The improvement of physical and mechanical properties of sealers based on nitrile-butadiene rubber and combination of nano-metal oxides

2020 ◽  
pp. 174-182
Author(s):  
R.F. Khankishiyeva ◽  
◽  
H.N. Akhundzada ◽  
Keyword(s):  
Mechanical Properties ◽  
Metal Oxides ◽  
Chemical Interaction ◽  
Physical And Mechanical Properties ◽  
Mechanical Tests ◽  
Butadiene Rubber ◽  
Nanosized Powders ◽  
Nitrile Butadiene Rubber ◽  
Crosslinking Process ◽  
First Time

The chemical interaction of disulphochloride aromatic compounds with nitrile butadiene rubber (NBR) in the presence of combined nanosized powders of metal oxides (ZnO and Al2O3) was studied for the first time. Vulcanization of the prepared blends has been induced with two methods: by irradiation of gamma rays (D=300 kGy) and by pre-heating in the hydraulicpress and then subsequent irradiation (150 oC x 5', 300 kGy). In order to activate the crosslinking process, a combination of nano-oxides ZnO and Al2O3 were used. The surface of the nanocomposite was studied by using scanning electron microscopy. The mechanical properties of modified blends were studied and then compared with controlling sample (vulcanized with sulphur) and analyzed by the mechanical tests in aggressive environments after thermal aging. The study found that the use of 1,3-disulphochloride benzene with nano oxides produces cured materials with good resistance to aging and provides high service properties in air, seawater, and oil-bearing solution.

Environmental Factors on Aging of Nitrile Butadiene Rubber (NBR) - A Review

2014 ◽  
Vol 1033-1034 ◽  
pp. 987-990 ◽  
Author(s):  
Qing Yun Tang ◽  
Wei Fang Zhang
Keyword(s):  
Mechanical Properties ◽  
Aging Process ◽  
Physical And Mechanical Properties ◽  
External Factors ◽  
Future Research ◽  
Butadiene Rubber ◽  
Liquid Environment ◽  
Oxidative Aging ◽  
Nitrile Butadiene Rubber ◽  
Micro Analysis

Nitrile butadiene rubber (NBR) comes into widespread applications due to the excellent performances, but it is susceptible to aging during its storage and usage periods. This paper surveys the external factors that act on the aging process of NBR. The aging of NBR in liquid environment, and non-liquid environment such as thermo-oxidative aging, ozone aging, stress aging and radiation aging, are considered. The emphasis of present works is test of physical and mechanical properties of NBR, and the micro analysis should gain special attention. One direction of future research on NBR aging is the coupling effects of various factors included in this paper.

scholarly journals Enhanced Physical and Mechanical Properties of Nitrile-Butadiene Rubber Composites with N-Cetylpyridinium Bromide-Carbon Black

Molecules ◽  
2021 ◽  
Vol 26 (4) ◽  
pp. 805
Author(s):  
Egor A. Kapitonov ◽  
Natalia N. Petrova ◽  
Vasilii V. Mukhin ◽  
Leonid A. Nikiforov ◽  
Vladimir D. Gogolev ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Carbon Black ◽  
Physical And Mechanical Properties ◽  
Butadiene Rubber ◽  
Volumetric Wear ◽  
Shore Hardness ◽  
Cetylpyridinium Bromide ◽  
Rubber Composites ◽  
Nitrile Butadiene Rubber

The physical and mechanical properties of nitrile–butadiene rubber (NBR) composites with N-cetylpyridinium bromide-carbon black (CPB-CB) were investigated. Addition of 5 parts per hundred rubber (phr) of CPB-CB into NBR improved the tensile strength by 124%, vulcanization rate by 41%, shore hardness by 15%, and decreased the volumetric wear by 7% compared to those of the base rubber-CB composite.

