scholarly journals Assessment of Quality Parameters of Ecofriendly Biolubricant from Waste Cooking Palm Oil

2018 ◽  
pp. 1-11 ◽  
Author(s):  
M. U. Dabai ◽  
F. J. Owuna ◽  
M. A. Sokoto ◽  
A. L. Abubakar
Keyword(s):  
Quality Assessment ◽  
Palm Oil ◽  
Pour Point ◽  
Design Method ◽  
Viscosity Index ◽  
Acid Value ◽  
Quality Parameters ◽  
Lubricating Oil ◽  
Engine Oils ◽  
Waste Cooking Palm Oil

The use of vegetable oils as a renewable source for the production of ecofriendly biolubricant is gaining the attention of the renewable energy researchers and lubricating oil producers. This study evaluates the quality assessment parameters of ecofriendly biolubricant from waste cooking palm oil (WCPO). The crude WCPO was filtered, centrifuged at 500 rpm, and dried over Na2SO4 crystals overnight. The quality assessment parameters of the pretreated WCPO (PWCPO) were determined to authenticate its potential for the production of multigrade lubricating oils. Kinematic viscosities at 100°C (8.26±0.03 cSt) and 40°C (36.98±0.01 cSt) were determined according to ASTMD-446 method, while the viscosity index (208±0.11) was determined according to ASTMD-2270 method. A design of experiment (Mixture Design Method using Minitab 17) was used to determine the proportion of PWCPO (68.75%), SN 500 (23.75%), and additives (7.50%) that gave the mixture with the optimum quality parameters of the produced biolubricant. The produced biolubricant had kinematic viscosities at 100oC (10.72±0.13 cSt) and 40°C (59.32±0.20 cSt) respectively, a viscosity index of 173±0.10, flash point of 234±1.13°C, pour point of -31±0.10°C, acid value of 21.04±1.21 mg KOH g-1, and iodine value of 1.28±1.40 mg I2 g-1. The produced biolubricant has quality parameters that are comparable to available ecofriendly lubricating oil and was also found within standards for engine oils.

scholarly journals Formulation of Lubricant from Calabash Seed Oil

2018 ◽  
pp. 1-8
Author(s):  
F. J. Owuna ◽  
M. U. Dabai ◽  
M. A. Sokoto ◽  
U. Z. Faruq ◽  
A. L. Abubakar
Keyword(s):  
Chemical Engineering ◽  
Seed Oil ◽  
Design Method ◽  
Viscosity Index ◽  
Quality Parameters ◽  
Engine Oil ◽  
Engine Oils ◽  
Oil Market ◽  
Oil Formulation ◽  
Complex Chemical Reactions

The engine oil market is faced with complex chemical reactions and difficult chemical engineering involved in the formulation of synthetic based engine oils, and therefore, the need to source for alternative base oils for engine oil formulation from vegetable oils has become urgent and inevitable. This research is aimed at formulation of lubricant using calabash seed oil (CSO). An experiment designed (Mixture Design Method using Minitab 17) was used to obtain the blend of CSO (28.75%), SN 500 (68.75%), and additive (2.50%) with improved physicochemical parameters. The lubricant obtained had kinematic viscosities 9.30±2.11 cSt (at 100°C) and 53.11±1.03 cSt (at 40°C), a viscosity index of 167±0.51, flash point of 240±2.01°C, and pour point of -28±1.31°C. The lubricant obtained in this research had quality parameters that are comparable to those of synthesised environmentally acceptable engine oils, and are within the standard for engine oils.

scholarly journals Pengaruh Penambahan Minyak Kelapa dan Sawit Terhadap Sifat Fisik dan Tribologi Pelumas SAE 40

Jurnal METTEK ◽  
2019 ◽  
Vol 5 (1) ◽  
pp. 1
Author(s):  
Dedison Gasni ◽  
KM Abdul Razak ◽  
Ahmad Ridwan ◽  
Muhammad Arif
Keyword(s):  
Fatty Acids ◽  
Coefficient Of Friction ◽  
Tribological Properties ◽  
Palm Oil ◽  
Boundary Lubrication ◽  
Viscosity Index ◽  
Coconut Oil ◽  
High Viscosity ◽  
Mineral Oil ◽  
Lubricating Oil

