scholarly journals Alleviating aluminum toxicity in an acid sulfate soil from Peninsular Malaysia by calcium silicate application

Solid Earth ◽  
2016 ◽  
Vol 7 (2) ◽  
pp. 367-374 ◽  
Author(s):  
A. A. Elisa ◽  
S. Ninomiya ◽  
J. Shamshuddin ◽  
I. Roslan
Keyword(s):  
Soil Ph ◽  
Calcium Silicate ◽  
Soil Acidity ◽  
Aluminum Toxicity ◽  
Peninsular Malaysia ◽  
Population Increase ◽  
Acid Sulfate ◽  
Exchangeable Ca ◽  
Exchangeable Al ◽  
Ameliorative Effect

Abstract. In response to human population increase, the utilization of acid sulfate soils for rice cultivation is one option for increasing production. The main problems associated with such soils are their low pH values and their associated high content of exchangeable Al, which could be detrimental to crop growth. The application of soil amendments is one approach for mitigating this problem, and calcium silicate is an alternative soil amendment that could be used. Therefore, the main objective of this study was to ameliorate soil acidity in rice-cropped soil. The secondary objective was to study the effects of calcium silicate amendment on soil acidity, exchangeable Al, exchangeable Ca, and Si content. The soil was treated with 0, 1, 2, and 3 Mg ha−1 of calcium silicate under submerged conditions and the soil treatments were sampled every 30 days throughout an incubation period of 120 days. Application of calcium silicate induced a positive effect on soil pH and exchangeable Al; soil pH increased from 2.9 (initial) to 3.5, while exchangeable Al was reduced from 4.26 (initial) to 0.82 cmolc kg−1. Furthermore, the exchangeable Ca and Si contents increased from 1.68 (initial) to 4.94 cmolc kg−1 and from 21.21 (initial) to 81.71 mg kg−1, respectively. Therefore, it was noted that calcium silicate was effective at alleviating Al toxicity in acid sulfate, rice-cropped soil, yielding values below the critical level of 2 cmolc kg−1. In addition, application of calcium silicate showed an ameliorative effect as it increased soil pH and supplied substantial amounts of Ca and Si.

scholarly journals Alleviating aluminium toxicity on an acid sulphate soils in Peninsular Malaysia with application of calcium silicate

2015 ◽  
Vol 7 (4) ◽  
pp. 2903-2926
Author(s):  
A. A. Elisa ◽  
S. Ninomiya ◽  
J. Shamshuddin ◽  
I. Roslan
Keyword(s):  
Soil Ph ◽  
Calcium Silicate ◽  
Peninsular Malaysia ◽  
Al Toxicity ◽  
Acid Sulphate ◽  
Rice Growth ◽  
Acid Sulphate Soils ◽  
Exchangeable Al ◽  
Si Content ◽  
Positive Effect

Abstract. A study was conducted to alleviate Al toxicity of an acid sulphate soils collected from paddy cultivation area in Kedah, Peninsular Malaysia. For this purpose, the collected acid sulphate soils were treated with calcium silicate. The treated soils were incubated for 120 days in submerged condition in a glasshouse. Subsamples were collected every 30 days throughout the incubation period. Soil pH and exchangeable Al showed positive effect; soil pH increased from 2.9 to 3.5, meanwhile exchangeable Al was reduced from 4.26 to 0.82 cmolc kg−1, which was well below the critical Al toxicity level for rice growth of 2 cmolc kg−1. It was noted that the dissolution of calcium silicate (CaSiO3) supplied substantial amount of Ca2+ and H4SiO42− ions into the soil, noted with increment in Si (silicate) content from 21.21 to 40 mg kg−1 at day 30 and reduction of exchangeable Al at day 90 from 4.26 to below 2 cmolc kg−1. During the first 60 days of incubation, Si content was positively correlated with soil pH, while the exchangeable Al was negatively correlated with Si content. It is believed that the silicate anions released by calcium silicate were active in neutralizing H+ ions that governs the high acidity (pH 2.90) of the acid sulphate soils. This scenario shows positive effect of calcium silicate to reduce soil acidity, therefore creates a favourable soil condition for good rice growth during its vegetative phase (30 days). Thus, application of calcium silicate to alleviate Al toxicity of acid sulphate soils for rice cultivation is a good soil amendment.

