scholarly journals Pollution Evaluation Based on Physicochemical and Heavy Metal Levels of Miniokoro Stream, Port Harcourt, Nigeria

Author(s):  
D. M. Abbey ◽  
M. E. Abbey ◽  
T. C. Ogunyemi ◽  
M. E. Abbey

Evaluation of physicochemical parameters and heavy metal levels in surface water of the Miniokoro stream, Port Harcourt, Nigeria were investigated to determine its potability and pollution status at various stations along the stream.  The physicochemical parameters analyzed in the water samples were: pH, Temperature, Salinity, Electrical conductivity, TDS, DO, BOD, Alkalinity, Chloride, NH4+, NO3-, PO43-, SO42- while heavy metals such as Nickel, lead, Iron, Zinc and Chromium were analyzed using atomic absorption spectrophotometer. The results from the research showed an average concentration level of the physicochemical parameters such as pH (5.79-7.01), EC (136.43 - 960.67µS/cm), TDS (90.17 - 1517.67) and the spatial distribution of heavy metals: zinc (0.07 - 1.09mg/l), chromium (0.03 - 0.09mg/l), nickel (0.07 - 0.08mg/l) and iron (12.29 - 39.95mg/l). Water samples from various stations depicts the varying level of pollution along the stream when compared with national and international permissible limit. Thus, it suggests that the government should develop and implement an effective waste management plans due to environmental and other anthropogenic impacts on the stream.

2020 ◽  
Author(s):  
Francis Hamwiinga ◽  
Chisala D. Meki ◽  
Patricia Mubita ◽  
Hikabasa Halwiindi

Abstract Background: One of the factors impeding access to safe water is water pollution. Of particular concern is heavy metal contamination of water bodies. This study was aimed at determining the levels of heavy metals in drinking water sources of Chingola District of Zambia. Methods: A cross sectional study was employed. A total of 60 water samples were collected. Thirsty (30) samples were collected in the dry season in the month of October 2016 and another 30 in the wet season in the months of February and March, 2017. For each season 10 water samples were collected from each of the three water sources. i.e. Tap water, Urban ground water sources and Rural ground water sources. Heavy metal analysis was done using Atomic Absorption Spectrophotometer (AAS).Results: This study revealed that the concentrations of Iron, Manganese, Lead, Nickel and Arsenic were beyond maximum permissible levels in various water sources. Combined averages for both dry and wet seasons were as follows: Iron: 2.3, Copper: 0.63, Cobalt: 0.02, Manganese: 0.36, Lead: 0.04, Zinc:3.2, Nickel: 0.03, Arsenic: 0.05. Chromium and Cadmium were below detection limit in all water samples. The median concentrations of iron, arsenic, copper, manganese in drinking water from the Tap, rural and urban ground water sources were different, and this difference was statistically significant (p<0.05). The median concentrations of arsenic, nickel, manganese and cobalt were different between dry and wet season, and this difference was statistically significant (p<0.05).Conclusions: Sources of heavy metals in water seems to be both natural and from human activities. The concentration of heavy metals in different water sources in this study was found to be above the recommended levels. This calls for improvement in water monitoring to protect the health of the public. Therefore, there is need for continuous monitoring of heavy metals in drinking water sources by regulatory authorities.


Author(s):  
Khalid Mahmood Anjum ◽  
Atif Yaqub ◽  
Ehsan Mehmood Bhatti ◽  
Muhamad Yameen ◽  
Muhammad Sharif Mughal ◽  
...  

