. Repeated periods of high and low erosion rates in South China have enabled the gradual development of thick weathering crusts at the ridgetops that are sufficiently enriched in REEs to now constitute a major resource of these economically important elements.

Evolution of the Martian Crust

2017 ◽  
Author(s):  
John C. Bridges
Keyword(s):  
Plate Tectonics ◽  
Chemical Weathering ◽  
Compositional Data ◽  
Crustal Contamination ◽  
Planetary Science ◽  
Mantle Metasomatism ◽  
Igneous Rocks ◽  
Forthcoming Article ◽  
Physical Weathering ◽  
Igneous Activity

This is an advance summary of a forthcoming article in the Oxford Encyclopedia of Planetary Science. Please check back later for the full article.Mars, which has a tenth of the mass of Earth, has cooled as a single lithospheric plate. Current topography gravity maps and magnetic maps do not show signs of the plate tectonics processes that have shaped the Earth’s surface. Instead, Mars has been shaped by the effects of meteorite bombardment, igneous activity, and sedimentary—including aqueous—processes. Mars also contains enormous igneous centers—Tharsis and Elysium, with other shield volcanoes in the ancient highlands. In fact, the planet has been volcanically active for nearly all of its 4.5 Gyr history, and crater counts in the Northern Lowlands suggest that may have extended to within the last tens of millions of years. Our knowledge of the composition of the igneous rocks on Mars is informed by over 100 Martian meteorites and the results from landers and orbiters. These show dominantly tholeiitic basaltic compositions derived by melting of a relatively K, Fe-rich mantle compared to that of the Earth. However, recent meteorite and lander results reveal considerable diversity, including more silica-rich and alkaline igneous activity. These show the importance of a range of processes including crystal fractionation, partial melting, and possibly mantle metasomatism and crustal contamination of magmas. The figures and plots of compositional data from meteorites and landers show the range of compositions with comparisons to other planetary basalts (Earth, Moon, Venus). A notable feature of Martian igneous rocks is the apparent absence of amphibole. This is one of the clues that the Martian mantle had a very low water content when compared to that of Earth.The Martian crust, however, has undergone hydrothermal alteration, with impact as an important heat source. This is shown by SNC analyses of secondary minerals and Near Infra-Red analyses from orbit. The associated water may be endogenous.Our view of the Martian crust has changed since Viking landers touched down on the planet in 1976: from one almost entirely dominated by basaltic flows to one where much of the ancient highlands, particularly in ancient craters, is covered by km deep sedimentary deposits that record changing environmental conditions from ancient to recent Mars. The composition of these sediments—including, notably, the MSL Curiosity Rover results—reveal an ancient Mars where physical weathering of basaltic and fractionated igneous source material has dominated over extensive chemical weathering.

scholarly journals Dynamic responses of DOC and DIC transport to different flow regimes in a subtropical small mountainous river

2018 ◽  
Vol 22 (12) ◽  
pp. 6579-6590 ◽  
Author(s):  
Yu-Ting Shih ◽  
Pei-Hao Chen ◽  
Li-Chin Lee ◽  
Chien-Sen Liao ◽  
Shih-Hao Jien ◽  
...  
Keyword(s):  
Chemical Weathering ◽  
Mixing Model ◽  
Dynamic Responses ◽  
Flow Paths ◽  
Dissolved Carbon ◽  
Southwestern Taiwan ◽  
Event Flow ◽  
Mountainous River ◽  
Annual Time ◽  
Global Carbon