The use of Ca-modified, brown-coal-derived humates and fulvates for treatment of soil acidity

Soil Research ◽  
2002 ◽  
Vol 40 (7) ◽  
pp. 1171 ◽  
Author(s):  
Damayanthi Peiris ◽  
Antonio F. Patti ◽  
W. Roy Jackson ◽  
Marc Marshall ◽  
Christopher J. Smith
Keyword(s):  
Brown Coal ◽  
Soil Ph ◽  
Soil Acidity ◽  
Soil Column ◽  
Chemical Properties ◽  
Soil Surface ◽  
Al Content ◽  
Exchangeable Ca ◽  
Exchangeable Al ◽  
Over The Top

Previous workers have demonstrated the amelioration of soil acidity with Ca-saturated, at least slightly soluble, organic materials. This study investigated the effectiveness of a new source of such materials, the humate- or fulvate-rich products of oxidation (hydrogen peroxide) of Loy Yang brown coal. The products were characterised by physical and spectroscopic measurements and by elemental analysis. Two products, one approximately half fulvate (fulvate-rich), the other predominantly humate (humate-rich) were mixed with CaCl2 and then used to treat columns of an acid red podzol soil from Book Book, NSW. Leachate fractions were collected and analysed for pH, ionic strength, and concentration of Ca, Mg, K, Mn, Fe, and Al. After leaching (3 pore volumes), each soil column was sectioned and exchangeable Ca and Al contents were determined. The results were compared with those obtained from lime-treated and untreated columns.The Ca-fulvate-rich product was the most effective in lowering the exchangeable Al content of the soil whilst increasing exchangeable Ca and soil pH. About 90% of the reduction in exchangeable Al was due to loss of Al in the leachate rather than immobilisation. The pH increased over the top 15 cm of the column from 3.8 ± 0.1 to 4.5–5.4. The Ca-humate-rich oxidised product was less effective in ameliorating soil acidity, as expected from its chemical properties, but it increased soil pH (to 4.0–4.7) and exchangeable Ca in the top 6 cm of the column and decreased exchangeable Al in the top 12 cm. More of the reduction in exchangeable Al than for the treatment with Ca-fulvate-rich material was due to conversion to an immobile form. This material was superior to lime, which only gave significant improvement near the soil surface. The leachates from treated columns contained the same amounts of Mg, Mn, and K as a control, but more Fe was leached from treated columns, particularly that treated with the Ca-fulvate-rich product.

scholarly journals Crop Response to Soil Acidity Factors in Ultisols and Oxisols in Puerto Rico. XII. Tomatoes

1969 ◽  
Vol 69 (3) ◽  
pp. 357-365
Author(s):  
Edmundo Rivera ◽  
José Rodríguez ◽  
Fernando Abruña
Keyword(s):  
Puerto Rico ◽  
Cation Exchange ◽  
Soil Ph ◽  
Cation Exchange Capacity ◽  
Soil Acidity ◽  
Exchange Capacity ◽  
Crop Response ◽  
Exchangeable Al

The effect of acidity factors of two Ultisols and one Oxisol on yield and foliar composition of tomatoes was determined. Yields were not markedly reduced by acidity in the Ultisols until pH dropped to around 4.6 with 45% Al saturation of the cation exchange capacity (CEC), and no yield was produced at about pH 4.1 and 80% Al saturation. In the Oxisol, tomato yields dropped steadily from 39.7 t/ha, when there was no exchangeable AI, to 17.5 t/ha at the highest level of acidity, pH 4.4 and 43% AI saturation. In all soils, yields were closely correlated with soil pH, exchangeable Al and Ca and Al/Ca.

