scholarly journals Nanoscale spectroscopic origins of photoinduced tip–sample force in the midinfrared

2019 ◽  
Vol 116 (52) ◽  
pp. 26359-26366 ◽  
Author(s):  
Junghoon Jahng ◽  
Eric O. Potma ◽  
Eun Seong Lee
Keyword(s):  
Thermal Response ◽  
Light Illumination ◽  
Force Detection ◽  
Lorentzian Line ◽  
Chemical Measurements ◽  
Induced Dipole ◽  
Metal Tip ◽  
Dipole Response ◽  
Chemical Selectivity ◽  
Induced Dipoles

When light illuminates the junction formed between a sharp metal tip and a sample, different mechanisms can contribute to the measured photoinduced force simultaneously. Of particular interest are the instantaneous force between the induced dipoles in the tip and in the sample, and the force related to thermal heating of the junction. A key difference between these 2 force mechanisms is their spectral behavior. The magnitude of the thermal response follows a dissipative (absorptive) Lorentzian line shape, which measures the heat exchange between light and matter, while the induced dipole response exhibits a dispersive spectrum and relates to the real part of the material polarizability. Because the 2 interactions are sometimes comparable in magnitude, the origin of the chemical selectivity in nanoscale spectroscopic imaging through force detection is often unclear. Here, we demonstrate theoretically and experimentally how the light illumination gives rise to the 2 kinds of photoinduced forces at the tip–sample junction in the midinfrared. We comprehensively address the origin of the spectroscopic forces by discussing cases where the 2 spectrally dependent forces are entwined. The analysis presented here provides a clear and quantitative interpretation of nanoscale chemical measurements of heterogeneous materials and sheds light on the nature of light–matter coupling in optomechanical force-based spectronanoscopy.

Measurements and analysis of rototranslational absorption spectra of low density H2–Ar mixtures

1988 ◽  
Vol 66 (9) ◽  
pp. 803-809 ◽  
Author(s):  
P. Dore ◽  
A. Filabozzi ◽  
G. Birnbaum
Keyword(s):  
Shape Analysis ◽  
Line Shape ◽  
Low Frequency ◽  
Frequency Component ◽  
Low Density ◽  
Spectral Moment ◽  
Line Shape Analysis ◽  
Induced Dipole ◽  
Good Agreement ◽  
Induced Dipoles

We present new measurements of the rototranslational absorption of H2–Ar mixtures at 195 and 298 K. Measurements were made at densities as low as possible. The first accurate (5% error) rototranslational spectrum of the H2–Ar pair was thus derived. We performed a line-shape analysis of these spectra; as a result, we found a low-frequency component associated with an isotropic overlap induced dipole. We also found an important anisotropic overlap contribution associated with the dominant quadrupolar induction. Through a spectral-moment analysis we determined the intensity of isotropic (λ0 = 2.35 ± 0.15 × 10−3ea0) and anisotropic (λ1 = 0.9 ± 0.1 × 10−3ea0) overlap induced dipoles. The range of the isotropic overlap induced dipole was found to be ρ0 = (0.105 ± 0.010)σ, in very good agreement with the value 0.11 σ frequently assumed in the literature for the range of overlap induced dipoles. Our measurements and the results of our analysis were in good agreement with results of recent computations.

scholarly journals Detecting Subsecond Dopamine Release with Fast-Scan Cyclic Voltammetry in Vivo

2003 ◽  
Vol 49 (10) ◽  
pp. 1763-1773 ◽  
Author(s):  
Donita L Robinson ◽  
B Jill Venton ◽  
Michael L A V Heien ◽  
R Mark Wightman
Keyword(s):  
Cyclic Voltammetry ◽  
Dopamine Neurons ◽  
Fast Scan Cyclic Voltammetry ◽  
Extracellular Dopamine ◽  
Chemical Measurements ◽  
Concentration Changes ◽  
Motivated Behaviors ◽  
Chemical Selectivity ◽  
Suitable Technique

Abstract Background: Dopamine is a potent neuromodulator in the brain, influencing a variety of motivated behaviors and involved in several neurologic diseases. Measurements of extracellular dopamine in the brains of experimental animals have traditionally focused on a tonic timescale (minutes to hours). However, dopamine concentrations are now known to fluctuate on a phasic timescale (subseconds to seconds). Approach: Fast-scan cyclic voltammetry provides analytical chemical measurements of phasic dopamine signals in the rat brain. Content: Procedural aspects of the technique are discussed, with regard to appropriate use and in comparison with other methods. Finally, examples of data collected using fast-scan cyclic voltammetry are summarized, including naturally occurring dopamine transients and signals arising from electrical stimulation of dopamine neurons. Summary: Fast-scan cyclic voltammetry offers real-time measurements of changes in extracellular dopamine concentrations in vivo. With its subsecond time resolution, micrometer-dimension spatial resolution, and chemical selectivity, it is the most suitable technique currently available to measure transient concentration changes of dopamine.

