scholarly journals Physicochemical Characteristics and Heavy Metal Levels of Four Rivers in Nkanu West and Nkanu East Local Government Areas of Enugu State Nigeria

Author(s):  
Melford C. Egbujor ◽  
Ogechi J. Ogbodo ◽  
Jacob A. David ◽  
Eramus O. Anieze ◽  
Ifeanyi S. Amasiatu ◽  
...  

The physicochemical properties and the concentrations of heavy metals of water samples collected from four different rivers of Nkanu east and west Local Government Areas of Enugu of state Nigeria were investigated because of the prevalent water borne diseases in these localities attributable to the drinking of contaminated water. The water samples were collected from different sites of Esu, Umuekwe, Umuobeagu and Atafu rivers and their physicochemical properties and heavy metal contents were measured. Sampling Stations were selected; samples were collected avoiding contamination from the selected sites in same season, from same depth. On site measurement of parameters was done with the same instruments. Rests of the parameters were measured in Laboratory. Lead (Pb) was present in Esu, Umuekwe, Umuobeagu and Atafu rivers at a concentration of 0.14, 0.03, 0.00 and 0.16 mg/L respectively; Zn was only detected in Esu and Umuobeagu at 0.07 and 0.01 mg/L respectively and cadmium (Cd) concentrations of 0.14, 0.14. 0.08 and 0.08 mg/L respectively. Iron was detected in only Umuekwe river having 0.17 mg/L and Atafu river having 0.21 mg/L while Ni was detected at 3.01, 4.20, 1.20 and 3.83 mg/L respectively. Only Atafu river had Cr at 0.01 mg/L, only Esu river had Co content at 0.05 mg/L, Mn content in Esu, Umuekwe, and Umuobeagu was found to be 0.01, 0.02 and 0.02 mg/L respectively with Atafu river having none. Hg concentration was found to be 0.57, 0.06, 0.42 and 0.82 mg/L for Esu, Umuekwe, Umuobeagu and Atafu rivers respectively. The concentrations of Pb and Cd were higher in all the four samples especially in Esu river as a result of its closeness to construction sites and refuse dump and the concentrations were above the acceptable limits of WHO standard of 0.010 and 0.005 mg/L respectively for drinking water while Hg, Fe, and Ni were found within the W.H.O limits of 0.001, 3.000 and 0.100 mg/L respectively. The rest were below the standard, thus confirming conclusively that the rivers are polluted with the presence of heavy metals.

2020 ◽  
Author(s):  
Francis Hamwiinga ◽  
Chisala D. Meki ◽  
Patricia Mubita ◽  
Hikabasa Halwiindi

Abstract Background: One of the factors impeding access to safe water is water pollution. Of particular concern is heavy metal contamination of water bodies. This study was aimed at determining the levels of heavy metals in drinking water sources of Chingola District of Zambia. Methods: A cross sectional study was employed. A total of 60 water samples were collected. Thirsty (30) samples were collected in the dry season in the month of October 2016 and another 30 in the wet season in the months of February and March, 2017. For each season 10 water samples were collected from each of the three water sources. i.e. Tap water, Urban ground water sources and Rural ground water sources. Heavy metal analysis was done using Atomic Absorption Spectrophotometer (AAS).Results: This study revealed that the concentrations of Iron, Manganese, Lead, Nickel and Arsenic were beyond maximum permissible levels in various water sources. Combined averages for both dry and wet seasons were as follows: Iron: 2.3, Copper: 0.63, Cobalt: 0.02, Manganese: 0.36, Lead: 0.04, Zinc:3.2, Nickel: 0.03, Arsenic: 0.05. Chromium and Cadmium were below detection limit in all water samples. The median concentrations of iron, arsenic, copper, manganese in drinking water from the Tap, rural and urban ground water sources were different, and this difference was statistically significant (p<0.05). The median concentrations of arsenic, nickel, manganese and cobalt were different between dry and wet season, and this difference was statistically significant (p<0.05).Conclusions: Sources of heavy metals in water seems to be both natural and from human activities. The concentration of heavy metals in different water sources in this study was found to be above the recommended levels. This calls for improvement in water monitoring to protect the health of the public. Therefore, there is need for continuous monitoring of heavy metals in drinking water sources by regulatory authorities.


