Removal of selected pesticides, alkylphenols, hormones and bisphenol A from domestic wastewater by electrooxidation process

In this study, seven compounds of environmental and health concern were treated by electrooxidation to determine their removal efficiencies from domestic wastewater. A batch type lab-scale reactor was used for the treatment process, and the analytes studied included two obsolete pesticides, two alkylphenols, two hormones, and bisphenol A. Titanium oxide and graphite electrodes were used as anode and cathode, respectively. Parameters of the electrooxidation process including pH of wastewater, ionic strength, applied current and treatment period were optimized by the univariate approach to maximize the removal efficiency of the analytes from wastewater. The optimum conditions were determined as nonadjusted pH of wastewater, 1.5 A current, 15 min treatment period and 5.0 g/L sodium chloride. Dispersive liquid-liquid microextraction was used to preconcentrate analytes before and after treatment in order to calculate the removal efficiency of analytes. The removal efficiency obtained under the optimum conditions was satisfactory for all seven analytes at different influent concentrations.

Legal regulation of utilization non-suitable pesticides accumulated during the USSR

The article provides a scientific and theoretical analysis of the legislation of the USSR, Ukrainian legislation. Particular attention is paid to establishing features in the legal regulation of seizure, utilization, destruction and disposal of unusable or prohibited pesticides and agrochemicals and containers from them. The authors conclude that today, given the need to improve the environment, more efforts are needed at the state level to utilize pesticides accumulated during the Soviet era, primarily to approve the state program with clear measures for its implementation and sources of funding. Today, regional state administrations have the opportunity without the intervention of the Ministry of Environmental Protection and Natural Resources of Ukraine to solve problems with obsolete pesticides and agrochemicals, as well as to determine where it is most profitable to dispose of these substances. Thus, to date, the process of reducing unusable pesticides has been launched. It aims to improve the ecological situation in the country, help reduce the negative impact on people's lives and health, and allow agriculture to develop. Keywords: waste, industrial waste, pesticides, plants protecting products, utilization of pesticides, container, agriculture

The Improving Conditions for the Aerobic Bacteria Performing the Degradation of Obsolete Pesticides in Polluted Soils

Currently, in the territory of Kyrgyzstan, 50 storage facilities of obsolete pesticides exist; they store about 5000 tons of these hazardous chemicals. The storage conditions have become unusable for a long time. They pose a serious threat to the people living there, livestock, and the environment. The main purpose of this research was the use of selected bacteria with cytochrome P450 genes for the bioremediation of polluted soils around the burial sites in model soil experiments. In the first trial of biodegradation experiments, one contaminated soil was used without any changes in chemical contents, and in the second, the physical and chemical contents of the soil were improved to maintain the bioremediation conditions. The soils in both variants were treated 3 times (ie, once a month) with suspensions of a single culture or a blend of active bacteria (1 × 108 cells/mL) selected from in vitro biodegradation experiments. Two control units without the addition of the bacteria culture were also run. The quantification of targeted persistent organic pollutants (POPs) before and after biodegradation was performed by capillary gas chromatography (GC) coupled to a mass spectrometer. In 6 months, obsolete pesticides such as dieldrin, α-endosulfan, β-endosulfan, and 4-heptachlor-epox pure were able to degrade almost completely, up to 98% to 99.0%, by the blend of bacteria and the single culture of bacteria. Endrin aldehyde showed more resistance as the blend of bacteria was able to degrade it to 59.77%. To improve the aerobic degradation for elimination of pesticides from contaminated soils, it is necessary to create optimal agrotechnical and agrochemical conditions.

Perception Practice and Existing Knowledge Level of Farmers towards Agrochemical Use in Sitakunda Upazilla of Bangladesh

Aims: This study aimed to know the knowledge level and perception of the farmers regarding the use and impact of agrochemical and to find out the correlation of knowledge level and pesticide use with their age, education, farm size, number of pesticide use. Place and Duration of Study: The study was carried out in the Chittagong District of Bangladesh in four different unions of Sitakunda Upazilla between May 2018 and June 2018. Methodology: We surveyed 142 farmer households from nine villages of three unions, selected through multistage purposive random sampling. They were interviewed through a semi-structured questionnaire. A key informant survey was done by interviewing Upazila agriculture officers and agrochemical retailers. Results: No overuse of fertilizer and pesticide were found. Findings showed that 66.2% of farmers were medium knowledgeable, with 14.79% low and 19.01% high knowledgeable. Applications of obsolete pesticides were found to be used. Farmers’ knowledge level is significantly correlated with the education level and the number of pesticide uses. Conclusion: There was a gap between amounts of fertilizer applied than the recommended level except for gypsum. Most of them did not know the standard application rate of fertilizer and pesticide. Farmers’ knowledge level should be improved and the adoption of rational use of agrochemicals is needed through extension activity to get proper yield and to inform them of precautionary measures.

A Critical Review of the Status of Pesticide Exposure Management in Malawi

Pesticides pose a significant risk to humans and the environment. This paper analyzes the measures used to manage pesticides in Malawi. Malawi’s regulatory authority of pesticides, the Pesticides Control Board (PCB), faces a number of challenges including lack of facilities for analyzing pesticides and inadequate personnel to conduct risk assessment of pesticides. The PCB needs to provide access to information and opportunities among the public to make contributions regarding requirements, processes and policies for assessing pesticide risk and efficacy. There is also a need to enhance the capacity of PCB to assess pesticide poisoning in workers, monitor pesticide residues in food and environmental contamination, as well as to control the illegal importation and sale of pesticides. Just like in other countries such as South Africa, India and Sri Lanka, Malawi urgently needs to implement measures that can restrict the importation, production, sale and use of very toxic pesticides. Malawi also needs to develop measures for the effective management of pesticide waste containers as well as obsolete pesticides, where potential solutions include reducing the purchase of (unneeded) pesticides, treatment of obsolete pesticides in high-temperature cement kilns, as well as requesting pesticide dealers to adopt life-cycle management of their products.

Phytoremediation and Bioremediation of Pesticide-Contaminated Soil

Management and destruction of obsolete pesticides and the remediation of pesticide-contaminated soil are significant global issues with importance in agriculture, environmental health and quality of life. Pesticide use and management have a history of problems because of insufficient knowledge of proper planning, storage, and use. This manuscript reviews recent literature with an emphasis on the management of obsolete pesticides and remediation of pesticide-contaminated soil. The rhizosphere of plants is a zone of active remediation. Plants also take up contaminated water and remove pesticides from soil. The beneficial effects of growing plants in pesticide-contaminated soil include pesticide transformation by both plant and microbial enzymes. This review addresses recent advances in the remediation of pesticide-contaminated soil with an emphasis on processes that are simple and can be applied widely in any country.