A Novel Fluorocarbon Elastomer for High-Temperature Sealing Applications in Aggressive Motor-Oil Environments

1990 ◽  
Vol 63 (4) ◽  
pp. 516-522 ◽  
Author(s):  
W. M. Grootaert ◽  
R. E. Kolb ◽  
A. T. Worm

Abstract The tendency in the automotive industry to use smaller engines has resulted in a situation where lubricating oils are exposed to higher operating temperatures. This is especially the case in countries where there is no restriction on highway speed. Amine-based additives present in the oils (e.g., as dispersants and corrosion inhibitors) tend to slowly attack the conventional fluorocarbon elastomer seals under these conditions. As a result of that attack, the seal becomes brittle and eventually fails. A novel fluorocarbon elastomer of vinylidene fluoride, tetrafluoroethylene, and propylene has shown excellent aging behavior in the laboratory toward many aggressive engine oils at elevated temperature. Its improved resistance as compared to conventional fluorocarbon elastomers is attributed to the replacement of hexafluoropropylene with propylene.

2014 ◽  
Vol 1 (3-4) ◽  
Author(s):  
Cary Baur ◽  
Yuan Zhou ◽  
Justin Sipes ◽  
Shashank Priya ◽  
Walter Voit

AbstractIndustrial use of piezoelectric polymers is currently limited by low piezoelectric response and large performance losses at elevated operating temperatures. Leading polymers such as poly(vinylidene fluoride) and poly(vinylidene fluoride-co-trifluoroethylene) (P(VDF-TrFE)) possess piezoelectric d


Author(s):  
R. E. Franck ◽  
J. A. Hawk ◽  
G. J. Shiflet

Rapid solidification processing (RSP) is one method of producing high strength aluminum alloys for elevated temperature applications. Allied-Signal, Inc. has produced an Al-12.4 Fe-1.2 V-2.3 Si (composition in wt pct) alloy which possesses good microstructural stability up to 425°C. This alloy contains a high volume fraction (37 v/o) of fine nearly spherical, α-Al12(Fe, V)3Si dispersoids. The improved elevated temperature strength and stability of this alloy is due to the slower dispersoid coarsening rate of the silicide particles. Additionally, the high v/o of second phase particles should inhibit recrystallization and grain growth, and thus reduce any loss in strength due to long term, high temperature annealing.The focus of this research is to investigate microstructural changes induced by long term, high temperature static annealing heat-treatments. Annealing treatments for up to 1000 hours were carried out on this alloy at 500°C, 550°C and 600°C. Particle coarsening and/or recrystallization and grain growth would be accelerated in these temperature regimes.


Alloy Digest ◽  
1964 ◽  
Vol 13 (6) ◽  

Abstract UDIMET 41 is a vacuum induction melted precipitation hardening nickel-base alloy having outstanding room and elevated temperature properties. It possesses excellent corrosion and oxidation resistance. It is designed for highly stressed components operating in the 1400-1700 deg F temperature range. This datasheet provides information on composition, physical properties, hardness, elasticity, and tensile properties as well as creep. It also includes information on low and high temperature performance as well as forming, heat treating, machining, and joining. Filing Code: Ni-92. Producer or source: Special Metals Inc..


Alloy Digest ◽  
1998 ◽  
Vol 47 (12) ◽  

Abstract MO-RE 40MA is a fully austenitic heat-resistant alloy for elevated temperature applications. The alloy is microalloyed for creep strength and oxidation resistance. This datasheet provides information on composition, physical properties, and tensile properties as well as creep. It also includes information on high temperature performance. Filing Code: Ni-548. Producer or source: Duraloy Technologies Inc.


Alloy Digest ◽  
1987 ◽  
Vol 36 (12) ◽  

Abstract UHB QRO 80 MICRODIZED is a chromium-molybdenum-vanadium tool steel with improved performance for tooling used at elevated temperature as in forging, extrusion and die casting. It is electro-slag refined. This datasheet provides information on composition, physical properties, hardness, elasticity, and tensile properties as well as fracture toughness. It also includes information on high temperature performance as well as forming, heat treating, machining, and joining. Filing Code: TS-486. Producer or source: Uddeholm Aktiebolag.


Alloy Digest ◽  
2003 ◽  
Vol 52 (12) ◽  

Abstract Type 309 (UNS S30900) is an austenitic chromium-nickel stainless steel widely used for elevated-temperature services. It has a good combination of oxidation resistance and corrosion-resisting properties. The alloy is essentially nonmagnetic when annealed and become slightly magnetic when cold worked. It is intended primarily for high-temperature applications at 816 deg C (1500 deg F) or higher where resistance to oxidation and/or corrosion is required. This datasheet provides information on composition, physical properties, hardness, and tensile properties as well as creep. It also includes information on corrosion resistance as well as forming, heat treating, and joining. Filing Code: SS-896. Producer or source: J & L Specialty Steel Inc.


