ВПЛИВ МЕХАНІЧНОЇ АКТИВАЦІЇ НА РОЗМІРНІ ХАРАКТЕРИСТИКИ ТА ФОРМУ ЧАСТИНОК ГЛИНОПОРОШКІВ РІЗНОГО ТИПУ

Purpose. Determination of the influence of the process of preliminary mechanical activation on the dimensional characteristics and shape of particles of different types of clay powders.Methodology. Clay powders of montmorillonite and palygorskite type were chosen as the objects of research in this work. The process of mechanical activation of clay powders was carried out using a laboratory ball mill. For microanalysis of sample particles, the method of optical polarizing microscopy was used. Morphometric analysis of clay powder particles was performed by image analysis using the ImageJ software. At the same time, the area and perimeter were determined, and the equivalent diameter and also the shape index of the particles of the samples were calculated. The experimental data were statistically processed using the Statistica and Excel software packages.Results. The paper investigates the effect of the process of mechanical activation on the dimensional characteristics and shape of particles of montmorillonite and palygorskite type clay powders. It was found that the decrease in the average values of the equivalent particle diameter in the process of mechanical action (~14–15%) is realized mainly due to the destruction of their largest aggregates. Moreover, the intensity of this process is noticeably higher for clay of the montmorillonite type. It is shown that for both studied samples, the process of mechanical activation leads to an increase in the average values of the particle shape index (~ by 9–10%) and an increase in the uniformity of their distribution by this index.Scientific novelty. Using a detailed morphometric analysis of particles of various types of clay powders, the regularities of the influence of the mechanical activation process on the quantitative statistical characteristics of their distribution over the equivalent diameter and shape index have been established.Practical value. The results obtained will make it possible to reasonably approach the choice of pretreatment methods for clay powders intended for the production of polymer filled nanocomposite materials.

Application of the space-based optical interferometer towards measuring cosmological distances of quasars.

Measuring the quasar distance through joint analysis of spectroastrometry (SA) and reverberation mapping (RM) observations is a new method for driving the development of cosmology. In this paper, we carry out detailed simulation and analysis to study the effect of four basic observational parameters (baseline length, exposure time, equivalent diameter and spectral resolution) on the data quality of differential phase curves (DPCs), furthermore on the accuracy of distance measurement. In our simulation, we adopt an axis symmetrical disc model of broad line region (BLR) to generate differential phase signals. We find that the differential phases and their Poisson errors could be amplified by extending the baseline, while the influence of OPD errors can be reduced during fitting the BLR model. Longer exposure time or larger equivalent diameter helps reduce the absolute Poisson error. Therefore, the relative error of DPCs could be reduce by increasing any of the above three parameters, then the the accuracy of distance measurement could be improved. In contrast, the uncertainty of $D_{\rm{A}}$ could be improved with higher spectral resolution, although the relative error of DPCs would be amplified. We show how the uncertainty of distance measurement varies with the relative error of DPCs. It is found that the relative error of DPCs $<$ 20$\%$ is a limit for accurate distance measurement. As any of the basic observational parameters become larger, the relative error of DPCs have a lower limit (roughly 5$\%$) and the uncertainty of distance measurement can be better than 2$\%$.

Heat Exchange and Hydrodynamic Characteristics of Unified Package of Cold Layer of RAH

Heating the air in the boiler air heater with the heat of fuel combustion products performs the functions of increasing the fuel combustion temperature, increasing the temperature level of gases in convective heating surfaces, improving ignition and fuel combustion conditions, increasing boiler efficiency by utilizing waste gas heat, improving fuel quality due to its preliminary supply, etc. However, the peculiarities of the process of heating the air in the air heaters do not allow to achieve a decrease in the temperature of the exhaust gases. This is due to the unfavorable ratio of heat capacities of flue gases and air, as well as corrosion and contamination of the heating surfaces of air heaters. The research of heat transfer processes and hydraulic resistance of unified package of cold layer of RAH is depicted at this work. The graphic dependence of the change in the coefficient of hydraulic resistance and Nu number for unified packages with single line of sheets and simplified profile with corrosion resistance enamel from the Reynolds number for different values of the length of the replaced areas was constructed. The unified packing of the simplified profile has increased by 1.17 times equivalent diameter and is characterized by good operational parameters and takes into account the risk of contamination of heating surfaces due to the enamel coating.