Microcalorimeters for X-Ray Spectroscopy

1988 ◽  
Vol 102 ◽  
pp. 41
Author(s):  
E. Silver ◽  
C. Hailey ◽  
S. Labov ◽  
N. Madden ◽  
D. Landis ◽  
...  
Keyword(s):  
High Resolution ◽  
High Efficiency ◽  
Thermal Response ◽  
Low Noise ◽  
High Resolution Spectroscopy ◽  
Superconducting Transition ◽  
Sapphire Substrates ◽  
Laboratory Plasmas ◽  
Adiabatic Demagnetization ◽  
Theoretical Predictions

The merits of microcalorimetry below 1°K for high resolution spectroscopy has become widely recognized on theoretical grounds. By combining the high efficiency, broadband spectral sensitivity of traditional photoelectric detectors with the high resolution capabilities characteristic of dispersive spectrometers, the microcalorimeter could potentially revolutionize spectroscopic measurements of astrophysical and laboratory plasmas. In actuality, however, the performance of prototype instruments has fallen short of theoretical predictions and practical detectors are still unavailable for use as laboratory and space-based instruments. These issues are currently being addressed by the new collaborative initiative between LLNL, LBL, U.C.I., U.C.B., and U.C.D.. Microcalorimeters of various types are being developed and tested at temperatures of 1.4, 0.3, and 0.1°K. These include monolithic devices made from NTD Germanium and composite configurations using sapphire substrates with temperature sensors fabricated from NTD Germanium, evaporative films of Germanium-Gold alloy, or material with superconducting transition edges. A new approache to low noise pulse counting electronics has been developed that allows the ultimate speed of the device to be determined solely by the detector thermal response and geometry. Our laboratory studies of the thermal and resistive properties of these and other candidate materials should enable us to characterize the pulse shape and subsequently predict the ultimate performance. We are building a compact adiabatic demagnetization refrigerator for conveniently reaching 0.1°K in the laboratory and for use in future satellite-borne missions. A description of this instrument together with results from our most recent experiments will be presented.

Experiments with a scanning tunneling microscope (STM) mounted in a scanning electron microscope (SEM)

1986 ◽  
Vol 44 ◽  
pp. 636-639
Author(s):  
Oliver C. Wells ◽  
Mark E. Welland
Keyword(s):  
Electron Microscope ◽  
Scanning Electron Microscope ◽  
Mechanical Stability ◽  
Tunneling Current ◽  
Feedback System ◽  
Scanning Tunneling ◽  
Surface Profiling ◽  
Close Proximity ◽  
Metal Tip ◽  
Scanning Electron

Scanning tunneling microscopes (STM) exist in two versions. In both of these, a pointed metal tip is scanned in close proximity to the specimen surface by means of three piezos. The distance of the tip from the sample is controlled by a feedback system to give a constant tunneling current between the tip and the sample. In the low-end STM, the system has a mechanical stability and a noise level to give a vertical resolution of between 0.1 nm and 1.0 nm. The atomic resolution STM can show individual atoms on the surface of the specimen.A low-end STM has been put into the specimen chamber of a scanning electron microscope (SEM). The first objective was to investigate technological problems such as surface profiling. The second objective was for exploratory studies. This second objective has already been achieved by showing that the STM can be used to study trapping sites in SiO2.

Low-light-level three-dimensional video microscope with long working distance objective lenses

1994 ◽  
Vol 52 ◽  
pp. 226-227
Author(s):  
W. Lin ◽  
J. Gregorio ◽  
T.J. Holmes ◽  
D. H. Szarowski ◽  
J.N. Turner
Keyword(s):  
Three Dimensional ◽  
Light Level ◽  
Stereo Pair ◽  
Light Illumination ◽  
Initial Image ◽  
Low Light ◽  
Image Recording ◽  
Depth Discrimination ◽  
Video Microscope ◽  
Working Distance

A low-light level video microscope with long working distance objective lenses has been built as part of our integrated three-dimensional (3-D) light microscopy workstation (Fig. 1). It allows the observation of living specimens under sufficiently low light illumination that no significant photobleaching or alternation of specimen physiology is produced. The improved image quality, depth discrimination and 3-D reconstruction provides a versatile intermediate resolution system that replaces the commonly used dissection microscope for initial image recording and positioning of microelectrodes for neurobiology. A 3-D image is displayed on-line to guide the execution of complex experiments. An image composed of 40 optical sections requires 7 minutes to process and display a stereo pair.The low-light level video microscope utilizes long working distance objective lenses from Mitutoyo (10X, 0.28NA, 37 mm working distance; 20X, 0.42NA, 20 mm working distance; 50X, 0.42NA, 20 mm working distance). They provide enough working distance to allow the placement of microelectrodes in the specimen.

