Geotechnical characterization of Beka-Gotto rock massif (Adamawa Region-Cameroon) for the use in civil engineering

Beka-Gotto is a village of Ngaoundal located in the Adamawa region (Cameroon). The present study is carried out to determine the physical and mechanical characteristics of the local rock massifs, in order to determine their possible uses in various fields of civil engineering. The methodology used consists of petrographic and geotechnical characterization of the different massifs. The rocks crop outas domes or slabs. The rock is light gray. Under the microscope, the rock presents a grainy microstructure composed of plagioclase, potassium feldspar, biotite and quartz. Zircon and opaque minerals represent the accessory phase. With this composition, rock is granodiorite. The geotechnical study, on the other hand, made it possible to understand that, on the physical level, the rock massif has very good properties. In fact, the specific weight on class 6/10 and 10/14 obtained has mean values of ​​2.73 and 2.68 kN/m3 respectively. While the apparent density obtained of the class 6/10 and 10/14 has mean values 1.35 and 1.46 g/cm3 respectively. Mechanically, Los Angeles coefficient is 24-46.3% while the Micro-Deval coefficient is 7-35% and the coefficient of dynamic fragmentation is 18-30%. In accordance with geotechnical standards, with the exception of the Gbago massif, the other massifs have a choc resistance and a wear resistance of satisfactory to limited grade as well as good resistance to dynamic fragmentation and therefore usable in any type of structure.

Influence of accessory phases and surrogate type on accelerated leaching of zirconolite wasteforms

A fraction of the UK Pu inventory may be immobilised in a zirconolite ceramic matrix prior to disposal. Two zirconolite compositions, targeting CaZr0.80Ce0.20Ti2O7 and CaZr0.80U0.20Ti2O7, were fabricated by hot isostatic pressing, alongside a reformulated composition, nominally Ca0.80Zr0.90Ce0.30Ti1.60Al0.40O7, with an excess of Ti and Zr added to preclude the formation of an accessory perovskite phase. Materials were subjected to accelerated leaching in a variety of acidic and alkaline media at 90 °C, over a cumulative period of 14 d. The greatest Ce release was measured from CaZr0.80Ce0.20Ti2.00O7 exposed to 1 M H2SO4, for which 14.7 ± 0.2% of the original Ce inventory was released from the wasteform into solution. The extent of Ce leaching into the solution was correlated with the quantity of perovskite present in the wasteform, and associated with the incorporation and preferential dissolution of Ce3+. CaZr0.80U0.20Ti2.00O7 exhibited improved leach resistance relative to CaZr0.80Ce0.20Ti2.00O7, attributed to the decreased proportion of accessory perovskite, with 7.1 ± 0.1% U released to in 8 M HNO3 after 7 d. The Ca0.80Zr0.90Ce0.30Ti1.60Al0.40O7 composition, with no accessory perovskite phase, presented significantly improved leaching characteristics, with < 0.4%Ce released in both 8 M HNO3 and 1 M H2SO4. These data demonstrate the need for careful compositional design for zirconolite wasteforms with regard to accessory phase formation and surrogate choice.

