Acid-based cement slurry with controllable properties

Author(s):  
Sh.P. Kazimov ◽  
◽  
K.K. Mehdiyev ◽  

Intensive occurrence of sand related problems in wells diminishes oil flow rate and leads to heavy expenses on production and equipment maintenance. Hard geological factors on field bedding, heterogeneity of reservoir porosity and permeability, strict constraints on physicochemical property of oil and produced water restrict the efficient application of several available methods and technologies for sand control. The increasing densification of sand related problems at late stages of development gives rise to implementation of different type of workover. There exist several backfilling compositions with a number of draw-backs to control sand influx from the reservoir into the well. With the purpose to work out more effective technology to ensure the consolidation of reservoir there was developed a new grouting mortar. This slurry contains cement, hydrated aluminum silicate and 7-8% hydrochloric acid solution. Barrier of grouting mortar has high resistance and adhesive characteristics and penetrates much deeper into pores increasing consolidation efficiency.

2021 ◽  
Author(s):  
Hongtao Liu ◽  
Zhengqing Ai ◽  
Jingcheng Zhang ◽  
Zhongtao Yuan ◽  
Jianguo Zeng ◽  
...  

Abstract The average porosity and permeability in the developed clastic rock reservoir in Tarim oilfield in China is 22.16% and 689.85×10-3 μm2. The isolation layer thickness between water layer and oil layer is less than 2 meters. The pressure of oil layer is 0.99 g/cm3, and the pressure of bottom water layer is 1.22 g/cm3, the pressure difference between them is as bigger as 12 to 23 MPa. It is difficult to achieve the layer isolation between the water layer and oil layer. To solve the zonal isolation difficulty and reduce permeable loss risk in clastic reservoir with high porosity and permeability, matrix anti-invasion additive, self-innovate plugging ability material of slurry, self-healing slurry, open-hole packer outside the casing, design and control technology of cement slurry performance, optimizing casing centralizer location technology and displacement with high pump rate has been developed and successfully applied. The results show that: First, the additive with physical and chemical crosslinking structure matrix anti-invasion is developed. The additive has the characteristics of anti-dilution, low thixotropy, low water loss and short transition, and can seal the water layer quickly. Second, the plugging material in the slurry has a better plugging performance and could reduce the permeability of artificial core by 70-80% in the testing evaluation. Third, the self-healing cement slurry system can quickly seal the fracture and prevent the fluid from flowing, and can ensuring the long-term effective sealing of the reservoir. Fourth, By strict control of the thickening time (operation time) and consistency (20-25 Bc), the cement slurry can realize zonal isolation quickly, which has achieved the purpose of quickly sealing off the water layer and reduced the risk of permeable loss. And the casing centralizers are used to ensure that the standoff ratio of oil and water layer is above 67%. The displacement with high pump rate (2 m3/min, to ensure the annular return velocity more than 1.2 m/s) can efficiently clean the wellbore by diluting the drilling fluid and washing the mud cake, and can improve the displacement efficiency. The cementing technology has been successfully applied in 100 wells in Tarim Oilfield. The qualification rate and high quality rate is 87.9% and 69% in 2019, and achieve zone isolation. No water has been produced after the oil testing and the water content has decreased to 7% after production. With the cementing technology, we have improved zonal isolation, increased the crude oil production and increased the benefit of oil.


2019 ◽  
Vol 2019 ◽  
pp. 1-11
Author(s):  
Zhihan Tian ◽  
Yiqun Gan

A three-dimensional hierarchically structured flowerlike zeolite was synthesized using naturally occurring nanohalloysite (HNT) by hydrothermal methods. Halloysite a hydrated aluminum silicate with nanohollow morphology, microporosity, and environmentally friendly properties was chosen to be the sole precursor. The morphology and structure of the composite that was prepared was characterized using XRD, FT-IR, BET, TG, SEM, HRTEM, and NMR. SEM and HRTEM images indicated that the synthesized zeolite has a flowerlike hierarchical structure, with well-defined edges and uniform pore channels. FT-IR and NMR spectra indicated that different species of silicon and aluminum were present in the synthesized zeolite. The zeolite was applied in fluoride (F-) removal from aqueous solutions. Single-factor studies, including the initial concentration of F-, initial adsorbent concentration, and the effect of pH value on the adsorption properties, were investigated to evaluate the removal behavior of F- by the zeolite. The zeolite exhibited strong adsorption properties for fluoride ions (F-), with an adsorption capacity up to 161 mg g-1. The pseudo-second-order kinetics and Freundlich models were the best fit to the kinetics and isotherm experimental data, respectively.


