Exceptional points in composite structures consisting of two dielectric diffraction gratings with Lorentzian line shape

Using scattering matrix formalism we derive analytical expressions for the eigenmodes of a composite structure consisting of two dielectric diffraction gratings with Lorentzian profile in reflection. Analyzing these expressions we prove formation of two distinct pairs of exceptional points, provide analytical approximations for their coordinates and by rigorous simulation demonstrate eigenmodes interchange as a result of encircling said exceptional points.

One-Dimensional Topological Photonic Crystal Mirror Heterostructure for Sensing

A paradigm for high-quality factor (Q) with a substantial fulfillment for appraising sensing ability and performance has been investigated. Through constructing a 1D (one-dimensional) topological photonic crystal (PhC) mirror heterostructure, which is formed by the image view of 1D topological PhC stacking with its original one. In the 1D topological PhC-mirror heterostructure, there is an interesting mode that appeared with the symmetric, typical Lorentzian-line shape with 100% transmittance in the topological mirror edge-state mode (hybrid resonance mode) at the heterostructure interface. Physically, such a mode is a defect mode, but the defect is introduced through topological operations. The high Q-factor of 5.08 × 104 is obtained due to the strong optical localization of the defect mode at the topological edge area. Consequently, this device acts as a narrow passband filter. Moreover, due to the narrow bandpass property, it may be an advantageous reference for many applications in filtering, switching, and sensing. Thus, introducing an electro-optical (EO) polymer layer at the interface to modify the edge defect can tune the defect mode both in frequency and Q-factor for higher spatial pulse compression and higher EO sensitivity. Accordingly, the Q-factor of 105, the sensitivity of 616 nm/RIU, and the figure of merit of 49,677.42 RIU−1 are obtained. The sensing ability and performance are attributable to the strong optical localization in the interface region and enhanced light-matter interaction. We predict that the 1D topological PhC mirror heterostructure will be an outstanding point in the field of optical sensing, filters, and optical switching in different fields.

An R-Package for the Deconvolution and Integration of 1D NMR Data: MetaboDecon1D

NMR spectroscopy is a widely used method for the detection and quantification of metabolites in complex biological fluids. However, the large number of metabolites present in a biological sample such as urine or plasma leads to considerable signal overlap in one-dimensional NMR spectra, which in turn hampers both signal identification and quantification. As a consequence, we have developed an easy to use R-package that allows the fully automated deconvolution of overlapping signals in the underlying Lorentzian line-shapes. We show that precise integral values are computed, which are required to obtain both relative and absolute quantitative information. The algorithm is independent of any knowledge of the corresponding metabolites, which also allows the quantitative description of features of yet unknown identity.

Role of the paramagnetic donor-like defects in the high n-type conductivity of the hydrogenated ZnO microparticles

The magnetic and electronic properties of the hydrogenated highly conductive zinc oxide (ZnO) microparticles were investigated by electron paramagnetic resonance (EPR) and contactless microwave (MW) conductivity techniques in the wide temperature range. The EPR spectra simulation allowed us to resolve four overlapping EPR signals in ZnO microparticles. The Lorentzian EPR line with isotropic g-factor 1.9623(5) was related to the singly ionized oxygen vacancy. Another Lorentzian line with g|| = 1.9581(5), g⊥ = 1.9562(5) was attributed to the zinc interstitial shallow donor center, while EPR signal with g|| = 1.9567(5), g⊥ = 1.9556(5) and Gaussian lineshape was assigned to the hydrogen interstitial shallow effective-mass-like donor. The EPR signal with g|| = 1.9538(5), g⊥ = 1.9556(5) and Lorentzian lineshape was tentatively attributed to the shallow donor center. The charge transport properties in ZnO microparticles have been investigated by the contactless MW conductivity technique at T = 5–296 K. Two conduction mechanisms, including ionization of electrons from the shallow donors to the conduction band and hopping conduction process, have been distinguished. The hopping conduction process follows Mott’s variable-range hopping T−1/4 law at T = 10–100 K. The evaluated values of the average hopping distance (15.86 Å), and hopping energy (1.822 meV at 40 K) enable us to estimate the donor concentration in the investigated ZnO microparticles as ~ 1018 cm−3.