Monazite Microstructures and Their Interpretation in Petrochronology

The phosphate mineral monazite (LREE,Y,Th,Ca,Si)PO4 occurs as an accessory phase in peraluminous granites and Ca-poor meta-psammopelites. Due to negligible common Pb and very low Pb diffusion rates at high temperatures, monazite has received increasing attention in geochronology. As the monazite grain sizes are mostly below 100 μm in upper greenschist to amphibolite facies meta-psammopelites, and rarely exceed 250 μm in granulite facies gneisses and in migmatites, microstructural observation and mineral chemical analysis need the investigation by scanning electron microscope and electron probe microanalyzer, with related routines of automated mineralogy. Not only the microstructural positions, sizes and contours of the grains, but also their internal structures in backscattered electron imaging gray tones, mainly controlled by the Th contents, can be assessed by this approach. Monazite crystallizes mostly euhedral to anhedral with more or less rounded crystal corners. There are transitions from elliptical over amoeboid to strongly emarginated grain shapes. The internal structures of the grains range from single to complex concentric over systematic oszillatory zonations to turbulent and cloudy, all with low to high contrast in backscattered electron imaging gray tones. Fluid-mediated partial alteration and coupled dissolution-reprecipitation can lead to Th-poor and Th-rich rim zones with sharp concave boundaries extending to the interior. Of particular interest is the corona structure with monazite surrounded by apatite and allanite, which is interpreted to result from a replacement during retrogression. The satellite structure with an atoll-like arrangement of small monazites may indicate re-heating after retrogression. Cluster structures with numerous small monazite grains, various aggregation structures and coating suggest nucleation and growth along heating or/and enhanced fluid activity. Microstructures of monazite fluid-mediated alteration, decomposition and replacement are strongly sutured grain boundaries and sponge-like porosity and intergrowth with apatite. Garnet-bearing assemblages allow an independent reconstruction of the pressure-temperature evolution in monazite-bearing meta-psammopelites. This provides additional potential for evaluation of the monazite microstructures, mineral chemistry and Th-U-Pb ages in terms of clockwise and counterclockwise pressure-temperature-time-deformation paths of anatectic melting, metamorphism and polymetamorphism. That way, monazite microstructures serve as unique indicators of tectonic and geodynamic scenarios.

Preliminary petrographic study of dolerites related to Sb-Au mineralizations: example of Ribeiro da Serra mine (Dúrico-Beirão mining district, NW Portugal)

&lt;p&gt;In the D&amp;#250;rico-Beir&amp;#227;o mining district, several occurrences of Sb-Au are known, which were exploited since the Roman occupation in Iberia until mid-last century. This region is located in the Central Iberian Zone of the Iberian Massif, part of the Ibero-Armorican Arc. The country rocks in the area consist of folded metasedimentary rocks from Cambrian to Carboniferous surrounded by syn- to post-orogenic Variscan granites. The Ribeiro da Serra Sb-Au mine, intensively exploited in the 19&lt;sup&gt;th&lt;/sup&gt; century, occurs west of the western limb of the Valongo Anticline, a major ante-Stephanian structure with NW-SE trend. This Sb-Au deposit consist mainly of stibnite-bearing quartz veins hosted by slates, quartzites and conglomerates of the Schist-Greywacke Complex in a possible spatial relationship with dolerite dykes. These mafic dykes are emplaced in sub-parallel shear zones to the sinistral Douro Shear Zone and their presence may suggest the existence of mafic/ultramafic bodies at depth, which contributed to the occurrence of Sb-Au deposits.&lt;/p&gt;&lt;p&gt;This study aims to describe the dolerite dykes present through the region (petrographic composition, weathering, distribution, and dimension) considering a possible contribution for the Sb-Au occurrence. Dolerites are greyish-green colored and are intensely weathered. The samples surface shows a few millimeters of brownish supergenic alteration. The petrographic study highlighted an intense chloritization and saussuritization of plagioclase, whose tabular form and twinning are still preserved. The primary igneous texture is better preserved than the primary mineralogy. The texture is ophitic to sub-ophitic although the interstitial mass of the pyroxene is totally altered. &amp;#160;Chlorites occur as fresh, green-colored patches, sometimes with radiated fibrous textures. Frequent polycrystalline quartz lenses and veins occur, also as consequence of the hydrothermal/metamorphic alteration. The opaques, not yet identified, occur in a great modal percentage, and are frequently associated with titanite. They do not seem to have a special concentration related to quartz veins and lenses. Apatite is a frequent accessory phase and appears to be preferentially associated with opaque minerals.&lt;/p&gt;&lt;p&gt;The knowledge of the petrographic characteristics of these dolerite dykes, associated with geochemical data, can be a great contribution to the understanding of the distribution of Sb mineralization and corroborate the hypothesis of non-outcropping mafic/ultramafic bodies.&lt;/p&gt;&lt;p&gt;&amp;#160;&lt;/p&gt;&lt;p&gt;&lt;strong&gt;Acknowledgment&lt;/strong&gt;&lt;/p&gt;&lt;p&gt;The work was financial supported within the compass of the ERA-MIN/0005/2018&amp;#8212;AUREOLE project, FEDER through operation POCI-01-0145-FEDER-007690 funded by the Programa Operacional Competitividade Internacionaliza&amp;#231;&amp;#227;o&amp;#8212;COMPETE2020 and by National Funds through FCT within the ICT (reference UIDB/04683/2020).&lt;/p&gt;