2013 ◽  
Vol 544 ◽  
pp. 152-155
Author(s):  
Cheng Chen ◽  
Hao Wu ◽  
Qiang Li

Montmorillonite (MMT) mainly consist of hydrated aluminum silicate. Montmorillonite has particular properties and many practical applications, because of their special crystal structure. Here, mechano-chemical method was used to prepare MMT nanosheets by controlling the pH value. MMT nanosheets were obtained by ballmilling, and the impact of pH value on the nanosheets preparing was studied. TEM was employed to emamine the microstructure of MMT nanosheets. The size are analyzed to study the status of MMT nanosheets. Different rare earth ions as a fluorescence center were assembled on nanosheets,and composites were obtained. The luminescent properties of composite materials were studied.


2019 ◽  
Vol 11 (23) ◽  
pp. 6776 ◽  
Author(s):  
Abdulmalek Ahmed ◽  
Ahmed Abdulhamid Mahmoud ◽  
Salaheldin Elkatatny ◽  
Weiqing Chen

In deep hydrocarbon development wells, cement slurry with high density is required to effectively balance the high-pressure formations. The increase in the slurry density could be achieved by adding different heavy materials. In this study, the effect of the weighting materials (barite, hematite, and ilmenite) on the properties of Saudi Class G cement matrix of vertical homogeneity, compressive strength, porosity, and permeability was evaluated. Three cement slurries were weighted with barite, hematite, and ilmenite, and cured at 294 °F and 3000 psi for 24 h. All slurries have the same concentration of the different additives except the weighting material. The amount of weighting material used in every slurry was determined based on the targeted density of 18 lbm/gal. The results of this study revealed that the most vertically homogenous cement matrix was the ilmenite-weighted sample with a vertical variation of 17.6% compared to 20.2 and 24.8% for hematite- and barite-weighted cement, respectively. This is attributed to the small particle size of the ilmenite. The medical computerized tomography (CT) scan confirmed that the ilmenite-weighted sample is the most homogeneous, with a narrow range of density variation vertically along the sample. Hematite-weighted cement showed the highest compressive strength of 55.3 MPa, and the barite- and ilmenite-weighted cement compressive strengths are each 18.4 and 36.7% less than the compressive strength of the hematite-weighted cement, respectively. Barite-weighted cement has the lowest porosity and permeability of 6.1% and 18.9 mD, respectively. The maximum particle size of ilmenite used in this study is less than 42 μm to ensure no abrasion effect on the drilling system, and it minimized the solids segregation while maintaining a compressive strength that is higher than the minimum acceptable strength, which is the recommended weighting material for Saudi Class G cement.


2007 ◽  
Vol 65 (4a) ◽  
pp. 974-977 ◽  
Author(s):  
Daniela Pretti da Cunha Tirapelli ◽  
Luiza da Silva Lopes ◽  
João José Lachat ◽  
Benedicto Oscar Colli ◽  
Luís Fernando Tirapelli

Hydrocephalus is one of the most frequent and complex neurological diseases characterized by the abnormal buildup of cerebrospinal fluid (CSF) in the ventricles of the brain, due to an altered CSF dynamics. To detect possible ultrastructural alterations of the lateral ventricles choroid plexus (responsible for the CSF production), rats seven days after birth were submitted to an intracisternal injection of 20% kaolim (hydrated aluminum silicate) for the hydrocephalus induction. Twenty-eight or 35 days after injection, injected animals and respective controls were processed for observation under a transmission electron microscopy. Alterations found: presence of concentric cell membrane fragments, larger number of primary and secondary lysossomes, vacuoles, and cytoplasmic vesicles, and an enlargement of the intercellular space and between the basolateral interdigitation of the choroid epithelium. The alterations observed are probably associated to an increase of the ventricular pressure, inducing morpho-functional effects on the choroid plexus integrity.


