Optical lattice with spin-dependent sub-wavelength barriers

We analyze a tripod atom light coupling scheme characterized by two dark states playing the role of quasi-spin states. It is demonstrated that by properly configuring the coupling laser fields, one can create a lattice with spin-dependent sub-wavelength barriers. This allows to flexibly alter the atomic motion ranging from atomic dynamics in the effective brick-wall type lattice to free motion of atoms in one dark state and a tight binding lattice with a twice smaller periodicity for atoms in the other dark state. Between the two regimes, the spectrum undergoes significant changes controlled by the laser fields. The tripod lattice can be produced using current experimental techniques. The use of the tripod scheme to create a lattice of degenerate dark states opens new possibilities for spin ordering and symmetry breaking.

Ultrafast signatures of spin and orbital order in antiferromagnetic α-Sr2CrO4

We used femtosecond optical spectroscopy to study ultrafast spin and orbital ordering dynamics in the antiferromagnetic Mott insulator α-Sr2CrO4. This chromate system possesses multiple spin and orbital ordered phases, and therefore could enable us to study the unique interplay between these collective phases through their non-equilibrium response to photoexcitation. Here, by varying the pump photon energy, we selectively drove inter-site spin hopping between neighboring Cr t2g orbitals and charge transfer-type transitions between oxygen 2p and Cr eg orbitals. The resulting transient reflectivity dynamics revealed temperature-dependent anomalies across the Neel temperature for spin ordering as well as the transition temperatures linked to different types of orbital order. Our results reveal distinct relaxation timescales for spin and orbital orders in α-Sr2CrO4 and provide experimental evidence for the phase transition at TO, possibly related to antiferro-type orbital ordering.

Spin pinning effect to reconstructed oxyhydroxide layer on ferromagnetic oxides for enhanced water oxidation

Producing hydrogen by water electrolysis suffers from the kinetic barriers in the oxygen evolution reaction (OER) that limits the overall efficiency. With spin-dependent kinetics in OER, to manipulate the spin ordering of ferromagnetic OER catalysts (e.g., by magnetization) can reduce the kinetic barrier. However, most active OER catalysts are not ferromagnetic, which makes the spin manipulation challenging. In this work, we report a strategy with spin pinning effect to make the spins in paramagnetic oxyhydroxides more aligned for higher intrinsic OER activity. The spin pinning effect is established in oxideFM/oxyhydroxide interface which is realized by a controlled surface reconstruction of ferromagnetic oxides. Under spin pinning, simple magnetization further increases the spin alignment and thus the OER activity, which validates the spin effect in rate-limiting OER step. The spin polarization in OER highly relies on oxyl radicals (O∙) created by 1st dehydrogenation to reduce the barrier for subsequent O-O coupling.

Spin-singlet to triplet Cooper pair converter interface

Combining magnetic and superconducting functionalities enables lower energy spin transfer and magnetic switching in quantum computing and information storage, owing to the dissipationless nature of quasi-particle mediated supercurrents. Here, we put forward a system where emergent spin-ordering and diffusion of Cooper pairs are achieved at a non-intrinsically magnetic nor superconducting metallo-molecular interface. Electron transport, magnetometry and low-energy muon spin rotation are used to probe time-reversal symmetry breaking in these structures. By comparing the Meissner expulsion in a system including a Cu/C60 spin-converter interface to one without, we observe a paramagnetic contribution that can be explained due to the conversion of spin-singlet Cooper pair states into odd-frequency triplet states. These results demonstrate the potential of metallo-molecular interfaces to achieve singlet to triplet Cooper pair conversion, a capability not present in either metal or molecule separately that could be used in the generation and controlled diffusion of spin polarised dissipationless currents.

Supercurrent Induced by Chiral Coupling in Multiferroic/Superconductor Nanostructures

We study the transport and the superconducting dynamics in a layer of type II superconductor (SC) with a normal top layer that hosts a helical magnetic ordering that gives rise to spin-current-driven ferroelectric polarization. Proximity effects akin to this heterostructure result in an anisotropic supercurrent transport and modify the dynamic properties of vortices in the SC. The vortices can be acted upon and controlled by electric gating or other means that couple to the spin ordering in the top layer, which, in turn, alter the superconducting/helical magnet coupling characteristics. We demonstrate, using the time dependent Ginzburg–Landau approach, how the spin helicity of the top layer can be utilized for pinning and guiding the vortices in the superconducting layer.

Antiferromagnetic spin ordering in two-dimensional honeycomb lattice of SiP3

Two-dimensional buckled honeycomb lattice of SiP3 shows antiferromagnetic coupling between triangular ferromagnetic domains, arising from the Fermi-instability of itinerant π-electrons.