Adapting phase equilibria modelling to crustal and planetary scale problems

&lt;p&gt;Modern quantitative phase equilibria modelling techniques utilizing internally consistent datasets and activity-composition models have been successfully applied to a number of problems in metamorphic geology from hand sample to outcrop scale. Attesting to this the term &amp;#8220;phase equilibria&amp;#8221; appears in 1&amp;#160;548 articles in the Journal of Metamorphic Geology and one third of those are within the last 10 years. These techniques traditionally proceed either through the manual solution of non-linear equations or by a more automated Gibbs free energy minimization approach. However in order for these techniques to be scaled up to deal with crustal or planetary scale problems a number of hurdles still need to be overcome.&lt;/p&gt;&lt;p&gt;Spatial dimensions in a crustal or planetary model are estimated by grids with modelling conducted on individual cells. This allows processes within cells to effect chemical change to partner cells and thereby approximate open or conditionally open systems. Compositional constraints to the chemical system such as oxygen fugacity are pressure and temperature dependent therefore in order to model a planet wide set of conditions oxygen fugacity buffers are enabled that are dependent on the pressures and temperature of the individual grid cells. Stratigraphic layering is introduced by automating the procedure for setting the initial composition of cells and dependence relations determine the hierarchy of compositional change induced within crustal columns. Phase manipulations such as fluid, melt or crystal addition or extraction are defined by mechanistic parameters that simulate boundary conditions for example melt accumulation thresholds, fluid porosity threshold, rheological lockup conditions etc. Since certain key chemical parameters used in identifying crustal processes such as trace element ratios cannot be traditionally modelled due to their absence from the internally consistent thermodynamic datasets new methods of component approximation are introduced following the methods of trace element partitioning and accessory phase saturation for supersolidus systems.&lt;/p&gt;&lt;p&gt;Finally the increased complexity and number of calculations required to scale up phase equilibria modelling systems to the crustal or planetary scale provides an increased computational challenge therefore new potential strategies are explored for the optimizing of calculation load via parallel processing.&lt;/p&gt;

Eclogite and Garnet Pyroxenite Xenoliths from Kimberlites Emplaced Along the Southern Margin of the Kaapvaal Craton, Southern Africa: Mantle or Lower Crustal Fragments?

Eclogite xenoliths, together with garnet pyroxenites and some mafic garnet granulites, found in kimberlites located along the southern margin of the Kaapvaal craton in southern Africa have been analysed by electron microprobe and mass spectrometry techniques to determine their geochemical characteristics. The majority of eclogites are bimineralic with garnet and omphacitic clinopyroxene in subequal proportions, with rutile as the main accessory phase; a few contain kyanite. Based on K2O in clinopyroxene and Na2O in garnet, the eclogites can be classified as Group II eclogites, and the majority are high-Ca in character. Garnet pyroxenites comprise garnet clinopyroxenites and garnet websterites. Major and trace element concentrations and isotope ratios of reconstituted bulk rock compositions of the eclogites and garnet pyroxenites allow constraints to be placed on depth of origin and likely protolith history. Calculated Fe–Mg exchange equilibration temperatures for the eclogites range from 815 to 1000 °C, at pressures of 1·7 ± 0·4 GPa as determined by REE partitioning, indicating that they were sampled from depths of 50–55 km; i.e. within the lower crust of the Namaqua–Natal Belt. The garnet pyroxenites show slightly lower temperatures (686–835 °C) at similar pressures of equilibration. Initial 143Nd/144Nd and 87Sr/86Sr ratios (calculated to time of kimberlite emplacement) of both lithologies overlap the field for lower crustal samples from the Namaqua–Natal Belt. Further evidence for a crustal origin is found in the similar REE patterns shown by many of the associated garnet granulite xenoliths. Garnet pyroxenites are interpreted to have a similar origin as the associated eclogites but with the mafic protolith having insufficient Na (i.e. low modal plagioclase) to allow for development of omphacitic pyroxene. Metamorphism of the mafic protoliths to these eclogites and garnet pyroxenites is inferred to have occurred during crustal shortening and thickening associated with the collision of the Namaqua–Natal Belt with the Kaapvaal craton at 1–1·2 Ga.

