S-Matrix and Anomaly of de Sitter

S-matrix formulation of gravity excludes de Sitter vacua. In particular, this is organic to string theory. The S-matrix constraint is enforced by an anomalous quantum break-time proportional to the inverse values of gravitational and/or string couplings. Due to this, de Sitter can satisfy the conditions for a valid vacuum only at the expense of trivializing the graviton and closed-string S-matrices. At non-zero gravitational and string couplings, de Sitter is deformed by corpuscular 1/N effects, similarly to Witten–Veneziano mechanism in QCD with N colors. In this picture, an S-matrix formulation of Einstein gravity, such as string theory, nullifies an outstanding cosmological puzzle. We discuss possible observational signatures which are especially interesting in theories with a large number of particle species. Species can enhance the primordial quantum imprints to potentially observable level even if the standard inflaton fluctuations are negligible.

Condensation/immersion mode ice-nucleating particles in a boreal environment

Ice-nucleating particle (INP) measurements were performed in the boreal environment of southern Finland at the Station for Measuring Ecosystem–Atmosphere Relations (SMEAR II) in the winter–spring of 2018. Measurements with the Portable Ice Nucleation Chamber (PINC) were conducted at 242 K and 105 % relative humidity with respect to water. The median INP number concentration [INP] during a 6-week measurement period was 13 L−1. The [INP] spanned 3 orders of magnitude and showed a general increase from mid-February until early April. No single dominant local or regional sources of INPs in the boreal environment of southern Finland could be identified. Rather, it is hypothesised that the INPs detected at SMEAR II are a result of long-range transport and dilution of INPs sourced far from the measurement site. Despite high variability, the measured [INP] values fall within the range expected for the [INP] measured elsewhere under similar thermodynamic conditions. The [INP] did not correlate with any of the examined parameters during the entire field campaign, indicating that no one single parameter can be used to predict the [INP] at the measurement location during the examined time period. The absence of a correlation across the entire field campaign also suggests that a variety of particles act as INPs at different times, although it was indirectly determined that ambient INPs are most likely within the size range of 0.1–0.5 µm in diameter on average. On shorter timescales, several particle species correlated well with the [INP]. Depending on the meteorological conditions, black carbon (BC), supermicron biological particles and sub-0.1 µm particles, most likely nanoscale biological fragments such as ice-nucleating macromolecules (INMs), correlated with the INP signal. However, an increase in the concentration of any of these particle species may not necessarily lead to the increase in the [INP]; the reasons for this remain unknown. Limitations of the instrumental set-up and the necessity for future field INP studies are addressed.

A computational study of a multi-solid liquid fluidized bed incorporating inclined channels

Simulations were performed under continuous processing conditions using the 2D continuum model to describe the internal state of a multi-solid system comprising solid particles of different sizes and densities at the same time. The feed consisted of 35 types of solid particle species with five different sizes, 1.70, 1.20, 0.85, 0.60 and 0.35 mm and seven different densities ranging 1400 to 2000 kg/m3. The simulations results have been used to plot the concentration profiles of solid particles along the bed height. The concentration profiles of the solid particles depicted that the fine dense particles, 0.60 mm, having density equal to 1900 kg/m3 and terminal velocity 0.058 m/s moved downwards and discharged into the underflow. However, the low-density coarse particles, 1.20 mm, having density equal to 1400 kg/m3 and terminal velocity 0.068 m/s moved upwards and conveyed to the overflow, hence, showing a separation process based on the density difference. Furthermore, simulation results showed that the particle species having densities close to the value of the separation relative density exhibited higher concentrations along the system height and the suspension within the system was mainly composed of these species.

Condensation/immersion mode ice nucleating particles in a boreal environment

Ice nucleating particle (INP) measurements were performed in the boreal environment of southern Finland at the Station for Measuring Ecosystem-Atmosphere Relations SMEAR II in the winter-spring of 2018. Measurements with the Portable Ice Nucleation Chamber (PINC) were conducted at 242 K and 105 % relative humidity with respect to water. The median INP number concentration [INP] during a six-week measurement period was found to be 13 L−1. [INP] spanned 3 orders of magnitude and showed a general increase from mid-February until early April. No persistent local or regional sources of INPs in the boreal environment of southern Finland could be identified. Rather, it is hypothesised that the INPs at SMEAR II are a result of dilution during long-range transport. Despite high variability, the measured [INP] values fall within the range expected for INP number concentrations measured elsewhere at similar thermodynamic conditions. [INP] did not correlate with any of the examined relevant parameters during the entire field campaign, indicating that no one single parameter can be used to predict the INP number concentration at the measurement location during the examined time period. The absence of correlation across the entire field campaign also suggests that a variety of particles are acting as INPs at different times, although it was indirectly determined that, on average, ambient INPs are most likely in the size range of 0.1–0.5 μm in diameter. On shorter time scales, several particle species correlated well with [INP] implying their potential role as INPs. Depending on the meteorological conditions, signatures of black carbon (BC), supermicron biological particles and sub-0.1 μm particles, most likely nanoscale biological fragments such as ice nucleating macromolecules (INMs), have been found in the INP signal. However, an increase in the concentration of any of these particle species may not necessarily lead to the increase in [INP], reasons for which remain unknown. Limitations of the instrumental setup and the necessity of the future field INP studies are addressed.

Pyrene-based aggregation-induced emission luminogens (AIEgen): structure correlated with particle size distribution and mechanochromism

The morphology of pyrene-based AIEgens changes depending on the water fraction. The different size distribution and morphological changes of nano-particle species play a significant role in enhancing the emission intensity in the aggregated state.

Binary colloidal glasses: linear viscoelasticity and its link to the microscopic structure and dynamics

We determine the contributions of each particle species to the macroscopic rheology of highly asymmetric binary colloidal mixtures.