Penelitian ini bertujuan untuk mengetahui efek dari penambahan minyak kelapa dan sawit terhadap sifat fisik dan tribologi pelumas SAE 40. Vegetabel oil, seperti; minyak kelapa dan sawit, memiliki nilai viskositas indek yang tinggi dan sifat pelumasan yang baik terutama didaerah boundary lubrication jika dibandingkan dengan mineral oil (SAE 40). Hal ini disebabkan karena vegetabel oil memiliki kandungan fatty acids yang tidak dimiliki oleh mineral oil. Keunggulan lain dari minyak kelapa dan sawit adanya sifat yang ramah lingkungan karena mudah terurai di alam dan dapat diperbaharui. Pada penelitian ini sifat yang baik dari minyak kelapa dan sawit ini akan dimanfaatkan sebagai zat aditif pada minyak pelumas SAE 40. Pengujian dilakukan terhadap sifat fisik dan tribology dengan penambahan 5%, 10%, 15%, dan 20% berat dari minyak kelapa dan sawit ke dalam minyak pelumas SAE 40. Pengujian sifat fisik terdiri dari pengukuran viskositas pada temperatur 400C dan 1000C dan viskositas index. Pengujian sifat tribologi untuk menentukan keausan dan koefisien gesek berdasarkan ASTM G99 dengan menggunakan alat uji pin on disk. Dari hasil pengujian diperoleh bahwa dengan penambahan minyak kelapa dan sawit kedalam minyak pelumas SAE 40 terjadi peningkatan viskositas indeks. Peningkatan viskositas indeks sebanyak  17% dengan penambahan 20% minyak sawit. Terjadi perubahan sifat tribologi dengan penambahan minyak sawit, berupa penurunan keausan dan nilai koefisien gesek dibandingkan dengan penambahan minyak kelapa. This study aims to determine the effect of coconut and palm oils as additives to physical and tribological properties of SAE 40 lubricating oil . Vegetable oils, such as; coconut oil and palm oil, have high viscosity index and good lubrication properties, especially in boundary lubrication compared to mineral oil. This is due to vegetable oil having fatty acids that are not owned by mineral oil. The advantages of coconut oil and palm oil are environmentally friendly properties because they are biodegradable and renewable. In this study, the good properties of coconut and palm oils will be used as additives in SAE 40 lubricating oil. Tests are carried out on the physical and tribological properties with the addition of 5%, 10%, 15%, and 20% by weight of coconut and palm oils into SAE 40 lubricating oil. Physical properties testing consists of measuring viscosity at temperatures of 400C and 1000C and viscosity index. The tribological test is to determine wear and coefficient of friction based on ASTM G99 using a pin on disc test equipment. From the test results,  it was found that coconut and palm oils as additives into SAE 40 lubricating oil could increase in viscosity index. The increase of  the viscosity index was 17% by adding 20% of palm oil. There was a change of tribological properties in the form of decreasing on the wear and the coefficient of friction with the addition of palm oil compare to addition of coconut oil.

scholarly journals Effects of Acid Washing and Additives on Qualities of Waste Lubricating Oil

1970 ◽  
Vol 43 (4) ◽  
pp. 529-536
Author(s):  
M Naimul Haque ◽  
M Yunus Miah ◽  
S Ali Ashruf ◽  
M Rafiqul Islam ◽  
A Kumar Das
Keyword(s):  
Pour Point ◽  
Environmental Problem ◽  
Economic Effect ◽  
Viscosity Index ◽  
Maximum Yield ◽  
Lubricating Oil ◽  
Acid Washing ◽  
Different Types ◽  
Fuller’S Earth ◽  
Tga Analysis

Waste lubricating oil has been reclaimed by treatment with commercial sulphuric acid followed by adsorption on fuller's earth. A maximum yield (75%) of reclaimed oil at acid- oil ratio of 10:100 with addition of 10% (w/v) fuller's earth has been obtained. Properties of reclaimed oil such as viscosity index, pour point, colour etc. have been improved from 93.4, +2, 5.0 to 109, -10.5, 4.0 by addition of certain proportion of additives. TGA analysis of waste lubricating oil, reclaimed oil and fresh lubricating oil has also been studied. The reclaimed oil obtained after addition of different types of additives is very comparable to SAE 30 grade lubricating oil in terms of properties and is applicable as a standard lubricant. Such a reuse of waste lubricating oil, in addition to its economic effect will help to reduce environmental problem. Key words: Lubricating oil, TGA analysis, Envirormentl problem and Vscosity index.      doi: 10.3329/bjsir.v43i4.2243 Bangladesh J. Sci. Ind. Res. 43(4), 529-536, 2008

scholarly journals Lubricity, Tribological and Rheological Properties of Green Ester Oil Prepared from Bio-Based Azelaic Acid

