scholarly journals Sediment Quality Assesment by Using Geochemical Index at Saguling Reservoir West Java Province Indonesia

2018 ◽  
Vol 8 (2) ◽  
pp. 34
Author(s):  
Eka Wardhani ◽  
Suprihanto Notodarmojo ◽  
Dwina Roosmini

Heavy metal pollution is one of the problems that continue to occur in Indonesia which is very important because it is non-degradable, persistent, and can accumulate in the bodies of living things. Heavy metal in the water is usually present in low concentrations but human activity shall increase. Saguling Reservoir is one of the largest manmade lake in West Java Province which has experienced water contamination. The purpose of this study is to assess the quality of sediments related to the pollution of four heavy metals ie Cd, Cr, Cu, and Pb contained in Saguling Reservoir sediment using CF, MPI, Igeo and PERI methods in the rainy and dry seasons.Sediment samples are taken in twelve points around the reservoir by 2015-2017. Based on the results of this study it can be concluded that the sediment quality of Saguling Reservoir has been contaminated by heavy metals Cd, Cr, Cu, and Pb. This is caused by human activity in the water catchment area of the reservoir. Based on the results of the analysis of sediment quality using Igeo and CF the sediment of Saguling Reservoir has been polluted by heavy metals, specifically Cd in the rainy and dry seasons. The result of assessment of sediment quality by MPI method can be concluded that the sediment of Saguling Reservoir as a whole has been contaminated by Cd, Cr, Cu, and Pb. Based on calculations using PERI method, the sediment quality of Saguling Reservoir has contaminated Cd with serious ecological risk category during rainy and dry season, contaminated with Cr and Pb with low grade ecologogical risk category during rainy and dry season, has been contaminated with Cu with low grade ecological risk in the rainy season and moderate ecological risk in the dry season. Based on the results of this study that the Cd must be cautioned carefully, because of the highest concentration in the rainy and dry season than three other heavy metals.

2011 ◽  
Vol 137 ◽  
pp. 262-268 ◽  
Author(s):  
Guo Tao Liu ◽  
Xiao Yan Zheng ◽  
Xu Ya Peng ◽  
Jian Hua Li

The concentrations of heavy metals (Cu, Zn, Pb, Cd, Ni, Cr, As) in the surface sediment of Liangtan River were determined by using atomic absorption spectrometry (AAS) and atomic fluorescence spectrometry (AFS), and the toxic effects and sediment pollution assessment were conducted systematically by using Sediment Quality Guidelines (SQG), Hakanson Potential Ecological Risk Index. Moreover, the underlying source of heavy metal was analyzed. The results indicated that the concentrations of Cu, Zn, Pb, Cd, Ni, Cr, As were 29.4-158.1, 40.2-291.3, 23.4-148.2, 0.01-0.79, 6.4-106.2, 17.9-170.6, 1.3-45.1mg/kg respectively. Base on the SQG, besides Cd concentrations of few sampling sites were above the threshold effects level (TEL), the rest heavy metal concentrations of most sampling sites were all between TEL and the probable effects level (PEL), and biological toxicity effects may take place, especially Baishiyi, Hangu and Huilongba, harmful biological toxicity effects may frequently take place. Compared to background values of soil heavy metals in the Three Gorges Reservoir Region, the heavy metals in Liangtan River sediments showed higher ecological risk, and the ecological risk of the heavy metals, arranged from the highest to lowest pollution degree, was as follows Cd, As, Cu, Pb, Ni, Zn, Cr.


2020 ◽  
Vol 20 (2) ◽  
pp. 77-85
Author(s):  
S. A. Ndur ◽  
S. Y. Nyarko ◽  
I. Quaicoe ◽  
L. B. Osei

Sediment contamination by heavy metals resulting from anthropogenic activities is increasingly becoming a global concern due to the risk it poses to human well-being and ecological integrity at large. The purpose of this study was to assess the heavy metals loading in sediment along the Kawere stream. Ten sediment samples were collected, acid digested and analysed for copper (Cu), lead (Pb), cadmium (Cd), manganese (Mn), zinc (Zn), nickel (Ni), chromium (Cr), cobalt (Co) and iron (Fe) using a Varian AA240FS Atomic Absorption Spectrometer (AAS). The Australian and New Zealand Environment and Conservation Council (ANZECC) guidelines for freshwater sediment quality was used as the benchmark against which the measured metal concentrations were compared. Nemerow’s pollution and potential ecological risk indices were used to evaluate the pollution status and ecological risk levels of the heavy metals in the stream. The results obtained indicated that, except Cu which exceeded the ANZECC trigger value of 65 mg/kg at three sampling sites (K01=171.29 mg/kg, K05=170.83 mg/kg and K07=113.31 mg/kg), all other measured heavy metals concentrations were below their corresponding ANZECC values. Heavy metal pollution assessment showed that three samples (K01, K05 and K07) were slightly polluted, suggesting the likelihood of posing a health threat to the aquatic organisms and humans. Calculated Ecological Risk Index (RI) ranged from 3.229 to 19.750 (RI < 150), representing a low ecological risk. As such, the metals, Cu, Ni, Cd, Pb, Cr, and Zn pose a low ecological risk to the aquatic ecosystem. Although the ecological risk is low based on the current results, constant monitoring of the stream quality is recommended due to the increasing human activities along the stream as well as the sediments ability to accumulate and remobilise heavy metals back into the water column and possibly transferring them through the food chain.   Keywords: Heavy Metals, Sediment, Ecological Risk Assessment, Pollution, Stream