Trace Elements in Magnetite from the Pagoni Rachi Porphyry Prospect, NE Greece: Implications for Ore Genesis and Exploration

Magnetite is a common accessory phase in various types of ore deposits. Its trace element content has proven to have critical implications regarding petrogenesis and as guides in the exploration for ore deposits in general. In this study we use LA-ICP-MS (laser ablation-inductively coupled plasma-mass spectrometry) analyses of trace elements to chemically characterize magnetite from the Pagoni Rachi Cu–Mo–Re–Au porphyry-style prospect, Thrace, northern Greece. Igneous magnetite mostly occurs as euhedral grains, which are commonly replaced by hematite in fresh to propylitic-altered granodiorite porphyry, whereas, hydrothermal magnetite forms narrow veinlets or is disseminated in sodic/potassic-calcic altered (albite + K-feldspar + actinolite + biotite + chlorite) granodiorite porphyry. Magnetite is commonly associated with chalcopyrite and pyrite and locally exhibits martitization. Laser ablation ICP-MS analyses of hydrothermal magnetite yielded elevated concentrations in several trace elements (e.g., V, Pb, W, Mo, Ta, Zn, Cu, and Nb) whereas Ti, Cr, Ni, and Sn display higher concentration in its magmatic counterpart. A noteworthy enrichment in Mo, Pb, and Zn is an unusual feature of hydrothermal magnetite from Pagoni Rachi. High Si, Al, and Ca values in a few analyses of hydrothermal magnetite imply the presence of submicroscopic or nano-inclusions (e.g., chlorite, and titanite). The trace element patterns of the hydrothermal magnetite and especially the decrease in its Ti content reflect an evolution from the magmatic towards the hydrothermal conditions under decreasing temperatures, which is consistent with findings from analogous porphyry-style deposits elsewhere.

Constraining the timing and character of crustal melting in the Adirondack Mountains using multi-scale compositional mapping and in-situ monazite geochronology

Migmatites are common in the hinterland of orogenic belts. The timing and mechanism (in situ vs. external, P-T conditions, reactions, etc.) of melting are important for understanding crustal rheology, tectonic history, and orogenic processes. The Adirondack Highlands has been used as an analog for mid/deep crustal continental collisional tectonism. Migmatites are abundant, and previous workers have interpreted melting during several different events, but questions remain about the timing, tectonic setting, and even the number of melting events. We use multiscale compositional mapping combined with in situ geochronology and geochemistry of monazite to constrain the nature, timing, and character of melting reaction(s) in one locality from the eastern Adirondack Highlands. Three gray migmatitic gneisses, studied here, come from close proximity and are very similar in microscopic and macroscopic (outcrop) appearance. Each of the rocks is interpreted to have undergone biotite dehydration melting (i.e., Bt + Pl + Als + Qz = Grt + Kfs + melt). Full-section compositional maps show the location of reactants and products of the melting reaction, especially prograde and retrograde biotite, peritectic K-feldspar, and leucosome, in addition to all monazite and zircon in context. In addition, the maps provide constraints on kinematics during melting and a context for interpretation of accessory phase composition and geochronology. More so than zircon, monazite serves as a monitor of melting and melt loss. The growth of garnet during melting leaves monazite depleted in Y and HREEs while melt loss from the system leaves monazite depleted in U. Results show that in all three localities, partial melting occurred during at ca. 1160–1150 Ma (Shawinigan orogeny), but the samples show high variability in the location and degree of removal of the melt phase, from near complete to segregated into layers to dispersed. All three localities experienced a second high-T event at ca. 1050 Ma, but only the third (non-segregated) sample experienced further melting. Thus, in addition to bulk composition, the fertility for melting is an important function of the previous history and the degree of mobility of earlier melt and fluids. Monazite is also a sensitive monitor of retrogression; garnet breakdown leads to increased Y and HREE in monazite. Results here suggest that all three samples remained at depth between the two melting events but were rapidly exhumed after the second event.