Abstract. Transport of riverine dissolved carbon (including DOC and DIC) is a crucial process linking terrestrial and aquatic C reservoirs, but has rarely been examined in subtropical small mountainous rivers (SMRs). This study monitored DOC and DIC concentrations on a biweekly basis during non-event flow periods and at 3 h intervals during two typhoon events in three SMRs in southwestern Taiwan between January 2014 and August 2016. Two models, HBV (the Hydrologiska Byråns Vattenbalansavdelning model) and a three-endmember mixing model, were applied to determine the quantities of DOC and DIC transport from different flow paths. The results show that the annual DOC and DIC fluxes were 2.7–4.8 and 48.4–54.3 t C km−2 yr−1, respectively, which were approx. 2 and 20 times higher than the global mean of 1.4 and 2.6 t C km−2 yr−1, respectively. The DIC ∕ DOC ratio was 14.08, which is much higher than the mean of large rivers worldwide (1.86), and indicates the high rates of chemical weathering in this region. The two typhoons contributed 12 %–14 % of the annual streamflow in only 3 days (about 1.0 % of the annual time), whereas 15.0 %–23.5 % and 9.2 %–12.6 % of the annual DOC and DIC flux, respectively, suggested that typhoons play a more important role in DOC transport than DIC transport. The endmember mixing model suggested that DOC and DIC export was mainly from surface runoff and deep groundwater, respectively. The unique patterns seen in Taiwan SMRs characterized by high dissolved carbon flux, high DIC ∕ DOC ratio, and large transport by intense storms should be taken into consideration when estimating global carbon budgets.

scholarly journals Arctic–alpine blockfields in the northern Swedish Scandes: late Quaternary – not Neogene

2014 ◽  
Vol 2 (2) ◽  
pp. 383-401 ◽  
Author(s):  
B. W. Goodfellow ◽  
A. P. Stroeven ◽  
D. Fabel ◽  
O. Fredin ◽  
M.-H. Derron ◽  
...  
Keyword(s):  
Chemical Weathering ◽  
Late Quaternary ◽  
Time Frame ◽  
Temporal Variations ◽  
Early Pleistocene ◽  
Slope Position ◽  
Physical Weathering ◽  
Weathering Processes ◽  
Erosion Rates ◽  
Surrounding Landscape

Abstract. Autochthonous blockfield mantles may indicate alpine surfaces that have not been glacially eroded. These surfaces may therefore serve as markers against which to determine Quaternary erosion volumes in adjacent glacially eroded sectors. To explore these potential utilities, chemical weathering features, erosion rates, and regolith residence durations of mountain blockfields are investigated in the northern Swedish Scandes. This is done, firstly, by assessing the intensity of regolith chemical weathering along altitudinal transects descending from three blockfield-mantled summits. Clay / silt ratios, secondary mineral assemblages, and imaging of chemical etching of primary mineral grains in fine matrix are each used for this purpose. Secondly, erosion rates and regolith residence durations of two of the summits are inferred from concentrations of in situ-produced cosmogenic 10Be and 26Al in quartz at the blockfield surfaces. An interpretative model is adopted that includes temporal variations in nuclide production rates through surface burial by glacial ice and glacial isostasy-induced elevation changes of the blockfield surfaces. Together, our data indicate that these blockfields are not derived from remnants of intensely weathered Neogene weathering profiles, as is commonly considered. Evidence for this interpretation includes minor chemical weathering in each of the three examined blockfields, despite consistent variability according to slope position. In addition, average erosion rates of ~16.2 and ~6.7 mm ka−1, calculated for the two blockfield-mantled summits, are low but of sufficient magnitude to remove present blockfield mantles, of up to a few metres in thickness, within a late Quaternary time frame. Hence, blockfield mantles appear to be replenished by regolith formation through, primarily physical, weathering processes that have operated during the Quaternary. The persistence of autochthonous blockfields over multiple glacial–interglacial cycles confirms their importance as key markers of surfaces that were not glacially eroded through, at least, the late Quaternary. However, presently blockfield-mantled surfaces may potentially be subjected to large spatial variations in erosion rates, and their Neogene regolith mantles may have been comprehensively eroded during the late Pliocene and early Pleistocene. Their role as markers by which to estimate glacial erosion volumes in surrounding landscape elements therefore remains uncertain.

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