Effect of Welding Heat Input on Microstructure and Impact Toughness in the Simulated CGHAZ of Low Carbon Mo-V-Ti-N-B Steel

Welding thermal cycles with heat inputs ranging from 25 to 75 kJ/cm were performed on a Gleeble 3500. The impact energy improved significantly (from 10 to 112 J), whereas the simulated coarse-grain heat-affected zone (CGHAZ) microstructure changed from lath bainite ferrite (LBF) and granular bainite ferrite (GBF) + martensite/austenite (M/A) to acicular ferrite (AF) + polygonal ferrite (PF) + M/A as the heat input increased. Simultaneously, the mean coarse precipitate sizes and the degree of V(C,N) enrichment on the precipitate surface increased, which provided favorable conditions for intragranular ferrite nucleation. The Ar3 of CGHAZ increased from 593 °C to 793 °C with increasing heat inputs; the longer high-temperature residence time inhibited the bainite transformation and promoted the ferrite transformation. As a result, acicular ferrite increased and bainite decreased in the CGHAZ. The CGHAZ microstructure was refined for the acicular ferrite segmentation of the prior austenite, and the microstructure mean equivalent diameter (MED) in the CGHAZ decreased from 7.6 µm to 4.2 µm; the densities of grain boundaries higher than 15° increased from 20.3% to 45.5% and significantly increased the impact toughness. The correlation of heat input, microstructure, and impact toughness was investigated in detail. These results may provide new ideas for the development of high welding heat input multiphase steels.

Optimization of the operation mode of regenerative heat exchangers

The paper considers the operation of regenerative heat exchangers with a fixed checkerwork. Such a checkerwork allows for high-temperature heating of gases and is made of refractory materials with a relatively high heat capacity, but low thermal conductivity. The article presents calculations of regenerative heat transfer for devices with block checkerwork. It is shown that a decrease in the equivalent diameter of the channel d e leads to an increase in the average air heating temperature over the period. An increase in the relative water section of the checkerwork f also leads to an increase in the air heating temperature, but only to a certain limit. On the one hand, with an increase in the relative water section, the specific heat exchanger surface increases. On the other hand, at a certain value f, the accumulating mass of the checkerwork significantly decreases, and as a result, the air heating temperature decreases. For the same reason, for checkerwork with a high value of the relative water section, it is necessary to reduce the duration of the heating/cooling periods of the checkerwork. The paper also examines several types of compact checkerwork, which are very promising, including in heat storage systems. It is noted that the use of such attachments in conventional regenerate heat exchangers is impossible. First, it is necessary to increase the water section of the heat exchanger and significantly reduce its height, otherwise, the pressure loss will increase sharply. Secondly, it is necessary to significantly reduce the duration of the heating/cooling periods, otherwise, due to more intense heat exchange, the air temperature at the outlet of the regenerative heat exchanger changes much more than in the block checkerwork.

Applicability of The Equivalent Diameter Approach to Estimate Vortex Shedding Frequency and Acoustic Resonance Excitation From Different Finned Cylinders In Cross-Flow

This article explores the applicability of utilizing different equivalent diameter (Deq) equations to estimate the vortex shedding frequency and onset of self-excited acoustic resonance for various types of finned cylinders. The focus is on three finned cylinder types that are commonly used in industrial heat exchangers: straight, twist-serrated, and crimped spirally finned cylinders. Within each type of fins, at least three different finned cylinders are investigated. The results indicate that at off-resonance conditions, utilizing the appropriate equivalent diameter collapses the Strouhal number data within the typical Strouhal number variations of an equivalent diameter circular, bare cylinder. However, when acoustic resonance is initiated, the onset and the peak of resonance excitation in all of the finned cylinder cases generally occurred at a reduced flow velocity earlier than that observed from their equivalent diameter bare cylinders. This suggests that although utilizing the appropriate equivalent diameter can reasonably estimate the vortex shedding frequency away from acoustic resonance excitation, it cannot be used to predict the onset of acoustic resonance in finned tubes. The findings of this study indicate that the effective diameter approach is not sufficient to capture the intrinsic changes in the flow-sound interaction mechanism as a result of adding fins to a bare cylinder. Thus, a revision of the acoustic Strouhal number charts is required for finned tubes of different types and arrangements.

