Reclined trend of alkyl chain of sodium dodecylbenzenesulfonate molecules induced by friction

Surfactants tend to adsorb on the surface/interface mostly in a directional manner. The alkyl chain orientation and conformation order for molecular monolayers of sodium dodecylbenzenesulfonate (SDBS) at low concentrations are studied by using the sum frequency generation vibrational spectroscopy (SFG-VS). The molecular arrangement of the surfactants adsorbed at the solid/liquid interface is further investigated. It is found that the arrangement of the SDBS at the interface becomes relatively ordered with increasing bulk concentration. Meanwhile, the orientation angle reduces gradually, and the molecules tend to be upright state. In addition, the effect of friction on the conformation order and orientation angle are also analyzed. The intensity of the SDBS vibrational contraction peak becomes lower after friction, which indicates that the anion has a reorientation process at the interface. The arrangement of molecules becomes more disordered due to friction. The orientation angle increases slightly, which indicates the monolayer has an inclined trend relative to the lateral direction on the interface. A modified adsorption model considering friction effect is proposed. This work may provide a reference for the further study of adsorption mechanism and application of surfactants.

The influences of radiation effects on DC/RF performances of Lg=22 nm gate-all-around nanosheet field-effect transistor

In this paper, we carried out detailed TCAD simulations to investigate the radiation effects, e.g., total ionizing dose (TID) and single-event effects (SEEs), on direct current (DC) and radio frequency (RF) characteristics of the gate-all-around (GAA) nanosheet field-effect transistor (FET). The simulation model used is composed of 7-layer stacked GAA nanosheet FET with Lg=22 nm, which was implemented in this study. The open current and the drain-induced barrier lowering of the device are ~ 3mA/μm and 47mV/V, respectively. The results indicate that the TID have little influence on the DC and RF characteristics when the transistor is working in an open state. During the SEEs simulation, we considered three incident directions for the high energy particle, including the lateral direction of the channels, the vertical direction of the channels and the top of the channels. The influence of the particle injecting along the lateral and vertical directions of the channels shows stronger relation with the distance from the incident point compared to the influence of the particle from the top. Besides, the general influence of the particle injecting along the lateral directions of the channels is higher than the other two directions. The total injected charge of the particle injecting along the lateral direction, along the vertical direction and from the top are 3 fC, 1.4 fC and 2.1 fC, respectively. As compared to the FinFET, the GAA nanosheet has superior RF performances and less sensitivity to TID effect. This work can provide a guideline for the GAA nanosheet devices in aerospace and avionic RF applications.

Investigation of Dynamic Responses and Vibration Serviceability of Temporary Grandstands by a 3 DOF Interaction Model due to Swaying Motion

Excessive vibration of temporary grandstand by the crowd has lateral rhythmic motions, which attracted increasing attention in the recent years. This paper focuses on experiments where a temporary grandstand occupied by 20 participants is oscillated by a shaking table with a series of random waves and the crowd-induced rhythmic swaying motions at lateral direction, respectively. The dynamic forces that were induced by participants who have swayed at 0.5–1.8 Hz are recorded by a tri-axial human biomechanics force plate. A new relationship between the annoyance rate and structural acceleration at logarithmic coordinate is investigated and proposed, and the swaying load model is given. Based on these experimental results, a simplified three-degree-of-freedom lumped dynamic model of the joint human–structure system is reinterpreted. Afterwards, combined with a feasible range of crowd/structural dynamic parameters, a series of interaction models are analyzed, the vibration dose value (VDV) of the structure is obtained and discussed, and the notable parameters for interaction model are predicted. The experimental results show that the lateral serviceability limit is 1.29 m/s1.75 and the upper boundary is 2.32 m/s1.75. The dynamic response of model indicated that the VDV of structure will be decreased with increasing the mass of static crowd and damping ratio of the dynamic crowd. The max response of the model is α ≤ 0.6, f2 = 1.8 Hz or α > 0.6, f2 = 1.5 Hz or f1 = 2.5–3.5 Hz. It may be used as a reference value in vibration safety and serviceability assessment of TDGs, to estimate realistically the vibration response on the occasions when the crowds are swaying.