Author(s):  
Addy Jose Vershima ◽  
Kabough Jonathan Terkimbi ◽  
Azua Terese ◽  
Aliyu Ibrahim

Water samples of six sampling sites (two downstream, two abattoir sites and two upstream sites) were analyzed using standard methods to determined and assessed heavy metal content of abattoir effluent on surface water quality of River Katsina-Ala, Benue State, Nigeria for rainy and dry seasons. Rainy season heavy metals results were; Cr6+ (0.032+0.06mg/l); Mn2+ (0.16+0.034mg/l); Cu2+ (0.86 +0.46mg/l); Pb2+(0.006+0.002mg/;Cd2+(0.0023+0.004mg/l) and the dry season results were: Cr6+(0.028+0.007mg/l); Mn2+(0.07+0.05mg/l); Cu2+(0.85+0.16mg/l); Pb2+(0.0030+0.014mg/l); Cd2+(0.0021+0.012mg/). Most heavy metals for both seasons were within the maximum permissible limit set by Federal Ministry of Environment, Nigeria (1991). The mean concentrations of Zn2+(1.70+0.29 mg/l) for rainy season and Zn2+(1.33+0.23mg/l) dry season were above the control and standard safe limits of < 1mg/l FMEnv (1991) for surface water quality. There was no significance difference (p<0.05) between the means from upstream and downstream sites for both seasons; though significance difference (p<0.05) existed at the abattoir sites. River Katsina –ala is slightly polluted. Heavy metal content from effluents from abattoir contributed to upset the physicochemical balance of the river. Bioaccumulation and bio-magnification of heavy metals may occur from prolong usage of the river water for drinking. It is suggested that the abattoir effluent be treated before discharge into the river to reduce environmental and health hazards.


2020 ◽  
Author(s):  
Dnyaneshwar Shinde ◽  
Dnyanesh M. Mahajan ◽  
Sanjay D. Chakane

Abstract The study was conducted to investigate heavy metal contents namely, Iron (Fe), Copper (Cu), Zinc (Zn), and Manganese (Mn) from surface sediment and water samples collected from the Ujjani Reservoir. The concentrations (mg kg− 1) of Fe, Cu, Zn and Mn in sediment detected were 4455.0, 184.05, 97.4, 1090.5 respectively, while in water metal contents (mg l− 1) Fe, Cu, Zn, and Mn were 3.05, 0.5, 0.82, and 2.56 correspondingly. The contents of metals in the studied samples showed a descending order such as Fe, Mn, Zn and Cu. It was observed that the mean concentrations of Fe, Cu, and Mn were more in sediment and water, whereas, Zn contents were detected lesser than the standard levels proposed by USEPA 2004. The sediment pollution analysis was achieved using a Pollution load index (PLI), Geoaccumulation index (Igeo) and Potential ecological risk index (RI). Similarly, risk of metals in water was evaluated using Average absorption dose (ADD), Hazardous quotient (HQ), and Hazardous index (HI). In our study, the ADD, HQ and HI values for metals were lower than 1, indicating that there is no health risk associated with studied heavy metals present in surface water. Also sediment quality assessment shows that there is minor ecological risk of studied heavy metals. Even though, the Ujjani Reservoir has a lower ecological risk, its water and sediment quality is declining day by day. Therefore, there is a need to make a policy for ecological restoration to avoid further damage to the ecosystem and human beings.