2020 ◽  
Vol 3 (3a) ◽  
pp. 38-45
Author(s):  
JK Makpo ◽  
SM Ameh ◽  
A Asarya ◽  
YP Gambo

This work assessed the presence of heavy metals in water contaminated with petroleum products in Keffi Local Government Area. Two water sampling station were selected based on the stratified method of sampling of Antau River. Station A is located along Federal Government College Keffi popularly known as Antau Bridge where Agricultural and mechanical activities, with sales of petroleum product take place. Station B was located at Dadin Kowa known as Gada Manu where human activities such as bathing and washing takes place which served as control. The distance between stations is 1km. The procedural plan of this study was monthly sampling of water from both Stations. Materials such as funnel, sampling container, distilled water, conical flask, filter paper, 50ml polypropylene centrifuge tube, cooler were used. Heavy metal concentration was determined using X – ray Fluorescent Spectroscopy (XRF) at the Center for Energy Research and Training (CERT), Ahmadu Bello University Zaria. The water parameters of the four samples were determined using the Extech instrument. The result on Physico – chemical parameters revealed the values obtained from contaminated water samples to be pH (7.31), Dissolved Oxygen (1.14), Electrical Conductivity (8.22), Total Dissolved Solid (4.13), Temperature (27.45) and Salinity (0.091) while the controlled Station at point B were pH (7.43), DO (7.35), EC (3.14), TDS (1.54), Temperature (26.75), Salinity (0.o94) respectively. From the result obtained, the heavy metal contaminated samples had the following values: Mg (29.31±), Al (218.69±), Si (230.12±), S (1153.65±), Cl (54.25±), Ca (106.56±), Ti (23.66±), Cr (3.15±), Fe (15.92±), Cd (7.54±). For the control sample at point B, the following values were obtained: Mg (27.49±), Al (223.71±), Si (243.21±), S (94.84±), Cl (23.52±), Ca (28.44±), Ti (32.99±), Fe (16.63±), Cd (7.67±) respectively. The P-value was 0.8105 (p>0.05) for the water quality parameters while for the concentration of heavy metal P-value was 0.2054 (p>0.05). This implies that there was no significant difference between the concentrations of elements. However, the concentration values of heavy metals in the contaminated water at Station A and control water samples at Station B were higher than the World Health Organization values (Standard) for drinking water


Author(s):  
N. P. Udeh ◽  
A. C. Ikegwuonu ◽  
O. A. Okeke ◽  
C. Obudulu ◽  
K. P. Okafor ◽  
...  

Soil samples and cassava tubers collected from farmlands within Nnamdi Azikiwe University, Awka vicinity were analyzed for their heavy metal levels using Atomic Absorption Spectrophotometer (AAS) in order to assess their levels of contamination on the environment as a result of excessive fertilizers and automobile emission. Physiochemical properties of the soil samples were determined using standard methods. The soil pH had a mean value of 6.27 ± 0.07, 6.10 ± 0.06 and 6.57 ± 0.03 respectively indicating that the soils were slightly acidic to neutrality. Total organic carbon and nitrate mean values were 105.20 ± 6.20, 95.75 ± 9.57 and 94.6 ± 2.27 and 138.07 ± 12.09, 149.35 ± 14.25 and 149.20 ± 1.17 respectively showing presence of some organic matters. The mean levels of heavy metals in the soil samples were 0.01 ± 0.01, 0.05 ± 0.03 and 0.05 ± 0.03 for lead (Pb), 0.24 ± 0.16, 0.001 ± 0.001 and 0.001 ± 0.000 for cadmium (Cd) and 0.00 ± 0.00, 0.010 ± 0.006 and 0.001 ± 0.001 for chromium (Cr). These metals levels were in the abundance trend of Pb>Cd> Cr. The mean metal concentrations obtained in the cassava tubers respectively were 0.001 ± 0.001, 0.001 ± 0.001 and 0.005 ± 0.005 for lead (Pb), 0.000 ± 0.000, 0.0003 ± 0.0003 and 0.000 ± 0.000 for cadmium (Cd) and 0.002 ± 0.002, 0.000 ± 0.000 and 0.002 ± 0.002 for chromium (Cr). These metals levels were in the abundance trend of Pb> Cr > Cd. For both the soil and cassava samples, there were no significant variations in the heavy metal concentrations and also in physicochemical parameter except for pH; this showed that there is low heavy metal enrichment in the soils studied. Based on the study, the following heavy metals (Pb, Cd, and Cr) falls within the Codex maximum permissible limits 0.1mg/l or ppm expect soil cadmium in science village which is above the Codex limit. The overall results showed that the farmlands (on soils and cassava tuber) appear to be free from poisoning or some metal enrichment and safe for agricultural purposes and also safe for human health and consumption.