Reasonable evidences suggest that heavy metal pollutants have been added by factories and other industries to our local water bodies. The present study was conducted to determine the heavy metal (zinc and lead) concentrations in muscle tissues of Labeo rohita inhabiting local water bodies as well as those being raised at farms. Sampling was performed to collect Labeo rohita from two different stations along river Ravi, viz. Lahore Siphon (upstream) and Balloki Headworks (downstream). Additionally, samples were also obtained from the government operated as well as private fish farms located in Lahore District, Pakistan. The fish were dissected; their muscles were digested, filtered, and finally analyzed for concentrations of Zn and Pb. Significant variation of heavy metal ions were observed between two sites along river Ravi as well as government operated and private fish farms. Significantly high mean concentrations of Zn (10.7±1.268) and Pb (0.61±0.082) were observed at Balloki Head-works; whereas, the lowest Zn (1.58±0.235) and Pb (0.16±0.008) heavy metal levels were recorded in the muscle samples collected from private fish farms. It was also observed that the heavy metal concentration in the muscles of Labeo rohita, collected from Balloki Head-works was much higher than the permissible limits laid down by WHO/FAO. Further the recorded highest level of heavy metals in water samples collected from River Ravi indicates that the bioaccumulation of heavy metals is severely affecting the aquatic life of fresh water and industries should not be allowed to release their effluent directly into the river Ravi in their vicinity.


Author(s):  
Melford C. Egbujor ◽  
Ogechi J. Ogbodo ◽  
Jacob A. David ◽  
Eramus O. Anieze ◽  
Ifeanyi S. Amasiatu ◽  
...  

The physicochemical properties and the concentrations of heavy metals of water samples collected from four different rivers of Nkanu east and west Local Government Areas of Enugu of state Nigeria were investigated because of the prevalent water borne diseases in these localities attributable to the drinking of contaminated water. The water samples were collected from different sites of Esu, Umuekwe, Umuobeagu and Atafu rivers and their physicochemical properties and heavy metal contents were measured. Sampling Stations were selected; samples were collected avoiding contamination from the selected sites in same season, from same depth. On site measurement of parameters was done with the same instruments. Rests of the parameters were measured in Laboratory. Lead (Pb) was present in Esu, Umuekwe, Umuobeagu and Atafu rivers at a concentration of 0.14, 0.03, 0.00 and 0.16 mg/L respectively; Zn was only detected in Esu and Umuobeagu at 0.07 and 0.01 mg/L respectively and cadmium (Cd) concentrations of 0.14, 0.14. 0.08 and 0.08 mg/L respectively. Iron was detected in only Umuekwe river having 0.17 mg/L and Atafu river having 0.21 mg/L while Ni was detected at 3.01, 4.20, 1.20 and 3.83 mg/L respectively. Only Atafu river had Cr at 0.01 mg/L, only Esu river had Co content at 0.05 mg/L, Mn content in Esu, Umuekwe, and Umuobeagu was found to be 0.01, 0.02 and 0.02 mg/L respectively with Atafu river having none. Hg concentration was found to be 0.57, 0.06, 0.42 and 0.82 mg/L for Esu, Umuekwe, Umuobeagu and Atafu rivers respectively. The concentrations of Pb and Cd were higher in all the four samples especially in Esu river as a result of its closeness to construction sites and refuse dump and the concentrations were above the acceptable limits of WHO standard of 0.010 and 0.005 mg/L respectively for drinking water while Hg, Fe, and Ni were found within the W.H.O limits of 0.001, 3.000 and 0.100 mg/L respectively. The rest were below the standard, thus confirming conclusively that the rivers are polluted with the presence of heavy metals.


2020 ◽  
Vol 18 ◽  
pp. 89-95
Author(s):  
I Ochelebe ◽  
E.A. Kudamnya ◽  
G.E. Nkebem

The assessment of the level of heavy metal concentrations in water sources around quarries and barite mine sites in central Cross River State, Southeastern Nigeria, was carried out to evaluate the degree of contamination due to mining and quarrying activity in the area. The investigation involved the collection of twelve water samples from ponds, streams, river and boreholes around the area. The water samples were passed through 0.45 µm filter paper and preserved with a drop of 0.1M HNO3 acid. The preserved samples were analyzed for their heavy metal (Ba, Cr, Cu, Fe, Mn, Pb and Zn) content, using inductively coupled plasma-mass spectrometry (ICP-MS). The results show that the average concentration of Ba, Cu, MN, Pb and Zn were above WHO guideline value for drinking water quality, hence not suitable for drinking. The average concentration of the metals is in the order Ba>Mn>Cu>Fe>Pb>Zn>Cr. Computed values of contamination index show that the samples from four locations were contaminated. Single factor pollution index computation indicates that the waters are not contaminated with Cr, but slightly polluted with Fe and Zn, moderately polluted with Ba and severely polluted with Cu, Mn and Pb. Further, Nemerow comprehensive pollution index indicates that samples from four locations were severely contaminated. The study revealed that the water sources around the barite mines had elevated level of heavy metal concentration compared to location around the quarries. It is recommended therefore, that the water be treated before use for drinking purpose. Keywords: heavy metals, contamination index, pollution index, barite mine, quarry