2020 ◽  
Vol 29 (3) ◽  
pp. 289-297
Author(s):  
Eva Singovszka ◽  
Magdalena Balintova

Quality is one of the most important risk indicators in river basins. Therefore, monitoring and evaluating water and sediment quality has a very important role in process of risk management. The aim of the monitoring is provide for the sustainability of water bodies and these results are the basis for the risk management in the river catchment area. Hornad, Laborec and Poprad are the rivers in Eastern Slovakia. Hornad and Laborec belongs to basin of Danube and Poprad belongs to basin of Vistula. Sediment sampling was carried out according to ISO 5667-6. Monitoring was carried out in the spring on 2017–2018. The chemical composition of sediments was determined by means of X-ray fluorescence (XRF) using SPECTRO iQ II (Ametek, Germany, 2000). The results of sediment quality evaluated by method PERI revealed that the quality of sediment in 2018 was better than 2017. Results of XRF analysis of sediments were compared with the limited values according to the Slovak Act 188/2003 Coll. of Laws on the application of treated sludge and bottom sediments to fields. It can be state that limit values comparing with Slovak legislation were not exceeding in all sediment samples in rivers in Eastern Slovakia. Based on the monitoring data of sediment quality in the study area, a quantitative analysis of heavy-metal pollution in sediment was conducted using the method of potential ecological risk index (PERI) which is method for evaluate the potential ecological risk of heavy metals. It is based exclusively on chemical parameters of sediments because sediment data show mean integrated values in time, with higher stability than water column parameters; sediments are easily sampled at field work; sediment samples are more representative for time and space scales and analytical data are easily obtained, especially because sediments present high concentrations of contaminants, decreasing the possible errors due to detection limits of the applied analytical method. This method comprehensively considers the synergy, toxic level, concentration of the heavy metals and ecological sensitivity of heavy metals. Potential ecological risk index can be obtained using three basic modules: degree of contamination (CD), toxic-response factor (TR) and potential ecological risk factor (ER). The results show on the basis on potential ecological risk index that the quality of sediment in 2018 is better than 2017. The worst result shows Hornad in 2017. Significant improvement occurred at the sampling point S2 in Hornad in 2018. The best results show Laborec in 2018. The results show on the basis on potential ecological risk index that quality of sediment in 2018 is better than 2017.


Author(s):  
Sangeetha Annam ◽  
Anshu Singla

Abstract: Soil is a major and important natural resource, which not only supports human life but also furnish commodities for ecological and economic growth. Ecological risk has posed a serious threat to the ecosystem by the degradation of soil. The high-stress level of heavy metals like chromium, copper, cadmium, etc. produce ecological risks which include: decrease in the fertility of the soil; reduction in crop yield & degradation of metabolism of living beings, and hence ecological health. The ecological risk associated, demands the assessment of heavy metal stress levels in soils. As the rate of stress level of heavy metals is exponentially increasing in recent times, it is apparent to assess or predict heavy metal contamination in soil. The assessment will help the concerned authorities to take corrective as well as preventive measures to enhance the ecological and hence economic growth. This study reviews the efficient assessment models to predict soil heavy metal contamination.


Minerals ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 486
Author(s):  
Alcina Johnson Sudagar ◽  
Slávka Andrejkovičová ◽  
Fernando Rocha ◽  
Carla Patinha ◽  
Maria R. Soares ◽  
...  

Metakaolins (MKs) prepared from low-grade kaolins located in the Alvarães (A) and Barqueiros (B) regions of Portugal were used as the aluminosilicate source to compare their effect on the compressive strength and heavy metal adsorption of geopolymers. Natural zeolite, an inexpensive, efficient adsorbent, was used as an additive in formulations to enhance geopolymers’ adsorption capacities and reduce MK utilization’s environmental footprint. Geopolymers were synthesized with the replacement of MK by zeolite up to 75 wt.% (A25, B25—25% MK 75% zeolite; A50, B50—50% MK 50% zeolite; A75, B75—75% MK 25% zeolite; A100, B100—100% MK). The molar ratios of SiO2/Al2O3 and Na2O/Al2O3 were kept at 1 to reduce the sodium silicate and sodium hydroxide environmental impact. Geopolymers’ crystallography was identified using X-ray diffraction analysis. The surface morphology was observed by scanning electron microscopy to understand the effect of zeolite incorporation. Chemical analysis using X-ray fluorescence spectroscopy and energy dispersive X-ray spectroscopy yielded information about the geopolymers’ Si/Al ratio. Compressive strength values of geopolymers obtained after 1, 14, and 28 days of curing indicate high strengths of geopolymers with 100% MK (A100—15.4 MPa; B100—32.46 MPa). Therefore, zeolite did not aid in the improvement of the compressive strength of both MK-based geopolymers. The heavy metal (Cd2+, Cr3+, Cu2+, Pb2+, and Zn2+) adsorption tests exhibit relatively higher adsorption capacities of Barqueiros MK-based geopolymers for all the heavy metals except Cd2+. Moreover, zeolite positively influenced divalent cations’ adsorption on the geopolymers produced from Barqueiros MK as B75 exhibits the highest adsorption capacities, but such an influence is not observed for Alvarães MK-based geopolymers. The general trend of adsorption of the heavy metals of both MK-based geopolymers is Pb2+ > Cd2+ > Cu2+ > Zn2+ > Cr3+ when fitted by the Langmuir isotherm adsorption model. The MK and zeolite characteristics influence geopolymers’ structure, strength, and adsorption capacities.