Numerical simulation of the tree higro-thermal response in forest fire environment

2020 ◽  
pp. 57-65
Author(s):  
Eusébio Conceiçã ◽  
João Gomes ◽  
Maria Manuela Lúcio ◽  
Jorge Raposo ◽  
Domingos Xavier Viegas ◽  
...  
Keyword(s):  
Forest Fire ◽  
Numerical Study ◽  
Thermal Response ◽  
View Factor ◽  
Tree Model ◽  
Pine Tree ◽  
Surface Temperatures ◽  
Fire Environment ◽  
Fire Front ◽  
Heat Exchanges

This paper refers to a numerical study of the hypo-thermal behaviour of a pine tree in a forest fire environment. The pine tree thermal response numerical model is based on energy balance integral equations for the tree elements and mass balance integral equation for the water in the tree. The simulation performed considers the heat conduction through the tree elements, heat exchanges by convection between the external tree surfaces and the environment, heat exchanges by radiation between the flame and the external tree surfaces and water heat loss by evaporation from the tree to the environment. The virtual three-dimensional tree model has a height of 7.5 m and is constituted by 8863 cylindrical elements representative of its trunks, branches and leaves. The fire front has 10 m long and a 2 m high. The study was conducted taking into account that the pine tree is located 5, 10 or 15 m from the fire front. For these three analyzed distances, the numerical results obtained regarding to the distribution of the view factors, mean radiant temperature and surface temperatures of the pine tree are presented. As main conclusion, it can be stated that the values of the view factor, MRT and surface temperatures of the pine tree decrease with increasing distance from the pine tree in front of fire.

A New Scanning Thermal Microprobe

1997 ◽  
Vol 503 ◽  
Author(s):  
Yongxia Zhang ◽  
Yanwei Zhang ◽  
Juliana Blaser ◽  
T. S. Sriiram ◽  
R. B. Marcus
Keyword(s):  
Thin Film ◽  
High Resolution ◽  
Thermal Response ◽  
Temperature Sensing ◽  
Thermal Sensor ◽  
Atomic Force ◽  
Thin Film Thermocouple ◽  
Processing Steps ◽  
Thermocouple Junction

ABSTRACTA thermal microprobe has been designed and built for high resolution temperature sensing. The thermal sensor is a thin-film thermocouple junction at the tip of an Atomic Force Microprobe (AFM) silicon probe needle. Only wafer-stage processing steps are used for the fabrication. The thermal response over the range 25–s 4.5–rovolts per degree C and is linear.

Efficient Treatment of Fixed and Induced Dipolar Interactions

2000 ◽  
Vol 653 ◽  
Author(s):  
Celeste Sagui ◽  
Thoma Darden
Keyword(s):  
Molecular Dynamics ◽  
Md Simulations ◽  
Lagrangian Formalism ◽  
Dipolar Interactions ◽  
Time Step ◽  
Efficient Treatment ◽  
Particle Mesh Ewald ◽  
Fixed Charges ◽  
Self Consistency ◽  
Induced Dipoles

AbstractFixed and induced point dipoles have been implemented in the Ewald and Particle-Mesh Ewald (PME) formalisms. During molecular dynamics (MD) the induced dipoles can be propagated along with the atomic positions either by interation to self-consistency at each time step, or by a Car-Parrinello (CP) technique using an extended Lagrangian formalism. The use of PME for electrostatics of fixed charges and induced dipoles together with a CP treatment of dipole propagation in MD simulations leads to a cost overhead of only 33% above that of MD simulations using standard PME with fixed charges, allowing the study of polarizability in largemacromolecular systems.

Effect of Illumination on Organic Polymer Thin-Film Transistors

2003 ◽  
Vol 771 ◽  
Author(s):  
Michael C. Hamilton ◽  
Sandrine Martin ◽  
Jerzy Kanicki
Keyword(s):  
Thin Film ◽  
Thin Film Transistors ◽  
Drain Current ◽  
Charge Carriers ◽  
Electrical Performance ◽  
Organic Polymer ◽  
Light Illumination ◽  
Polymer Thin Film ◽  
Channel Region ◽  
White Light Illumination

AbstractWe have investigated the effects of white-light illumination on the electrical performance of organic polymer thin-film transistors (OP-TFTs). The OFF-state drain current is significantly increased, while the drain current in the strong accumulation regime is relatively unaffected. At the same time, the threshold voltage is decreased and the subthreshold slope is increased, while the field-effect mobility of the charge carriers is not affected. The observed effects are explained in terms of the photogeneration of free charge carriers in the channel region due to the absorbed photons.

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