Temporal variation in soil acidity

Soil Research ◽  
1997 ◽  
Vol 35 (5) ◽  
pp. 1115 ◽  
Author(s):  
M. K. Conyers ◽  
N. C. Uren ◽  
K. R. Helyar ◽  
G. J. Poile ◽  
B. R. Cullis
Keyword(s):  
Temporal Variation ◽  
Soil Ph ◽  
Soil Acidity ◽  
Soil Depth ◽  
Weather Conditions ◽  
Climatic Conditions ◽  
Variable Response ◽  
Related Factors ◽  
Exchangeable Al ◽  
Eastern Australia

Seasonal variation in the response of crops and pastures to limestone application has been observed on acidic soils in south-eastern Australia. Our hypothesis was that temporal variation in soil acidity related factors may contribute to this variable response. Soils from 4 annual pasture sites were sampled at least monthly for 3 years during 1988–1990 to monitor changes in pH(CaCl2) and in concentrations of exchangeable aluminium (Al) and manganese (Mn). The sites received no fertiliser or cultivation and therefore allowed for the estimation of natural temporal variation. Temporal variation in soil pH during a year ranged from 0 to 0·45 pH units depending on the site, soil depth, and the weather conditions. The larger changes in soil pH were associated with more extreme climatic conditions than normal, e.g. following the break of season after a hot, dry summer (autumn 1988) or during periods of above-average rainfall in autumn and early spring (1990). Temporal variation in pH was less than the spatial variability at the sites but greater than the long-term net acidification rate reported for the region. Temporal variation in the concentration of exchangeable Al ranged from 0 to 0·4 cmol(+)/kg during a year and varied primarily with the inverse of pH. Variations in the concentration of exchangeable Mn ranged from 0·05 to 0·35 cmol(+)/kg during a year. The concentration of exchangeable Mn increased over summer to an extent dependent on the drying of the soil. At the 2 sites with duplex profiles, maxima in the concentration of exchangeable Mn also occurred in spring, particularly in the warm wet spring of 1990. Soil tests for soil acidity therefore represent guides to probable risks of toxicity, as pH and the concentrations of exchangeable Al and Mn may change between soil sampling, sowing, and the period of crop or annual pasture growth. Such variations will alter the responsiveness of crops and pastures to lime.

Effect of Soil pH and Related Acidity Factors on Yields of Sweetpotatoes and Soybeans Grown on Typical Soils of the Humid Tropics

1969 ◽  
Vol 61 (1) ◽  
pp. 82-89
Author(s):  
Raúl Pérez-Escolar
Keyword(s):  
Puerto Rico ◽  
Soil Ph ◽  
Soil Acidity ◽  
Humid Tropics ◽  
Soybean Yield ◽  
Base Content ◽  
Exchangeable Al ◽  
Soybean Leaf ◽  
Leaf N Content ◽  
Leaf N

The effects of soil pH and related acidity factors on the yields of sweetpotatoes, Miguela var., and soybeans, Jupiter var., were determined on typical Oxisols and Ultisols of Puerto Rico. The study revealed no significant effect of pH and acidity factors on the yield of the sweetpotato variety, which was quite tolerant to high soil acidity and exchangeable Al. Yields were similar to those obtained by other researchers who worked with other varieties. Soybeans, although relatively tolerant to high levels of exchangeable Al, were adversely affected when values surpassed 5.5 meq/100 g of soil in a clayey Ultisol. Exchangeable base content was directly related to soybean yield grown on a light textured Oxisol. Yields obtained are considered excellent. Highly significant correlations between soybean leaf N content and yield was found in the clayey Ultisol.

Crop Response to Soil Acidity Factors in Ultisols and Oxisols in Puerto Rico. X. Pigeon Peas

1969 ◽  
Vol 68 (4) ◽  
pp. 433-443
Author(s):  
F. Abruña ◽  
E. Rivera ◽  
J. A. Rodríguez-García
Keyword(s):  
Puerto Rico ◽  
Soil Ph ◽  
Cajanus Cajan ◽  
Soil Acidity ◽  
Crop Response ◽  
Al Content ◽  
Exchangeable Al ◽  
Leaf Composition

