Potential Usage of Hybrid Polymers Binders Based on Fly Ash with the Addition of PVA with Satisfying Mechanical and Radiological Properties

Since recycled technologies usage is mandatory for environmental safety, and in this regard, it is important to examine new materials that can be used in construction and are primarily produced from fly ash. In addition to characteristics such as hardness and compressive strength, the given materials must also be radiologically and environmentally safe. The main concept of engineered geopolymer gel composites based on fly ash residues is focused on developing binder materials via gel formation processes that can replace ordinary cement materials. This study is unique in researching the potential use of fly ash from the Nikola Tesla thermal power plant in Serbia, where the hybrid geopolymeric materials synthesized from fly ash are experimentally examined with the addition 1 wt% and 2 wt% of polyvinyl alcohol (PVA). This paper aims to investigate the structural, morphological, mechanical, and radiological properties of hybrid materials with the addition of PVA and without additive in the period of ageing for 28 days at room temperature. The phase composition was investigated using X-ray powder diffraction (XRPD) analysis, while morphological characteristics of these materials were examined using scanning electron microscopy and energy dispersive X-ray analysis (SEM-EDS). Vibrational spectra of obtained samples are investigated using diffuse reflectance infrared Fourier transform (DRIFT) and Fourier transform infrared (FTIR) techniques. The hardness and compressive strength are also examined, indicating that the 1 wt% addition in geopolymeric matrix results in the best mechanical properties. Radiological measurements of investigated all geopolymer samples show decreasing activity concentrations of radionuclides for 50% compared to fly ash.

Phosphogypsum and its potential use in Croatia: challenges and opportunities

Phosphogypsum (PG) is a waste by-product (residue) originating from the production of phosphoric acid and phosphate fertilisers. PG contains chemical and radioactive impurities, which is why it is mostly stockpiled in controlled areas. Worldwide, only about 15 % of PG is recycled or reused. Today, policies and business strategies prioritise sustainable development through circular economy, which certainly includes PG. This provides new opportunities for Croatia to manage its PG and make an effort to use it as an additive in different industries, such as agriculture and construction. Due to its chemical and radiological properties, PG can potentially cause problems for the environment and human health. Hence, before using PG, detailed knowledge of potential hazards is necessary to protect people and the environment. The aim of this review is to summarise available data on Croatian PG, compare them with other countries, and to identify knowledge gaps and the lack of data on potential hazardous substances in PG in order to assess the opportunities of using PG in Croatia.

Building of the Al-containing Secondary Raw Materials Registry for the Production of Low CO2 Mineral Binders in South-Eastern European Region

The bottleneck in the process for increasing production of low CO2 mineral binders, based on BCSA (belite sulfoaluminate) clinkers, is the availability of Al-rich raw materials. For that purpose, a new registry of Al-containing secondary mineral residues (industrial and mine waste) has been developed and is presented in this paper. The methodology of creating the registry consists of three main steps: Gathering ideas, consolidation of ideas, and implementation. In order to achieve this, the following methodology was adopted: Analysis of similar registries by potential end-users and seeking potential solutions and tools to be used, and conducting 3 rounds of stakeholder consultations via workshops in order to determine crucial parameters and features the registry needs to contain. The key discussion points were about which data the registry needs to contain, who shall be the potential users, and what are the stakeholder’s expectations from the registry’s portal. Potential individual registry variables were identified as being relevant/irrelevant or available/unavailable, and potential solutions for the registry’s sustainability were explored. Each Al-rich waste/residue data entry is divided into 10 slots, describing legal status, location, quantities, chemical (REE included), mineralogical, physical and radiological properties, life-cycle assessment, additional data, and data relevancy. The registry will act as a matchmaking tool between producers/holders of Al-rich secondary raw materials and potential producers of cement clinkers.

Assessing the impacts of scale residues from offshore oil and gas decommissioning on marine organisms

Successful decommissioning of offshore oil and gas infrastructure requires an effective and safe approach to assessing and managing chemical and radiological residues. Scale frequently accumulates on the interior surfaces of pipes and other structures and may persist long after extraction operations have ceased. Scale materials can contain a range of metal contaminants (including mercury), as well as naturally occurring radioactive materials. In newer or more accessible infrastructure, the scale is routinely removed, and becomes a waste product. The persistent nature of scale contaminants can result in a radiological dose to the organisms living on, or near an intact pipeline. Eventually, infrastructure corrosion following insitu decommissioning (abandonment) could lead to metal and radionuclide contaminants being accessible to the surrounding seafloor environment, where bioaccumulation and subsequent ecotoxicological effects from the chemical and radiological properties of the scale could occur. The paper describes a tiered approach to assess the ecological impacts of pipeline scale in order to assist operators with their plans for decommissioning offshore infrastructure, especially when considering ‘leave in place’ options.

Synthesis, characterization and low energy photon attenuation studies of bone tissue substitutes

Epoxy composites with different weight percentages of calcium carbonate and calcium phosphate were synthesized as bone tissue substitutes (BTS) for internal dosimetry. The Fourier-transform infrared spectroscopy analysis confirmed that no chemical reaction occurred between the polymer and the fillers. Thermogravimetric analysis also showed improvement in the thermal properties of the composites due to the fillers. The uniform distribution of fillers in the epoxy matrix was established by X-ray radiography. The attenuation behavior of BTS was probed for low energy γ source 241Am (59.5 keV) using planar HPGe detector. The measured mass attenuation coefficients of BTS were found to match with the values calculated using XCOM software. The radiological properties derived for these composites were found to be on par with those of ICRU-44 cortical bone and B-100 bone equivalent plastic.