Блочные и монокристаллические пленки сплава висмут--сурьма 3-12 ат% с подслоем сурьмы

We investigated the effect of the antimony underlayer (10 nm) on the structure and galvanomagnetic properties of bismuth-antimony solid solution thin films (3-12 at.% Sb). The films were obtained on mica substrates by discrete vacuum evaporation and zone recrystallization. We found that the misorientation of the crystallite plane (111) increases relative to the film plane as well as the crystallite sizes decrease. The antimony underlayer does not change the crystallographic orientation during recrystallization and increases the film adhesion. The change in the galvanomagnetic coefficients when using a sublayer is due to the classical dimensional effect and increasing plane deformation.

Copper-Coated Polypropylene Filter Face Mask with SARS-CoV-2 Antiviral Ability

Face masks will be used to prevent pandemic recurrence and outbreaks of mutant SARS-CoV-2 strains until mass immunity is confirmed. The polypropylene (PP) filter is a representative disposable mask material that traps virus-containing bioaerosols, preventing secondary transmission. In this study, a copper thin film (20 nm) was deposited via vacuum coating on a spunbond PP filter surrounding a KF94 face mask to provide additional protection and lower the risk of secondary transmission. Film adhesion was improved using oxygen ion beam pretreatment, resulting in cuprous oxide formation on the PP fiber without structural deformation. The copper-coated mask exhibited filtration efficiencies of 95.1 ± 1.32% and 91.6 ± 0.83% for NaCl and paraffin oil particles, respectively. SARS-CoV-2 inactivation was evaluated by transferring virus-containing media onto the copper-coated PP filters and subsequently adding Vero cells. Infection was verified using real-time polymerase chain reaction and immunochemical staining. Vero cells added after contact with the copper-coated mask did not express the RNA-dependent RNA polymerase and envelope genes of SARS-CoV-2. The SARS-CoV-2 nucleocapsid immunofluorescence results indicated a reduction in the amount of virus of more than 75%. Therefore, copper-coated antiviral PP filters could be key materials in personal protective equipment, as well as in air-conditioning systems.

Evolution of the Laser-Induced Spallation Technique in Film Adhesion Measurement

Laser-induced spallation is a process in which a stress wave generated from a rapid, high-energy laser pulse initiates the ejection of surface material opposite the surface of laser impingement. Through knowledge of the stress wave amplitude that causes film separation, the adhesion and interfacial properties of a film-on-substrate system are determined. Some advantages of the laser spallation technique are the non-contact loading, development of large stresses (on the order of GPa) and high strain rates, up to 108 /s. The applicability to both relatively thick films, tens of microns, and thin films, tens of nm, make it a unique technique for a wide range of materials and applications. This review combines the available knowledge and experience in laser spallation, as a state-of-the-art measurement tool, in a comprehensive pedagogical publication for the first time. An historical review of adhesion measurement by the laser-induced spallation technique, from its inception in the 1970s through the present day, is provided. An overview of the technique together with the physics governing the laser-induced spallation process, including functions of the absorbing and confining materials, are also discussed. Special attention is given to applications of laser spallation as an adhesion quantification technique in metals, polymers, composites, ceramics, and biological films. A compendium of available experimental parameters is provided that summarizes key laser spallation experiments across these thin film materials. This review concludes with a future outlook for the laser spallation technique, which approaches its semicentennial anniversary.

Development and finishing technology of waterborne UV lacquer-coated wooden flooring

To develop a waterborne wooden flooring coating, the existing problems of the current waterborne coated wooden floorings were analyzed, and their corresponding solutions were considered. In this paper, based on the final effects of a novel waterborne UV wooden floor coating, the authors used a waterborne UV coating with different solids contents, as well as finishing and drying technology to treat the substrate with different tree species. According to the LY/T standard 1859-2009 (2009) and Q/YFL standard 0035-2018 (2018), the performance of the varnish film of the waterborne UV wooden floor coating was determined. The waterborne coating wooden flooring processes and effects of the varnish film were optimized to provide excellent performance. The performance of the varnish film and the developed waterborne coated wooden flooring met the standard requirements: the surface wear-resistance was less than or equal to 0.15 g/100r, the varnish film hardness was greater than or equal to H, the level of varnish film adhesion was less than or equal to 2, and the total volatile organic compounds was less than or equal to 20 µg/m3. This study provided a demonstration and basis for wooden flooring companies to develop a waterborne wooden floor coating.

High-adhesion unlayered films: physical and technological basis of their production

Using the modernized three-electrode ion-plasma sputtering method, high-adhesion Cu-films without underlayer were obtained. Films were deposited on glass-ceramic (sitall) substrates. The film thickness was ~500 nm. In this case, the calculated cooling rate reached ~ 1012–1014 K/s. The adhesion properties of Cu films were investigated by the standard method of mechanical separation of the film from the substrate – the “fungus” method. It is established that such film adhesion is more than 20 MPa. It is determined that the obtained high adhesion depends on bias potential value. Using these Cu films in strip resonators without a sublayer makes it possible to increase their Q-factor by 1.5–1.7 times and thereby significantly reduce the resulting operating noise.