2021 ◽  
Vol 33 (1) ◽  
Author(s):  
Dongping Liu ◽  
Jian Wang ◽  
Huibin Yu ◽  
Hongjie Gao ◽  
Weining Xu

Abstract Background Heavy metal pollution of aquatic systems is a global issue that has received considerable attention. Canonical correlation analysis (CCA), principal component analysis (PCA), and potential ecological risk index (PERI) have been applied to heavy metal data to trace potential factors, identify regional differences, and evaluate ecological risks. Sediment cores of 200 cm in depth were taken using a drilling platform at 10 sampling sites along the Xihe River, an urban river located in western Shenyang City, China. Then they were divided into 10 layers (20 cm each layer). The concentrations of the As, Cd, Cr, Cu, Hg, Ni, Pb and Zn were measured for each layer. Eight heavy metals, namely Pb, Zn, As, Cd, Cr, Cu, Ni, and Hg, were measured for each layer in this study. Results The average concentrations of the As, Cd, Cu, Hg, and Zn were significantly higher than their background values in soils in the region, and mainly gathered at 0–120 cm in depth in the upstream, 0–60 cm in the midstream, and 0–20 cm downstream. This indicated that these heavy metals were derived from the upstream areas where a large quantity of effluents from the wastewater treatment plants enter the river. Ni, Pb, and Cr were close or slightly higher than their background values. The decreasing order of the average concentration of Cd was upstream > midstream > downstream, so were Cr, Cu, Ni and Zn. The highest concentration of As was midstream, followed by upstream and then downstream, which was different to Cd. The potential factors of heavy metal pollution were Cd, Cu, Hg, Zn, and As, especially Cd and Hg with the high ecological risks. The ecological risk levels of all heavy metals were much higher in the upstream than the midstream and downstream. Conclusions Industrial discharge was the dominant source for eight heavy metals in the surveyed area, and rural domestic sewage has a stronger influence on the Hg pollution than industrial pollutants. These findings indicate that effective management strategies for sewage discharge should be developed to protect the environmental quality of urban rivers.


Water ◽  
2021 ◽  
Vol 13 (13) ◽  
pp. 1801
Author(s):  
Valentina Andreea Calmuc ◽  
Madalina Calmuc ◽  
Maxim Arseni ◽  
Catalina Maria Topa ◽  
Mihaela Timofti ◽  
...  

It is a well–known fact that heavy metal pollution in sediments causes serious problems not only in the Danube basin, but also in the large and small adjacent river streams. A suitable method for assessing the level of heavy metals and their toxicity in sediments is the calculation of pollution indices. The present research aims to assess heavy metal pollution in the Lower Danube surface sediments collected along the Danube course (between 180 and 60 km) up to the point where the Danube River flows into the Danube Delta Biosphere Reserve (a United Nations Educational, Scientific and Cultural Organization – UNESCO, protected area). In addition, this monitored area is one of the largest European hydrographic basins. Five heavy metals (Cd, Ni, Zn, Pb, Cu) were analyzed in two different seasons, i.e., the autumn of 2018 and the spring of 2019, using the Inductively Coupled Plasma Mass Spectrometry (ICP– MS) technique. Our assessment of heavy metal pollution revealed two correlated aspects: 1. a determination of the potential risks of heavy metals in sediments by calculating the Potential Ecological Risk Index (RI), and 2. an evaluation of the influence of anthropogenic activities on the level of heavy metal contamination in the surface sediments, using three specific pollution indices, namely, the Geo–Accumulation Index (Igeo), the Contamination Factor (CF), and the Pollution Load Index (PLI). The results of this pioneering research activity in the region highlighted the presence of moderate metal (Ni and Cd) pollution and a low potential ecological risk for the aquatic environment.


2020 ◽  
Vol 206 ◽  
pp. 02004
Author(s):  
Nianting Si ◽  
Liang Qu

Distribution of heavy metals (Hg, Cu, Pb, Zn, Cd and Cr) in the seawater and sediments were studied based on data from two oceanographic surveys carried out in Liaodong Bay in May and October 2016. The results showed that the values of heavy metals in seawater represent a uniform distribution, while no trends were detected for spatial distribution. High values of heavy metals in sediment were generally distributed nearshore areas in October. Concentrations of Pb, Zn, Hg in seawater were higher than the national guideline values of Mar. sediment quality of China. Values of Cu, Zn, Cd and Hg were higher than the national guideline values of Mar. sediment quality of China in October, while quality was in good condition in May. Correlation analysis showed that TOC was mainly contributed for the variations of heavy metals. The potential ecological risk analysis of heavy metals indicates that Hg, Cd and Cu should be listed as the priority contaminant metals in Liaodong Bay.


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