Determination of Mercury, Methylmercury and Selenium Concentrations in Elasmobranch Meat: Fish Consumption Safety

This study measures total mercury (THg), methylmercury (MeHg) and selenium (Se) concentrations in elasmobranch fish from an Italian market with the aim of evaluating the risk-benefit associated with their consumption, using estimated weekly intake (EWI), permissible safety level (MeHgPSL), selenium health benefit value (HBVSe) and monthly consumption rate limit (CRmm) for each species. THg and Se were analysed by atomic absorption spectrometry, while MeHg was determined by HrGc/Ms. THg and MeHg concentrations ranged from 0.61 to 1.25 μg g−1 w.w. and from 0.57 to 0.97 μg g−1 w.w., respectively, whereas Se levels were 0.49–0.65 μg g−1 w.w. In most samples European Community limits for THg were surpassed, while for MeHg none of the fish had levels above the limit adopted by FAO/WHO. EWIs for THg and MeHg in many cases were above the provisional tolerable weekly intakes (PTWIs). MeHgPSL estimate showed that fish should contain approximately 50% of the concentration measured to avoid exceeding the PTWI. Nevertheless, the HBVSe index indicated that solely skates were safe for human consumption (HBVSe = 3.57–6.22). Our results highlight the importance of a constant monitoring of THg and MeHg level in fish, especially in apex predators, to avoid the risk of overexposure for consumers.

Assessment of Hydrogen and LNG buses adoption as sustainable alternatives to diesel fuel buses in public transportation: Applications to Italian perspective

This work deals with a technical and economical comparison between hydrogen and liquid natural gas (LNG) fueled buses with reference to the standard solution based on diesel fuel internal combustion engines. The level of service is evaluated considering the number of buses replaced and the average kilometers traveled each year for two levels. The economical comparison is made using the Total Cost of Ownership (TCO) method considering capital and operating costs. The costs of LNG and Diesel (at the pump in Italian market) are estimated with reference to the year 2020. Furthermore, an assessment of greenhouse gas emissions will be carried out starting from energy needs, adopting a “cradle to grave” approach, thus evaluating emissions from the well to the tank and from the tank to the wheel. The results show that the operating costs (0.778 €/km) of LNG solution are lower than the Diesel ones (1.072 €/km), while the hydrogen buses can become competitive in the next few .The production of hydrogen with water electrolysis considering the current electricity costs of the Italian market is expensive and involves a cost to the hydrogen pump 7,60 €/kg which makes the operating cost of the hydrogen solution is equal to about 1.420 €/km which makes this solution uncompetitive. It is also important to underline that the cost of green hydrogen production from water electrolysis strongly depends on the cost of electricity. The Life Cicle Analisis (LCA) analysis shows strong environmental benefits of the hydrogen solution in terms of CO2eq if the hydrogen is produced by electrolysis using renewable energy sources. In the other cases, the advantage of using hydrogen is not very strong as it is associated with the use of fossil fuels that release climate-altering substances.

Release of Heavy Metals from Plastic Statuettes Used as Souvenirs and/or Toys Handled by Children

Different plastic toys are on sale in the Italian market: they are sold as souvenirs and/or as toys. Such statuettes, called Gongoli, represent a famous character (a soccer player, a politician, the Pope, etc.). In particular, these products are widely sold, but the material composition is not sufficiently defined. Further, the effect of the release of dangerous compounds on human health is not sufficiently documented. Following this hypothesis, a study on eight different statuettes was carried out both for evaluating the possible presence of heavy metals and for evidencing their release from these objects. Preliminary analysis by means of EDS spectroscopy highlighted the percentage chemical composition of different products, especially the presence of total Cr and Ni. Release tests evidenced the release of Cr, Cu, Ni, and Pb: Pb reached 74 mg kg−1, which is an interesting value even if it is lower than reported in the legislation. This study should be considered preliminary due to its limitations, such as the number of items investigated and the large variability found for some elements, but it highlights a serious problem related to the classification of these products which are marketed as souvenirs but manipulated by children.