Active Corrosion Protection by Epoxy Coating on Li2CO3-Pretreated Anodized Aluminum Alloy 2024-T3

The fast leaching and robust barrier property of inhibitors are the basic fundamentals for the formation of active protective coatings to protect aluminum alloys. Herein, an active protective surface was developed based on an epoxy coating and an underlying lithium carbonate (Li2CO3)-treated anodized aluminum alloy 2024-T3. The morphology of the Li-LDH layer was studied to know its formation mechanism. The electrochemical studies revealed that the fast and adequate leaching of lithium led to a substantial increment of corrosion resistance of the scratched coating in 3.5 wt% NaCl from 1 to 8 days. Time of flight secondary ion mass spectroscopy (ToF-SIMS) results indicated that Li was distributed in the lateral direction and covered the scratched area. The 3D images indicated that different lithium compounds were formed and 90% of the scratched area was covered with the lithium protective layer over immersion time. A combined approach of morphology observations, electrochemical measurements, and ToF-SIMS showed the lithium protective layer offered good corrosion resistance. On the contrary, lithium provided fast and adequate leaching from the coating, demonstrating good active protection for aluminum and its alloys.

Basic Experimental Evaluation of Fresh and Hardened Properties of Mortar Using Additive Manufacturing

Recently, the three-dimensional concrete printing (3DCP) method has been garnering considerable interest owing to its ability to significantly reduce the construction time. In this study, 3D printing or additive manufacturing was applied to mortar using a small gantry type equipment and the performance of the method was evaluated. The mixture proportioning for good mortar printing and deposition was derived. The parameters of printability, buildability, compressive strength, flexural tensile strength, and anti-washout were considered for the performance evaluation. The results showed good printability with a constant width and no surface defects. In the buildability test, the rate of yield stress development increased, and the rate of change in the layer height decreased as the interlayer time interval increased during underwater printing. The flexural tensile strength of the specimen cast into the mold was lower than that of the specimen extracted from the additive parts owing to the longitudinal confinement during printing. The compressive strength in the lateral direction was slightly higher than that in the perpendicular direction, whereas the compressive strength of the specimen extracted from the part printed underwater was higher than that of the specimen cast into the mold.

Determination of the maximum dangerous width of a rail track on a reinforced concrete base with fasteners of the КБ type, taking into account all influencing factors

Railway track retention standards in Ukraine do not take into account theconstruction of the subrail base, but regulate one for all types maximum dangerous value of the trackwidth, which was changed from 1546 mm to 1548 mm without any justification of scientific researchor explanations of the effects of tolerances the width of the rail track and the wheel track, which ingeneral at that time were not fully investigated but taking into account the emergence anddevelopment of new scientific problems associated with the emergence of intensive lateral wear ofrails and ridges of locomotive and wagon wheels. The deterministic dependences of lateralimpressions of the P65 type rail thread head on the simultaneous influence of vertical and horizontalforces for the newly installed repair profiles of UZ rolling stock on the basis of previously performedexperimental and theoretical studies were investigated. The results allow at this stage of research todetermine and calculate the practical values of the maximum dangerous width of the track, in whichthe subrail base consists of reinforced concrete sleepers and separate rail fasteners, which are usedboth on conventional highways with mixed traffic and on high-speed lines UZ.The article establishes the need to take into account new factors influencing the dangerouswidth of the rail track with intermediate rail fasteners of separate type depending on the load stress of sections and new repair profiles of rolling stock, as well as wear processes of intermediate railfasteners type KБ and its elements on the appearance of elastic backlash in the lateral direction fromthe influence of the guide wheels of the rolling stock. The recommended value of the maximum widthof the rail track for areas where service or emergency braking is applied - 1550 mm, taking intoaccount that the contact of the wheel and the rail is not at a point, but on an ellipse. The establishednorm of the maximum width of a rail track allows to define economic efficiency of introduction in theconditions of operation of a track in curved sections of a track of small radii with limited use of themaximum admissible lateral wear (15 mm) of a head of a rail thread provided that the normal-forcedentry of rolling stock carts.

Effect of Integrated Training on Balance and Ankle Reposition Sense in Ballet Dancers

Objective: To investigate the effects of a 6-week integrated training program on the ankle joint reposition sense and postural stability in ballet dancers. Methods: Sixteen female ballet dancers participated in the study and underwent a 6-week integrated training program consisting of plyometric, proprioception and core stability exercises along with a home program involving additional ankle muscle strengthening and stretching. The ankle joint reposition tests and the parameters of the center of pressure (COP) while performing grand-plie (deep squatting) and releve en demi-pointe (standing on balls of foot) movements were measured before and after training. Results: After 6 weeks, participants showed significantly smaller absolute ankle joint reposition errors in dorsiflexion (p = 0.031), plantarflexion (p = 0.003) and eversion (p = 0.019) compared to the pre-training measurement. Furthermore, after training, a significantly slower average COP speed at pre-equilibrium during grand-plie movement (p = 0.003) and pre-equilibrium phase of releve en demi-pointe (p = 0.023) were observed. In addition, the maximum COP displacement in the medial-lateral direction was significantly smaller at pre-equilibrium phase during grand-plie (p = 0.044) and releve en demi-pointe movements (p = 0.004) after training. Conclusions: The 6-week integrated training program improved the ankle joint reposition sense and postural control in the medial-lateral direction during grand-plie and releve en demi-pointe movements.

