Dynamic magnetic birefringence in a viscoelastic ferrocolloid

A model is developed to describe the oscillations of optical anisotropy induced in a viscoelastic ferrocolloid (nanodispersion of magnetic particles) by an AC magnetic field. The viscoelasticity of the matrix (carrier medium) is assumed to obey the Jeffreys rheological scheme, whose advantage is that with the aid of just two viscous parameters and a single one for elasticity it enables one to vary the retarded mechanical response of the carrier from a weakly Maxwellian fluid to a medium with the rheology of a Kelvin gel. As the orientational motion of the particles driven by the AC field is always strongly affected by thermal motion, the occurring process is described with the aid of a kinetic (Fokker–Planck type) equation that combines diffusional and drift terms. On this basis, an exact evolution equation for the macroscopic optical anisotropy of a ferrocolloid is derived that is, however, just one link in an infinite chain of equations for statistical moments. The solution is obtained by applying effective field approximation: reducing the number of moment equations to their minimum and closing the chosen set. This solution is substituted to the scheme of a standard polarimetric set-up, and it is demonstrated how the peculiarities imparted by viscoelasticity should manifest themselves on the intensity of the light transmitted through the set up containing a ferrocolloid sample. This article is part of the theme issue ‘Transport phenomena in complex systems (part 2)’.

Mechanical, Electrical, and Biological Properties of Mechanochemically Processed Hydroxyapatite Ceramics

The effect of the sintering temperature on densification and the resultant mechanical, electrical, and biological properties of mechanochemically processed hydroxyapatite (HAp) samples was investigated. HAp samples were sintered at 1200, 1250, and 1300 °C for 4 h, respectively. HAp samples sintered at 1250 °C showed better mechanical properties, which was attributed to their smaller grain size compared to HAp samples at higher sintering temperatures. The nearly identical value of the dielectric constant (εr) and better cell proliferation was exhibited by HAp samples sintered at 1250 and 1300 °C, respectively. At ~210 °C, in all the samples sintered at different temperatures, a dielectric anomaly was obtained, which was attributed to the phase transition temperature of the HAp system. Dielectric properties near the phase transition temperature showed a dielectric relaxation-type of behavior, which was attributed to the re-orientational motion of OH− ions in the HAp system. Higher cell proliferation and viability were exhibited by the HAp1300 samples, whereas comparatively equivalent cell growth and higher mechanical strength were observed in the HAp1250 samples.

A low-κ dielectric metal–organic-framework compound showing novel three-step dielectric relaxations originating from orientational motion of dipolar guest molecules

A metal–organic-framework compound shows novel three-step dielectric relaxations arising from reorientational motion of polar guest molecules and its guest-free framework is a low-κ dielectric material.