2021 ◽  
Vol 33 (6) ◽  
pp. 1363-1369
Author(s):  
Waled Abdo Ahmed ◽  
Nadia Salih ◽  
Jumat Salimon
Keyword(s):  
Rheological Properties ◽  
Azelaic Acid ◽  
Pour Point ◽  
Viscosity Index ◽  
Raw Material ◽  
Low Friction ◽  
Plant Oil ◽  
Engine Oils ◽  
Hydraulic Fluids ◽  
Gear Oils

Plant oil derived compounds have been used as the raw material for the synthesis of green biolubricant. Azelaic acid derived from oleic acid is one of the interesting compounds. The synthesis of azelate esters oil based synthetic green biolubricants was carried out. The esterification process of azelaic acid with variety type of alcohols was catalyzed by concentrated H2SO4. The yields percentages of azelate esters oil produced were varied depending their overall molecular structure. The azelate esters oil properties were evaluated for their suitability as a biolubricant. The results showed that the linear azelate esters oil showed high pour point values in a range of 15 to 5 ºC for di-decyl azelate, di-octyl azelate and di-hexyl azelate respectively. On the other hands, the branch azelate esters oil showed very low pour point of -70, -58 and -50 ºC for di-2-butyloctyl azelate, di-2-ethylhexanol azelate and di-2-ethylbutyl azelate, respectively. Moreover, the linear azelate esters oil gave high values of flash point, viscosity index and oxidative stability, and they were slightly affected by branching molecule structure. The tribological and rheological properties of high molecular azelate esters oil were also performed. Subsequently, most of them were classified as non-Newtonian fluids and having boundary lubrication properties with low friction coefficient. The branch azelate esters oil is plausible to be used as green biolubricants in many applications including automotive, marine engine oils, compressor oils, hydraulic fluids, gear oils and industrial biolubricants.

scholarly journals Study the Effect of Friendly Environmental Materials Addition on Viscosity Index and Pour Point of Engine Diesel Lubricating Oil

2018 ◽  
Vol 21 (3) ◽  
pp. 105-111
Author(s):  
Taghreed Mahdi Hameed ◽  
◽  
Muna Mahmood Khudhair ◽  
Lamyaa Adnan Abdulridha ◽  
◽  
...  
Keyword(s):  
Pour Point ◽  
Viscosity Index ◽  
Lubricating Oil ◽  
Environmental Materials

scholarly journals Rheological and Thermal Properties of Lubricating Oil Enhanced by the Effect of CuO and TiO2 Nano-Additives

2019 ◽  
Vol 15 (2) ◽  
pp. 24-33 ◽  
Author(s):  
Khalid A. Sukkar ◽  
Abullhassan A. Karamalluh ◽  
Thulfiqar N. Jaber
Keyword(s):  
Thermal Conductivity ◽  
Pour Point ◽  
Quality Parameters ◽  
Cuo Nanoparticles ◽  
Flash Point ◽  
Engine Oil ◽  
Lubricating Oil ◽  
Titanium Oxides ◽  
Spherical Nanoparticles ◽  
Nano Additives

The specifications of lubricating oil are fundamentally the final product of materials that have been added for producing the desired properties. In this research, spherical nanoparticles copper oxide (CuO) and titanium oxides (TiO2) are added to SAE 15W40 engine oil to study the thermal conductivity, stability, viscosity of nano-lubricants, which are prepared at different concentrations of 0.1%, 0.2%, 0.5%, and 1% by weight, and also their pour point, and flash point as five quality parameters. The obtained results show that CuO nanoparticles in all cases, give the best functionality and effect on engine oil with respect to TiO2. With 0.1 wt. % concentration, the thermal conductivity of CuO/oil and TiO2/oil increased by 7.27% and 4.54%, respectively. In the same time, the flash point of them increased by 12.62% and 9.3%, respectively in comparison with parent oil.

scholarly journals Potential of using polyethylene as viscosity enhancer of palm oil to use as a lubricating oil