Nanoscale spectroscopic origins of photoinduced tip–sample force in the midinfrared

When light illuminates the junction formed between a sharp metal tip and a sample, different mechanisms can contribute to the measured photoinduced force simultaneously. Of particular interest are the instantaneous force between the induced dipoles in the tip and in the sample, and the force related to thermal heating of the junction. A key difference between these 2 force mechanisms is their spectral behavior. The magnitude of the thermal response follows a dissipative (absorptive) Lorentzian line shape, which measures the heat exchange between light and matter, while the induced dipole response exhibits a dispersive spectrum and relates to the real part of the material polarizability. Because the 2 interactions are sometimes comparable in magnitude, the origin of the chemical selectivity in nanoscale spectroscopic imaging through force detection is often unclear. Here, we demonstrate theoretically and experimentally how the light illumination gives rise to the 2 kinds of photoinduced forces at the tip–sample junction in the midinfrared. We comprehensively address the origin of the spectroscopic forces by discussing cases where the 2 spectrally dependent forces are entwined. The analysis presented here provides a clear and quantitative interpretation of nanoscale chemical measurements of heterogeneous materials and sheds light on the nature of light–matter coupling in optomechanical force-based spectronanoscopy.

Magneto-Electroluminescence in ITO/MEH-PPV:PEO:LiCF3SO3/Al Polymer Light-Emitting Electrochemical Cells

Magnetic field effects (MFE) have been extensively studied in organic light emitting diodes because of their potential application in organic spintronics devices. However, only a few studies on MFE in organic light-emitting electrochemical cells (LEC) have been reported. In this paper, magnetic field effects on the electroluminescence of an LEC device with the structure of ITO/MEH-PPV:PEO:LiCF3SO3/Al were studied at various temperatures. The luminance–current–voltage curves of the device shows the typical bi-polar characteristics of LECs; positive magnetic electroluminescence (MEL) was observed with a value of about 2.5% (B = 42 mT, 250 K), showing a Lorentzian line shape. With a decrease in temperature, the MEL value and the threshold voltage increased accordingly, below the possible mechanism is discussed.

Detection of thermodynamic “valley noise” in monolayer semiconductors: Access to intrinsic valley relaxation time scales

Together with charge and spin, many novel two-dimensional materials also permit information to be encoded in an electron’s valley degree of freedom—that is, in particular momentum states in the material’s Brillouin zone. With a view toward valley-based (opto)electronic technologies, the intrinsic time scales of valley scattering are therefore of fundamental interest. Here, we demonstrate an entirely noise-based approach for exploring valley dynamics in monolayer transition-metal dichalcogenide semiconductors. Exploiting their valley-specific optical selection rules, we use optical Faraday rotation to passively detect the thermodynamic fluctuations of valley polarization in a Fermi sea of resident carriers. This spontaneous “valley noise” reveals narrow Lorentzian line shapes and, therefore, long exponentially-decaying intrinsic valley relaxation. Moreover, the noise signatures validate both the relaxation times and the spectral dependence of conventional (perturbative) pump-probe measurements. These results provide a viable route toward quantitative measurements of intrinsic valley dynamics, free from any external perturbation, pumping, or excitation.

Line Shapes

Line shapes describe how absorption and emission are spectrally distributed around the line positions formed by rotational, vibrational, and electronic transitions. Line shapes arise from the different processes that spectrally broaden the absorption and emission of radiation. Optical thickness and equivalent width are shown to be fundamentally related to line shape. The fundamental line shape functions for atmospheres including the Gaussian line shape due to molecular motion and the Lorentzian line shape from lifetime broadening, including collision (pressure) broadening are described. Their convolution, the Voigt line shape, which is important in some atmospheric conditions is also described. The standard HITRAN database of spectroscopic parameters of molecules for use in calculation of radiative transfer in planetary atmospheres, from radiofrequencies to the near ultraviolet, is introduced.