Investigating hollow corundum microspheres exfoliation of the elastomeric matrix

2019 ◽  
pp. 135-142
Author(s):  
N. V. Shadrinov ◽  
U. V. Evseeva
Keyword(s):  
Mechanical Properties ◽  
Atomic Force Microscope ◽  
Butadiene Rubber ◽  
Nitrile Butadiene Rubber ◽  
Elastomeric Matrix ◽  
Atomic Force

The results of study of the influence of hollow corundum microspheres HCM-S (5–100 µm) and HCM-L (70–180 µm) on the properties of nitrile butadiene rubber BNKS-18 are presented. The dependence of elastomer resistance to abrasion impact and physic and mechanical properties on the dispersion and concentration of hollow corundum microspheres is shown. The process of hollow corundum microspheres exfoliation of the elastomeric matrix, which largely determines the change of physic and mechanical properties, has been studied by specially developed stretching device compatible with an atomic force microscope. The paper describes microspheres exfoliation which is conventionally divided into 3 stages.

Novel modification of styrene butadiene rubber/acrylic rubber blends to improve mechanical, dynamic mechanical, and swelling behavior for oil sealing applications

2021 ◽  
pp. 096739112110313
Author(s):  
Ahmed Abdel-Hakim ◽  
Soma A el-Mogy ◽  
Ahmed I Abou-Kandil
Keyword(s):  
Mechanical Properties ◽  
Crosslink Density ◽  
Physical And Mechanical Properties ◽  
Dynamic Mechanical Properties ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Rubber Blends ◽  
Dynamic Mechanical ◽  
Oil Resistance ◽  
Styrene Butadiene

Blending of rubber is an important route to modify properties of individual elastomeric components in order to obtain optimum chemical, physical, and mechanical properties. In this study, a novel modification of styrene butadiene rubber (SBR) is made by employing acrylic rubber (ACM) to obtain blends of outstanding mechanical, dynamic, and oil resistance properties. In order to achieve those properties, we used a unique vulcanizing system that improves the crosslink density between both polymers and enhances the dynamic mechanical properties as well as its resistance to both motor and break oils. Static mechanical measurements, tensile strength, elongation at break, and hardness are improved together with dynamic mechanical properties investigated using dynamic mechanical analyses. We also proposed a mechanism for the improvement of crosslink density and consequently oil resistance properties. This opens new opportunities for using SBR/ACM blends in oil sealing applications that requires rigorous mechanical and dynamic mechanical properties.

scholarly journals ADSORPTION OF NANOWOLLASTONITE ON CELLULOSE SURFACE: EFFECTS ON PHYSICAL AND MECHANICAL PROPERTIES OF MEDIUM-DENSITY FIBERBOARD (MDF)

CERNE ◽  
2016 ◽  
Vol 22 (2) ◽  
pp. 215-222 ◽  
Author(s):  
Hamid Reza Taghiyari ◽  
Roya Majidi ◽  
Asghar Jahangiri
Keyword(s):  
Mechanical Properties ◽  
Density Functional ◽  
Medium Density Fiberboard ◽  
Physical And Mechanical Properties ◽  
Mechanical Tests ◽  
National Standard ◽  
Medium Density ◽  
Wood Fibers ◽  
Strong Adsorption ◽  
Cellulose Surface

ABSTRACT Effects of nanowollastonite (NW) adsorption on cellulose surface were studied on physical and mechanical properties of medium-density fiberboard (MDF) panels; properties were then compared with those of MDF panels without NW-content. The size range of NW was 30-110 nm. The interaction between NW and cellulose was investigated using density functional theory (DFT). Physical and mechanical tests were carried out in accordance with the Iranian National Standard ISIRI 9044 PB Type P2 (compatible with ASTM D1037-99) specifications. Results of DFT simulations showed strong adsorption of NW on cellulose surface. Moreover, mechanical properties demonstrated significant improvement. The improvement was attributed to the strong adsorption of NW on cellulose surface predicted by DFT, adding to the strength and integrity between wood fibers in NW-MDF panels. It was concluded that NW would improve mechanical properties in MDF panels as a wood-composite material, as well as being effective in improving its biological and thermal conductivity.

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