Characterization and Filtration Efficiency of Sustainable PLA Fibers Obtained via a Hybrid 3D-Printed/Electrospinning Technique

The enormous world demand for personal protective equipment to face the current SARS-CoV-2 epidemic has revealed two main weaknesses. On one hand, centralized production led to an initial shortage of respirators; on the other hand, the world demand for single-use equipment has had a direct and inevitable effect on the environment. Polylactide (PLA) is a biodegradable, biocompatible, and renewable thermoplastic polyester, mainly derived from corn starch. Electrospinning is an established and reproducible method to obtain nano- and microfibrous materials with a simple apparatus, characterized by high air filtration efficiencies. In the present work, we designed and optimized an open-source electrospinning setup, easily realizable with a 3D printer and using components widely available, for the delocalized production of an efficient and sustainable particulate matter filter. Filters were realized on 3D-printed PLA support, on which PLA fibers were subsequently electrospun. NaCl aerosol filtration tests exhibited an efficiency greater than 95% for aerosol having an equivalent diameter greater than 0.3 μm and a fiber diameter comparable to the commercially available FFP2 melt-blown face mask. The particulate entrapped by the filters when operating in real environments (indoors, outdoors, and working scenario) was also investigated, as well as the amount of heavy metals potentially released into the environment after filtration activity.

Effect of Moisture Content on Sunflower Seed Physical and Mechanical Properties

This study was carried out to measure some physical and mechanical properties of the sunflower seeds variety “DW667”. The physical properties (length, width, thickness, equivalent diameter, sphericity, surface area of seed, one thousand seed mass, bulk and true density, porosity) and mechanical properties (compressive load and displacement deformation for vertical and horizontal orientations) were measured at 4%, 10%, 15%, 20% and 25% Dray basis (d.b.) moisture contents. Higher moisture content from 4%to25% increased length, width, thickness, equivalent diameter, sphericity, surface area of seed, one thousand seed mass, bulk and true density, porosity and deformation displacement at the vertical and horizontal orientations of seeds increased from 10.57 to , 4.50 to , 2.85 to , 5.13 to , 49 to 50 %, 82.95 to 94.53 mm2, 33.70 to , 286.80 to 314.98 kg/m3, 406.47 to 483.61 kg/m3, 29.22 to 34.54 %, 1.63 to 2.63 mm and 0.70 to 1.87 mm, respectively. While the required compressive force for rupture seeds decreased from 25.3 to 12.39 N and 11.5 to 5.63 N for vertical and horizontal orientations, respectively with moisture contents uprising from 4 to 25 %. The findings of this study will open new windows in farm mechanization for the designing and improvement of treatment machines for this type of seed.

Systematic Study of the Effects of High Shear Granulation Parameters on Process Yield, Granule Size, and Shape by Dynamic Image Analysis

The aim of the work was to analyze the influence of process parameters of high shear granulation on the process yield and on the morphology of granules on the basis of dynamic image analysis. The amount of added granulation liquid had a significant effect on all monitored granulometric parameters and caused significant changes in the yield of the process. In regard of the shape, the most spherical granules with the smoothest surface were formed at a liquid to solid ratio of ≈1. The smallest granules were formed at an impeller speed of 700 rpm, but the granules formed at 500 rpm showed both the most desirable shape and the highest process yield. Variation in the shape factors relied not only on the process parameters, but also on the area equivalent diameter of the individual granules in the batch. A linear relationship was found between the amount of granulation liquid and the compressibility of the granules. Using response surface methodology, models for predicting the size of granules and process yield related to the amount of added liquid and the impeller speed were generated, on the basis of which the size of granules and yield can be determined with great accuracy.

Joint Monitoring and Analysis of Sea Fog Using Dual Visibility Lidar in Ningbo, China

Visibility lidar has obvious monitoring advantages over forward scatter visibility sensors or fog droplet spectrometers; it can measure visibility information over a large area. In 2021, two visibility lidar instruments (1064 or 532 nm wavelengths) were installed in Beilun, Ningbo Zhoushan Port, to monitor sea fog. Comparing their monitoring data to those of forward scatter visibility sensors and a fog droplet spectrometer revealed that the visibility lidar instruments could obtain energy progress information section-by-section in the monitoring path, and could directly reflect sea fog changes. The 1064 nm lidar outperformed the 532 nm lidar regarding sea fog detection. The effective detection range decreased significantly with decreasing visibility; the reliability decreased in low-visibility, uneven atmospheres. In a low-visibility but uniform atmosphere, however, lidar data corresponded well with forward dispersion data. The 532 nm and 1064 nm lidar data sometimes differed at the same monitoring position owing to differing heights and particle reflection angles. During a sea fog event on May 9, 2021, the maximum droplet concentration was 14 cm−3, the maximum liquid water content was 0.21 g·m−3, and the maximum equivalent diameter was 49 μm. The formation of this sea fog was dominated by large particles.