Enzymatic Conversion of Lignosulfonate into Wood Adhesives: A Next Step towards Fully Biobased Composite Materials

This study investigates the effect of the enzymatic polymerization of lignosulfonate for the formulation of a lignosulfonate-based adhesive. For this, beech lamellas were glued together and tested according to the EN 302-1 standard. The results showed that the laccase-polymerized lignosulfonate-based wood adhesives (LS-p) had similar mechanical properties as a standard carpenter’s glue (PVAc-based D3 class white glue), as no significant difference in tensile shear strength between these two adhesive types was found. However, carpenter’s glue showed almost 100% wood failure, while with the lignosulfonate-based wood glue, the samples failed, mainly in the glueline. Pre-polymerization of LS-p is the most critical factor to achieve the required viscosity, which is also connected to the wetting properties and the resulting tensile shear strength. The longer the pre-polymerization, the higher the viscosity of the LS-p adhesive, with the tensile shear strength reaching a plateau. The presented data show the potential of using enzymatically pre-polymerized lignosulfonate as a well-performing wood adhesive. Further development and optimization of the pre-polymerization process is required, which is also important to push towards upscaling and practical applications.

Effect of Surface Texture on Tensile Shear Strength of 1060Al-PET Welding Joints

Joining metal to plastic can lighten weight of products to reduce energy consumption. However, it is difficult to achieve high-strength welding between metal and plastic. To address this problem, the methods of surface texture pretreatment and laser irradiation welding was proposed to achieve the high-strength connection of metal and plastic. In this study, with different parameters of laser power and texture morphology, 1060 Al with surface texture treatment was joined to polyethylene terephthalate (PET) by laser irradiation welding from metal side. Study showed that as the laser power increased, the tensile shear strength of joints increased first, and decreased thereafter. Tensile shear tests demonstrated that the mechanical force of joint was strengthened contributed to mechanical anchorage formed by surface texture. The depth-width ratio of the texture grooves affected the tensile shear process of the joint. According to the result of temperature simulation, the existence of texture grooves reduced the heat transfer efficiency, and the heat dissipation at interface was also impeded in course of laser welding. Finally, the maximum tensile strength of 1060Al-PET joint reached 48.4 MPa, which was close to the strength of PET matrix. The bonding mechanism of the 1060Al-PET joints was composed of mechanical bonding and chemical bonding. This study proposes an effective method to join metal to plastic which achieved high-strength connection between metal and plastic.

Effects of Crosslinking and Silicone Coupling Agent on Properties of EVA Composite Hot Melt Adhesive

In order to improve the bonding performance, EVA composite hot melt adhesives were prepared by introducing crosslinking agent and silane coupling agent in this paper. A binary EVA resin blend as the base resin with appropriate viscosity and tensile shear strength was selected as hot melt adhesive. The effects of crosslinking agent and silane coupling agent on the properties of ethylene/vinyl acetate (EVA) composite hot melt adhesive were studied. By investigating the preparation and curing conditions of hot melt adhesive and the properties of hot melt adhesive after the introduction of dicumyl peroxide (DCP), the optimum temperature and dosage of DCP and its influence on the properties were determined. It was found that the tensile shear strength of hot melt adhesive increased from 0.247 MPa to 0.726 MPa when 2 phr DCP and 5 phr KH570 were added at the same time. The tensile strength and tensile shear strength of hot melt adhesive are only slightly improved when silicone coupling agents with different functional groups are added to EVA composite hot melt adhesive. However, it was found that excessive silane coupling agent would significantly reduce the tensile strength and shear peel strength of the material.

Influence humidity and heat on tensile shear strength of lap joints made of solid fir/spruce wood

Determination of tensile shear strength of lap joints is carried out according to three standards: BAS EN 205:2018 for adhesives used for non–load–bearing structures, and according to BAS EN 302-1:2014 for adhesives used for the manufacture of load-bearing structures and according to EN 14257:2019 for lap joints who are exposed to elevated temperatures. The paper presents the results of tensile shear strength of lap joints made of solid fir/spruce (Abies alba ssp./Picea abies spp). Tensile shear strength was tested in 4 groups of tests samples. The Group 1 consisted the samples were 7 days in standard atmosphere [20/65]. The Group 2 consisted the samples were previously soaked in water at (20 ± 5) °C, then recondition in standard atmosphere [20/65]. The Group 3 consisted the samples were previously 6 h soaked in boiling water 2 h, then soaked in water at (20 ± 5) °C; the samples tested in the wet state. The Group 4 consisted the samples were previously exposed to heat in a preheated fan oven, at (80 ± 2) °C, for (60 ± 2) min. The test results can be applied for gluing windows, doors, stairs, high-frequency gluing, veneering panels, etc.