2020 ◽  
Vol 12 (11) ◽  
pp. 168781402097074
Author(s):  
TKKS Pathmasiri ◽  
GIP Perera
Keyword(s):  
Vegetable Oils ◽  
Palm Oil ◽  
Low Temperatures ◽  
Kinematic Viscosity ◽  
Viscosity Index ◽  
Shear Thickening ◽  
Lubricating Oil ◽  
Shear Thickening Fluid ◽  
Major Constraint ◽  
Lubricating Properties

Biodegradable vegetable oil-based lubricating oil is a better auxiliary for mineral-based lubricants as their viscosity index, flash point, lubricity is high. Nonetheless, their limited viscosity range is a major constraint of their usage as lubricating oil. Polymers have proven their capability of increasing the viscosity of vegetable oils without adversely affecting their lubricating properties. Potentially of use of oxidized polyethylene (OPE) as a viscosity booster of palm oil to use as a lubricating oil is studied adding several weight percentages of OPE to the palm oil independently. The addition of 1.75 wt% of OPE to the palm oil resulted in a blend with comparable kinematic viscosity to H68 and the addition of 2.0 wt% of OPE to the palm oil resulted in a blend with comparable kinematic viscosity to SAE30. Palm oil behaves as Newtonian fluid at low temperatures and as the temperature increases, it behaves as shear thickening fluid while the addition of OPE cause to shear thinning behavior.

scholarly journals Analysis of selected results of engine oil tests

2019 ◽  
Vol 302 ◽  
pp. 01010
Author(s):  
Bogdan Landowski ◽  
Monika Baran
Keyword(s):  
Kinematic Viscosity ◽  
Viscosity Index ◽  
Engine Oil ◽  
Lubricating Oil ◽  
Drive Unit ◽  
Passenger Car ◽  
Engine Oils ◽  
Different Temperatures ◽  
Rotary Viscometer

The study presents selected results of viscosity tests performed for different temperatures of lubricating oil with viscosity marked as 5w30. Viscosity tests of new oil and oil right after being used have been compared. Lubricating oil used in a drive unit of a passenger car was tested. A vehicle in which oil had been changed irregularly was purposefully selected for the tests. Its mileage was over 15-20 thousand kilometers. Upon testing the vehicle mileage was above 265 thousand kilometers. The values of selected characteristics of the analyzed engine oils have been determined including: density, kinematic viscosity and viscosity index. FUNGILAB rotary viscometer was used for measurement of the oil kinematic viscosity.

Jojoba modified polymers as performance modifiers additives for engine oil

2015 ◽  
Vol 67 (5) ◽  
pp. 425-433 ◽  
Author(s):  
Nehal S. Ahmed ◽  
Amal M. Nassar ◽  
Rabab M. Nasser
Keyword(s):  
Vinyl Acetate ◽  
Pour Point ◽  
Viscosity Index ◽  
Vinyl Pyrrolidone ◽  
Proton Nuclear Magnetic Resonance ◽  
Engine Oil ◽  
Lubricating Oil ◽  
Content Type ◽  
Pour Point Depressants ◽  
Viscosity Index Improvers

Purpose – The purpose of this paper is to prepare novel types of copolymers and terpolymers depending on jojoba, and using them as additives for lubricating oil. Design/methodology/approach – Copolymerization of 1 mole of jojoba with 2 moles of vinyl acetate and copolymerization of 1 mole of jojoba with 2 moles of vinyl pyrrolidone were carried out. Then, two series of terpolymers were prepared by reacting (jojoba: vinyl acetate: alkylacrylate) and (jojoba: vinyl pyrrolidone: alkylacrylate), using free radical chain addition polymerization. Elucidation of the prepared polymers was carried out by using Fourier transform infrared spectroscopy, proton nuclear magnetic resonance and gel permeation chromatography, for determination of weight average molecular weight. The thermal stability of the prepared polymers was determined. The prepared polymers were evaluated as viscosity index improvers and pour point depressants for lubricating oil. Findings – It was found that the viscosity index increases with increasing the alkyl chain length of alkylacrylate. The effect of the monomer type was studied, and it was found that the polymers depending on vinyl acetate have great effect as viscosity index improvers and pour point depressants for lubricating oil. Originality/value – The polymerization of jojoba as different copolymers and terpolymers was carried out. The great influence of the prepared additives on modification of the viscosity properties and pour point of the oil was observed.

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