Local detailed balance

We review the physical meaning and mathematical implementation of the condition of local detailed balance for a class of nonequilibrium mesoscopic processes. A central concept is that of fluctuating entropy flux for which the steady average gives the mean entropy production rate. We repeat how local detailed balance is essentially equivalent to the widely discussed fluctuation relations for that entropy flux and hence is at most ``only half of the story.''

Types of flow in Green-Naghdi Thermoelasticity Theory

In this paper we will show a review of the Green-Naghdi thermoelasticity theory.Such model have beautiful foundations which contains since the law of heat conduction proposed byFourier, fundamentals variables such as Helmholtz free energy, entropy, flux of heat and etc. and the constitutive hypothesis. The nature of partial differential equation of parabolic (PDE) type derived from classical thermoelasticity lead us to a mathematical inconsistency well-know as thermal signal speed paradox. We will show how Green-Naghdi model solved those mathematical inconsistency introducing different types of flow and giving us a hyperbolic PDE.

Constraining the depth of the winds on Uranus and Neptune via Ohmic dissipation

ABSTRACT Determining the depth of atmospheric winds in the outer planets of the Solar system is a key topic in planetary science. We provide constraints on these depths in Uranus and Neptune via the total induced Ohmic dissipation, due to the interaction of the zonal flows and the planetary magnetic fields. An upper bound can be placed on the induced dissipation via energy and entropy flux throughout the interior. The induced Ohmic dissipation is directly linked to the electrical conductivity profile of the materials involved in the flow. We present a method for calculating electrical conductivity profiles of ionically conducting hydrogen–helium–water mixtures under planetary conditions, using results from ab initio simulations. We apply this prescription on several ice giant interior structure models available in the literature, where all the heavy elements are represented by water. According to the energy (entropy) flux budget, the maximum penetration depth for Uranus lies above 0.93 RU (0.90 RU) and for Neptune above 0.95 RN (0.92 RN). These results for the penetration depths are upper bounds and are consistent with previous estimates based on the contribution of the zonal winds to the gravity field. As expected, interior structure models with higher water abundance in the outer regions also have a higher electrical conductivity and therefore reach the Ohmic limit at shallower regions. Thus, our study shows that the likelihood of deep-seated winds on Uranus and Neptune drops significantly with the presence of water in the outer layers.

Fractional-order heat conduction models from generalized Boltzmann transport equation

The relationship between fractional-order heat conduction models and Boltzmann transport equations (BTEs) lacks a detailed investigation. In this paper, the continuity, constitutive and governing equations of heat conduction are derived based on fractional-order phonon BTEs. The underlying microscopic regimes of the generalized Cattaneo equation are thereafter presented. The effective thermal conductivity κ eff converges in the subdiffusive regime and diverges in the superdiffusive regime. A connection between the divergence and mean-square displacement 〈|Δ x | 2 〉 ∼ t γ is established, namely, κ eff ∼ t γ −1 , which coincides with the linear response theory. Entropic concepts, including the entropy density, entropy flux and entropy production rate, are studied likewise. Two non-trivial behaviours are observed, including the fractional-order expression of entropy flux and initial effects on the entropy production rate. In contrast with the continuous time random walk model, the results involve the non-classical continuity equations and entropic concepts. This article is part of the theme issue ‘Advanced materials modelling via fractional calculus: challenges and perspectives’.

Covariant Relativistic Non-Equilibrium Thermodynamics of Multi-Component Systems

Non-equilibrium and equilibrium thermodynamics of an interacting component in a relativistic multi-component system is discussed covariantly by exploiting an entropy identity. The special case of the corresponding free component is considered. Equilibrium conditions and especially the multi-component Killing relation of the 4-temperature are discussed. Two axioms characterize the mixture: additivity of the energy momentum tensors and additivity of the 4-entropies of the components generating those of the mixture. The resulting quantities of a single component and of the mixture as a whole, energy, energy flux, momentum flux, stress tensor, entropy, entropy flux, supply and production are derived. Finally, a general relativistic 2-component mixture is discussed with respect to their gravitation generating energy–momentum tensors.

On Entropic Framework Based on Standard and Fractional Phonon Boltzmann Transport Equations

Generalized expressions of the entropy and related concepts in non-Fourier heat conduction have attracted increasing attention in recent years. Based on standard and fractional phonon Boltzmann transport equations (BTEs), we study entropic functionals including entropy density, entropy flux and entropy production rate. Using the relaxation time approximation and power series expansion, macroscopic approximations are derived for these entropic concepts. For the standard BTE, our results can recover the entropic frameworks of classical irreversible thermodynamics (CIT) and extended irreversible thermodynamics (EIT) as if there exists a well-defined effective thermal conductivity. For the fractional BTEs corresponding to the generalized Cattaneo equation (GCE) class, the entropy flux and entropy production rate will deviate from the forms in CIT and EIT. In these cases, the entropy flux and entropy production rate will contain fractional-order operators, which reflect memory effects.

A Simple Derivation of Tropical Cyclone Ventilation Theory and Its Application to Capped Surface Entropy Fluxes

In a recent study, a theory was presented for the dependence of tropical cyclone intensity on the ventilation of dry air by environmental vertical wind shear. This theory was found to successfully capture the statistics of intensity dynamics in the historical record. This theory is rederived here from a simple three-term power budget and extended to analytical solutions for the complete phase space, including the change in storm intensity itself. The derivation is then generalized to the case of a capped surface entropy flux wind speed, including analytical solutions defined relative to both the traditional potential intensity and the capped-flux potential intensity. The results demonstrate that a cap on the surface entropy flux wind speed reduces the potential intensity of the system and effectively amplifies the detrimental effect of ventilation on the tropical cyclone heat engine. However, such a cap does not alter the qualitative structure of the phase-space solution for intensity change phrased relative to the capped-flux potential intensity. Thus, the wind speed dependence of surface entropy fluxes is important for intensity change in real-world storms, though it is not a necessary condition for intensification in general. Indeed, a residual power surplus may remain available to intensify a storm even in the presence of a cap, though intensification may be fully suppressed for sufficiently strong ventilation. This work complements a recent numerical simulation study and provides further evidence that there is no disconnect between extant tropical cyclone theory and the finding in numerical simulations that a storm may intensify in the presence of capped surface entropy fluxes.