OPTIMIZATION OF THE RESISTANCE SPOT WELDING PROCESS OF SECC-AF AND SGCC GALVANIZED STEEL SHEET USING THE TAGUCHI METHOD

This article present the optimization work describes out to joint the dissimilar galvanized steel of SECC-AF (JIS G 3313) and SGCC (JIS G 3302) material. A zinc coating on the surfaces of the galvanized steel sheets will decrease the weldability characteristic of the material. This study used dissimilar galvanised steel sheets to obtain the highest tensile shear strength from the specified resistance spot welding. This research used the Taguchi method with 4-variables and mixed-experimental levels. The mixed-experimental level, namely 2-experimental levels for the first variable and 3-experimental levels for other variables. The highest tensile shear strength was achieved in 5282.13 N. This condition is achieved at a squeezed time of 20 cycles, 27 kA-welding currents, welding time of 0.5 seconds, and holding time of 18 cycles. The S/N ratio analysis has shown the welding current had the most significant effect, followed by welding time, squeeze time, and holding time. The delta values of S/N ratio were 0.79, 0.64, 0.26 and 0.07, respectively. The ANOVA analysis has shown that the P-value of welding current and welding time is 0.006 (0.6%) and 0.015 (1.5%), respectively. This result is expected for optimizing resistance spot welding quality in other materials or significant aspects.

Interface Characteristics and Bonding Performance of the Corrugated Mg/Al Clad Plate

In this paper, a corrugated Mg/Al clad plate was successfully manufactured by an upper corrugated roller and a lower flat roller at 400 °C rolling temperature and 35% reduction ratio. Interface bonding performance of the corrugated Mg/Al clad plate was studied by tensile-shear test. The finite element method was used to simulate the corrugated rolling process. Experiment results revealed that the Mg/Al clad plate fabricated by corrugated roller had a tight bonding interface, no crack, and no intermetallic compounds. The transverse tensile-shear strength at the trough position reached 31.22 MPa, and the tensile-shear strength at the peak position was 17.61 MPa. It can be found that the stress and strain of interface metal at the trough position were the largest through numerical simulation results. Two cross-shear zones can be formed in the rolling deformation zone of the corrugated Mg/Al clad plate, which can accelerate the metal plastic flow and promote interface close bonding.

Enhancement of the tensile shear strength for joining low-ductility aluminium to high-strength steel by using electrically-assisted mechanical clinching (EAMC)

The present work studied the enhancement of the tensile shear strength for joining AA6061-T6 aluminium to galvanized DP590 steel via electrically-assisted mechanical clinching (EAMC) using an integrated 2D FE model. To defeat the difficulties of joining low-ductility aluminium alloy to high-strength steel, the electroplastic effect obtained from the electrically-assisted process was applied to enhance the clinch-ability. For this purpose, the results of experiments performed by the chamfering punches with and without electrically-assisted pre-heating were compared. Joint cross-section, failure load, failure mode, fracture displacement, material flow, and failure mechanism were assessed in order to study the failure behaviour. The results showed that the joints clinched at the EAMC condition failed with the dominant dimpled mechanism observed on the fracture surface of AA6061 side, achieved from the athermal effect of the electroplasticity. Besides, these joints were strengthened 32% with a much more fracture displacement around 20% compared with non-electrically-assisted pre-heating.

Optimasi parameter resistance spot welding pada pengabungan baja electro-galvanized menggunakan metode Taguchi

The present study features analytical and experimental results of optimizing resistance spot welding performed using a pneumatic (electrode) force system (PFS). This optimization was carried out to incorporate the galvanized steel sheet material SECC-AF (JIS G 3313) and SPCC-SD (JIS 3141) sheet plate coated with zinc with a thickness of about 2.5 microns. The zinc coating on the metal surface causes its weldability to decrease. This study aims to obtain the highest tensile shear strength test results from the combination of the specified resistance spot welding parameters. The research method used the Taguchi method using four variables and a combination of experimental tingkats. This study's experimental tingkat is two tingkats in the first parameter and three tingkats in other parameters. Taguchi optimization results show that the highest tensile shear strength test obtained is 5049.64 N. This was achieved at 22 cycles of squeeze time, 25 kA of welding current, and 0,6-second welding-time, and 12 cycles of holding-time. The S / N ratio analysis found that the welding time had the most significant effect, followed by welding current, holding time, and squeeze time. The delta S / N ratio values were 0.62, 0,41, 0.34 and 0.07, respectively.