Agriculture ◽  
2021 ◽  
Vol 12 (1) ◽  
pp. 27
Author(s):  
William Azuka Iyama ◽  
Kingsley Okpara ◽  
Kuaanan Techato

This study assessed the concentration of heavy metal, such as lead (Pb), cadmium (Cd), Chromium (Cr), iron (Fe), Nickel (Ni), and Silver (Ag), in Vernonia amygdalina Delile and agricultural soils of three university farms located in Port Harcourt, Nigeria. The soils and plants were taken randomly to form composite samples and analyzed for heavy metals by the use of atomic absorption spectroscopy (AAS) and X-ray fluorescence (XRF). The study stations were agricultural soils and Vernonia amygdalina Delile from the Ignatius Ajuru University of Education (I), River State University (R) and University of Port Harcourt (U). The soil samples recorded mean concentration ranges for Fe as 19.71 ± 1.77 (I)–27.24 ± 3.56 mg/kg (R) in soils and 12.95 ± 1.68 (R)–18.18 ± 2.02 mg/kg (U) for the bitter leaf samples. The mean range for Pb concentration in the soil and bitter leaf were 4.35 ± 0.87–6.80 ± 0.86 mg/kg and 0.24 ± 0.64–2.19 ± 0.74 mg/kg, while Cd concentration in the soil and bitter leaf were 0.46 ± 0.28–1.42 ± 0.40 mg/kg and 0.17 ± 0.22–0.42 ± 0.08 mg/kg, respectively. The respective mean ranges for Cr concentration in the soil and bitter leaf were 5.91 ± 1.14–8.77 ± 0.88 mg/kg and 4.04 ± 0.64–5.92 ± 0.69 mg/kg, while Ni in soil and bitter leaf were 0.54 ± 3.38–10.26 ± 3.50 mg/kg and 0.042 ± 1.42–3.30 ± 0.88 mg/kg, while Ag was negligible. Heavy metal levels in soils and Vernonia amygdalina followed the order Fe > Cr > Pb > Ni > Cd and Fe > Cr > Ni > Pb > Cd, respectively, and were lower than WHO/FAO and EPA, except Cd, which was higher in soil and in Vernonia amygdalina. The ecological risk factor (ErF) was comparatively lower in soils than in the plant, while pollution load index (PLI) showed high heavy metal retention capacities in Vernonia amygdalina due to more anthropogenic influences. The metal transfer factor (TF) was highest in Fe, followed by Cr > Cd > Ni > Pb, while Pb had the highest chances of cancer risks from the incremental lifetime cancer risk (ILCR), especially in both soil and plant (mean ILCR, 2.07 × 10−2 and 2.45 × 10−3), while Cd had the least (mean ILCR, 9.64 × 10−5 and 3.36 × 10−5). Anthropogenic activities must be regulated and monitored by government relevant agencies to reduce heavy metal inputs into soils and avoid excessive accruals in food chain.


2016 ◽  
Vol 8 (11) ◽  
pp. 9356 ◽  
Author(s):  
P. Vidya ◽  
Rajashekhar K. Patil

Sediment cores were collected from four different mangrove areas of northern Kerala and southern Karnataka, western coast of India.  The cores were analysed for the concentration of five heavy metals (Pb, Ni, Zn, Cu Fe) using Atomic Absorption Spectrometry.  The levels of heavy metals in the present study from all the four sediment cores were in the order Fe > Pb > Zn > Ni > Cu and the mean concentrations of each elements in different cores were comparable.  According to Sediment Quality Guidelines (SQG), the mangrove sediments analysed here were moderately contaminated with Ni and heavily contaminated with Pb.  The increased concentration of Ni and Pb in the sediments might be due to their atmospheric deposition or water discharge from different far away sources since the areas selected for study were not disturbed by direct anthropogenic impacts.  Elevated levels of Fe which is considered to be a common phenomenon in mangrove sediments have also been found in the present study.  Heavy metal levels in sediments showed statistically significant correlations with pH, calcium carbonate and organic matter.  This suggests the influence of physico-chemical parameters on the adsorption, deposition and persistence of heavy metals in mangrove sediments.  The heavy metal concentration and the pollution status of the mangroves of west coast, especially the areas selected in this work are less studied before. Hence the data provide from the present baseline study would be further helpful in remediation and management of mangrove ecosystem. 


