An Attempt at a Rational Classification of the Principal Accelerators of Vulcanization
Abstract AT the present time there are many accelerators on the market for the vulcanization of rubber, but it is often difficult to choose among them those best suited for a required purpose. Accelerators are often classed as slow medium, rapid and ultra rapid. These brief terms are entirely unsatisfactory for characterizing clearly the properties of these properties, and it frequently happens that two accelerators which have been placed together in one class behave in reality in very different ways and are not entirely replaceable one by the other. The object of this study is to establish a rational classification of the principal accelerators of vulcanization, which is based not only on their activity but also on their other important characteristics. The following points will be considered in their order: (1) The time required for the fixation of mixtures at different temperatures. (2) The time required to bring about vulcanization giving the maxima mechanical properties at different temperatures. (3) Aging. (4) These three points of view will be completed by a study of the plasticizing power and of the influence of different charges on the action of the accelerators.