2021 ◽  
pp. 60-74
Author(s):  
G. A. Smolyakov ◽  
N. V. Gilmanova ◽  
A. V. Sivkova

The article deals with the determination of the reservoir properties of Permian-age carbonate rocks. There is a section dissection technique, taking into account the fossil organisms prevailing for a particular geological age. It was noted a high content of silica in the lower Artinskian deposits of Toravey and Varandey fields of the Komi Republic. The presence of silicon is associated with an increase in the population of siliceous sponges during this period of sedimentation; this fact caused the maximum values of porosity and permeability in the corresponding intervals. However, this was also the reason for the high values of the residual water saturation factor and, as a result, low oil flow rates from the lower Artinskian stage. The need for detailed correlation and accounting for the content of fossils in the rocks when dissecting the well section made it necessary to systematize the available actual material on core and well testing. It became obvious that the separation of reservoirs and stages at the qualitative level isn't possible, so quantitative estimates of the parameters that are significantly different for the upper and lower Artinskian deposits and allow you to dissect the well section were proposed.


2021 ◽  
Vol 91 (11) ◽  
pp. 1113-1132
Author(s):  
Katie Smye ◽  
D. Amy Banerji ◽  
Ray Eastwood ◽  
Guin McDaid ◽  
Peter Hennings

ABSTRACT Deepwater siliciclastic deposits of the Delaware Mountain Group (DMG) in the Delaware Basin (DB) are the primary interval for disposal of hydraulic fracturing flowback and produced water from unconventional oil production. Understanding the storage capacity of the DMG is critical in mitigating potential risks such as induced seismicity, water encroachment on production, and drilling hazards, particularly with likely development scenarios and expected volumes of produced water. Here we present a basin-wide geologic characterization of the DMG of the Delaware Basin. The stratigraphic architecture, lithology, and fluid-flow properties including porosity, permeability, amalgamation ratios, and pore volumes, are interpreted and mapped. Lithologies are predicted using gamma-ray and resistivity log responses calibrated to basinal DMG cores and outcrop models. Sandstones exhibit the highest porosity and permeability, and sand depocenters migrate clockwise and prograde basinward throughout Guadalupian time. Permeability is highest at the top of the Cherry and Bell Canyon formations of the DMG, reaching tens to hundreds of millidarcies in porous sandstones. Porous and permeable sandstones are fully amalgamated at the bed scale, but at the channel scale, most sandstones are separated by low-permeability siltstones or carbonates where net sandstone is less than 30%. This geologic characterization can be used to assess the regional storage capacity of the DMG and as input for dynamic fluid-flow models to address pore-pressure evolution, zonal containment, and induced seismicity.


Author(s):  
Jie Wang ◽  
Fujian Zhou ◽  
Lufeng Zhang ◽  
Fan Fan ◽  
Hong Yang

Water logging problem in late production reservoir with abundant edge-bottom water and water-gas layer stagger is one of the main factors that lead to production wells stop flow. For the water plugging problem during gas well production, the common operation is coiled tubing through casing. So, coiled tubing technology without moving production string is explored. X oilfield is located in Sichuan basin of China southwest and belongs to the origin of gas pipeline from Sichuan to China east. Its main gas producing area is carbonatite full of edge water and controlled by structural and lithology. The relationship between water and gas is complex and water-gas system is independent of different blocks and different layers. Because the main gas producing layer is close to the water layer, lots of gas producing wells stop spray for high water cut. At the meantime, the difficulty and risk of water plugging increases for its high depth of main gas producing layer and high temperature at the well bottom. To solve the problem above, cement slurry system with the characteristics of high temperature and sulfur resistant and channeling preventing is developed. At the same time, the cement slurry system has low friction and high liquidity and is easy to flow through the coiled tubing. Besides, cement slurry pollution is reduced and the success rate of gas well produced water plugging is improved by the combination of coiled tubing and cementing process and the construction technology optimization, software simulation and laboratory evaluation is carried out. The key step is that log analysis of water and gas distribution is done first. Then, tubing-expansion bridge plug is placed under the water layer and the cement slurry is sent to the desired location. At last, coiled tubing is put down after cement solidification and gas production is recovered. The measurement of coiled tubing and cement slurry system is positive for water plugging in gas wells with high depth and temperature. The oilfield test results show that daily gas production is improved largely and liquid production is reduced by 90% of 4 wells with high water cut through water plugging. Besides, operation cost is reduced and the pollution problem caused by produced water is also solved, which can provide certain significance for the same type wells need water plugging operation.