Author(s):  
Antoine Nsabimana ◽  
Valens Habimana ◽  
Gaidashova Svetlana

Heavy metals are among the pollutants threatening the living organisms including human beings. The presence of heavy metals in water is of great concern due to their toxicity to aquatic organisms, humans and ability to accumulate in food chains. Thus, there is a need to regularly monitor heavy metal levels in aquatic medium. The present study was conducted to assess heavy metal concentrations in Lake Kivu water. Water samples from Lake Kivu were taken from three sites, namely: Rusizi, Karongi and Rubavu. Heavy metals in the samples were analyzed using Atomic Absorption spectro-photometer (SHIMADZU AAS-6800) and Inductively Coupled Plasma Optical Emission Spectroscopy (ICP-OES).Copper, lead, cadmium, chromium, manganese, mercury and arsenic concentrations were determined. Copper ranged from 3.24 to 10.01 μg/l, lead varied from 8.81 to 37.44 μg/l, cadmium ranged from 5.01 to 14.01 μg/l,chromium was between 139.5 and 226.6 μg/l, manganese varied from 598.3 to 795.7 μg/l, mercury ranged from 0 to 0.047 μg/l, while arsenic was not detected in any of the analyzed water samples. Except for arsenic, all the other heavy metals exceeded the EPA (US Environment Protection Agency) maximum permissible limit for class III surface water intended for fish consumption and recreation. Thus, there is a need to establish the sources of lake water pollution by heavy metals in order to design further strategies limiting the amounts of heavy metals entering Lake Kivu. Keywords: Cadmium, chromium, copper, lead, manganese, mercury


2021 ◽  
Vol 45 (1) ◽  
Author(s):  
Elijah Abakpa Adegbe ◽  
Oluwaseyi Oluwabukola Babajide ◽  
Lois Riyo Maina ◽  
Shola Elijah Adeniji

Abstract Background Heavy metal accumulation in the ecosystem constitutes a potential toxic effect which is hazardous to human health. Increasing environmental pollution has necessitated the use of cattle egrets to evaluate the levels of heavy metal contamination, to establish their use in biomonitoring of heavy metals and to provide data for monitoring pollution in the environment. Results The present study assessed the utilization of Bubulcus ibis in monitoring pollution in five abattoirs, namely Agege, Bariga, Kara, Itire and Idi-Araba, all situated in Lagos State. The concentration of five (5) heavy metals, cadmium (Cd), copper (Cu), nickel (Ni), lead (Pb) and zinc (Zn) was determined in the liver, muscle and feather of Bubulcus ibis using the atomic absorption spectrophotometer. The trend of metal accumulation was in the order: Zn > Cu > Pb > Cd > Ni for all the sampled tissues. The mean tissue concentrations of the metals were significantly different (p < 0.05) among the sites. The highest levels of metal concentration were reported in the liver in all the locations. Mean concentration of Cd in Kara (0.003 ± 0.00058) was significantly (p < 0.05) higher than those found at Agege (0.0013 ± 0.00058) and Idi-Araba (0.001 ± 0.001). A significant difference (p < 0.05) was also observed between the mean concentrations of Cu in Bariga (0.01 ± 0.001) and Idi-Araba (0.003 ± 0.001). Conclusion All the studied heavy metals were present in the liver, muscle and feathers of the cattle egrets. The contamination levels were ascertained from the study which indicated that cattle egrets are useful in biomonitoring studies and the generated data will serve as baseline data which could be compared with data from other locations for monitoring heavy metal pollution.