The effect of various soil acidity factors on yield and leaf composition of pigeon peas [Cajanus cajan (L.) Huth] was determined in two Ultisols and one Oxisol. Pigeon peas barely responded in yield to soil acidity levels in the Oxisol, but responded strongly to variations in soil acidity in the two Ultisols. Yields increased from almost zero at the highest level of acidity (about pH 4 and 80% Al saturation) to more than 8 t/ha at about pH 6.0 with no exchangeable Al present. Yields increased with increasing soil pH, decreasing exchangeable Al content, and increasing exchangeable Al:Ca ratio. Yields were highest when pH was about 6.0, exchangeable Al was less than 20%, and exchangeable Al:Ca was less than 1.0. Soil acidity did not affect leaf composition, except that Ca content decreased with increasing acidity and correlated well with yields, ranging from about 0.5% with lowest yields to more than 1% with the highest yields. Number of nodules per plant was not affected by acidity factors, except at the highest level of acidity, at which no nodules were found.

scholarly journals Reduction of exchangeable calcium and magnesium in soil with increasing pH

2001 ◽  
Vol 44 (2) ◽  
pp. 149-153 ◽  
Author(s):  
Mário Miyazawa ◽  
Marcos A. Pavan ◽  
Cláudio O. Ziglio ◽  
Júlio C. Franchini
Keyword(s):  
Chemical Reactions ◽  
Soil Ph ◽  
Laboratory Study ◽  
Soil Samples ◽  
Exchangeable Calcium ◽  
Exchangeable Ca ◽  
Exchangeable Al ◽  
Naoh Solution ◽  
Synthetic Solution ◽  
Calcium And Magnesium

A laboratory study was conducted with soil samples and synthetic solutions to investigate possible mechanisms related with reduction in KCl exchangeable Ca and Mg with increasing pH. Increasing soil pH over 5.3 with CaCO3 added to the soil and with NaOH solution added to soil/KCl suspension increased adsorptions of Ca and Mg. The reduction of Mg was greater than Ca and was related to the concentration of soil exchangeable Al. The decreases of soluble Ca and Mg following addition of Al in synthetic solution were at pH > 7.5. The isomorphic coprecipitation reaction with Al compounds may be the most possible mechanism responsible for the decrease of exchangeable Ca and Mg with increasing pH. Possible chemical reactions are presented.

scholarly journals Effect of Soil Acidity and Liming on Yields and Composition of Sugarcane Growing on an Ultisol

1969 ◽  
Vol 52 (2) ◽  
pp. 85-100
Author(s):  
Fernando Abruña Rodríguez ◽  
Juan Juárez ◽  
Raúl Pérez Escolar ◽  
José Vicente Chandler
Keyword(s):  
Soil Ph ◽  
Soil Acidity ◽  
Sucrose Content ◽  
Soil Factors ◽  
Base Content ◽  
Exchangeable Bases ◽  
Fertilized Soil ◽  
Exchangeable Al ◽  
Humid Region ◽  
Exchangeable Aluminum

Variable liming and heavy fertilization of a Cialitos clay (ultisol) over a 7-year period markedly affected soil properties and yields of subsequently planted sugarcane. A total of 3,680 pounds of N, 480 pounds of P, and 2,870 pounds of K had been applied per acre to all plots over this period. Cane yields increased from less than 1 ton per acre, when no lime had been applied, to over 40 tons when a total of 20 tons of limestone had been applied per acre over the previous 7-year period. Yields increased with increasing exchangeable base content in the upper 6 inches of soil from less than 10 tons per acre when exchangeable bases dropped below 3 meq., to over 40 tons when exchangeable bases exceeded 8 meq./l00 g. of soil (58-percent base saturation). Cane yields increased with decreasing exchangeable Al from less than 10 tons, when exchangeable Al exceeded 8 meq., to over 40 when exchange able Al was less than 2 meq./100 g. of soil. Yields increased with increasing soil pH, but the presence of free salts in this heavily fertilized soil made pH an unreliable criterion for determining the need for liming. Applying 8 tons of limestone per acre to the surface of a very acid Cialitos clay before planting increased cane yields from an average of 12.4 to 34.5 tons per acre, and decreased exchangeable Al from 7.3 to 0.5 meq. per 100 g. of soil. The foliar composition at 9 months of age, and the sucrose content of the sugarcane were not affected by the soil factors studied, or by lime applications, and remained unchanged, at satisfactory levels, in plots yielding from almost 0 to over 40 tons of cane per acre. A survey showed that in many sugarcane soils of the Humid Region exchangeable aluminum exceeded levels that depressed cane yields on Cialitos clay in this experiment.

