Modeling Dislocation-Mediated Hydrogen Transport and Trapping in Fcc Metals

The diffusion of hydrogen in metals is of interest due to the deleterious influence of hydrogen on material ductility and fracture resistance. It is becoming increasingly clear that hydrogen transport couples significantly with dislocation activity. In this work, we employ a coupled diffusion-crystal plasticity model to incorporate hydrogen transport associated with dislocation sweeping and pipe diffusion in addition to standard lattice diffusion. Moreover, we consider generation of vacancies via plastic deformation and stabilization of vacancies via trapping of hydrogen. The proposed hydrogen transport model is implemented in a physically-based crystal viscoplasticity framework to model the interaction of dislocation substructure and hydrogen migration. In this study, focus is placed on hydrogen transport and trapping within the intense deformation field of a crack tip plastic zone. We discuss the implications of the model results in terms of constitutive relations that incorporate hydrogen effects on crack tip field behavior and enable exploration of hydrogen embrittlement mechanisms.

Microscopic Image Segmentation and Morphological Characterization of Novel Chitosan/Silica Nanoparticle/Nisin Films Using Antimicrobial Technique for Blueberry Preservation

In the current work, the characterization of novel chitosan/silica nanoparticle/nisin films with the addition of nisin as an antimicrobial technique for blueberry preservation during storage is investigated. Chitosan/Silica Nanoparticle/N (CH-SN-N) films presented a stable suspension as the surface loads (45.9 mV) and the distribution was considered broad (0.62). The result shows that the pH value was increased gradually with the addition of nisin to 4.12, while the turbidity was the highest at 0.39. The content of the insoluble matter and contact angle were the highest for the Chitosan/Silica Nanoparticle (CH-SN) film at 5.68%. The use of nano-materials in chitosan films decreased the material ductility, reduced the tensile strength and elongation-at-break of the membrane. The coated blueberries with Chitosan/Silica Nanoparticle/N films reported the lowest microbial contamination counts at 2.82 log CFU/g followed by Chitosan/Silica Nanoparticle at 3.73 and 3.58 log CFU/g for the aerobic bacteria, molds, and yeasts population, respectively. It was observed that (CH) film extracted 94 regions with an average size of 449.10, at the same time (CH-SN) film extracted 169 regions with an average size of 130.53. The (CH-SN-N) film presented the best result at 5.19%. It could be observed that the size of the total region of the fruit for the (CH) case was the smallest (1663 pixels), which implied that the fruit lost moisture content. As a conclusion, (CH-SN-N) film is recommended for blueberry preservation to prolong the shelf-life during storage.

Structure–Property Relationships in Bionanocomposites for Pipe Extrusion Applications

In this work, bionanocomposites based on different biodegradable polymers and two types of nanofillers, namely a nanosized calcium carbonate and an organomodified nanoclay, were produced through melt extrusion, with the aim to evaluate the possible applications of these materials as a potential alternative to traditional fossil fuel-derived polyolefins, for the production of irrigation pipes. The rheological behavior of the formulated systems was thoroughly evaluated by exploiting different flow regimes, and the obtained results indicated a remarkable effect of the introduced nanofillers on the low-frequency rheological response, especially in nanoclay-based bionanocomposites. Conversely, the shear viscosity at a high shear rate was almost unaffected by the presence of both types of nanofillers, as well as the rheological response under nonisothermal elongational flow. In addition, the analysis of the mechanical properties of the formulated materials indicated that the embedded nanofillers increased the elastic modulus when compared to the unfilled counterparts, notwithstanding a slight decrease of the material ductility. Finally, the processing behavior of unfilled biopolymers and bionanocomposites was evaluated, allowing for selecting the most suitable material and thus fulfilling the processability requirements for pipe extrusion applications.