2009 ◽  
Vol 3 (2) ◽  
pp. 48-64
Author(s):  
Kadhim M. Ibrahim ◽  
Shaimaa A. Yousir

Several experiments were carried out to study heavy metal tolerance in tissue cultures or whole plants of S. grandiflora., Callus was induced and maintained on modified Murashige and Skoog, 1962 medium (MS) supplemented with (0.5)mg/l benzyl adenine and (2)mg/l 2,4-phenoxy acetic acid . Heavy metals (Cd, Co, Cu, Cr or Zn) were added to the culture medium at different concentrations as contamination agents. In order to asses the effect of these heavy metals on seed germination; seeds were sown in soil contaminated with different concentrations of heavy metals for 3 weeks. Atomic Absorption Spectrophotometer was used for analysis of samples taken from whole plants and callus cultures. Results showed that callus fresh weight decreased with increasing heavy metal concentration in cultural medium. Germination percentages and plant heights increased over time. However, a reduction occurred in these parameters with increasing heavy metal levels. Percentages of metals accumulated in calli were (0.001, 0.011, 0.012 and 0.013%) at (0.0, 0.05, 0.075 and 0.1)mg/l Cd respectively; (0.001, 0.008, 0.016 and 0.006%) at (0.0, 0.1, 0.25 and 0.5)mg/l Co respectively; (0.001, 0.020, 0.034 and 0.015%) at (0.0, 0.075, 0.2 and 0.5)mg/l Cu respectively; (0.001, 0.013, 0.012 and 0.010%) at (0.0, 0.25, 0.4 and 0.5)mg/l Cr respectively and (0.027, 0.051, 0.059 and 0.056%) at (0.0 , 0.75, 1.0 and 1.5)mg/l Zn respectively. Percentages of metals accumulated in whole plants were (0.08, 0.55, 1.11, 0.83 and 0.44%) at (0.0, 1.0, 2.0, 3.0 and 4.0)mg/Kg soil Cd respectively; (0.11, 0.22, 0.55, 0.47 and 0.44%) at (0.0, 15.0, 30.0 45.0 and 60.0)mg/Kg soil Co respectively; (0.01, 0.10, 0.57, 0.58 and 0.72%) at (0.0, 25.0, 50.0, 75.0 and 100.0)mg/Kg soil Cu respectively. (0.08, 0.80, 1.28, 1.31 and 0.88%) at (0.0, 25.0, 50.0, 75.0 and 100.0)mg/Kg soil Cr respectively and (0.06, 1.11, 1.20, 1.83 and 2.22%) at (0.0, 100.0, 200.0, 300.0 and 400.0)mg/Kg soil Zn respectively.


2020 ◽  
Vol 9 (3) ◽  
Author(s):  
Hawraz Sami Khalid ◽  
Hoshyar Saadi Ali ◽  
Dhary Almashhadany

The present study was conducted to evaluate the quality of drinking water in randomly selected schools in Erbil city, Kurdistan Region, Iraq. The water quality indices such as the Heavy metal Pollution Index (HPI) and Heavy metal Evaluation Index (HEI) were applied to characterize water quality. Eighteen schools were incorporated and sampled for their water storage tanks available to students. Water samples and sediment samples from tanks floor were analyzed by Inductively Coupled Plasma Optical Emission Spectrometer for the determination of twenty-two metal elements. In drinking water samples, all detected metals did not exceed the permissible limits of the World Health Organization. The results of this study showed that the average values of HPI and HEI for As, Cd, Cr, Cu, Fe, Pb, Mn, Ni, and Zn were 54.442 and 0.221, respectively. According to data of the water quality indices, the schools drinking water quality are good and suitable for drinking in terms of heavy metals. However, sediments samples contained high concentrations of all elements including the toxic heavy metals (As, Cd, Cr, and Pb). Re-suspension of sediments into water column after refilling storage tanks can pose a serious threat to students drinking water from such vessels. It is therefore recommended that proper storage tanks are provided to the schools accompanied by continuous sanitation and hygiene practice to mitigate the corrosion of tanks to avoid health risks of toxic metal


Sign in / Sign up

Export Citation Format

Share Document