scholarly journals Interaction of liming and long-term fertilization increased crop yield and phosphorus use efficiency (PUE) through mediating exchangeable cations in acidic soil under wheat–maize cropping system

2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Muhammad Qaswar ◽  
Li Dongchu ◽  
Huang Jing ◽  
Han Tianfu ◽  
Waqas Ahmed ◽  
...  
Keyword(s):  
Crop Yield ◽  
Soil Ph ◽  
Base Cations ◽  
Acidic Soil ◽  
Phosphorus Use Efficiency ◽  
Exchangeable Ca ◽  
Exchangeable Al ◽  
Use Efficiency ◽  
Lime Application

AbstractLow phosphorus use efficiency (PUE) is one of the main problems of acidic soil that limit the crop growth. Therefore, in the present study, we investigated the response of crop yield and PUE to the long-term application of fertilizers and quicklime (CaO) in the acidic soil under wheat–maize rotation system. Treatments included, CK (no fertilization), NP (inorganic nitrogen and P fertilization), NPK (inorganic N, P and potassium fertilization), NPKS (NPK + straw return), NPCa (NP + lime), NPKCa (NPK + lime) and NPKSCa (NPKS + lime). Results showed that, fertilizer without lime treatments, significantly (p ≤ 0.05) decreased soil pH and crop yield, compared to the fertilizer with lime treatments during the period of 2012–2018. Average among years, compared to the CK treatment, wheat grain yield increased by 138%, 213%, 198%, 547%, 688% and 626%, respectively and maize yield increased by 687%, 1887%, 1651%, 2605%, 5047% and 5077%, respectively, under the NP, NPK, NPKS, NPCa, NPKCa and NPKSCa treatments. Lime application significantly increased soil exchangeable base cations (Ca2+ and Mg2+) and decreased Al3+ cation. Compared to the NP treatment, phosphorus use efficiency (PUE) increased by 220%, 212%, 409%, 807% and 795%, respectively, under the NPK, NPKS, NPCa, NPKCa and NPKSCa treatments. Soil pH showed significant negative relationship with exchangeable Al3+ and soil total N. While, soil pH showed significant (p ≤ 0.05) positive relationship with exchangeable Ca2+, PUE and annual crop yield. PUE was highly negatively correlated with soil exchangeable Al3+. In addition, soil exchangeable Ca2+, pH, exchangeable Al3+ and available N were the most influencing factors of crop yield. Therefore, we concluded that lime application is an effective strategy to mitigate soil acidification and to increase PUE through increasing exchangeable base cations and reducing the acidic cations for high crop yield in acidic soil.

scholarly journals Effects of soil acidity on Douglas fir seedlings. 1. Rooting characteristics of natural regeneration of Douglas fir in strongly acid forest soils.

1987 ◽  
Vol 35 (4) ◽  
pp. 533-536
Author(s):  
H.P. Smit ◽  
N. van Breemen ◽  
W.G. Keltjens
Keyword(s):  
Pseudotsuga Menziesii ◽  
Natural Regeneration ◽  
Soil Acidity ◽  
Mineral Soil ◽  
Field Studies ◽  
Douglas Fir ◽  
Total Root Length ◽  
Exchangeable Ca ◽  
Exchangeable Al ◽  
Acid Forest Soils

Results of field studies suggested that total root length of Douglas fir (Pseudotsuga menziesii) in mineral soil was affected by high exchangeable Al accompanied by low exchangeable Ca. This was only true, however, if the mineral soil to 5 cm depth was extremely acid (pH

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