Model of the Ultimate Stress State of the Coated Tool Cutter Material

The article proposes a model of the ultimate stress state of the material of the coated tool cutter. It is found that with an increase in the fracture toughness of a tool in connection with the material ductility the machining accuracy deteriorates due to arising elastic-plastic vibrations of the tool cutter. In case when no ultimate stress state is reached, that is, a tool operates in the elastic region, then an alternating stress distribution diagram is realized for the tool cutter at the beam approximation. Therefore, in addition to the frictional vibrations, arising from the interaction between the tool cutter and a workpiece, the elastic vibrations can arise, which affects the machining accuracy and the service life of the coated tool cutter. The use of coatings makes it possible not only to increase the wear resistance of cutting tools, but also to transform the stress distribution diagrams of the normal σN and tangential τγ contact stresses acting on the rake face of the cutting tool. In particular, it is possible to control the length of the total contact area between the chips and the tool rake face.

The Effect of Grain Size on the Susceptibility Towards Strain Age Cracking of Wrought Haynes® 282®

The effect of grain size on the suceptibility towards strain age cracking (SAC) has been investigated for Haynes® 282® in the tempeature range of 750 to 950∘C after isothermal exposure up to 1800s. Grain growth was induced by heat treating the material at 1150∘C for 2h, resulting in a fourfold increase in grain size. Hardness was significanlty reduced after heat treatment as compared to mill-annealed material. Large grain size resulted in intergranular fracture over a wider temperature range than small grain size material. Ductility was lowest at 850∘C, while lower values were observed to be correlated to increased grain size. The rapid formation of grain boundary carbide networks in Haynes® 282® is found to be not able to compensate for higher local stresses on grain boundaries due to incresed grain size.

Weld Hydrogen Cracking Susceptibility

Weld hydrogen cracking has been recognized as an issue of concern and a wide range of hardenability criteria and single pass weld testing techniques have been developed to demonstrate material weldability, however, hydrogen cracks continue to be identified in welds. The potential for hydrogen cracking is related to the presence of hydrogen, the local tensile strain state and the susceptibility of the material microstructure. The weldment slow bend test and hydrogen effusion and cracking model has been used in Pipeline Research Council International (PRCI) research reported in this paper to support the development of an understanding of the interaction of these factors in promoting hydrogen cracking. The slow bend testing procedure is described with examples of the effects of increasing hydrogen and/or strain conditions are used to illustrate hydrogen cracking susceptibility. The slow bend testing procedure was applied to a range of steel weld metals to develop an understanding of the factors which make one more or less susceptible to hydrogen cracking. Combining the results of slow bend testing, the susceptibility of deposited shielded metal arc weld material to hydrogen cracking is defined using a hydrogen susceptibility curve that establishes the critical strain to form a crack as a function of hydrogen concentration. Cracking susceptibility is described through the definition of material ductility and embrittlement indices, which are derived from the hydrogen susceptibility curves. Cracking susceptibility is then correlated with mechanical, chemical and microstructure properties of the deposited welds. This model to predict weld metal hydrogen cracking susceptibility was developed to support electrode selection and welding procedure development to preclude hydrogen cracking. The results in this paper can be used to reduce the risk of hydrogen cracking and support the development of industry guidance.

Quantification of the Material Ductility Effect on Notch Fracture Toughness Using Numerical Damage Analysis Method

In this study, the finite element (FE) damage analysis based on the multi-axial fracture strain model was applied to investigate the effect of the material ductility on fracture resistance of notched defect. (The fracture toughness is used only for a cracked specimen and the fracture resistance is used for notched specimens throughout the paper.) To obtain the material property with different ductility, the tensile and fracture toughness tests of the cold-worked SUS316 were used. The damage model was determined from comparing the experimental data with simulated FE analysis results. Then the FE analysis was applied to calculate the fracture resistance according to the notch radius in each material. It shows that the slope of initiation resistance according to the notch radius was related to the material ductility. To quantify this effect of ductility, the relationship between notch fracture resistance and material tensile properties was confirmed.