2001 ◽  
Vol 4 (05) ◽  
pp. 366-374 ◽  
Author(s):  
Yarlong Wang ◽  
Carl C. Chen

Summary A coupled reservoir-geomechanics model is developed to simulate the enhanced production phenomena in both heavy-oil reservoirs (northwestern Canada) and conventional oil reservoirs (i.e., North Sea). The model is developed and implemented numerically by fully coupling an extended geomechanics model to a two-phase reservoir flow model. Both the enhanced production and the ranges of the enhanced zone are calculated, and the effects of solid production on oil recovery are analyzed. Field data for solid production and enhanced oil production, collected from about 40 wells in the Frog Lake area (Lloydminster, Canada), are used to validate the model for the cumulative sand and oil production. Our studies indicate that the enhanced oil production is mainly contributed (1) by the reservoir porosity and permeability improvement after a large amount of sand is produced, (2) by higher mobility of the fluid caused by the movement of the sand particles, and (3) by foamy oil flow. A relative permeability reduction after a certain period of production may result in a pressure-gradient increase, which can promote further sand flow. This process can further improve the absolute permeability and the overall sand/fluid slurry production. Our numerical results simulate the fact that sand production can reach up to 40% of total fluid production at the early production period and decline to a minimum level after the peak, generating a high-mobility zone with a negative skin near the wellbore. Such an improvement reduces the near-well pressure gradient so that the sanding potential is weakened, and it permits an easier path for the viscous oil to flow into the well. Our studies also suggest that the residual formation cement is a key factor for controlling the cumulative sand production, a crucial factor that determines the success of a cold production operation and improved well completion. Introduction Field results from many heavy-oil reservoirs in northwestern Canada, such as Lindbergh and Frog Lake in the Lloydminster fields, suggest that primary recovery is governed mainly by the processes of sand production and foamy-oil flow.1–3 To manage production in such reservoirs, the challenge we face is optimizing production so that sand production is under control. For decades, industries have developed various highly effective tools for sand control. In practice, however, sand control often results in reduced oil flow or no production at all, particularly in heavy-oil reservoirs. For example, it has been observed that an average oil production of only 0.0 to 1.5 m3/d can be achieved in a well in which no sand production is allowed, while 7 to 15 m3/d oil may be produced with sand production.4 A significant improvement in production also has been reported by allowing a certain amount of sand produced before gravel packing in the high-rate production well in conventional reservoirs.5 It seems that sanding corresponds to a high oil production in these reservoirs, as sand production either increases the reservoir mobility or allows the development of highly permeable zones such as channels (wormholes).1 Encouraging sand production to enhance oil production, on the other hand, increases oil production costs owing to environmental problems. Consequently, neither trying to eliminate the sand production completely nor letting sand be produced freely, we attempt to develop a quantified model linking sand rate and reservoir enhancement so that we can forecast the economic outcome of such an operation. The investigation of sand production has been extensive, but it has been limited primarily to the areas of incipience of sand production and control. Sand arching and production initiation from a cavity simulating a perforating tunnel were studied, and a critical flow rate before sanding was found for single-phase steady-state flow.6 Such a study was extended to gas reservoirs, in which the gas density is a function of pressure,7 and to those formations subject to nonhydrostatic loading.8,9 Studying the enhanced production and the cumulative sand production, a series of simplified models for massive sand production have been developed.10,11 Similar models based on a coupled classic geomechanics model were also proposed thereafter.12,13 Because these aforementioned sand-production models are somewhat restricted by the fact that they are simplified by analytical methods, and in reality reservoir formations are much more complex (i.e. nonlinear behaviors), a numerical model coupling a multiphase transient fluid flow to elastoplastic geomechanical deformation is thus developed in this article; its purpose is to simulate these major nonlinear effects. According to the proposed model, a corresponding plastic yielding zone (or a disturbed zone) propagates into reservoir formation because of the transient fluid pressure diffusion, and the corresponding effective stresses change near a wellbore. A possible absolute permeability change inside the yielding zone is also considered, as dilatant deformation developed may enhance the permeability in the plastic zone. As a primary unknown, saturation is assumed to change with the induced pore-pressure change. The relative permeability is updated by the saturation, which in turn changes the response of the pore pressure and the skeleton deformation. A continuum mechanics approach is used in our calculation. Rather than characterizing each random wormhole proposed,1,4,5 we impose a homogeneous medium with an average permeability to make the numerical solutions manageable. The wormholes or geomechanical dilatation zone can be represented by a higher-permeability region in the plastic yielding zone owing to porosity enhancement,1 and solid flow is considered as a continuous moving phase along the transient fluid flow. Alternatively, a sand erosion model was introduced, and the geomechanics coupling to a single-phase flow was presented previously.14,15


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