Designing Materials and Processes for Strong Polyacrylonitrile Precursor Fibers

Although polyacrylonitrile (PAN)-based carbon fibers have been successfully commercialized owing to their excellent material properties, their actual mechanical performance is still much lower than the theoretical values. Meanwhile, there is a growing demand for the use of superior carbon fibers. As such, many studies have been conducted to improve the mechanical performance of carbon fibers. Among the various approaches, designing a strong precursor fiber with a well-developed microstructure and morphology can constitute the most effective strategy to achieve superior performance. In this review, the efforts used to modulate materials, processing, and additives to deliver strong precursor fibers were thoroughly investigated. Our work demonstrates that the design of materials and processes is a fruitful pathway for the enhancement of the mechanical performance of carbon fibers.

Effect of Polyacrylonitrile Precursor Orientation on the Structures and Properties of Thermally Stabilized Carbon Fiber

The thermal stabilization process of polyacrylonitrile (PAN) precursor fiber was the key step to prepare high-performance carbon fiber. During the thermal stabilization process, the aggregation structure and the reactivity of molecular chains have significant effects on the microstructures and mechanical properties of carbon fiber. In the present paper, the effects of the orientation structure of PAN precursor fiber on the thermal stabilization reaction and the mechanical properties of carbon fiber were experimentally studied. Using multi-dimensional structural and mechanical properties tests, such as XRD, DSC, 13C NMR and Instron machine testing, the crystalline and skeleton structure, exothermic behavior, and tensile properties of PAN precursor fiber with different orientations in the process of thermal stabilization were characterized to reveal the relationship between microstructure evolution and tensile properties. The results showed that the orientation structure of PAN precursor fiber had an obvious effect on the thermal stabilization process and the tensile stress–strain characteristic. When the heat treatment temperature was lower than 200 °C, the crystallinity and crystallite size of PAN fibers with higher orientation degrees increased significantly. After sufficient thermal stabilization, the original PAN precursor fiber with a higher orientation degree could form more aromatic lamellar structures and showed better regularity. Furthermore, the yield strength and initial modulus of the fibers with a higher orientation degree increased due to the formation of more aromatic rings. The maximum increase in the percentages of yield strength and tensile modulus of the PAN fibers were achieved when the heat-treated temperature was 200 °C, and the percentage values were 138.4% and 158.7% compared to the precursor without heat-treatment. In addition, the elongation at break of the fibers with a higher orientation degree was also relatively larger.

High performance and tunable artificial muscle based on two-way shape memory polymer

Polymeric artificial muscle by twist insertion in precursor fiber is a recent discovery. This study shows that chemically cross-linked two-way shape memory polymer muscles have remarkable and tunable axial actuation with lower actuation temperature.

Fabrication Parameters and Performance Relationship of Twisted and Coiled Polymer Muscles

Twisted and Coiled Polymer (TCP) muscles are soft actuators made by inserting twist in a precursor fiber while attaching a dead weight at the end, followed by heat treatment. TCP muscles are thermally driven actuators with high power to weight ratio, large strain and low cost. These muscles have a wide variety of applications in engineering, specifically for robotics since these actuators have large linear deformation in response to applied power (Joule’s Effect). The performance of these muscles depend on numerous fabrication parameters such as speed of the coiling, dead weight used, precursor fiber type, number of filament in precursor fiber, number of plies and training cycles. An in-depth study of the fabrication parameters is required to understand the performance of the muscles. We have designed experimental setup to study the performance of the muscles on different input parameters such as load, current, voltage and output results such as displacement, force and temperature. We present the study of single, double and tripled plied muscles that are fabricated by plying together a twisted and coiled filament. Further, the power consumption of the muscles under various conditions is discussed. This study would help to establish a procedure to fabricate these materials with consistent properties.