Hazard Identification Related to the Presence of Vibrio spp., Biogenic Amines, and Indole-Producing Bacteria in a Non-Filter Feeding Marine Gastropod (Tritia mutabilis) Commercialized on the Italian Market

Tritia mutabilis is a carrion-feeder edible marine gastropod with an open circulatory system. Therefore, biological, and chemical contaminants associated with the feed can reach all body tissues. The aim of the present study was to investigate the possible association of these characteristics with some food safety hazards. Vibrio spp. load, and the prevalence of pathogenic V. parahaemolyticus, V. vulnificus, and V. cholerae, were investigated. Moreover, biogenic amines (BAs) and indole-producing bacteria (IPB), markers of seafood decomposition, were quantified for the first time in an edible carrion-feeder. Overall, 49 batches were analyzed (38 from retail, and 11 from primary production). The Vibrio spp. load resulted of 5.64 ± 0.69 log10 CFU g−1 at retail, and 5.27 ± 0.74 at harvest but all batches resulted negative for pathogenic Vibrio. Histamine, putrescine, cadaverine, and tyramine were detected both at harvest and at the retail level. Their sum (BAs Index) showed a mean value of 50.45 and 65.83 mg Kg−1 in batches at harvest and at retail, respectively. IPB were detected at harvest and upon refrigeration for three days (T1–T3). The mean load resulted in 2.52 ± 0.85 log10 MPN g−1 at T0, 3.31 ± 1.23 at T3 in batches immediately refrigerated, and 3.22 ± 1.18 at T3 in batches previously immersed in clean seawater. Our results contribute to identifying food-borne hazards for T. mutabilis that may be related to the retention of biogenic amines and indole-producing bacteria due to carrion feeding.

Market Segmentation and Dynamic Analysis of Sparkling Wine Purchases in Italy

The Italian market of sparkling wines increases as volume and assortment (such as brands, appellations, typologies) mainly because of sparkling Prosecco consumption. We investigate the repeated purchase behavior of sparkling wines in two years within the supermarket channel through scanner data collected from a consumer panel. We propose a Hidden Markov Model to analyze these data, assuming an unobservable process to capture consumers’ preferences and allowing us to consider purchases sparsity over time. We consider multivariate responses defining types of purchases, namely price, appellation, and sugar content. Customers’ covariates influence the initial and transition probabilities of the latent process. We identify five market segments, and we track their evolution over time. One segment includes Prosecco-oriented consumers, and we show that loyalty to Prosecco changes strongly over time according to the region of residence, income, and family type. The findings improve the understanding of the market and may provide evidence to design successful marketing strategies. (JEL Classifications: C33, C51, D12, L66)

Design and Manufacturing of Adaptive Facades in a Life Cycle Approach: A Survey on Challenges and Solutions in the Italian Building Industry

The market of Adaptive Building Skins has been growing at a slow but incremental speed, as these technologies ensure better indoor climatic comfort and more efficient energy management than traditional solutions. Nonetheless, if we acknowledge the building as a system of physical qualities oriented to overall environmental performance, the resource optimization has to be extended to considering a wider range of environmental impacts along the entire building life cycle. For this purpose, the Life Cycle Assessment (LCA) method is recognized by stakeholders as the most world-renowned standardized tool for weighting environmental impacts. The aim of this study is to scrutinize the state of the art of LCA among stakeholders enrolled in the design and manufacturing of building and adaptive facades in the Italian market. Data have been collected throughout interviews and an online survey focusing on investigating the knowledge and experience level of participants. Results not only draw the attention to develop new market models by implementing sustainable building protocols concerning adaptive technologies, but also provided a positive assessment on the usability degree of a parametric design mapping based on a systemic and life-cycle-oriented approach to achieve environmental scopes and introduce competitive factors and boost innovation in the Italian building industry.