Author(s):  
D. M. Abbey ◽  
M. E. Abbey ◽  
T. C. Ogunyemi ◽  
M. E. Abbey

Evaluation of physicochemical parameters and heavy metal levels in surface water of the Miniokoro stream, Port Harcourt, Nigeria were investigated to determine its potability and pollution status at various stations along the stream.  The physicochemical parameters analyzed in the water samples were: pH, Temperature, Salinity, Electrical conductivity, TDS, DO, BOD, Alkalinity, Chloride, NH4+, NO3-, PO43-, SO42- while heavy metals such as Nickel, lead, Iron, Zinc and Chromium were analyzed using atomic absorption spectrophotometer. The results from the research showed an average concentration level of the physicochemical parameters such as pH (5.79-7.01), EC (136.43 - 960.67µS/cm), TDS (90.17 - 1517.67) and the spatial distribution of heavy metals: zinc (0.07 - 1.09mg/l), chromium (0.03 - 0.09mg/l), nickel (0.07 - 0.08mg/l) and iron (12.29 - 39.95mg/l). Water samples from various stations depicts the varying level of pollution along the stream when compared with national and international permissible limit. Thus, it suggests that the government should develop and implement an effective waste management plans due to environmental and other anthropogenic impacts on the stream.


2021 ◽  
Vol 38 (4) ◽  
pp. 507-514
Author(s):  
Numan Emre Gümüş ◽  
Cengiz Akköz

In this research, in order to observe the seasonal change between April 2014 and February 2015, heavy metal contents in the water, sediment and the Carassius gibelio (Bloch, 1782) tissues (muscle, gill and liver) growing in Eber Lake were determined. The obtained results showed that trace elements were founded in water, sediment and fish tissues. Among the average annual concentrations of water samples, the highest concentration was found for Mn (0.1584 mg/L) element and the lowest concentration was found for Pb element in the spring season. the maximum Average annual concentration was calculated for Mn (0.1584 mg/L, Spring) and the minimum was determined for Pb in water. In the sediment, Fe (16245.84 mg/kg, Spring) was found to be maximum and Co was the minimum. In fish, the highest concentrations were found in liver (Mo, Ni, Pb, Co, Cu, Fe), while the lowest concentrations were found in gill (Mn, Zn) and muscle (Cd, Cr, Se) tissues While the highest heavy metal concentrations were observed in the sediment, the minimum was found in the fish tissues (the ranking was the following; liver, gill and muscle). It was concluded that the heavy metal levels measured in the Lake Eber have no risk to the environment and to the public health.


2018 ◽  
Vol 73 ◽  
pp. 06009
Author(s):  
Wardhani Eka ◽  
Notodarmojo Suprihanto ◽  
Roosmini Dwina

Saguling reservoir in West Java Province is becoming increasingly polluted by heavy metals. The purpose of this study was to determine the level of four heavy metals such as Cd, Cr, Cu, and Pb concentration at Saguling Reservoir at ’2 sampling location. Water samples were collected during rainy and summer 2008-2017 to determine the spatial distribution seasonal and temporal variation of different heavy metal contents. Mean metals concentrations in summer seasons were Cd, Cr, Cu, and Pb higher than rainy season. Mean concentration of Cd, Cu, Cr, and Pb in water samples were accordance water quality standard in both season. Heavy metal pollution that occurs in the Saguling reservoir must be monitored because this reservoir is planned to be a source of raw water for Bandung City.


2018 ◽  
Vol 69 (1) ◽  
pp. 11-16 ◽  
Author(s):  
Katarzyna Kajka ◽  
Beata Rutkowska

Abstract The aim of the study was to determine the levels of selected trace elements in soils and in the common dandelion depending on the distance from a traffic route. The study was conducted in Warsaw near one of the main roads in the suburb of Ursynów. Samples for testing were taken from the 0–25 cm layer at sites located directly alongside the roadway and at a distance of 30, 60 and 300 m from its edge. The amounts of Pb, Ni, Cu, Zn and Cd in the soils were determined by the AAS method, after extraction in HCl at a concentration of 1 mol·dm−3, and in the aboveground parts and roots of dandelion plants after wet mineralization in a mixture of HNO3 and HClO4 by the AAS method. On the basis of the results obtained, it was shown that the concentrations of the tested metals, both in the soils and in the biomass of the test plant, were highest directly at the edge of the roadway and decreased significantly with the distance away from the road. This correlation indicates a significant impact of road transport on heavy metal levels in the environment bordering a traffic route. It was also shown that dandelion plants accumulate higher amounts of heavy metals in the aboveground parts than in the roots, and the heavy metal contents in the dandelion biomass were found to be significantly positively correlated with the amounts of these elements in the soils.


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