RESULTS OF STATIC TESTS OF PROTECTIVE STRUCTURES OF AGRICULTURAL TRACTORS CABINS

The purpose of research is determination of cabin deformation indicators using standardized methods and developed technical means. Research methods. The tests were performed according to the methods described in [DSTU ISO 5700, 2019] using a loading bench, pressure and displacement sensors, digital measuring amplifier Spider 8 and laptop Panasonic CF-19 Touchbook, model: CF-19KHR88PE. Research results. The protective structure AI.209.45.011.00 of the cab of tractors type C25 "Slobozhanets" was provided for testing. Before the tests, the dimensions of the cab structure were measured and recorded. During the first longitudinal loading from front to right, the load was applied to the upper transverse element of the protective structure. The point of application of the load was at a distance of 260 mm from the outer corner of the edge of the protective structure. An even load distribution in the direction perpendicular to the direction of action and along the loading beam was ensured using a sealing element. The value of the energy absorbed by the protective structure was 13100 J (required energy - 12586 J) with a maximum applied force of 82 kN and a displacement of 340 mm. During the first and second compression tests, the structure was loaded vertically with a force of 180 kN along the front and rear upper transverse elements of the protective structure with a holding of the specified force for 5 s. The side load was applied horizontally to the upper right longitudinal element of the protective structure at a distance of 85 mm forward from the control point of the driver's seat. The length of the loading beam was 600 mm. The value of the energy absorbed by the protective structure of 17000 J (required energy - 15732 J) at a maximum applied force of 80 kN and a displacement of 290 mm was achieved. After all test stages, the frontmost point of the protective structure was 70 mm and the front left point was 35 mm. The rear end points were also shifted backwards by 45 mm - right and 30 mm - left. In the lateral direction, the front right extreme point moved forward by 15 mm. After the tests, the free space area was not violated. Conclusions. The methods and technical means used during the tests allow determine the magnitude of the applied forces and deformation with the necessary accuracy and reliability. During the compression tests, the values of the test force (180 kN) were achieved, and during the application of horizontal loads - the energy absorbed by the protective structure (13100 J - longitudinal load and 17000 J - lateral load). The greatest final deformation was suffered by the protective structure at the front extreme point - 70 mm, while the violation of the zone of free space of the driver by the elements of the protective structure is not observed. Therefore, the protective structure AI.209.45.011.00 cab of tractors type C25 "Slobozhanets" withstood static tests for compliance with DSTU ISO 5700.

Forensic examination of a dog's corpse with signs of violent death: A case review

Increasingly, in the media, social networks, we encounter reports of cruelty to animals by companions, which led to their injury or death. Animal cruelty in Ukraine and all over the world, unfortunately, still remains an urgent problem. In this regard, forensic investigators ask veterinary experts questions that are aimed at assessing the severity of the damage, the mechanism of their formation and establishing the cause of death of the animal. According to the pre-trial investigation and the forensic veterinary examination results of the corpse of a dog, which was conducted at the request of investigative authorities in the inquiry of a criminal offense on the grounds of a crime under Part 1. Article. 299 of the Criminal code of Ukraine, the open craniocerebral trauma of a head of a dog with multiple fractures of the facial bones is established. The left eyeball is missing. There is a rupture of the muscular base and the mucous membrane of the tip of the tongue. Open fracture of the mandible with the discrepancy between the symphysis of the right and left arches. During the necropsy, it was noted that the subcutaneous tissue contains a small amount of fat, skeletal muscle is moderately developed, the stomach is empty and the dog's corpse is exhausted. Which indicates that the dog has spent a loong time without proper care of the pet owner. A torn-scalped wound with signs of purulent inflammation and the presence of fly larvae was noted in the head area, which may indicate that the process is 3–7 days old. Extensive left hemorrhage in the meninges of the frontal area and generalized cerebral edema caused by momentary action of a mechanical factor, a blow in the lateral direction were observed during the study of the brain. Traumatic injuries found on the dog's corpse have a lifetime character and are in a direct causal relationship between the injuries and the cause of death of the animal.