Author(s):  
William J. O’Donnell ◽  
Amy B. Hull ◽  
Shah Malik

Since the 1980s, the ASME Code has made numerous improvements in elevated-temperature structural integrity technology. These advances have been incorporated into Section II, Section VIII, Code Cases, and particularly Subsection NH of Section III of the Code, “Components in Elevated Temperature Service.” The current need for designs for very high temperature and for Gen IV systems requires the extension of operating temperatures from about 1400°F (760°C) to about 1742°F (950°C) where creep effects limit structural integrity, safe allowable operating conditions, and design life. Materials that are more creep and corrosive resistant are needed for these higher operating temperatures. Material models are required for cyclic design analyses. Allowable strains, creep fatigue and creep rupture interaction evaluation methods are needed to provide assurance of structural integrity for such very high temperature applications. Current ASME Section III design criteria for lower operating temperature reactors are intended to prevent through-wall cracking and leaking and corresponding criteria are needed for high temperature reactors. Subsection NH of Section III was originally developed to provide structural design criteria and limits for elevated-temperature design of Liquid-Metal Fast Breeder Reactor (LMFBR) systems and some gas-cooled systems. The U.S. Nuclear Regulatory Commission (NRC) and its Advisory Committee for Reactor Safeguards (ACRS) reviewed the design limits and procedures in the process of reviewing the Clinch River Breeder Reactor (CRBR) for a construction permit in the late 1970s and early 1980s, and identified issues that needed resolution. In the years since then, the NRC, DOE and various contractors have evaluated the applicability of the ASME Code and Code Cases to high-temperature reactor designs such as the VHTGRs, and identified issues that need to be resolved to provide a regulatory basis for licensing. The design lifetime of Gen IV Reactors is expected to be 60 years. Additional materials including Alloy 617 and Hastelloy X need to be fully characterized. Environmental degradation effects, especially impure helium and those noted herein, need to be adequately considered. Since cyclic finite element creep analyses will be used to quantify creep rupture, creep fatigue, creep ratcheting and strain accumulations, creep behavior models and constitutive relations are needed for cyclic creep loading. Such strain- and time-hardening models must account for the interaction between the time-independent and time-dependent material response. This paper describes the evolving structural integrity evaluation approach for high temperature reactors. Evaluation methods are discussed, including simplified analysis methods, detailed analyses of localized areas, and validation needs. Regulatory issues including weldment cracking, notch weakening, creep fatigue/creep rupture damage interactions, and materials property representations for cyclic creep behavior are also covered.


2014 ◽  
Vol 33 (3) ◽  
pp. 193-200 ◽  
Author(s):  
Jiteng Wang ◽  
Juan Wang ◽  
Yajiang Li ◽  
Deshuang Zheng

AbstractMolybdenum and molybdenum alloys are considered to be attractive structural materials for high-temperature applications. However, molybdenum alloys are sensitive to gas impurities and have the characteristics of low temperature embrittlement and less resistance to oxidation at elevated temperature. The toughness and strength of welded joint is not easy to be ensured by traditional technology. Recently, many efforts have been made to join molybdenum and its alloys. In this paper, we present the result of investigations on welding methods of molybdenum and its alloys and overview the practical applications in engineering. The key of joining molybdenum alloys is to improve the toughness of welded joint and prevent the generation of pores and cracks.


2006 ◽  
Vol 302-303 ◽  
pp. 138-149 ◽  
Author(s):  
Gai Fei Peng ◽  
Sammy Yin Nin Chan ◽  
Qi Ming Song ◽  
Quan Xin Yi

This paper presents a review on the effect of fire on concrete, citing 43 references. It was found that most of them are on the behavior of concrete under high temperature conditions more or less different from the standard fire condition. The problem of spalling, which high-strength concrete encounters when exposed to fire, is especially urgent to solve. Since the literature on the behavior of concrete under fire conditions is very limited, the literature even under elevated temperature has to be used as a part of the base of further research. The further research needs urgently to be carried out under the standard fire condition. Residual mechanical properties reported in most previous literature might be overestimated, where natural cooling was usually employed. Proper evaluation of fire resistance of concrete needs more experimental data obtained under various cooling regimes such as water spraying or water quenching.


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